CN105036592A - Preparation method of PAM (polyacrylamide) applied to artificial granite - Google Patents

Preparation method of PAM (polyacrylamide) applied to artificial granite Download PDF

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Publication number
CN105036592A
CN105036592A CN201510364901.3A CN201510364901A CN105036592A CN 105036592 A CN105036592 A CN 105036592A CN 201510364901 A CN201510364901 A CN 201510364901A CN 105036592 A CN105036592 A CN 105036592A
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China
Prior art keywords
pam
preparation
hilllock stone
artificial hilllock
high strength
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CN201510364901.3A
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Chinese (zh)
Inventor
贺志强
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Tang Xiongyue
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Tang Xiongyue
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Priority to CN201510364901.3A priority Critical patent/CN105036592A/en
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Abstract

The invention relates to a preparation method of PAM (polyacrylamide) applied to artificial granite. The preparation method is characterized in that the preparation method of an organic polymer water-based tackifier PAM applied to imitation of natural ice cracks of artificial granite comprises the following technological steps: (1) mixing the organic polymer water-based tackifier PAM and water according to a proportion to dissolve the organic polymer water-based tackifier PAM in water so as to prepare a PAM high-strength viscous wiredrawing liquid material; (2) adding color paste or color powder to the high-strength viscous wiredrawing liquid material prepared in the step (1), and sufficiently stirring and thus uniformly mixing to prepare a colored high-strength viscous wiredrawing liquid material; (3) preparing the artificial granite from the colored high-strength viscous wiredrawing liquid material obtained in the step (2) according to a color paste spraying process in the prior art. The preparation method disclosed by the invention is simple and feasible; the artificial granite highly imitates slender color patterns and micro ice crack effects of natural stone and has the characteristics of unique patterns and bright color.

