CN105040474A - Antibacterial rotary screen printing coating - Google Patents
Antibacterial rotary screen printing coating Download PDFInfo
- Publication number
- CN105040474A CN105040474A CN201510432846.7A CN201510432846A CN105040474A CN 105040474 A CN105040474 A CN 105040474A CN 201510432846 A CN201510432846 A CN 201510432846A CN 105040474 A CN105040474 A CN 105040474A
- Authority
- CN
- China
- Prior art keywords
- antibacterial
- printing coating
- solution
- pigment
- scream printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses an antibacterial rotary screen printing coating. The antibacterial rotary screen printing coating comprises plant pigment, a thickening agent, a bonding agent, a wetting agent, pearl powder, a bactericide and water, and comprises, by weight, 100-300 g of the plant pigment, 10-20 g of the thickening agent, 50-300 g of the bonding agent, 10-30 g of the wetting agent, 5-20 g of the bactericide and 100-300 g of the pearl powder in per liter of water. The antibacterial rotary screen printing coating has the main advantages that nano-silver is adopted as the bactericide, so that the antibacterial effect can be achieved efficiently, the pigment is not likely to be corroded by bacteria, and colors can last for a longer time on a fabric; the nano-silver solution obtained through a simple method is provided, so that the coating with the antibacterial effect can be produced by a factory conveniently; the pigment is environmentally friendly and healthy, no formaldehyde is released, and the plant pigment extraction method is simple, practical and suitable for industrial production.
Description
Technical field
The present invention relates to a kind of coating of textile cloth, especially relate to a kind of antibacterial ROTARY SCREAM PRINTING coating.
Background technology
At present at field of industrial production, ROTARY SCREAM PRINTING is the fastest printing method of speed of production.Its operation principle adopts scraper to utilize pressure to shift onto on cloth the pigment in cylinder, and the shape of pattern is controlled by wire netting.In order to ensure the quality of stamp, the color of pattern, gloss and COLOR FASTNESS, the coating of ROTARY SCREAM PRINTING carries out specific allotment.Coating composition comprises binding agent, thickener, wetting agent and pigment, the selection of these components is finally determined to the effect of pattern.Pigment is adhered to design on fabric surface by binding agent, thickener changes the viscosity of pigment can control the speed that pigment flows within the barrel, wetting agent guarantees that pigment can soak the effect that design on fabric surface reaches better dye transfer, and the color and luster of pigment itself also can be regulated by plasticizer simultaneously.Have now a lot of formula being applicable to the coating of ROTARY SCREAM PRINTING, but still there is a lot of deficiency in them: the pigment in coating is generally chemical synthesis material, can discharge toxic and harmful in use procedure; Coating can not resist bacterial corrosion, and Long-Time Service can cause fading.
Chinese patent Authorization Notice No.: CN104120608A, authorized announcement date on October 29th, 2014, disclose a kind of coating for ROTARY SCREAM PRINTING, its component comprises pigment, thickener, adhesive, super soft adhesive, pearl essence, water and wetting agent; This coating reaches general requirement on look gorgeous degree and COLOR FASTNESS, the removing residue formaldehyde in all right disperse dyes.Weak point is, the pigment in dyestuff is Prof. Du Yucang pigment, can discharge poisonous and harmful substance, and the such as starch of the additive in dyestuff, easily by bacterial corrosion, causes dyestuff inefficacy apt to deteriorate.
Summary of the invention
The present invention in order to overcome prior art coating in pigment can discharge poisonous and harmful substance, the deficiency that additive easily lost efficacy, provide a kind of antibacterial ROTARY SCREAM PRINTING coating.
