CN105034490A - High-flame-retardant and anti-corrosion glass fiber cloth - Google Patents
High-flame-retardant and anti-corrosion glass fiber cloth Download PDFInfo
- Publication number
- CN105034490A CN105034490A CN201510365850.6A CN201510365850A CN105034490A CN 105034490 A CN105034490 A CN 105034490A CN 201510365850 A CN201510365850 A CN 201510365850A CN 105034490 A CN105034490 A CN 105034490A
- Authority
- CN
- China
- Prior art keywords
- cloth
- glass fiber
- corrosion
- flame retardant
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/206—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/752—Corrosion inhibitor
Abstract
The invention discloses high-flame-retardant and anti-corrosion glass fiber cloth. The high-flame-retardant and anti-corrosion glass fiber cloth comprises glass fiber base cloth and a resin material layer which is combined to at least one side surface of the glass fiber base cloth; a curing agent layer is arranged between the glass fiber base cloth and the resin material layer; the glass fiber base cloth is medium-alkali glass fiber cloth; the resin material layer is vinyl resin; the weight of the vinyl resin occupies 30 to 45 percent of the total weight of the high-flame-retardant and anti-corrosion glass fiber cloth; the weight of a curing agent occupies 7 to 20 percent of the total weight of the high-flame-retardant and anti-corrosion glass fiber cloth; the weight of glass filament occupies 40 to 55 percent of the total weight of the high-flame-retardant and anti-corrosion glass fiber cloth; the curing agent comprises aromatic polyamine. The vinyl resin is adopted for producing the glass fiber cloth, so that the high-flame-retardant and anti-corrosion glass fiber cloth disclosed by the invention has the advantages of good insulating performance, strong thermal resistance, good corrosion resistance, good flame retardancy and high mechanical strength.
Description
Technical field
The present invention relates to a kind of glass fabric, specifically a kind of novel high flame retardant corrosion-resistant fiberglass cloth.
Background technology
The glass cloth that China produces, be divided into alkali-free and middle alkali two class, external great majority are E-GLASS alkali-free glass cloths.Glass cloth is mainly for the production of various electric insulation layer pressing plate, printed substrate, various carbody, basin, ships and light boats, mould etc.Middle alkali glass cloth mainly for the production of plastic-coated packing sheet, and for corrosion-resistant occasion.The characteristic of fabric determined by fibre property, thread count, yarn texture and weavy grain.
At present, much combustion-proof glass fiber cloth has been there is in industry, majority obtains at the phosphorus flame retardant adding such as red phosphorus, phosphate or halogenated phosphate and so in spinning process, it is not the fire resistance that raw material innately has, along with the increase of passage of time and washing times, flame retardant effect can be faded.Some combustion-proof glass fiber cloth has anti-flammability and does not but have corrosion-resistant.
Summary of the invention
The object of the present invention is to provide a kind of novel high flame retardant corrosion-resistant fiberglass cloth, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A kind of novel high flame retardant corrosion-resistant fiberglass cloth, comprise fiberglass-based cloth and be incorporated into the resin material layer of at least one side surface of fiberglass-based cloth, solidification oxidant layer is provided with between described glass fabric and resin material layer, described fiberglass-based cloth is medium alkali fiber cloth, and described resin material layer is vinylite;
Described vinylite accounts for the 30%-45% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, described curing agent accounts for the 7%-20% of the overall component of corrosion resistant glass fabric, described glass fiber accounts for the 40-55% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, and described curing agent includes aromatic polyamine.
Preferably, described one novel high flame retardant corrosion-resistant fiberglass cloth, the grammes per square metre of described fiberglass-based cloth is 220-320g/ ㎡.
Preferably, the thickness of described solidification oxidant layer is 40-80 μm.
Preferably, described vinylite accounts for 33% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, and described curing agent accounts for 18% of the overall component of corrosion resistant glass fabric, and described glass fiber accounts for 49% of the overall component of high flame retardant corrosion-resistant fiberglass cloth.
Compared with prior art, the invention has the beneficial effects as follows: adopt vinylite to produce glass fabric, make of the present invention to there is good insulating, heat resistance is strong, corrosion resistance good, good flame resistance, the advantage that mechanical strength is high.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated.
A kind of novel high flame retardant corrosion-resistant fiberglass cloth of the present invention, comprise fiberglass-based cloth and be incorporated into the resin material layer of at least one side surface of fiberglass-based cloth, solidification oxidant layer is provided with between described glass fabric and resin material layer, described fiberglass-based cloth is medium alkali fiber cloth, and described resin material layer is vinylite.
The grammes per square metre of described fiberglass-based cloth is 220-320g/ ㎡, and the thickness of described solidification oxidant layer is 40-80 μm.