Description

PAM is applied to the preparation method of artificial hilllock stone
Technical field
The present invention relates to the manufacture craft of a kind of artificial hilllock hardcore, particularly a kind of organic polymer aqueous tackifier PAM is applied to the preparation method of artificial hilllock stone, belongs to architectural decoration material field.
Background technology
The pattern of hilllock stone and filler present diversified trend; hilllock stone is had and more enriches moving pattern; but also there is certain difference in the decorative pattern of artificial hilllock stone and decorative effect and natural marble; imitative natural ice crackle artificial hilllock stone prepared by the present invention can reduce this species diversity further; not only can promote the decorative effect of artificial hilllock stone, these Nonrenewable resources of natural marble can also be protected on certain Cheng Du.
Summary of the invention
The object of the invention is to, propose the preparation method that a kind of PAM is applied to artificial hilllock stone.
PAM of the present invention is applied to the preparation method of artificial hilllock stone, it is characterized in that: organic polymer aqueous tackifier polyacrylamide (PAM) is applied to the preparation method that artificial hilllock stone imitates natural ice crackle, comprises following processing step:
1. organic polymer aqueous tackifier PAM and water are mixed in proportion, make it be dissolved in the water, obtained PAM high strength viscosity wire drawing fluent material.
2. mill base or toner are added in 1. the produced high strength viscosity wire drawing fluent material of step, fully stir and make it mix, obtained coloured high strength viscosity wire drawing fluent material;
3. by coloured high strength viscosity wire drawing fluent material of step 2. gained, according to the spraying mill base technique making artificial hilllock stone of prior art.
Step 1. described PAM molecular weight at 300w ~ 1800w.
The blending ratio of step 1. described PAM and water is 1 ~ 5:100.
Step 2. described mill base, toner refers to iron oxide red, iron oxide yellow, iron oxide black, bright red, middle Huang, the mill base of titanium dioxide or toner, and its proportion is no more than 30% of coloured high strength viscosity wire drawing liquid total amount of material.
Step is 3. in described spraying mill base technique, and the aperture of nozzle must not be greater than 1mm.
Step 3. in, the batch mixing of described spraying mill base technique making artificial hilllock stone is made up of the component of following weight percent:
Step 3. in, the imitative natural ice crackle artificial hilllock stone product of described spraying mill base technique making artificial hilllock stone, comprises following processing step:
1. Paris white, white building stones, pigment are added in stirrer together and stir;
2. unsaturated polyester resin, methylethyl ketone peroxide and cobalt iso-octoate are added step 1. in stirred material, make it mix and be stirred to agglomerating, vacuumize, and spray step 2. coloured high strength viscosity wire drawing fluent material described in claim 1 under vacuum conditions.
Beneficial effect of the present invention is embodied in:
The object of this invention is to provide a kind of high strength viscosity wire drawing liquid materials application in the preparation method of artificial hilllock stone, high strength viscosity wire drawing fluent material prepared by the inventive method has the characteristic of easily drawing-down long filament line in material, the artificial hilllock stone prepared with this material has elongated lathe work and small ice crack effect, and this preparation method is simple and easy to do, Be very effective, has good application prospect in whole rostone industry.
The hilllock stone adopting method of the present invention to obtain the manufacture of high strength viscosity wire drawing fluent material has the feature of height imitation natural stone, and decorative pattern is unique, bright in colour;
The hilllock stone adopting method of the present invention to obtain the manufacture of high strength viscosity wire drawing fluent material has better stereoscopic sensation, makes artificial hilllock stone have the new variety of more uniquenesses, meets more consumer demands.
Embodiment
Following non-limiting example can make the present invention of those of ordinary skill in the art's comprehend, but does not limit the present invention in any way.
Embodiment 1
PAM is applied to the preparation method of artificial hilllock stone, organic polymer aqueous tackifier polyacrylamide (PAM) is applied to the preparation method that artificial hilllock stone imitates natural ice crackle, comprises following processing step:
1. organic polymer aqueous tackifier PAM and water are mixed in proportion, make it be dissolved in the water, obtained PAM high strength viscosity wire drawing fluent material.
2. mill base or toner are added in 1. the produced high strength viscosity wire drawing fluent material of step, fully stir and make it mix, obtained coloured high strength viscosity wire drawing fluent material;
3. by coloured high strength viscosity wire drawing fluent material of step 2. gained, according to the spraying mill base technique making artificial hilllock stone of prior art.
Step 1. described PAM molecular weight at 300w ~ 1800w.
The blending ratio of step 1. described PAM and water is 1 ~ 5:100.
Step 2. described mill base, toner refers to iron oxide red, iron oxide yellow, iron oxide black, bright red, middle Huang, the mill base of titanium dioxide or toner, and its proportion is no more than 30% of coloured high strength viscosity wire drawing liquid total amount of material.
Step is 3. in described spraying mill base technique, and the aperture of nozzle must not be greater than 1mm.
Step 3. in, the batch mixing of described spraying mill base technique making artificial hilllock stone is made up of the component of following weight percent:
Step 3. in, the imitative natural ice crackle artificial hilllock stone product of described spraying mill base technique making artificial hilllock stone, comprises following processing step:
1. Paris white, white building stones, pigment are added in stirrer together and stir;
2. unsaturated polyester resin, methylethyl ketone peroxide and cobalt iso-octoate are added step 1. in stirred material, make it mix and be stirred to agglomerating, vacuumize, and spray step 2. coloured high strength viscosity wire drawing fluent material described in claim 1 under vacuum conditions.
Embodiment 2
1. high strength viscosity wire drawing liquid material preparation method.Concrete preparation method is:
A. take in 10kg clear water stirrer, add the PAM of each 200g800w molecular weight successively, limit edged stirs and makes it fully mix, and leaves standstill 3 hours;
B. after itself and water fully react completely, add 50g iron oxide yellow, 20g iron oxide red, stir and make it mixing, namely obtain colored high strength viscosity wire drawing fluent material.
2. high strength viscosity wire drawing liquid materials application is in the preparation method of artificial hilllock stone:
C. automatic material weighing system takes 3500kg Paris white respectively, the white building stones of 5900kg (80 order), and titanium dioxide 20kg is placed in blender, and then takes 570kg unsaturated polyester resin, adds the methylethyl ketone peroxide of 7.2kg simultaneously, stirs;
D. above-mentioned rostone Preblend is sprayed under vacuum 1. obtained colored high strength viscosity wire drawing fluent material, be cast in mould after stirring five circles, these die size length, width and height are 2.75m × 1.85m × 1.25m, and compression moulding under vacuum condition, obtains work in-process;
E. work in-process self-vulcanizing 7-10 days, cutting polishing obtains finished product further.The elongated striped of this rostone Chromatic color, decorative pattern is unique, and have good gradation sense, flexural strength is 105MPa.
Embodiment 3
The imitative artificial hilllock of natural ice crackle Preparation Method made of stones:
The batch mixing of spraying mill base technique making artificial hilllock stone is made up of the component of following weight:
Processing step is:
1. Paris white, white building stones, pigment are added in stirrer together and stir;
2. unsaturated polyester resin, methylethyl ketone peroxide and cobalt iso-octoate are added step 1. in stirred material, make it mix and be stirred to agglomerating, vacuumize, and spray step 2. coloured high strength viscosity wire drawing fluent material described in claim 1 under vacuum conditions.Be cast in mould after stirring five circles, these die size length, width and height are 2.75m × 1.85m × 1.25m, and compression moulding under vacuum condition, obtains work in-process.Work in-process self-vulcanizing 7-10 days, cutting polishing obtains finished product further.The hilllock stone starting material exquisiteness of this product owing to using, finished product has certain penetrating sense, adds elongated decorative pattern without stop, gives the sensation of ice facial cleft.