To achieve these goals, the present invention is by the following technical solutions:
A kind of antibacterial ROTARY SCREAM PRINTING coating, comprises following component: vegetable pigment, thickener, adhesive, wetting agent, pearl essence, bactericide and water; The weight of each component in every premium on currency is respectively: vegetable pigment: 100-300 milliliter; Thickener: 10-30 gram; Adhesive: 50-300 gram; Wetting agent: 10-30 gram; Bactericide: 10-50 milliliter; Pearl essence: 100-300 gram.The batching of component adds vegetable pigment in aqueous, utilizes phytochrome natural environmental-protective, the feature that Long-Time Service does not have harmful toxic matter to discharge yet; Then add the viscosity of thickener adjusting coating, coating can be regulated and controled from the rate of outflow the mesh of cylinder cylinder.Add adhesive simultaneously, increase the fixation of pigment, simultaneously can be miscible with the aqueous solution; Add the surface tension that wetting agent can reduce solution, make the complete moistening design on fabric surface of coating, ensure that cloth is painted completely; Adding pearl essence is color and luster in order to strengthen cloth.
As preferably, the extracting method of described vegetable pigment comprises the following steps:
A). get dye yielding herb 50-100 gram, chopping, boils, arranges boiling apparatus condensing reflux in 100-300 ml water, keeps boiling 20-40 minute;
B). leave standstill solution, filter by 20-100 mesh sieve after cooling, preservation leachate is vegetable colour.
The pigment of plant is stored in the cell liquid of plant, and ordinary circumstance is to being difficult to all take out.The present invention proposes simple method efficiently, with the pigment in aqueous phase extraction plant, first boiled by plant cell, cell wall rupture, the pigment then in cell liquid is because in the diffusion aqueous solution outside coming out to that outbound flows as much as possible.The time of boiling is heated in how many decisions according to planting consumption and water.Filtered out by plant residue finally by strainer filtering, pigment has just all remained into the medium one-tenth coating to be produced of filter liquor.The vegetable pigment leachate prepared is utilized to make coating; first add natural thickener; stir; leave standstill particle larger in liquid to precipitate because of adding of thickener; on thinner particle suspension liquid face; because particle diameter is too little, particle just can be discharged to liquid level surface by the surface tension of the water surface.In phytochrome, add binding agent, wetting agent and pearl essence successively, continue to stir, because evaporate outward heating water in the engineering of boiling always, stir so finally add supplementing water, obtained vegetable pigment is stand-by.Different dyestuffs to be got: the general blueness that is chosen as is got indigo or redness and got madder or yellow and get sophora flower or purple and get Asian puccoon or brownly get dye yam or black gets Chinese gall for different colors.In order to meet the demand to various pigment in dye transfer process.
Described bactericide is Nano silver solution, and its preparation methods steps is as follows:
A). get silver nitrate water-soluble, join mass fraction is the liquor argenti nitratis ophthalmicus 40-60 milliliter of 5-45%, liquor argenti nitratis ophthalmicus is boiled in heating;
B). in the process stirred, slowly drip the sodium citrate solution 2-4 milliliter that mass fraction is 0.3-3%;
C). continue heating agitating solution 20-60 minute, then cooling solution, obtains Nano silver solution.
Nano Silver, because it has special skin effect and can strengthen bactericidal effect widely, also can not affect the quality of coating and the health of human body simultaneously.This method is simple and practical for the preparation of Nano Silver, can facilitate industrial mass production pigment.
As preferably, described thickener is starch, and described adhesive is sodium alginate, and described wetting agent is glycerine.Starch is a kind of conventional natural thickener, and in water, the strand of starch is unfolded, utilizes the hydrogen bond action between strand and strand that the viscosity of the aqueous solution can be made greatly to increase.Sodium alginate is the natural high molecular substance extracted from marine alga, and described wetting agent is glycerine.When making binding agent in for coating, because sodium alginate can form gel, increase the fixation of pigment.If screen hole order is excessive, some plant residues can be caused to be detained in the solution, and after adding other component of coating, residue can form bulk, can have a great impact the quality of coating.Glycerine is fatty alcohol, there is the chemism of fatty alcohol, again polyalcohol simultaneously, so glycerine not only has the character of fatty alcohol but also has the chemical property of polyalcohol, industrially have many uses general, be used as lubricant, hygroscopic agent, crease-proofing textiles containing finishing agent, diffusant and bleeding agent in weaving and field of printing and dyeing.
