CN105019298A - Real-time hole forming cigarette paper and application of real-time hole forming cigarette paper in reducing CO and tar releasing amount of mainstream smoke - Google Patents
Real-time hole forming cigarette paper and application of real-time hole forming cigarette paper in reducing CO and tar releasing amount of mainstream smoke Download PDFInfo
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Abstract
The invention discloses real-time hole forming cigarette paper based on metal organic frame (MOF) materials and application thereof. The real-time hole forming cigarette paper is mainly used for reducing the CO and tar releasing amount of mainstream smoke without producing negative effects on the smoking quality of a cigarette. The real-time hole forming cigarette paper is characterized in that the MOF materials are used in the cigarette paper producing process; in the cigarette paper burning process, the MOF materials can produce more microcellular structures after being heated and decomposed, the diffusion rate of the part, near a carbonization line, of the cigarette paper in the cigarette burning process is obviously increased, and the hole structure of the cigarette paper is changed. The CO and tar releasing amount of the mainstream smoke is reduced. By means of the cigarette paper, the CO releasing amount of the mainstream smoke can be reduced by 15 percent or more, and the tar releasing amount can be reduced by 4 percent to 8 percent. The cigarette paper is simple in preparing method, cost is low, and industrial production can be achieved.
Description
Technical field
The present invention relates to a kind of cigarette paper and application thereof, specifically, relate to and a kind ofly pore in real time can reduce cigarette paper and the application of main flume CO and releasing content of coke tar; Belong to cigarette paper preparation field.
Technical background
In recent years, World tobacco industry has carried out a large amount of work in lowering harm and decreasing coking technical research and application field, establish the analysis test method of the cigarette smoke 44 kinds of harmful components paid close attention in the world, develop the practical technique of a collection of reduction harmful constituents in cigarette flue gas, and be applied in cigarette product.Along with the public is to the growing interest of smoking and health problem, the harmful components discharged in cigarette smoke also become the focal issue that people pay close attention to, and its burst size becomes the important indicator of evaluating cigarette harmfulness gradually.CO is the maximum and harmful components of the most difficult removal of content in cigarette smoke.In flue gas, CO is that cigarette is formed because of tobacco imperfect combustion in aspiration procedure.During smoking, CO can enter tracheae and lung along with flue gas, due to CO with the affinity of hemoglobin larger than oxygen more than 250 times, therefore namely CO is combined with hemoglobin once suction, reduce the oxygen concentration in blood, blood oxygen therapy amount is caused to decline, cause histanoxia, increase the probability of happening of disease.
Those skilled in the art is seeking a kind of cigarette product that simultaneously can reduce CO and tar always.
Summary of the invention
The present invention is directed to the deficiency of above-mentioned prior art existence and the demand of industry development, prepare a kind of cigarette paper with variable diffusivity and pore structure, for reducing the CO in cigarette mainstream flue gas and releasing content of coke tar, and do not affect cigarette smoking quality, poisonous and harmful element can not be produced in cigarette burning process simultaneously, this cigarette paper preparation method is simple, cost is low, can widely use.
Another object of the present invention is to provide the above-mentioned embody rule with the cigarette paper of variable diffusivity and pore structure, for reducing the CO in cigarette mainstream flue gas and releasing content of coke tar, poisonous and harmful element can not be produced in cigarette burning process simultaneously.
Further aim of the present invention is, provides the above-mentioned embody rule with the cigarette paper of variable diffusivity and pore structure, for reducing the CO in cigarette mainstream flue gas.
Further object of the present invention is, provides the above-mentioned embody rule with the cigarette paper of variable diffusivity and pore structure, the while of for reducing the CO in cigarette mainstream flue gas and releasing content of coke tar, does not affect cigarette smoking quality.
The invention provides a kind of real-time pore cigarette paper with variable diffusivity and pore structure, add in described cigarette paper and have MOF material, MOF material accounts for 2% ~ 8% of cigarette paper weight; The particle diameter of described MOF material is the nano particle of 30 ~ 300nm.
