CN105070686B - The preparation method and TFT substrate structure of TFT substrate - Google Patents

The preparation method and TFT substrate structure of TFT substrate Download PDF

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CN105070686B
CN105070686B CN201510514415.5A CN201510514415A CN105070686B CN 105070686 B CN105070686 B CN 105070686B CN 201510514415 A CN201510514415 A CN 201510514415A CN 105070686 B CN105070686 B CN 105070686B
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amorphous silicon
layer
tft substrate
preparation
boron ion
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CN105070686A (en
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张良芬
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TCL China Star Optoelectronics Technology Co Ltd
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Shenzhen China Star Optoelectronics Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/22Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
    • H01L21/2205Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities from the substrate during epitaxy, e.g. autodoping; Preventing or using autodoping

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Thin Film Transistor (AREA)

Abstract

The present invention provides a kind of preparation method and TFT substrate structure of TFT substrate.The preparation method of the TFT substrate of the present invention, during amorphous silicon layer is made, by the way of more one-step film formings, and it is surface-treated after every one-step film forming using hydroboron gas by CVD and boron ion injection is carried out to amorphous silicon membrane, finally give the amorphous silicon layer of boron ion doping, formed after channel region without being individually doped to channel region, be effectively simplified processing procedure, reduce production cost.The TFT substrate structure of the present invention, channel region complete boron ion injection in non-crystalline silicon film forming, and without individually carrying out channel doping processing procedure, making is simple, and production cost is low.

