CN105002784B - A kind of real-time pore cigarette paper and its preparation method and application - Google Patents
A kind of real-time pore cigarette paper and its preparation method and application Download PDFInfo
- Publication number
- CN105002784B CN105002784B CN201510494538.7A CN201510494538A CN105002784B CN 105002784 B CN105002784 B CN 105002784B CN 201510494538 A CN201510494538 A CN 201510494538A CN 105002784 B CN105002784 B CN 105002784B
- Authority
- CN
- China
- Prior art keywords
- cigarette paper
- cigarette
- mof
- paper
- kilograms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a kind of real-time pore cigarette paper and its application, are mainly used in reducing HCN burst size in cigarette mainstream flue gas, and the suction quality of cigarette are not had a negative impact.The present invention passes through MOF material used in cigarette paper production process, can reduce by more than 15% using the cigarette mainstream flue gas HCN burst size of the cigarette paper, obtain high suction quality.And the cigarette paper preparation method is simple, low cost, can industrialized production.
Description
Technical field
The present invention relates to a kind of real-time pore cigarette paper and its preparation method and application, belongs to cigarette preparation field.
Technical background
Contain substantial amounts of harmful components in cigarette smoke, how the harmful components effectively reduced in cigarette smoke are always cigarette
The study hotspot of careless industry.Thank to sword equality people to propose from CO, hydrogen cyanide (HCN), 4- (methyl nitrosamino group) -1- (3- pyridine
Base) -1- butanone (NNK), ammonia (NH3), benzo [a] pyrene (B [a] P), phenol, 7 kinds of most representational nuisances such as crotonaldehyde
Matter carrys out the harmfulness of evaluating cigarette.HCN is a kind of A class violent in toxicity of high volatile, and the threshold value to human body is only 10ppm.Cigarette
In HCN mostly come from the burning of nitrate and nitrogen-containing compound in tobacco, its content is about 30-300 μ g/ and props up.In flue gas
HCN be absorbed into rapidly body through respiratory tract, combined with high swage cytochrome oxidase and become the high swage cell color of cyaniding
Plain oxidizing ferment, loses the effect of transmission oxygen, causes histanoxia and be poisoned.
The method for reducing HCN at present mainly has filter tip ventilation dilution method, absorption process, absorption method and catalytic oxidation.Filter tip
Ventilation dilution method is to dilute main flume by introducing air, reaches the purpose for reducing harmful components.Absorption process is mainly profit
Soda acid is occurred to interact with alkaline matter with HCN；Absorption method mainly uses adsorbent or contains transition metal ion-modified
Adsorbent and HCN occur physical absorption or Absorptive complex wave to reduce the purpose of HCN burst size；Catalysis oxidation is mainly used
HCN deep oxidation is generated CO by catalyst2With NOx etc..Although above-mentioned technology can obtain reduction HCN burst size to a certain extent
Effect, but which all can cause significantly negative effect to the organoleptic quality of cigarette, it is difficult to promote the use of in industrial enterprise.
Content of the invention
The deficiency existed for above-mentioned prior art and the demand of industry development, first purpose of the present invention are to provide
A kind of with variable diffusivity and pore structure, with real-time pore function, for can obtain high suction product in cigarette simultaneously
The cigarette paper of matter.
Another object of the present invention is to providing, a kind of preparation method is simple, the preparation side of the above-mentioned cigarette paper of low cost
Method.
Another object of the present invention is to the above-mentioned concrete application with variable diffusivity Yu the cigarette paper of pore structure is provided,
For reducing HCN burst size in cigarette mainstream flue gas, while poisonous and harmful element will not be produced during cigarette burning.
Further object of the present invention is, provides above-mentioned concrete with the cigarette paper of pore structure with variable diffusivity
Application, while for reducing HCN burst size in cigarette mainstream flue gas, does not affect cigarette smoking quality.
Another object of the present invention is to provide a kind of HCN of real-time pore cigarette paper in cigarette mainstream flue gas are reduced releasing
High-volume, increase the application in the cigarette of diffusivity, and the cigarette smoking quality of the cigarette paper is high, produce nothing poisonous and harmful element.
Technical scheme：
A kind of real-time pore cigarette paper, the cigarette paper include MOF material, MOF material account for cigarette paper weight 1%～
8%；The particle diameter of described MOF material is 40～350nm.
MOF material preferably accounts for the 2%～4% of cigarette paper weight.
MOF material further preferably accounts for the 2.5%～3.5% of cigarette paper weight.