As preferably, the method step extracting vegetable pigment a) in, described dye yielding herb is selected from the one in indigo, madder, sophora flower, Asian puccoon, dye yam, Chinese gall.Indigoly provide blue pigment, madder provides red pigment, and sophora flower provides yellow uitramarine, and Asian puccoon provides violet pigment, and dye yam provides brown, and Chinese gall provides black pigment.
As preferably, extract the method step b of vegetable pigment) in, described filtration adopts 100 mesh sieve.The excessive plant residue of larger particles that easily causes of the hole order of sieve stays in the solution, the meticulous just easily blocking of sieve hole order, the efficiency that impact is filtered.
As preferably, preparation method's step of Nano Silver a) in, the mass fraction of described liquor argenti nitratis ophthalmicus is 10%.In order to prepare the homogeneous Nano Silver of domain size distribution, the concentration of reactant liquor argenti nitratis ophthalmicus needs Reasonable Regulation And Control, and the liquor argenti nitratis ophthalmicus of mass percent 10% is preferred version.
As preferably, the preparation method step b of Nano Silver) in, the mass fraction of described sodium citrate solution is 0.3%.In order to prepare the homogeneous Nano Silver of domain size distribution, the concentration of reactant sodium citrate solution needs Reasonable Regulation And Control, and the sodium citrate solution of mass percent 0.5% is preferred version.
As preferably, the preparation method step b of Nano Silver) in, the process of described dropping sodium citrate solution is 30 minutes.In order to prepare the homogeneous Nano Silver of domain size distribution, reaction speed is directly relevant with the speed dripping sodium citrate solution, and slowly dripping 30 minutes is preferred version.
Therefore, the present invention has following beneficial effect: have employed Nano Silver as bactericide, can reach the effect of sterilization efficiently, and the color of pigment can keep the time more of a specified duration on cloth; Provide a kind of simple method and prepare Nano silver solution, facilitate factory process production with the coating of antibacterial effect; Pigment environment protection health, not Diazolidinyl Urea, the method simple practical extracting vegetable pigment is applicable to industrial production.
Detailed description of the invention
The present invention will be further described to use detailed description of the invention below.
Embodiment one
A kind of antibacterial ROTARY SCREAM PRINTING coating, by vegetable pigment, thickener, adhesive, wetting agent, pearl essence, bactericide and water composition.The extraction of vegetable pigment: get plant 50 grams, chopping, boils, arranges boiling apparatus condensing reflux in 100 ml waters, keeps boiling 20 minutes; Leave standstill solution, filter by 100 mesh sieve after cooling, preservation leachate is vegetable colour.The preparation of Nano silver solution: get silver nitrate water-soluble, join mass fraction be 10% liquor argenti nitratis ophthalmicus 40 milliliters, heating boil liquor argenti nitratis ophthalmicus; The sodium citrate solution 4 milliliters that (dripping 30 minutes) mass fraction is 0.3% is slowly dripped in the process stirred; Continue heating agitating solution 20 minutes, then cooling solution, obtains Nano silver solution.Vegetable pigment is added: 100 milliliters in a premium on currency; Starch: 10 grams; Sodium alginate: 50 grams; Glycerine: 10 grams; Nano silver solution: 10 milliliters; Pearl essence: 100 grams.
The product that above embodiment is obtained: colour fastness to rubbing xerotripsis 3 grades, wet rubbing 2 grades, color fastness to washing water logging variable color 3 grades, staining 3 grades, degerming rate 85%.