Description

The preparation method and TFT substrate structure of TFT substrate
Technical field
The present invention relates to display technology field, more particularly to a kind of preparation method of TFT substrate and TFT substrate structure.
Background technology
In display technology field, liquid crystal display (Liquid Crystal Display, LCD) and Organic Light Emitting Diode The flat-panel monitors such as display (Organic Light Emitting Diode, OLED) progressively substitute CRT monitor.
Usual liquid crystal display device includes housing, the liquid crystal panel in housing and the backlight module in housing (Backlight module).Wherein, the structure of liquid crystal panel is mainly by a thin-film transistor array base-plate (Thin Film Transistor Array Substrate, TFT Array Substrate), a colored filter substrate (Color Filter, CF) and the liquid crystal layer (Liquid Crystal Layer) that is configured between two substrates formed, its operation principle It is to control the rotation of the liquid crystal molecule of liquid crystal layer by applying driving voltage on two panels glass substrate, by the light of backlight module Line reflects generation picture.
Thin-film transistor array base-plate is that TFT substrate is important component in liquid crystal display.In TFT substrate, In order to adjusting device threshold voltage, it is necessary to carry out channel doping.Generally after grid oxidation film formation, lead in channel region Cross ion embedding technology to enter a small amount of alms giver or acceptor impurity ion implanting, so as to complete channel doping.And it is ion implanted In processing procedure, with ion implantation apparatus realize be ion implanted it is most commonly seen, such as channel region, N-type heavily doped region, N-type lightly doped district and P Type doped region etc. generally uses ion implantation apparatus implanting ions, and when carrying out every one of ion implantation manufacture process, is required to Completed using one of light shield, and required precision of the ion implantation manufacture process to light shield is harsh, while board debugging difficulty be present, take The problems such as long.
The content of the invention
It is an object of the invention to provide a kind of preparation method of TFT substrate, can save channel doping processing procedure, simplifies system Journey, reduce production cost.
The present invention also aims to provide a kind of TFT substrate structure, channel region completed in non-crystalline silicon film forming boron from Son injection, without individually carrying out channel doping processing procedure.
To achieve the above object, the present invention provides a kind of preparation method of TFT substrate, comprises the following steps:
Step 1, substrate is provided, on the substrate buffer layer;
Step 2, an amorphous silicon membrane is deposited on the cushion, and hydroboration is passed through on the amorphous silicon membrane surface Compound gas, the amorphous silicon membrane is surface-treated using the method for chemical vapor deposition so that the non-crystalline silicon is thin The surface doping boron ion of film;
Step 3, repeat step 2 operation for several times, obtain the amorphous silicon membrane of several layer surfaces doping boron ions, described several layers The amorphous silicon membrane superposition of surface doping boron ion forms amorphous silicon layer;
Step 4, the amorphous silicon layer is made annealing treatment, remove the hydrogen ion adulterated in amorphous silicon layer, caused simultaneously The boron ion for being doped to every layer of amorphous silicon membrane surface is uniformly diffused into whole amorphous silicon layer, is realized to whole amorphous silicon layer Boron ion is adulterated;
Step 5, the boron ion is adulterated using twice light shield after amorphous silicon layer carry out ion implanting twice, obtain in place In two N-type heavily doped regions of the amorphous silicon layer both sides, the boron ion doped channel regions in the middle part of the amorphous silicon layer and Two N-type lightly doped districts between described two N-type heavily doped regions and boron ion doped channel regions;
Step 6, gate insulator, grid, interlayer insulating film and source, drain electrode are sequentially formed on the amorphous silicon layer.
The substrate is glass substrate or plastic base.
The cushion is the composite bed of silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer.
Amorphous silicon membrane described in chemical vapor deposition is passed through using silane and hydrogen.
The hydroboron gas is diborane.
The number that repeat step 2 operates in the step 3 is more than or equal to once.
The step 5 is using boiler tube, quasi-molecule laser annealing equipment or chemical vapor deposition heating chamber to the non-crystalline silicon Layer is made annealing treatment.
The interlayer insulating film is the composite bed of silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer.
The present invention also provides a kind of TFT substrate structure, including substrate, the cushion on the substrate, located at described Amorphous silicon layer on cushion, the gate insulator on the amorphous silicon layer, the grid on the gate insulator, Interlayer insulating film and the source electrode on the interlayer insulating film and the leakage of the grid are covered on the gate insulator Pole;