Described MOF material is one or more in MOF-Fe, MOF-Mn or MOF-Zn.
Described MOF material obtains having cause in real time preferably with including the raw material including wood pulp, filler by being beaten papermaking
The cigarette paper of hole function.
The wood pulp is preferably made up of softwood pulp and hardwood pulp, and softwood pulp accounts for the 9%～22% of cigarette paper weight,
Hardwood pulp accounts for the 22%～37% of cigarette paper quality.
Described filler is preferably calcium carbonate, and calcium carbonate accounts for the 23%～53% of cigarette paper weight.
Further preferably add account for cigarette paper weight 2%～4% combustion adjuvant in cigarette paper.
The combustion adjuvant is preferably selected from one or two in potassium citrate or sodium citrate.
The preparation method of above-mentioned real-time pore cigarette paper, wood pulp, MOF material and filler are mixed, and carry out being beaten, papermaking,
Add micro combustion adjuvant again, obtain final product cigarette paper.
Described combustion adjuvant preferably in the form of a solution, is added on cigarette paper in applying glue operation.
The purposes of above-mentioned real-time pore cigarette paper, uses it for reducing cigarette mainstream flue gas HCN burst size.
The purposes of above-mentioned real-time pore cigarette paper, under the suction quality for not affecting cigarette, is simultaneously used for reducing cigarette
Main flume HCN burst size.
Beneficial effects of the present invention：
In the prior art, the fields such as the preparation of battery are mainly used in metal-organic framework material.The present invention is first
By adding MOF material in regular-size cigarette paper, but inventor is had found in experimentation, and after adding MOF material, HCN contains
Amount does not have horse back and has declined, and inventor does not know it is what reason yet, just finds through research repeatedly, needs in the solution of the present invention
Further to control content and the particle size of MOF material, just can reduce the burst size of HCN after cigarette paper is added, this
Bright by MOF material used in cigarette paper, and by strictly controlling its content and particle diameter, obtained with real-time pore effect
Cigarette paper, by the cigarette paper be used for cigarette in, not only unexpectedly obtain the diffusivity of significantly larger than prior art cigarette paper,
HCN burst size in main flume is substantially reduced, and is found through experiments, different from the method for existing removal HCN, using the present invention
Cigarette paper, impact will not be produced on the suction quality of cigarette.And in experimentation, it is found that the present invention can significantly improve cigarette
The diffusivity of cigarette paper near line is carbonized in combustion process, changes the pore structure of cigarette paper, this is had the volume of variable diffusivity
Cigarette paper is used for preparing cigarette, can significantly reduce HCN burst size in cigarette mainstream flue gas, and relatively common cigarette paper cigarette, the range of decrease exist
More than 15%；Meanwhile, the method also has the advantage of a protrusion with respect to traditional flue gas dilution method to be with the addition of after MOF material
Cigarette smoking quality is high, produces nothing poisonous and harmful element, with the extremely strong value that promotes the use of.And the system of cigarette paper of the present invention
Preparation Method is simple, and low cost is appropriate to industrialized production and utilization.
Specific embodiment
Following examples are intended to the present invention, rather than the restriction further to the scope of the present invention are described.
Comparative example 1
150 kilograms of softwood pulps and 250 kilograms of hardwood pulps are taken, is added 300 kilograms of calcium carbonate that beating papermaking is carried out, prepares
Mass percent is 8% potassium citrate and 3% sodium citrate additive package solution, and the additive solution for preparing is existed
The applying glue workshop section of cigarette paper production is uniformly added in cigarette paper by metering stick type film transferring sizing applicator, routinely papermaking process
Production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2, air permeability 60CORESTA, additive is in cigarette paper
In addition be 1.00g m-2.This is control sample cigarette paper (numbering is P1).Spread using the automatic paper of Sodim company
The diffusivity of rate instrument test paper, test result are shown in Table 1.Prepared P1 cigarette paper is manufactured experimently the cigarette (numbering C1) of a certain trade mark,
Cigarette to rolling carries out the analysis of main flume HCN burst size and sensory quality assessment, is as a result shown in Table 2, table 3 respectively.
Comparative example 2
150 kilograms of softwood pulps and 250 kilograms of hardwood pulps are taken, 20 kilograms of particle diameters are the MOF-Fe of 10-30nm, add carbon
300 kilograms of sour calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate mixing interpolation
Agent solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniform by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2,
Air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2.This is that (numbering is control sample cigarette paper
P2).Using the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, test result is shown in Table 1.By prepared P2
The cigarette (numbering C2) of a certain trade mark manufactured experimently by cigarette paper, and the cigarette to rolling carries out the analysis of main flume HCN burst size and sense organ
Quality evaluation, is as a result shown in Table 2, table 3 respectively.