Claims (7)

1. PAM is applied to a preparation method for artificial hilllock stone, it is characterized in that: organic polymer aqueous tackifier polyacrylamide PAM is applied to the preparation method that artificial hilllock stone imitates natural ice crackle, comprises following processing step:
1. organic polymer aqueous tackifier PAM and water are mixed in proportion, make it be dissolved in the water, obtained PAM high strength viscosity wire drawing fluent material.
2. mill base or toner are added in 1. the produced high strength viscosity wire drawing fluent material of step, fully stir and make it mix, obtained coloured high strength viscosity wire drawing fluent material;
3. by coloured high strength viscosity wire drawing fluent material of step 2. gained, according to the spraying mill base technique making artificial hilllock stone of prior art.
2. PAM according to claim 1 is applied to the preparation method of artificial hilllock stone, it is characterized in that: step 1. described PAM molecular weight at 300w ~ 1800w.
3. PAM according to claim 1 is applied to the preparation method of artificial hilllock stone, it is characterized in that: the blending ratio of step 1. described PAM and water is 1 ~ 5:100.
4. PAM according to claim 1 is applied to the preparation method of artificial hilllock stone, it is characterized in that: step 2. described mill base, toner refers to iron oxide red, iron oxide yellow, iron oxide black, bright red, middle Huang, the mill base of titanium dioxide or toner, and its proportion is no more than 30% of coloured high strength viscosity wire drawing liquid total amount of material.
5. PAM according to claim 1 is applied to the preparation method of artificial hilllock stone, it is characterized in that: step is 3. in described spraying mill base technique, and the aperture of nozzle must not be greater than 1mm.
6. PAM according to claim 1 is applied to the preparation method of artificial hilllock stone, it is characterized in that: step 3. in, the batch mixing of described spraying mill base technique making artificial hilllock stone is made up of the component of following weight percent:
7. PAM is applied to the preparation method of artificial hilllock stone according to claim 1, it is characterized in that: step 3. in, the imitative natural ice crackle artificial hilllock stone product of described spraying mill base technique making artificial hilllock stone, comprises following processing step:
1. Paris white, white building stones, pigment are added in stirrer together and stir;
2. unsaturated polyester resin, methylethyl ketone peroxide and cobalt iso-octoate are added step 1. in stirred material, make it mix and be stirred to agglomerating, vacuumize, and spray step 2. coloured high strength viscosity wire drawing fluent material described in claim 1 under vacuum conditions.
CN201510364901.3A 2015-06-26 2015-06-26 Preparation method of PAM (polyacrylamide) applied to artificial granite Pending CN105036592A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109942228A (en) * 2019-04-08 2019-06-28 肇庆爱博新材料科技有限公司 A kind of preparation method of cracked ice pattern synthetic quartz plate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693619A (en) * 2009-10-16 2010-04-14 清华大学 Method for preparing high-imitation stone sculpture by utilizing stone powder
CN102320779A (en) * 2011-06-21 2012-01-18 云浮市新富云岗石有限公司 Celik dark beige artificial granite and preparation method thereof
CN102417336A (en) * 2011-08-31 2012-04-18 泉州市嘉利来石材工艺有限公司 Travertine-like arabesquitic vat and production technology thereof
CN104476654A (en) * 2014-11-19 2015-04-01 广西利升石业有限公司 Mosaic pattern man-made agglomerated stone product and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693619A (en) * 2009-10-16 2010-04-14 清华大学 Method for preparing high-imitation stone sculpture by utilizing stone powder
CN102320779A (en) * 2011-06-21 2012-01-18 云浮市新富云岗石有限公司 Celik dark beige artificial granite and preparation method thereof
CN102417336A (en) * 2011-08-31 2012-04-18 泉州市嘉利来石材工艺有限公司 Travertine-like arabesquitic vat and production technology thereof
CN104476654A (en) * 2014-11-19 2015-04-01 广西利升石业有限公司 Mosaic pattern man-made agglomerated stone product and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109942228A (en) * 2019-04-08 2019-06-28 肇庆爱博新材料科技有限公司 A kind of preparation method of cracked ice pattern synthetic quartz plate

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Application publication date: 20151111