CN105038663A - Environmentally friendly nano anti-ageing construction adhesive and preparation method therefor - Google Patents
Environmentally friendly nano anti-ageing construction adhesive and preparation method therefor Download PDFInfo
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- CN105038663A CN105038663A CN201510397526.2A CN201510397526A CN105038663A CN 105038663 A CN105038663 A CN 105038663A CN 201510397526 A CN201510397526 A CN 201510397526A CN 105038663 A CN105038663 A CN 105038663A
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Abstract
An objective of the present invention is to provide an environmentally friendly nano anti-ageing construction adhesive. The environmentally friendly nano anti-ageing construction adhesive comprises the following components in parts by weight percentage: 20-30 parts of a polypropylene emulsion; 10-16 parts of titanium dioxide; 3-5 parts of nano zinc oxide; 6-12 parts of a superfine barium sulfate; 0.3-0.6 parts of a dispersant; 0.1-0.2 parts of a wetting agent; 0.1-0.3 parts of a thickener; 10-15 parts of a polyvinyl alcohol; 10-15 parts of an acrylate; 1-3 parts of a catalyst; 1-3 parts of an antimildew agent; 10-15 parts of a gelatin; 1-3 parts of a curing agent; 10-15 parts of lignocellulose; and 33-47 parts of deionized water. The environmentally friendly nano anti-ageing construction adhesive has the advantages of being high in activity, good in stability, non-toxic, environmentally friendly and low in price. Meanwhile, the present invention also provides a preparation method for the environmentally friendly water-based nano anti-ageing adhesive, and the method is scientific, reasonable, simple, and easy to perform.
Description
Technical field
The present invention relates to a kind of tackiness agent, be specifically related to the anti-aging architecture adhesion agent of a kind of environment-friendly type nano.
Background technology
Along with the continuous progress of society, people have had higher requirement to building adhesive, and except bonding effect, people more focus on the feature of environmental protection and high-performance.But the problems such as in general environment-friendly type building field, ubiquity skin surface is easy to crack, seepage and hydrolysis efflorescence, and these problems are also large common quality defects of current building bonding.Further, it is short usually to there is the life-span in environment protection architecture bonding commercially available at present, the shortcomings such as weathering resistance difference.Therefore, in order to make up the deficiency of Traditional Environmental-protection tackiness agent, improving performance, must formula be improved.
Summary of the invention
The object of the invention is just to provide the anti-aging architecture adhesion agent of a kind of environment-friendly type nano, has active high, good stability, asepsis environment-protecting, the advantage such as cheap; Invention also provides the preparation method of the anti-aging tackiness agent of environment-friendly aqueous nanometer, scientific and reasonable, simple.
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, described component carries out proportioning by following weight percent: poly-propionic acid emulsion: 20-30 part; Titanium dioxide: 10-16 part; Nano zine oxide: 3-5 part; Ultra-fine barium sulfate 6-12 part; Dispersion agent: 0.3-0.6 part; Wetting agent: 0.1-0.2 part; Thickening material: 0.1-0.3 part; Polyvinyl alcohol 10-15 part, acrylate 10-15 part, catalyzer 1-3 part, mould inhibitor 1-3 part, gelatin 10-15 part, solidifying agent 1-3 part, lignocellulose 10-15 part, deionized water 33-47 part.
The described anti-aging architecture adhesion agent of a kind of environment-friendly type nano, is characterized in that: described dispersion agent is one or more in Potassium tripolyphosphate, water glass, Sodium hexametaphosphate 99.Described environment-friendly type superpolymer high flame retardant aging-proof building paint, is characterized in that: described thickening material is Natvosol.Described wetting agent is one or more in alkyl aryl polyethyleneglycol ether, hexamethyldisilazane, alkyl polyoxyethylene ether.Described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more; Described catalyzer is dibutyltin dilaurate; Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, described preparation process is as follows:
(1) in a kettle., deionized water 17-20 part is added, poly-propionic acid emulsion: 20-30 part, gelatin 10-15 part and titanium dioxide: 10-16 part; Nano zine oxide: 3-5 part; Ultra-fine barium sulfate 6-12 part; Heating to temperature is 70-75 DEG C, stirs and is mixed by mentioned component, and insulation 2-3 hour, can obtain solution A;
(2) again in another reactor, add deionized water 16-27 part, lignocellulose 10-15 part, acrylate 10-15 part, is warming up to 70-75 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 1-3 part, at the temperature of 70-75 DEG C, be incubated 30 minutes, add solidifying agent 1-3 part successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 1-3 part, stir finished product after half an hour.