Comparative example 3
150 kilograms of softwood pulps and 250 kilograms of hardwood pulps are taken, 20 kilograms of particle diameters are the MOF-Fe of 400-600nm, add
300 kilograms of calcium carbonate carries out beating papermaking, prepares potassium citrate that mass percent is 8% and 3% sodium citrate mixing adds
Plus agent solution, it is equal that the applying glue workshop section that the additive solution for preparing is produced in cigarette paper passes through metering stick type film transferring sizing applicator
Even be added in cigarette paper, routinely papermaking process production cigarette paper, on equipment control cigarette paper parameter be：Quantitative 32g m-2, air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2.This is that (numbering is control sample cigarette paper
P3).Using the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, test result is shown in Table 1.By prepared P3
The cigarette (numbering C3) of a certain trade mark manufactured experimently by cigarette paper, and the cigarette to rolling carries out the analysis of main flume HCN burst size and sense organ
Quality evaluation, is as a result shown in Table 2, table 3 respectively.
Comparative example 4
150 kilograms of softwood pulps and 250 kilograms of hardwood pulps are taken, 5 kilograms of particle diameters are the MOF-Fe of 40-350nm, add carbon
300 kilograms of sour calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate mixing interpolation
Agent solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniform by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2,
Air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2.This is that (numbering is control sample cigarette paper
P4).Using the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, test result is shown in Table 1.By prepared P4
The cigarette (numbering C4) of a certain trade mark manufactured experimently by cigarette paper, and the cigarette to rolling carries out the analysis of main flume HCN burst size and sense organ
Quality evaluation, is as a result shown in Table 2, table 3 respectively.
Comparative example 5
150 kilograms of softwood pulps and 250 kilograms of hardwood pulps are taken, 70 kilograms of particle diameters are the MOF-Fe of 40-350nm, add
300 kilograms of calcium carbonate carries out beating papermaking, prepares potassium citrate that mass percent is 8% and 3% sodium citrate mixing adds
Plus agent solution, it is equal that the applying glue workshop section that the additive solution for preparing is produced in cigarette paper passes through metering stick type film transferring sizing applicator
Even be added in cigarette paper, routinely papermaking process production cigarette paper, on equipment control cigarette paper parameter be：Quantitative 32g m-2, air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2.This is that (numbering is control sample cigarette paper
P5).Using the diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, test result is shown in Table 1.By prepared P5
The cigarette (numbering C5) of a certain trade mark manufactured experimently by cigarette paper, and the cigarette to rolling carries out the analysis of main flume HCN burst size and sense organ
Quality evaluation, is as a result shown in Table 2, table 3 respectively.
Comparative example 6
MOF-Fe material of the obtained particle diameter for 40-350nm is added to trial-production cigarette according to the ratio that addition is 5%
Filter tip in, using in comparative example cigarette paper P1 manufacture experimently cigarette, obtain in filter tip add MOF-Fe material cigarette C6,
The cigarette for rolling carries out the analysis of main flume HCN burst size and sensory quality assessment, is as a result shown in Table 2, table 3 respectively.
Embodiment 1
150 kilograms of softwood pulps, 250 kilograms of hardwood pulps, 20 kilograms of particle diameters are taken for the MOF-Fe of 40-350nm, add carbon
300 kilograms of sour calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate mixing interpolation
Agent solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniform by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2,
Air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P7).Using Sodim company
The diffusivity of automatic paper diffusivity instrument test paper, test result are shown in Table 1.Prepared P7 cigarette paper is manufactured experimently a certain trade mark
Cigarette (numbering C7), the cigarette to rolling carry out the analysis of main flume HCN burst size and sensory quality assessment, are as a result shown in Table respectively
2nd, table 3.
Embodiment 2
120 kg softwood pulp, 220 kilograms of hardwood pulps, 20 kilograms of particle diameters are taken for the MOF-Zn of 40-350nm, add carbon
300 kilograms of sour calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate mixing interpolation
Agent solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniform by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2,
Air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P8).Using Sodim company
The diffusivity of automatic paper diffusivity instrument test paper, test result are shown in Table 1.Prepared P8 cigarette paper is manufactured experimently a certain trade mark
Cigarette (numbering C8), the cigarette to rolling carry out the analysis of main flume HCN burst size and sensory quality assessment, are as a result shown in Table respectively
2nd, table 3.