Described MOF material is the mixture of MOF-Fe, MOF-Ca or MOF-Zn or wherein both or three.
The preferred MOF material of the present invention accounts for 2% ~ 5% of cigarette paper weight.
Described MOF material with comprise wood pulp, filler raw material by pull an oar papermaking, then add the cigarette paper of the real-time pore function that combustion adjuvant is prepared from.
Described combustion adjuvant in the form of a solution, is added on cigarette paper in applying glue operation.
Described combustion adjuvant of the present invention be selected from potassium citrate or natrium citricum one or both.
Described wood pulp main component is made up of softwood pulp and hardwood pulp; Described filler is calcium carbonate.
Softwood pulp accounts for 15% ~ 35% of cigarette paper weight, and hardwood pulp accounts for 20% ~ 40% of cigarette paper quality, and pearl filler accounts for 20% ~ 50% of cigarette paper weight, and combustion adjuvant accounts for 1% ~ 5% of cigarette paper weight.
Application of the present invention there are provided described real-time pore cigarette paper and is reducing the purposes in cigarette mainstream flue gas CO and releasing content of coke tar.
Further application of the present invention is embodied in the applications well effect of reduction cigarette mainstream flue gas CO burst size.
Further application of the present invention is, provides described real-time pore cigarette paper while reduction cigarette mainstream flue gas CO and releasing content of coke tar, still effectively maintains cigarette smoking quality.
Beneficial effect of the present invention: first passage of the present invention adds and has loose structure and can also the MOF material of thermal cracking pore in regular-size cigarette paper, but find in experimentation, after adding MOF material, the content of CO and tar does not decline at once to some extent, inventor does not know it is what reason yet, just finding through repeatedly studying, in the solution of the present invention, needing the particle size of further control MOF material, after adding cigarette paper, just can reduce the burst size of CO and tar simultaneously.By product of the present invention, in cigarette paper combustion process, after MOF material decomposes, club produces more microcellular structure, significantly improves the diffusivity carbonizing cigarette paper near line in cigarette burning process, changes the pore structure of cigarette paper.Cigarette made by the cigarette paper that this is had variable diffusivity, utilizes the real-time pore effect of MOF material in cigarette burning process, can significantly reduce CO burst size in cigarette mainstream flue gas, and reduce the burst size of tar simultaneously.The present invention's relative regular-size cigarette paper roll cigarette, the CO range of decrease more than 15%, the tar range of decrease 4% ~ 8%.Simultaneously, the present invention also has an outstanding advantage to be that after with the addition of MOF material, cigarette odor-absorbing significant change does not occur relative to traditional flue gas dilution method, solve while cannot reducing releasing content of coke tar in prior art and well can keep cigarette odor-absorbing again, this puzzlement those skilled in the art difficult problem, has the value promoted the use of.
Detailed description of the invention
Following examples are intended to the present invention is described, instead of the further restriction to scope.
Comparative example 1
Get 150 kilograms of softwood pulps and 300 kilograms of hardwood pulps, add 400 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2.This is control sample cigarette paper (being numbered P1).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained control sample cigarette paper is used for the production of cigarettes (being numbered C1) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Comparative example 2
Get 150 kilograms of softwood pulps, 300 kilograms of hardwood pulps, 5 kilograms of particle diameters are the MOF-Fe of 30-300nm, add 400 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P2).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C2) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Comparative example 3
Get 150 kilograms of softwood pulps, 300 kilograms of hardwood pulps, 100 kilograms of particle diameters are the MOF-Fe of 30-300nm, add 400 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P3).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C3) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Comparative example 4
Get 150 kilograms of softwood pulps, 300 kilograms of hardwood pulps, 30 kilograms of particle diameters are the MOF-Fe of 5-20nm, add 400 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P4).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C4) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Comparative example 5
Get 150 kilograms of softwood pulps, 300 kilograms of hardwood pulps, 30 kilograms of particle diameters are the MOF-Fe of 400-600nm, add 400 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P5).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C5) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Comparative example 6
By obtained particle diameter be 30-300nm MOF-Fe material according to the ratio that addition is 5% join trial-production cigarette filter tip in, the cigarette paper P1 in comparative example is adopted to manufacture experimently cigarette, obtain the cigarette C6 adding MOF-Fe material in filter tip, the cigarette rolled carries out main flume CO, releasing content of coke tar analysis and sensory quality assessment, and result is respectively in table 2, table 3.