Embodiment two
A kind of antibacterial ROTARY SCREAM PRINTING coating, by vegetable pigment, thickener, adhesive, wetting agent, pearl essence, bactericide and water composition.The extraction of vegetable pigment: get plant 50 grams, chopping, boils, arranges boiling apparatus condensing reflux in 100 ml waters, keeps boiling 20 minutes; Leave standstill solution, filter by 100 mesh sieve after cooling, preservation leachate is vegetable colour.The preparation of Nano silver solution: get silver nitrate water-soluble, join mass fraction be 10% liquor argenti nitratis ophthalmicus 40 milliliters, heating boil liquor argenti nitratis ophthalmicus; The sodium citrate solution 4 milliliters that (dripping 30 minutes) mass fraction is 0.3% is slowly dripped in the process stirred; Continue heating agitating solution 20 minutes, then cooling solution, obtains Nano silver solution.Vegetable pigment is added: 200 milliliters in a premium on currency; Starch: 20 grams; Sodium alginate: 100 grams; Glycerine: 20 grams; Nano silver solution: 30 milliliters; Pearl essence: 200 grams.
The product that above embodiment is obtained: colour fastness to rubbing xerotripsis 3 grades, wet rubbing 3 grades, color fastness to washing water logging variable color 2 grades, staining 3 grades, degerming rate 90%.
Embodiment three
A kind of antibacterial ROTARY SCREAM PRINTING coating, by vegetable pigment, thickener, adhesive, wetting agent, pearl essence, bactericide and water composition.The extraction of vegetable pigment: get plant 50g, chopping, boils, arranges boiling apparatus condensing reflux in 100 ml waters, keeps boiling 20 minutes; Leave standstill solution, filter by 100 mesh sieve after cooling, preservation leachate is vegetable colour.The preparation of Nano silver solution: get silver nitrate water-soluble, join mass fraction be 10% liquor argenti nitratis ophthalmicus 40 milliliters, heating boil liquor argenti nitratis ophthalmicus; The sodium citrate solution 4 milliliters that (dripping 30 minutes) mass fraction is 0.3% is slowly dripped in the process stirred; Continue heating agitating solution 20 minutes, then cooling solution, obtains Nano silver solution.Vegetable pigment is added: 300 milliliters in a premium on currency; Starch: 30 grams; Sodium alginate: 200 grams; Glycerine: 30 grams; Nano silver solution: 50 milliliters; Pearl essence: 300 grams.
The product that above embodiment is obtained: colour fastness to rubbing xerotripsis 3 grades, wet rubbing 2 grades, color fastness to washing water logging variable color 2 grades, staining 3 grades, degerming rate 95%.
These are only preferred embodiment of the present invention, being intended to embody outstanding technique effect of the present invention and advantage is not restriction to technical scheme of the present invention, and all are based in the amendment done by the technology of the present invention content, change or replace technical characteristic all should belong to technology category that claims of the present invention advocate.
Claims (9)
1. an antibacterial ROTARY SCREAM PRINTING coating, is characterized in that this antibacterial ROTARY SCREAM PRINTING coating is mixed by following component and 1L water: vegetable pigment: 100-300 milliliter; Thickener: 10-30 gram; Adhesive: 50-300 gram; Wetting agent: 10-30 gram; Bactericide: 10-50 milliliter; Pearl essence: 100-300 gram.
2. antibacterial ROTARY SCREAM PRINTING coating according to claim 1, it is characterized in that, the extracting method of described vegetable pigment comprises the following steps:
A) dye yielding herb 50-100 gram is got, described dye yielding herb is that blueness is got indigo or redness and got madder or yellow and get sophora flower or purple and get Asian puccoon or brownly get dye yam or black gets Chinese gall, chopping, boil in 100-300 ml water, boiling apparatus condensing reflux is set, keeps boiling 20-40 minute;
B) leave standstill solution, filter by 20-100 mesh sieve after cooling, preservation leachate is vegetable pigment.
3. antibacterial ROTARY SCREAM PRINTING coating according to claim 1, it is characterized in that, described bactericide is Nano silver solution, and its preparation methods steps is as follows:
A) get silver nitrate water-soluble, join mass fraction is the liquor argenti nitratis ophthalmicus 40-60 milliliter of 5-45%, liquor argenti nitratis ophthalmicus is boiled in heating;
B) in the process stirred, dripped with 10-60 minute the sodium citrate solution 2-4 milliliter that mass fraction is 0.3-3%;
C) continue heating agitating solution 20-60 minute, then cooling solution, obtains Nano silver solution.
