CN105054217A - 一种食品用复配防腐剂 - Google Patents
一种食品用复配防腐剂 Download PDFInfo
- Publication number
- CN105054217A CN105054217A CN201510539880.4A CN201510539880A CN105054217A CN 105054217 A CN105054217 A CN 105054217A CN 201510539880 A CN201510539880 A CN 201510539880A CN 105054217 A CN105054217 A CN 105054217A
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- CN
- China
- Prior art keywords
- sodium acetate
- food
- antiseptic agent
- days
- nisin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title abstract description 8
- 235000019249 food preservative Nutrition 0.000 title abstract description 8
- 239000005452 food preservative Substances 0.000 title abstract description 8
- 235000013305 food Nutrition 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 24
- -1 sucrose fatty acid ester Chemical class 0.000 claims abstract description 21
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims abstract description 20
- NVNLLIYOARQCIX-MSHCCFNRSA-N Nisin Chemical compound N1C(=O)[C@@H](CC(C)C)NC(=O)C(=C)NC(=O)[C@@H]([C@H](C)CC)NC(=O)[C@@H](NC(=O)C(=C/C)/NC(=O)[C@H](N)[C@H](C)CC)CSC[C@@H]1C(=O)N[C@@H]1C(=O)N2CCC[C@@H]2C(=O)NCC(=O)N[C@@H](C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(NCC(=O)N[C@H](C)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CCSC)C(=O)NCC(=O)N[C@H](CS[C@@H]2C)C(=O)N[C@H](CC(N)=O)C(=O)N[C@H](CCSC)C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(N[C@H](C)C(=O)N[C@@H]3C(=O)N[C@@H](C(N[C@H](CC=4NC=NC=4)C(=O)N[C@H](CS[C@@H]3C)C(=O)N[C@H](CO)C(=O)N[C@H]([C@H](C)CC)C(=O)N[C@H](CC=3NC=NC=3)C(=O)N[C@H](C(C)C)C(=O)NC(=C)C(=O)N[C@H](CCCCN)C(O)=O)=O)CS[C@@H]2C)=O)=O)CS[C@@H]1C NVNLLIYOARQCIX-MSHCCFNRSA-N 0.000 claims abstract description 20
- 108010053775 Nisin Proteins 0.000 claims abstract description 20
- 235000010297 nisin Nutrition 0.000 claims abstract description 20
- 239000004309 nisin Substances 0.000 claims abstract description 20
- 235000010241 potassium sorbate Nutrition 0.000 claims abstract description 20
- 239000004302 potassium sorbate Substances 0.000 claims abstract description 20
- 229940069338 potassium sorbate Drugs 0.000 claims abstract description 20
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 claims abstract description 15
- 239000000194 fatty acid Substances 0.000 claims abstract description 15
- 229930006000 Sucrose Natural products 0.000 claims abstract description 8
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 8
- 239000004310 lactic acid Substances 0.000 claims abstract description 8
- 239000005720 sucrose Substances 0.000 claims abstract description 8
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000004599 antimicrobial Substances 0.000 claims description 45
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 23
- 239000001632 sodium acetate Substances 0.000 claims description 23
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000000600 sorbitol Substances 0.000 claims description 6
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 4
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 4
- BDKLKNJTMLIAFE-UHFFFAOYSA-N 2-(3-fluorophenyl)-1,3-oxazole-4-carbaldehyde Chemical compound FC1=CC=CC(C=2OC=C(C=O)N=2)=C1 BDKLKNJTMLIAFE-UHFFFAOYSA-N 0.000 abstract 1
- 229920001214 Polysorbate 60 Polymers 0.000 abstract 1
- 239000004288 Sodium dehydroacetate Substances 0.000 abstract 1
- 230000000813 microbial effect Effects 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 230000035755 proliferation Effects 0.000 abstract 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 abstract 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 abstract 1
- 229940079839 sodium dehydroacetate Drugs 0.000 abstract 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 abstract 1
- 230000005856 abnormality Effects 0.000 description 32
- 241000894006 Bacteria Species 0.000 description 25
- 230000000052 comparative effect Effects 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000002994 raw material Substances 0.000 description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 235000008429 bread Nutrition 0.000 description 5
- 206010016766 flatulence Diseases 0.000 description 4
- 235000013622 meat product Nutrition 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 235000013351 cheese Nutrition 0.000 description 3