Embodiment 1
Get 150 kilograms of softwood pulps, 300 kilograms of hardwood pulps, 30 kilograms of particle diameters are the MOF-Fe of 30-300nm, add 400 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P7).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C7) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Embodiment 2
Get 160 kilograms of softwood pulps, 320 kilograms of hardwood pulps, 15 kilograms of MOF-Fe, 10 kilograms of MOF-Ca, add 420 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P8).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C8) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Embodiment 3
Get 190 kilograms of softwood pulps, 330 kilograms of hardwood pulps, 15 kilograms of MOF-Fe, 15 kilograms of MOF-Zn, add 450 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P9).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C9) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Embodiment 4
Get 200 kilograms of softwood pulps, 350 kilograms of hardwood pulps, 15 kilograms of MOF-Zn, 20 kilograms of MOF-Ca, add 460 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P10).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C10) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Embodiment 5
Get 180 kilograms of softwood pulps, 290 kilograms of hardwood pulps, 10 kilograms of MOF-Fe, 10 kilograms of MOF-Ca, 8 kilograms of MOF-Zn, add 380 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P11).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C11) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
Embodiment 6
Get 160 kilograms of softwood pulps, 300 kilograms of hardwood pulps, 10 kilograms of MOF-Fe, 10 kilograms of MOF-Ca, 10 kilograms of MOF-Zn, add 370 kilograms, calcium carbonate and carry out making beating papermaking, preparation mass percent is the potassium citrate of 10% and the natrium citricum additive package solution of 6%, the applying glue workshop section that the additive solution prepared is produced at cigarette paper is evenly added in cigarette paper by metering stick type film transferring sizing applicator, papermaking process produces cigarette paper routinely, and equipment controls cigarette paper parameter is: quantitatively 27g m
-2, air permeability 60CORESTA, the addition of additive in cigarette paper is 1.00g m
-2(being numbered P12).Utilize the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company.Before and after the heating of test paper, diffusivity change process of the test is as follows: when first time test paper diffusivity, mark is drawn in the region of test, paper heats 20min at 240 ~ 300 DEG C, when having heated rear test paper diffusivity, alignment mark tests this regional diffusion rate again.Same sample selects 10 some tests, the results are shown in Table 1.Table 1 result shows, cigarette mainstream flue gas CO burst size is negative correlativing relation with the diffusivity of the rear cigarette paper of baking, and after baking, diffusivity is larger, and its CO burst size is lower.Obtained real-time pore cigarette paper and regular-size cigarette paper are used for the production of cigarettes (being numbered C12) of a certain trade mark, the cigarette rolled is carried out to harmful components analysis and the sensory quality assessments such as main flume CO, tar, result is respectively in table 2, table 3.