4. antibacterial ROTARY SCREAM PRINTING coating according to claim 1, is characterized in that, described thickener is starch, and described adhesive is sodium alginate, and described wetting agent is glycerine.
5. antibacterial ROTARY SCREAM PRINTING coating according to claim 2, is characterized in that, step a) in, described dye yielding herb is selected from the one in indigo, madder, sophora flower, Asian puccoon, dye yam, Chinese gall.
6. antibacterial ROTARY SCREAM PRINTING coating according to claim 2, is characterized in that, step b) in, described filtration adopts 100 mesh sieve.
7. antibacterial ROTARY SCREAM PRINTING coating according to claim 3, is characterized in that, step a) in, the mass fraction of described liquor argenti nitratis ophthalmicus is 10%.
8. antibacterial ROTARY SCREAM PRINTING coating according to claim 3, is characterized in that, step b) in, the mass fraction of described sodium citrate solution is 0.3%.
9. antibacterial ROTARY SCREAM PRINTING coating according to claim 3, is characterized in that, step b) in, the process of described dropping sodium citrate solution is 30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510432846.7A CN105040474A (en) | 2015-07-22 | 2015-07-22 | Antibacterial rotary screen printing coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510432846.7A CN105040474A (en) | 2015-07-22 | 2015-07-22 | Antibacterial rotary screen printing coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105040474A true CN105040474A (en) | 2015-11-11 |
Family
ID=54447427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510432846.7A Pending CN105040474A (en) | 2015-07-22 | 2015-07-22 | Antibacterial rotary screen printing coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105040474A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109736104A (en) * | 2019-01-28 | 2019-05-10 | 绍兴市天基印刷材料厂 | A kind of indigo slurry dyeing of all-cotton fabric |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6452886A (en) * | 1987-08-24 | 1989-02-28 | Seiko Co Ltd | Print cloths of beddings having miticidal and fungicidal properties |
| CN1865580A (en) * | 2006-06-20 | 2006-11-22 | 大连轻工业学院 | Method for mordant printing on fabric dyed by natural vegetable dye |
| CN102392366A (en) * | 2011-09-06 | 2012-03-28 | 珠海建轩服装有限公司 | Method for printing by using colorable plant and edible starch mixed pigment |
| CN102634995A (en) * | 2012-04-20 | 2012-08-15 | 浙江理工大学 | Method for preparing silk fabric for cultural relic protection |
| CN103046399A (en) * | 2012-12-17 | 2013-04-17 | 常州大学 | Natural dye transfer printing color paste as well as preparation method and printing method |
| CN103790032A (en) * | 2013-03-15 | 2014-05-14 | 辽东学院 | Natural plant dye colored textile fiber knitted fabric and preparation method thereof |
| CN103966861A (en) * | 2014-05-19 | 2014-08-06 | 常州美胜生物材料有限公司 | Environment-friendly digital printing ink and preparation method thereof |
| CN104120608A (en) * | 2014-07-29 | 2014-10-29 | 湖州诚鑫纺织印染有限公司 | Coatings for rotary screen printing |
| CN104278548A (en) * | 2014-10-15 | 2015-01-14 | 嘉兴市梦迪织造有限公司 | Digital ink-jet printing ink based on extract of stems and leaves of celosia cristata L. |
| CN104741621A (en) * | 2015-04-24 | 2015-07-01 | 北京化工大学 | Preparation method of nano-silver colloid with antibacterial property |
-
2015
- 2015-07-22 CN CN201510432846.7A patent/CN105040474A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6452886A (en) * | 1987-08-24 | 1989-02-28 | Seiko Co Ltd | Print cloths of beddings having miticidal and fungicidal properties |
| CN1865580A (en) * | 2006-06-20 | 2006-11-22 | 大连轻工业学院 | Method for mordant printing on fabric dyed by natural vegetable dye |