Advantage of the present invention is:
Beneficial effect: the anti-aging tackiness agent of environment-friendly aqueous nanometer of the present invention, cost is low, and pollute few, few to harm, erasibility is good, and resistance of aging is strong simultaneously, resistance toly fire-retardantly can carry out blade coating, roller coating and spraying, is suitable for buildings operation.
Embodiment
Embodiment 1:
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, described component carries out proportioning by following weight percent: poly-propionic acid emulsion: 20 parts; Titanium dioxide: 10 parts; Nano zine oxide: 3 parts; Ultra-fine barium sulfate 6 parts; Dispersion agent: 0.3 part; Wetting agent: 0.1 part; Thickening material: 0.1 part; Polyvinyl alcohol 10 parts, acrylate 10 parts, catalyzer 1 part, mould inhibitor 1 part, 10 parts, gelatin, 1 part, solidifying agent, lignocellulose 10 parts, deionized water 33 parts.
The described anti-aging architecture adhesion agent of a kind of environment-friendly type nano, is characterized in that: described dispersion agent is one or more in Potassium tripolyphosphate, water glass, Sodium hexametaphosphate 99.Described environment-friendly type superpolymer high flame retardant aging-proof building paint, is characterized in that: described thickening material is Natvosol.Described wetting agent is one or more in alkyl aryl polyethyleneglycol ether, hexamethyldisilazane, alkyl polyoxyethylene ether.Described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more; Described catalyzer is dibutyltin dilaurate; Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, described preparation process is as follows:
(1) in a kettle., deionized water 17 parts is added, poly-propionic acid emulsion: 20 parts, 10 parts, gelatin and titanium dioxide: 10 parts; Nano zine oxide: 3 parts; Ultra-fine barium sulfate 6 parts; Heating to temperature is 70 DEG C, stirs and is mixed by mentioned component, be incubated 2 hours, can obtain solution A;
(2) again in another reactor, add deionized water 16 parts, lignocellulose 10 parts, acrylate 10 parts, is warming up to 70 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 1 part, at the temperature of 70 DEG C, be incubated 30 minutes, add 1 part, solidifying agent successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 1 part, stir finished product after half an hour.
Embodiment 2:
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, described component carries out proportioning by following weight percent: poly-propionic acid emulsion: 30 parts; Titanium dioxide: 16 parts; Nano zine oxide: 5 parts; Ultra-fine barium sulfate 12 parts; Dispersion agent: 0.6 part; Wetting agent: 0.2 part; Thickening material: 0.3 part; Polyvinyl alcohol 15 parts, acrylate 15 parts, catalyzer 3 parts, mould inhibitor 3 parts, 15 parts, gelatin, 3 parts, solidifying agent, lignocellulose 15 parts, deionized water 47 parts.
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, is characterized in that: described dispersion agent is one or more in Potassium tripolyphosphate, water glass, Sodium hexametaphosphate 99.Described environment-friendly type superpolymer high flame retardant aging-proof building paint, is characterized in that: described thickening material is Natvosol.Described wetting agent is one or more in alkyl aryl polyethyleneglycol ether, hexamethyldisilazane, alkyl polyoxyethylene ether.Described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more; Described catalyzer is dibutyltin dilaurate; Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
The anti-aging architecture adhesion agent of a kind of environment-friendly type nano, described preparation process is as follows:
(1) in a kettle., deionized water 20 parts is added, poly-propionic acid emulsion: 30 parts, 15 parts, gelatin and titanium dioxide: 16 parts; Nano zine oxide: 5 parts; Ultra-fine barium sulfate 12 parts; Heating to temperature is 75 DEG C, stirs and is mixed by mentioned component, be incubated 3 hours, can obtain solution A;
(2) again in another reactor, add deionized water 27 parts, lignocellulose 15 parts, acrylate 15 parts, is warming up to 75 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 3 parts, at the temperature of 75 DEG C, be incubated 30 minutes, add 3 parts, solidifying agent successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 3 parts, stir finished product after half an hour.
It is low that the anti-aging architecture adhesion agent of a kind of environment-friendly type nano that the present invention prepares has cost, and pollute few, few to harm, erasibility is good, and resistance of aging is strong simultaneously, can carry out blade coating, roller coating and spraying, be suitable for buildings operation.