Described vinylite accounts for the 30%-45% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, described curing agent accounts for the 7%-20% of the overall component of corrosion resistant glass fabric, described glass fiber accounts for the 40-55% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, and described curing agent includes aromatic polyamine.
Preferably, described vinylite accounts for 33% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, and described curing agent accounts for 18% of the overall component of corrosion resistant glass fabric, and described glass fiber accounts for 49% of the overall component of high flame retardant corrosion-resistant fiberglass cloth.
The present invention selects vinylite to carry out production high flame retardant corrosion-resistant fiberglass cloth, and vinylite is internationally recognized height corrosion-resistant resin.The type resin has following characteristics: the double bond 1, at strand two ends is extremely active, makes vinylite energy rapid solidification, obtains working strength very soon, obtain having high corrosion resistance polymer; 2, adopt methacrylic acid synthesis, the methyl on ester bond limit can shield, and improves hydrolytic resistance; 3, resin is few containing ester bond amount, and the few 35-50% of every mol ratio chemically-resistant polyester (bisphenol-A-fumaric acid UPR), makes its alkaline resistance properties improve; 4, more secondary hydroxyl can improve wettability to glass fibre and caking property, improves the mechanical strength of laminate; 5, due to only crosslinked at molecule two ends.
Vinylite generally adopts brominated epoxy resin to synthesize, due in resin due to brominated, therefore flame-proof ethylene base resin has chemical-resistant simultaneously, again can be fire-retardant.
Claims (4)
1. a novel high flame retardant corrosion-resistant fiberglass cloth, it is characterized in that, comprise fiberglass-based cloth and be incorporated into the resin material layer of at least one side surface of fiberglass-based cloth, solidification oxidant layer is provided with between described glass fabric and resin material layer, described fiberglass-based cloth is medium alkali fiber cloth, and described resin material layer is vinylite;
Described vinylite accounts for the 30%-45% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, described curing agent accounts for the 7%-20% of the overall component of corrosion resistant glass fabric, described glass fiber accounts for the 40-55% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, and described curing agent includes aromatic polyamine.
2. one according to claim 1 novel high flame retardant corrosion-resistant fiberglass cloth, is characterized in that, the grammes per square metre of described fiberglass-based cloth is 220-320g/ ㎡.
3. one according to claim 1 novel high flame retardant corrosion-resistant fiberglass cloth, is characterized in that, the thickness of described solidification oxidant layer is 40-80 μm.
4. one according to claim 1 novel high flame retardant corrosion-resistant fiberglass cloth, it is characterized in that, described vinylite accounts for 33% of the overall component of high flame retardant corrosion-resistant fiberglass cloth, described curing agent accounts for 18% of the overall component of corrosion resistant glass fabric, and described glass fiber accounts for 49% of the overall component of high flame retardant corrosion-resistant fiberglass cloth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510365850.6A CN105034490A (en) | 2015-06-29 | 2015-06-29 | High-flame-retardant and anti-corrosion glass fiber cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510365850.6A CN105034490A (en) | 2015-06-29 | 2015-06-29 | High-flame-retardant and anti-corrosion glass fiber cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105034490A true CN105034490A (en) | 2015-11-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510365850.6A Pending CN105034490A (en) | 2015-06-29 | 2015-06-29 | High-flame-retardant and anti-corrosion glass fiber cloth |
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| Country | Link |
|---|---|
| CN (1) | CN105034490A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105803785A (en) * | 2016-04-21 | 2016-07-27 | 邵帅 | Alkali-resisting glass fiber cloth |
| CN106634452A (en) * | 2016-12-23 | 2017-05-10 | 江苏玖尚新材料有限公司 | Storage tank liner protective material |
| CN107379711A (en) * | 2017-06-15 | 2017-11-24 | 广州云凯复合材料有限公司 | A kind of multifunctional honeycomb board production technology |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104369475A (en) * | 2014-12-04 | 2015-02-25 | 常熟市东宇绝缘复合材料有限公司 | Anticorrosive glass fiber cloth |
-
2015
- 2015-06-29 CN CN201510365850.6A patent/CN105034490A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104369475A (en) * | 2014-12-04 | 2015-02-25 | 常熟市东宇绝缘复合材料有限公司 | Anticorrosive glass fiber cloth |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105803785A (en) * | 2016-04-21 | 2016-07-27 | 邵帅 | Alkali-resisting glass fiber cloth |
| CN106634452A (en) * | 2016-12-23 | 2017-05-10 | 江苏玖尚新材料有限公司 | Storage tank liner protective material |
| CN106634452B (en) * | 2016-12-23 | 2019-01-29 | 江苏玖尚新材料有限公司 | A kind of storage tank liner protection materials |
| CN107379711A (en) * | 2017-06-15 | 2017-11-24 | 广州云凯复合材料有限公司 | A kind of multifunctional honeycomb board production technology |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151111 |
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| RJ01 | Rejection of invention patent application after publication |