The amorphous silicon layer includes corresponding to the source electrode positioned at the both sides of amorphous silicon layer and two N-types of drain electrode lower section are heavily doped Miscellaneous area, correspond to positioned at the middle part of amorphous silicon layer boron ion doped channel regions below the grid and positioned at described two N-type weights Two N-type lightly doped districts between doped region and boron ion doped channel regions;
The gate insulator corresponds to on interlayer insulating film to be respectively equipped with above described two N-type heavily doped regions Hole, the source electrode are in contact with draining via the via with the N-type heavily doped region.
The cushion is the composite bed of silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer;The interlayer is exhausted Edge layer is the composite bed of silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer.
Beneficial effects of the present invention:The preparation method of TFT substrate provided by the invention, making the process of amorphous silicon layer In, by the way of more one-step film formings, and boron ion is carried out to amorphous silicon membrane using hydroboron gas after every one-step film forming Injection, the amorphous silicon layer of boron ion doping is finally given, formed after raceway groove without being individually doped to raceway groove, be effectively simplified Processing procedure, reduce production cost.The TFT substrate structure of the present invention, channel region complete boron ion injection in non-crystalline silicon film forming, Without individually carrying out channel doping processing procedure, make simply, production cost is low.
Brief description of the drawings
In order to be further understood that the feature of the present invention and technology contents, refer to below in connection with the detailed of the present invention Illustrate and accompanying drawing, however accompanying drawing only provide with reference to and explanation use, be not used for being any limitation as the present invention.
In accompanying drawing,
Fig. 1 is the flow chart of the preparation method of the TFT substrate of the present invention;
Fig. 2 is the schematic diagram of the step 1 of the preparation method of the TFT substrate of the present invention;
Fig. 3-Fig. 4 is the schematic diagram of the step 2 of the preparation method of the TFT substrate of the present invention;
Fig. 5-Fig. 6 is the schematic diagram of the step 3 of the preparation method of the TFT substrate of the present invention;
Fig. 7 is the schematic diagram of the step 4 of the preparation method of the TFT substrate of the present invention;
Fig. 8 is the schematic diagram of the step 5 of the preparation method of the TFT substrate of the present invention;
Fig. 9 is the schematic diagram of step 6 and the cuing open for TFT substrate structure of the present invention of the preparation method of the TFT substrate of the present invention Face schematic diagram.
Embodiment
Further to illustrate the technological means and its effect of the invention taken, below in conjunction with being preferable to carry out for the present invention Example and its accompanying drawing are described in detail.
Referring to Fig. 1, present invention firstly provides a kind of preparation method of TFT substrate, comprise the following steps:
Step 1, as shown in Figure 2, there is provided substrate 1, the buffer layer 2 on the substrate 1.
Specifically, the substrate 1 can be glass substrate or plastic base.
Specifically, the cushion 2 can be silica (SiOx) layer, silicon nitride (SiNx) layer or silicon oxide layer and nitrogen The composite bed of SiClx layer.In this embodiment, the cushion 2 is the composite bed of silicon oxide layer and silicon nitride layer.
Step 2, as shown in figure 3, deposit a non-crystalline silicon (a-Si) film 301 on the cushion 2, as shown in figure 4, The surface of amorphous silicon membrane 301 is passed through hydroboron gas, thin to the non-crystalline silicon using the method for chemical vapor deposition Film 301 is surface-treated so that the surface doping boron ion of the amorphous silicon membrane 301.
Specifically, the amorphous silicon membrane 301 is deposited by chemical vapor deposition (CVD) method using silane and hydrogen.
Specifically, the hydroboron gas is diborane (B2H6) or other hydroborons.
Specifically, the process of the amorphous silicon membrane 301 is deposited with using non-crystalline silicon described in hydroboron gas treatment The process of film 301 can be carried out continuously in same chamber, can also be divided among in two chambers and be carried out.
Step 3, repeat step 2 operation for several times, obtain the amorphous silicon membrane 301 of several layer surfaces doping boron ions, it is described The superposition of amorphous silicon membrane 301 of number layer surface doping boron ion forms amorphous silicon layer 3.
Specifically, the number that repeat step 2 operates in the step 3 is more than or equal to once.
As shown in Fig. 5-Fig. 6, in embodiments of the invention, the step 3 for repeating said steps 2 operation once, i.e. Finally deposited two layers of amorphous silicon membrane 301 on the buffer layer 2, the amorphous silicon layer 3 finally given by two layers of surface adulterate boron from The amorphous silicon membrane 301 of son is formed by stacking.