The change of (afterwards) diffusivity before the baking of table 1 cigarette paper
| Cigarette paper sample | Diffusivity (cm/s) before baking | Diffusivity (cm/s) after baking | Increment rate |
| P1 | 1.56 | 3.22 | 106.4％ |
| P2 | 1.57 | 3.14 | 100.0％ |
| P3 | 1.60 | 3.09 | 93.1％ |
| P4 | 1.55 | 3.29 | 112.3％ |
| P5 | 1.57 | 3.32 | 111.5％ |
| P7 | 1.55 | 3.91 | 152.2％ |
| P8 | 1.52 | 3.85 | 153.2％ |
| P9 | 1.50 | 3.78 | 152.0％ |
| P10 | 1.53 | 4.03 | 163.4％ |
| P11 | 1.60 | 3.95 | 146.9％ |
| P12 | 1.57 | 3.87 | 146.5％ |
The conventional flue gas data of table 2 cigarette mainstream flue gas
Table 3 Sensory Quality of Cigarette is smoked panel test data (judging panel's number 9 people)
| Cigarette sample | Gloss (5) | Fragrance (32) | Coordinate (6) | Assorted gas (12) | Excitant (20) | Pleasant impression (25) | Add up to |
| C1 | 5.0 | 30.0 | 5.1 | 10.9 | 17.7 | 22.2 | 90.9 |
| C2 | 5.0 | 30.0 | 5.1 | 10.8 | 17.7 | 22.2 | 90.8 |
| C3 | 5.0 | 30.0 | 5.0 | 10.7 | 17.7 | 22.1 | 90.5 |
| C4 | 5.0 | 30.0 | 5.1 | 10.8 | 17.8 | 22.3 | 91.0 |
| C5 | 5.0 | 30.0 | 5.0 | 10.8 | 17.7 | 22.1 | 90.7 |
| C6 | 5.0 | 29.3 | 5.0 | 10.7 | 17.5 | 22.0 | 89.5 |
| C7 | 5.0 | 30.0 | 5.1 | 10.8 | 17.7 | 22.3 | 91.0 |
| C8 | 5.0 | 30.0 | 5.1 | 10.9 | 17.8 | 22.2 | 91.0 |
| C9 | 5.0 | 30.0 | 5.0 | 10.8 | 17.8 | 22.2 | 90.8 |
| C10 | 5.0 | 30.0 | 5.1 | 10.9 | 17.8 | 22.3 | 91.0 |
| C11 | 5.0 | 30.1 | 5.0 | 10.8 | 17.7 | 22.2 | 90.7 |
| C12 | 5.0 | 30.1 | 5.1 | 10.9 | 17.8 | 22.3 | 91.1 |
Claims (10)
1. a real-time pore cigarette paper, is characterized in that, adding in described cigarette paper has MOF material, and MOF material accounts for 2% ~ 8% of cigarette paper weight; The particle diameter of described MOF material is the nano particle of 30 ~ 300nm.
2. real-time pore cigarette paper according to claim 1, is characterized in that, described MOF material is the mixture of MOF-Fe, MOF-Ca or MOF-Zn or wherein both or three.
3. real-time pore cigarette paper according to claim 2, is characterized in that, described MOF material accounts for 2% ~ 5% of cigarette paper weight.
4. real-time pore cigarette paper according to claim 1, is characterized in that, described cigarette paper be by described MOF material with comprise wood pulp, filler raw material by pull an oar papermaking, then add combustion adjuvant and be prepared from.
5. real-time pore cigarette paper according to claim 4, is characterized in that, described wood pulp main component is made up of softwood pulp and hardwood pulp; Described filler is calcium carbonate.
6. real-time pore cigarette paper according to claim 5, is characterized in that, described combustion adjuvant be selected from potassium citrate or natrium citricum one or both.
7. real-time pore cigarette paper according to claim 5, it is characterized in that, softwood pulp accounts for 15% ~ 35% of cigarette paper weight, and hardwood pulp accounts for 20% ~ 40% of cigarette paper quality, pearl filler accounts for 20% ~ 50% of cigarette paper weight, and combustion adjuvant accounts for 1% ~ 5% of cigarette paper weight.
8. a purposes for the real-time pore cigarette paper described in any one of claim 1-7, it is for reducing cigarette mainstream flue gas CO and releasing content of coke tar simultaneously.
9. a purposes for the real-time pore cigarette paper described in any one of claim 1-7, it is for reducing cigarette mainstream flue gas CO burst size.