| CN102392366A (en) * | 2011-09-06 | 2012-03-28 | 珠海建轩服装有限公司 | Method for printing by using colorable plant and edible starch mixed pigment |
| CN102634995A (en) * | 2012-04-20 | 2012-08-15 | 浙江理工大学 | Method for preparing silk fabric for cultural relic protection |
| CN103046399A (en) * | 2012-12-17 | 2013-04-17 | 常州大学 | Natural dye transfer printing color paste as well as preparation method and printing method |
| CN103790032A (en) * | 2013-03-15 | 2014-05-14 | 辽东学院 | Natural plant dye colored textile fiber knitted fabric and preparation method thereof |
| CN103966861A (en) * | 2014-05-19 | 2014-08-06 | 常州美胜生物材料有限公司 | Environment-friendly digital printing ink and preparation method thereof |
| CN104120608A (en) * | 2014-07-29 | 2014-10-29 | 湖州诚鑫纺织印染有限公司 | Coatings for rotary screen printing |
| CN104278548A (en) * | 2014-10-15 | 2015-01-14 | 嘉兴市梦迪织造有限公司 | Digital ink-jet printing ink based on extract of stems and leaves of celosia cristata L. |
| CN104741621A (en) * | 2015-04-24 | 2015-07-01 | 北京化工大学 | Preparation method of nano-silver colloid with antibacterial property |
Non-Patent Citations (1)
| Title |
|---|
| 孙墨杰等: ""纳米银的制备研究"", 《东北电力大学学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109736104A (en) * | 2019-01-28 | 2019-05-10 | 绍兴市天基印刷材料厂 | A kind of indigo slurry dyeing of all-cotton fabric |
| CN109736104B (en) * | 2019-01-28 | 2021-09-10 | 绍兴市天基印刷材料厂 | Indigo pulp dyeing process for all-cotton fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103669031B (en) | The colouring method of blended yarn woven fabric | |
| CN101469517B (en) | Method for dyeing peony pigment on protein fibre fabric | |
| CN101280525A (en) | Natural staining agent, preparation thereof and application thereof to silk dyeing | |
| Hamdy et al. | Various natural dyes from different sources | |
| Tayyab et al. | Dyeing and colour fastness of natural dye from Citrus aurantium on Lyocell fabric | |
| CN102587153A (en) | Method for dyeing silk broadcloth by using plant dye solution extracted from lily | |
| CN101962917B (en) | Printing raw paste capable of improving reactive printing fineness of real silk fabrics | |
| CN105970697A (en) | Color fixing process method for natural dyeing of textiles | |
| CN103938466A (en) | Discharge printing and stripping production methods of gambiered Canton gauze | |
| Sanda et al. | Natural dye extraction and dyeing of different fibers: a review | |
| CN104059382A (en) | Natural textile dye and preparation method thereof | |
| Bydoon | Extraction of natural dye from tea leaves and its application on Giza 86 Egyptian cotton fabric | |
| CN104278548A (en) | Digital ink-jet printing ink based on extract of stems and leaves of celosia cristata L. | |
| Vankar | Structure-mordant interaction, replacement by biomordants and enzymes | |
| CN105040474A (en) | Antibacterial rotary screen printing coating | |
| CN106986953A (en) | A kind of chitosan derivatives as dispersant and its application in fabrics printing and dyeing | |
| CN105113287A (en) | Method for dyeing pure cotton fabric by using tea green pigment | |
| CN109295759A (en) | A kind of preparation method of environment-friendly type phase transformation color changing type reactive dye digit printing ink | |
| CN105040475A (en) | Environment-friendly rotary screen printing coating | |
| US6749647B2 (en) | Fiber dyeing method and dyed fiber products | |
| Panda et al. | Natural dyes—A way forward | |
| CN115928461A (en) | Digital direct-injection printing process for cellulose fiber fabric by using plant dye ink | |
| Manian | The role of mordants in fixation of natural dyes | |
| CN102433031A (en) | Process flow of reductive dye | |
| CN102392366B (en) | Method for printing by using colorable plant and edible starch mixed pigment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151111 |