Step 4, as shown in fig. 7, made annealing treatment to the amorphous silicon layer 3, remove the hydrogen that is adulterated in amorphous silicon layer 3 from Son, while the boron ion for be doped to every layer of surface of amorphous silicon membrane 301 is uniformly diffused into whole amorphous silicon layer 3, is realized The boron ion of whole amorphous silicon layer 3 is adulterated.
Specifically, boiler tube, quasi-molecule laser annealing (ELA) equipment or chemical vapor deposition heating chamber (CVD can be used Heating Chamber) amorphous silicon layer 3 is made annealing treatment.
Step 5, as shown in figure 8, using twice light shield to the boron ion adulterate after amorphous silicon layer 3 carry out two secondary ions Injection, obtain two N-type heavily doped regions 31 positioned at the both sides of amorphous silicon layer 3, positioned at the middle part of the amorphous silicon layer 3 boron from Sub- doped channel regions 33 and two N-type lightly doped districts 32 between described two N-type heavily doped regions 31 and channel region 33.
Because amorphous silicon layer 3 completes the injection of boron ion in film forming, therefore without carrying out ion to channel region 33 again Dopping process.
Step 6, as shown in figure 9, sequentially forming gate insulator 5, grid 6, interlayer insulating film on the amorphous silicon layer 3 7 and source, drain electrode 81,82.The step 6 can use prior art to realize.
Specifically, the interlayer insulating film 7 can be silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer Composite bed.In this embodiment, the interlayer insulating film 7 is the composite bed of silicon oxide layer and silicon nitride layer.
The preparation method of above-mentioned TFT substrate, during amorphous silicon layer is made, by the way of more one-step film formings, and Boron ion injection is carried out to amorphous silicon membrane using hydroboron gas after per one-step film forming, finally gives the non-of boron ion doping Crystal silicon layer, formed after raceway groove without being individually doped to raceway groove, be effectively simplified processing procedure, reduce production cost.
Referring to Fig. 9, the present invention also provides a kind of TFT substrate structure, including substrate 1, the buffering on the substrate 1 Layer 2, the amorphous silicon layer 3 on the cushion 2, the gate insulator 5 on the amorphous silicon layer 3, located at the grid Grid 6 on pole insulating barrier 5, cover on the gate insulator 5 interlayer insulating film 7 of the grid 6 and located at described Source electrode 81 and drain electrode 82 on interlayer insulating film 7.
Specifically, the amorphous silicon layer 3 includes corresponding to the source electrode 81 and the lower section of drain electrode 82 positioned at the both sides of amorphous silicon layer 3 Two N-type heavily doped regions 31, correspond to positioned at the middle part of amorphous silicon layer 3 lower section of the grid 6 boron ion doped channel regions 33, And two N-type lightly doped districts 32 between the N-type heavily doped region 31 and boron ion doped channel regions 33.
The top that the gate insulator 5 corresponds to described two N-type heavily doped regions 31 with interlayer insulating film 7 is respectively equipped with Via 80, the source electrode 81 are in contact via the via 80 with the N-type heavily doped region 31 respectively with drain electrode 82.
Specifically, the boron ion doped channel regions 33 are using the boron ion doping in the preparation method of above-mentioned TFT substrate The preparation method of channel region 33 is prepared.
Specifically, the cushion 2 can be the compound of silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer Layer;The interlayer insulating film 7 can be the composite bed of silicon oxide layer, silicon nitride layer or silicon oxide layer and silicon nitride layer.In the reality Apply in example, the cushion 2, interlayer insulating film 7 are the composite bed of silicon oxide layer and silicon nitride layer.
Above-mentioned TFT substrate structure, channel region completes boron ion injection in non-crystalline silicon film forming, without individually carrying out raceway groove Dopping process, make simply, production cost is low.
In summary, the preparation method of TFT substrate provided by the invention, during amorphous silicon layer is made, using more The mode of one-step film forming, and boron ion injection is carried out to amorphous silicon membrane using hydroboron gas after every one-step film forming, finally The amorphous silicon layer of boron ion doping is obtained, is formed after raceway groove without being individually doped to raceway groove, is effectively simplified processing procedure, reduces Production cost.The TFT substrate structure of the present invention, channel region completes boron ion injection in non-crystalline silicon film forming, without independent Channel doping processing procedure is carried out, is made simply, production cost is low.
It is described above, for the person of ordinary skill of the art, can be with technique according to the invention scheme and technology Other various corresponding changes and deformation are made in design, and all these changes and deformation should all belong to the appended right of the present invention It is required that protection domain.