10. a purposes for the real-time pore cigarette paper described in any one of claim 1-7, under the suction quality not affecting cigarette, simultaneously for reducing cigarette mainstream flue gas CO burst size.
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| CN110115395A (en) * | 2018-02-06 | 2019-08-13 | 湖南中烟工业有限责任公司 | It is a kind of thermally expand agent application, added with thermally expand agent burning type cigarette and its preparation |
| CN112779816A (en) * | 2020-12-24 | 2021-05-11 | 浙江华丰纸业科技有限公司 | Tar-reducing cigarette paper and preparation method thereof |
| WO2023098632A1 (en) * | 2021-12-02 | 2023-06-08 | 湖北中烟工业有限责任公司 | Carbonyl compound trapping agent and trapping device and detection method for carbonyl compound in output flue gas |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030089377A1 (en) * | 2001-11-15 | 2003-05-15 | Mohammad Hajaligol | Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles |
| CN101604580A (en) * | 2009-04-03 | 2009-12-16 | 中国科学院上海硅酸盐研究所 | Single one step of source compound decomposition method prepares the method for porous carbon electrode material |
| CN103556541A (en) * | 2013-10-18 | 2014-02-05 | 湖南中烟工业有限责任公司 | Cigarette paper with variable diffusion rate and pore structure and application thereof |
| CN104418315A (en) * | 2013-08-22 | 2015-03-18 | 苏州奥索特新材料有限公司 | Preparation method of ordered mesoporous carbon material with high specific surface area by using metal organic skeleton |
| CN104452479A (en) * | 2014-11-05 | 2015-03-25 | 中国烟草总公司郑州烟草研究院 | Compounded cigarette paper with aluminum foil layer and application method thereof |
-
2015
- 2015-08-12 CN CN201510492682.7A patent/CN105019298B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030089377A1 (en) * | 2001-11-15 | 2003-05-15 | Mohammad Hajaligol | Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles |
| CN101604580A (en) * | 2009-04-03 | 2009-12-16 | 中国科学院上海硅酸盐研究所 | Single one step of source compound decomposition method prepares the method for porous carbon electrode material |
| CN104418315A (en) * | 2013-08-22 | 2015-03-18 | 苏州奥索特新材料有限公司 | Preparation method of ordered mesoporous carbon material with high specific surface area by using metal organic skeleton |
| CN103556541A (en) * | 2013-10-18 | 2014-02-05 | 湖南中烟工业有限责任公司 | Cigarette paper with variable diffusion rate and pore structure and application thereof |
| CN104452479A (en) * | 2014-11-05 | 2015-03-25 | 中国烟草总公司郑州烟草研究院 | Compounded cigarette paper with aluminum foil layer and application method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110115395A (en) * | 2018-02-06 | 2019-08-13 | 湖南中烟工业有限责任公司 | It is a kind of thermally expand agent application, added with thermally expand agent burning type cigarette and its preparation |
| CN110115395B (en) * | 2018-02-06 | 2021-11-12 | 湖南中烟工业有限责任公司 | Application of thermal expansion agent, combustion type cigarette added with thermal expansion agent and preparation method of combustion type cigarette |
| CN108912340A (en) * | 2018-07-20 | 2018-11-30 | 河南中烟工业有限责任公司 | A kind of humectation type cigarette paper and preparation method thereof |
| CN108912340B (en) * | 2018-07-20 | 2021-04-20 | 河南中烟工业有限责任公司 | Moisture-retaining cigarette paper and preparation method thereof |
| CN112779816A (en) * | 2020-12-24 | 2021-05-11 | 浙江华丰纸业科技有限公司 | Tar-reducing cigarette paper and preparation method thereof |
| WO2023098632A1 (en) * | 2021-12-02 | 2023-06-08 | 湖北中烟工业有限责任公司 | Carbonyl compound trapping agent and trapping device and detection method for carbonyl compound in output flue gas |
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