Claims (6)
1. the anti-aging architecture adhesion agent of environment-friendly type nano, described component carries out proportioning by following weight percent: poly-propionic acid emulsion: 20-30 part; Titanium dioxide: 10-16 part; Nano zine oxide: 3-5 part; Ultra-fine barium sulfate 6-12 part; Dispersion agent: 0.3-0.6 part; Wetting agent: 0.1-0.2 part; Thickening material: 0.1-0.3 part; Polyvinyl alcohol 10-15 part, acrylate 10-15 part, catalyzer 1-3 part, mould inhibitor 1-3 part, gelatin 10-15 part, solidifying agent 1-3 part, lignocellulose 10-15 part, deionized water 33-47 part.
2. the anti-aging architecture adhesion agent of a kind of environment-friendly type nano according to claim 1, is characterized in that: described dispersion agent is one or more in Potassium tripolyphosphate, water glass, Sodium hexametaphosphate 99.
3. the anti-aging architecture adhesion agent of a kind of environment-friendly type nano according to claim 1, is characterized in that: described thickening material is Natvosol.
4. the anti-aging architecture adhesion agent of a kind of environment-friendly type nano according to claim 1, is characterized in that: described wetting agent is one or more in alkyl aryl polyethyleneglycol ether, hexamethyldisilazane, alkyl polyoxyethylene ether.
5. the anti-aging architecture adhesion agent of a kind of environment-friendly type nano according to claim 1, is characterized in that: described mould inhibitor be that five grab phenol, sodium pentachlorophenol, five grabs phenol copper, orthoxenol, lauric acid five grab phenol and to grab in Resorcinol one or more;
Described catalyzer is dibutyltin dilaurate;
Described solidifying agent is aliphatie diamine, aliphatic polyamine, aromatic polyamine are the mixture of 1:1:1 according to mass ratio.
6. a preparation method for the anti-aging architecture adhesion agent of environment-friendly type nano, is characterized in that: described preparation process is as follows:
(1) in a kettle., deionized water 17-20 part is added, poly-propionic acid emulsion: 20-30 part, gelatin 10-15 part and titanium dioxide: 10-16 part; Nano zine oxide: 3-5 part; Ultra-fine barium sulfate 6-12 part; Heating to temperature is 70-75 DEG C, stirs and is mixed by mentioned component, and insulation 2-3 hour, can obtain solution A;
(2) again in another reactor, add deionized water 16-27 part, lignocellulose 10-15 part, acrylate 10-15 part, is warming up to 70-75 DEG C by reactor, is incubated 45 minutes, can obtains B solution;
(3) solution A is dropped in B solution, then stir, then add catalyzer 1-3 part, at the temperature of 70-75 DEG C, be incubated 30 minutes, add solidifying agent 1-3 part successively more afterwards, when reacting 3 hours and be cooled to 40 DEG C, drop into mould inhibitor 1-3 part, stir finished product after half an hour.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510397526.2A CN105038663A (en) | 2015-07-09 | 2015-07-09 | Environmentally friendly nano anti-ageing construction adhesive and preparation method therefor |
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| CN201510397526.2A CN105038663A (en) | 2015-07-09 | 2015-07-09 | Environmentally friendly nano anti-ageing construction adhesive and preparation method therefor |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358227A (en) * | 2011-08-29 | 2012-02-22 | 东莞方皓汽车配件有限公司 | Cargo fixing net for automobile and production method thereof |
| CN102936471A (en) * | 2012-10-18 | 2013-02-20 | 青州市天源化工有限公司 | Aqueous polymer-isocyanate adhesive and preparation method thereof |
| WO2014159798A1 (en) * | 2013-03-13 | 2014-10-02 | Avery Dennison Corporation | Improving adhesive properties |
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2015
- 2015-07-09 CN CN201510397526.2A patent/CN105038663A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358227A (en) * | 2011-08-29 | 2012-02-22 | 东莞方皓汽车配件有限公司 | Cargo fixing net for automobile and production method thereof |
| CN102936471A (en) * | 2012-10-18 | 2013-02-20 | 青州市天源化工有限公司 | Aqueous polymer-isocyanate adhesive and preparation method thereof |
| WO2014159798A1 (en) * | 2013-03-13 | 2014-10-02 | Avery Dennison Corporation | Improving adhesive properties |
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Application publication date: 20151111 |