Embodiment 3
110 kilograms of softwood pulps, 200 kilograms of hardwood pulps, 20 kilograms of particle diameters are taken for the MOF-Mn of 40-350nm, add carbon
280 kilograms of sour calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate mixing interpolation
Agent solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniform by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2,
Air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P9).Using Sodim company
The diffusivity of automatic paper diffusivity instrument test paper, test result are shown in Table 1.Prepared P9 cigarette paper is manufactured experimently a certain trade mark
Cigarette (numbering C9), the cigarette to rolling carry out the analysis of main flume HCN burst size and sensory quality assessment, are as a result shown in Table respectively
2nd, table 3.
Embodiment 4
170 kilograms of softwood pulps, 260 kilograms of hardwood pulps, 10 kilograms of MOF-Fe, 16 kilograms of MOF-Zn are taken, adds carbonic acid
400 kilograms of calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate additive package
Solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniformly added by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2, thoroughly
Manner 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P10).Using the complete of Sodim company
The diffusivity of automatic paper diffusivity instrument test paper, test result are shown in Table 1.Prepared P10 cigarette paper is manufactured experimently a certain trade mark
Cigarette (numbering C10), the cigarette to rolling carry out the analysis of main flume HCN burst size and sensory quality assessment, as a result see respectively
Table 2, table 3.
Embodiment 5
140 kilograms of softwood pulps, 240 kilograms of hardwood pulps, 15 kilograms of MOF-Fe, 8 kilograms of MOF-Mn are taken, adds calcium carbonate
290 kilograms carry out beating papermaking, prepare potassium citrate that mass percent is 8% and 3% sodium citrate additive package molten
Liquid, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper is uniformly added by metering stick type film transferring sizing applicator
To in cigarette paper, routinely papermaking process produces cigarette paper, and on equipment, control cigarette paper parameter is：Quantitative 32g m-2, breathe freely
Degree 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P11).Using Sodim company complete from
The diffusivity of paper tested by dynamic paper diffusivity instrument, and test result is shown in Table 1.Prepared P11 cigarette paper is manufactured experimently the volume of a certain trade mark
Cigarette (numbering C11), the cigarette to rolling carry out the analysis of main flume HCN burst size and sensory quality assessment, are as a result shown in Table respectively
2nd, table 3.
Embodiment 6
150 kilograms of softwood pulps, 250 kilograms of hardwood pulps, 10 kilograms of MOF-Mn, 17 kilograms of MOF-Zn are taken, adds carbonic acid
300 kilograms of calcium carries out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate additive package
Solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper are uniformly added by metering stick type film transferring sizing applicator
It is added in cigarette paper, routinely papermaking process production cigarette paper, on equipment, control cigarette paper parameter is：Quantitative 32g m-2, thoroughly
Manner 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P12).Using the complete of Sodim company
The diffusivity of automatic paper diffusivity instrument test paper, test result are shown in Table 1.Prepared P12 cigarette paper is manufactured experimently a certain trade mark
Cigarette (numbering C12), the cigarette to rolling carry out the analysis of main flume HCN burst size and sensory quality assessment, as a result see respectively
Table 2, table 3.
Embodiment 7
Take 170 kilograms of softwood pulps, 260 kilograms of hardwood pulps, 8 kilograms of MOF-Fe, 10 kilograms of MOF-Zn, 9 kilograms of MOF-
Mn, adds 400 kilograms of calcium carbonate to carry out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate
Additive package solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper is applied by measuring bar type film transfer
Glue machine is uniformly added in cigarette paper, routinely papermaking process production cigarette paper, and on equipment, control cigarette paper parameter is：Quantitative
32g m-2, air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P13).Utilize
The diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, test result are shown in Table 1.Prepared P13 cigarette paper is tried
The cigarette (numbering C13) of a certain trade mark is made, the cigarette to rolling carries out the analysis of main flume HCN burst size and aesthetic quality comments
Valency, is as a result shown in Table 2, table 3 respectively.