Claims (10)

1. a kind of preparation method of TFT substrate, it is characterised in that comprise the following steps:
Step 1, provide substrate (1), the buffer layer (2) on the substrate (1);
Step 2, an amorphous silicon membrane (301) is deposited on the cushion (2), and on the amorphous silicon membrane (301) surface Hydroboron gas is passed through, the amorphous silicon membrane (301) is surface-treated using the method for chemical vapor deposition, made Obtain the surface doping boron ion of the amorphous silicon membrane (301);
Step 3, repeat step 2 operation for several times, obtain the amorphous silicon membrane (301) of several layer surfaces doping boron ions, the number Amorphous silicon membrane (301) superposition of layer surface doping boron ion forms amorphous silicon layer (3);
Step 4, the amorphous silicon layer (3) is made annealing treatment, remove the hydrogen ion of doping in amorphous silicon layer (3), make simultaneously The boron ion that every layer of amorphous silicon membrane (301) surface must be doped to uniformly is diffused into whole amorphous silicon layer (3), is realized to whole The boron ion doping of amorphous silicon layer (3);
Step 5, the boron ion is adulterated using twice light shield after amorphous silicon layer (3) carry out ion implanting twice, obtain in place Two N-type heavily doped regions (31) in the amorphous silicon layer (3) both sides, the boron ion in the middle part of the amorphous silicon layer (3) are mixed Miscellaneous channel region (33) and two N-types between described two N-type heavily doped regions (31) and boron ion doped channel regions (33) Lightly doped district (32);
Step 6, sequentially form on the amorphous silicon layer (3) gate insulator (5), grid (6), interlayer insulating film (7) and Source, drain electrode (81,82).
2. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that the substrate (1) is glass substrate or modeling Expect substrate.
3. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that the cushion (2) be silicon oxide layer, The composite bed of silicon nitride layer or silicon oxide layer and silicon nitride layer.
4. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that chemical gas is passed through using silane and hydrogen Amorphous silicon membrane (301) described in phase deposition method.
5. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that the hydroboron gas is second boron Alkane.
6. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that repeat step 2 operates in the step 3 Number be more than or equal to once.
7. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that the step 5 is using boiler tube, quasi-molecule Laser annealing apparatus or chemical vapor deposition heating chamber make annealing treatment to the amorphous silicon layer (3).
8. the preparation method of TFT substrate as claimed in claim 1, it is characterised in that the interlayer insulating film (7) is silica Layer, silicon nitride layer or the composite bed of silicon oxide layer and silicon nitride layer.
A kind of 9. TFT substrate structure made by preparation method of TFT substrate according to claim 1, it is characterised in that Cushion (2) including substrate (1), on the substrate (1), the amorphous silicon layer (3) on the cushion (2), set In the gate insulator (5) on the amorphous silicon layer (3), the grid (6) on the gate insulator (5), located at described The interlayer insulating film (7) of the grid (6) and the source electrode on the interlayer insulating film (7) are covered on gate insulator (5) (81) with draining (82);
The amorphous silicon layer (3) includes corresponding to below the source electrode (81) and drain electrode (82) positioned at the both sides of amorphous silicon layer (3) Two N-type heavily doped regions (31), positioned at the middle part of amorphous silicon layer (3) correspond to the boron ion doped channel below the grid (6) Area (33) and two N-types between described two N-type heavily doped regions (31) and boron ion doped channel regions (33) are lightly doped Area (32);
The top that the gate insulator (5) corresponds to described two N-type heavily doped regions (31) with interlayer insulating film (7) is set respectively There is via (80), the source electrode (81) is with drain electrode (82) respectively via the via (80) and N-type heavily doped region (31) phase Contact.
10. TFT substrate structure as claimed in claim 9, it is characterised in that the cushion (2) is silicon oxide layer, silicon nitride Layer or the composite bed of silicon oxide layer and silicon nitride layer;The interlayer insulating film (7) is silicon oxide layer, silicon nitride layer or silica The composite bed of layer and silicon nitride layer.
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CN106601595B (en) * 2016-12-30 2019-11-26 武汉华星光电技术有限公司 A kind of preparation method of semiconductor, semiconductor, display panel and display device
CN108198754B (en) * 2017-12-04 2021-01-29 武汉华星光电半导体显示技术有限公司 Manufacturing method of polycrystalline silicon TFT substrate and polycrystalline silicon TFT substrate
CN109920796B (en) * 2017-12-13 2021-06-15 湘潭宏大真空技术股份有限公司 Film coating method of TFT substrate
TWI783583B (en) * 2020-07-21 2022-11-11 美商應用材料股份有限公司 Ion implantation for reduced hydrogen incorporation in amorphous silicon

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