- 235000010199 sorbic acid Nutrition 0.000 description 3
- 239000004334 sorbic acid Substances 0.000 description 3
- 229940075582 sorbic acid Drugs 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 239000002207 metabolite Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 238000009461 vacuum packaging Methods 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- 244000057717 Streptococcus lactis Species 0.000 description 1
- 235000014897 Streptococcus lactis Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010331 calcium propionate Nutrition 0.000 description 1
- 239000004330 calcium propionate Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000019990 fruit wine Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 235000015094 jam Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- WSWCOQWTEOXDQX-MQQKCMAXSA-N sorbic acid group Chemical group C(\C=C\C=C\C)(=O)O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | 对比例1 | 对比例2 | 对比例3 | |
山梨酸钾 | 3 | 1 | 6 | 7 | 4 | 6 | 2 | 8 | \ | 6 | 6 |
脱氢乙酸钠 | 2 | 4 | 1.5 | 1 | 2 | 1.5 | 3 | 0.5 | 2 | \ | 1.5 |
乳酸链球菌素 | 0.4 | 0.1 | 0.1 | 0.1 | 0.1 | 0.2 | 0.2 | 0.05 | 0.2 | 0.2 | \ |
乙酸钠 | 5 | 5 | 5 | \ | 5 | \ | 5 | 2 | 5 | \ | 5 |
EDTA-2Na | 0.03 | \ | \ | 0.03 | 0.075 | \ | 0.03 | 0.04 | 0.3 | \ | 0.03 |
乳酸 | 20 | 1 | 15 | 10 | 0.1 | 20 | 10 | 15 | 5 | 5 | 5 |
蔗糖脂肪酸脂 | 8 | 5 | 5 | 4 | 0.1 | 8 | 5 | 4 | 3 | 5 | 5 |
聚氧乙烯山梨醇酐单硬脂肪酸脂 | 2 | 2 | 3 | 5 | 0.1 | \ | 3 | 3 | 5 | 5 | 5 |
水 | 59.57 | 81.9 | 64.4 | 67.87 | 88.525 | 64.3 | 71.77 | 67.41 | 79.5 | 78.8 | 72.47 |
半固体复合调味料 | 果酱 | 面包 | 肉类样品 | |
实施例1 | 150天未见异常 | 150天未见异常 | 150天未见异常 | 150天未见异常 |
实施例2 | 140天未见异常 | 140天未见异常 | 140天未见异常 | 140天未见异常 |
实施例3 | 150天未见异常 | 150天未见异常 | 150天未见异常 | 150天未见异常 |
实施例4 | 150天未见异常 | 150天未见异常 | 150天未见异常 | 150天未见异常 |
实施例5 | 150天未见异常 | 150天未见异常 | 150天未见异常 | 150天未见异常 |
实施例6 | 150天未见异常 | 150天未见异常 | 150天未见异常 | 150天未见异常 |
实施例7 | 130天未见异常 | 130天未见异常 | 135天未见异常 | 130天未见异常 |
实施例8 | 135天未见异常 | 135天未见异常 | 136天未见异常 | 135天未见异常 |
对比例1 | 85天后可见斑菌 | 90天后可见斑菌 | 80天后可见斑菌 | 70天后可见斑菌 |
对比例2 | 93天后可见斑菌 | 105天后可见斑菌 | 82天后可见斑菌 | 96天后可见斑菌 |
对比例3 | 118天后可见斑菌 | 112天后可见斑菌 | 110天后可见斑菌 | 120天后可见斑菌 |
山梨酸钾 | 55天后可见斑菌 | 46天后可见斑菌 | 43天后可见斑菌 | 45天后可见斑菌 |
脱氢乙酸钠 | 42天后可见斑菌 | 32天后可见斑菌 | 36天后可见斑菌 | 31天后可见斑菌 |
乳酸链球菌素 | 26天后可见斑菌 | 20天后可见斑菌 | 18天后可见斑菌 | 13天后可见斑菌 |
Claims (6)
Priority Applications (1)
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CN201510539880.4A CN105054217A (zh) | 2015-08-28 | 2015-08-28 | 一种食品用复配防腐剂 |
Applications Claiming Priority (1)
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CN201510539880.4A CN105054217A (zh) | 2015-08-28 | 2015-08-28 | 一种食品用复配防腐剂 |
Publications (1)
Publication Number | Publication Date |
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CN105054217A true CN105054217A (zh) | 2015-11-18 |
Family
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106261464A (zh) * | 2016-08-17 | 2017-01-04 | 安泰生物工程股份有限公司 | 一种扩大乳酸链球菌素杀菌范围和提高杀菌能力的配方 |
CN107319248A (zh) * | 2017-08-02 | 2017-11-07 | 太仓市荣德生物技术研究所 | 一种应用范围广的生物防腐剂 |
CN109566730A (zh) * | 2019-01-21 | 2019-04-05 | 山东元泰生物工程有限公司 | 一种防腐剂及其制备方法以及应用 |
CN111632119A (zh) * | 2020-06-10 | 2020-09-08 | 山东维赫生物科技有限公司 | 一种复方抑菌薄荷乳膏及其制备方法 |
CN112971000A (zh) * | 2021-02-05 | 2021-06-18 | 河南欧禾生物科技有限公司 | 一种植物提取复配液体食品防腐保鲜剂 |
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US20050191393A1 (en) * | 2004-02-27 | 2005-09-01 | James Postma | Food grade natural/organic method for treating food |
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CN101014255A (zh) * | 2004-05-05 | 2007-08-08 | 丹尼斯科有限公司 | 抗微生物组合物 |
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CN101720969A (zh) * | 2009-11-13 | 2010-06-09 | 合肥工业大学 | 用于水果、面制品和豆制品的复合保鲜剂 |
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US20050191393A1 (en) * | 2004-02-27 | 2005-09-01 | James Postma | Food grade natural/organic method for treating food |
CN101014255A (zh) * | 2004-05-05 | 2007-08-08 | 丹尼斯科有限公司 | 抗微生物组合物 |
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CN111632119A (zh) * | 2020-06-10 | 2020-09-08 | 山东维赫生物科技有限公司 | 一种复方抑菌薄荷乳膏及其制备方法 |
CN112971000A (zh) * | 2021-02-05 | 2021-06-18 | 河南欧禾生物科技有限公司 | 一种植物提取复配液体食品防腐保鲜剂 |
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