Embodiment 8
Take 130 kilograms of softwood pulps, 240 kilograms of hardwood pulps, 10 kilograms of MOF-Fe, 6 kilograms of MOF-Zn, 6 kilograms of MOF-
Mn, adds 300 kilograms of calcium carbonate to carry out beating papermaking, and preparation mass percent is 8% potassium citrate and 3% sodium citrate
Additive package solution, the applying glue workshop section that the additive solution for preparing is produced in cigarette paper is applied by measuring bar type film transfer
Glue machine is uniformly added in cigarette paper, routinely papermaking process production cigarette paper, and on equipment, control cigarette paper parameter is：Quantitative
32g m-2, air permeability 60CORESTA, addition of the additive in cigarette paper are 1.00g m-2(numbering is P14).Utilize
The diffusivity of the automatic paper diffusivity instrument test paper of Sodim company, test result are shown in Table 1.Prepared P14 cigarette paper is tried
The cigarette (numbering C14) of a certain trade mark is made, the cigarette to rolling carries out the analysis of main flume HCN burst size and aesthetic quality comments
Valency, is as a result shown in Table 2, table 3 respectively.
The change of (afterwards) diffusivity before the baking of 1 cigarette paper of table
| Cigarette paper sample | Diffusivity (cm/s) before baking | Diffusivity (cm/s) after baking | Increment rate |
| P1 | 1.56 | 3.19 | 104.5% |
| P2 | 1.59 | 3.23 | 103.1% |
| P3 | 1.55 | 3.07 | 98.1% |
| P4 | 1.60 | 3.15 | 96.9% |
| P5 | 1.54 | 3.10 | 101.3% |
| P7 | 1.56 | 3.88 | 148.7% |
| P8 | 1.58 | 3.76 | 138.0% |
| P9 | 1.60 | 3.79 | 136.9% |
| P10 | 1.59 | 3.69 | 132.1% |
| P11 | 1.54 | 3.86 | 150.6% |
| P12 | 1.51 | 4.05 | 168.2% |
| P13 | 1.58 | 4.16 | 163.3% |
| P14 | 1.54 | 3.96 | 157.1% |
2 cigarette mainstream flue gas HCN burst size of table
3 Sensory Quality of Cigarette of table is smoked panel test data (9 people of judging panel's number)
| Cigarette sample | Gloss (5) | Fragrance (32) | Coordinate (6) | Miscellaneous gas (12) | Excitant (20) | Pleasant impression (25) | Total |
| C1 | 5.0 | 30.0 | 5.1 | 10.8 | 17.7 | 22.2 | 90.8 |
| C2 | 5.0 | 29.8 | 5.1 | 10.9 | 17.7 | 22.2 | 90.7 |
| C3 | 5.0 | 29.9 | 5.1 | 10.8 | 17.6 | 22.1 | 90.5 |
| C4 | 5.0 | 29.6 | 5.1 | 10.8 | 17.7 | 22.0 | 90.2 |
| C5 | 5.0 | 29.7 | 5.1 | 10.8 | 17.7 | 22.2 | 90.5 |
| C6 | 5.0 | 29.2 | 5.0 | 10.8 | 17.5 | 22.1 | 89.6 |
| C7 | 5.0 | 30.0 | 5.1 | 10.8 | 17.8 | 22.3 | 91.0 |
| C8 | 5.0 | 30.0 | 5.1 | 10.8 | 17.9 | 22.3 | 91.1 |
| C9 | 5.0 | 30.0 | 5.1 | 10.8 | 17.9 | 22.3 | 91.1 |
| C10 | 5.0 | 30.0 | 5.1 | 10.7 | 17.7 | 22.2 | 90.7 |
| C11 | 5.0 | 30.0 | 5.1 | 10.8 | 17.8 | 22.3 | 91.0 |
| C12 | 5.0 | 30.0 | 5.1 | 10.9 | 17.9 | 22.3 | 91.2 |
| C13 | 5.0 | 30.0 | 5.1 | 10.8 | 17.8 | 22.4 | 91.1 |
| C14 | 5.0 | 30.0 | 5.1 | 10.8 | 17.7 | 22.2 | 90.8 |
Claims (13)
1. a kind of real-time pore cigarette paper, it is characterised in that the cigarette paper includes MOF material, and MOF material accounts for cigarette paper weight
1%～8%；40～the 350nm of particle diameter of the MOF material.
2. cigarette paper according to claim 1, it is characterised in that MOF material accounts for the 2%～4% of cigarette paper weight.
3. cigarette paper according to claim 1, it is characterised in that MOF material accounts for the 2.5%～3.5% of cigarette paper weight.
4. the cigarette paper according to any one of claim 1-3, it is characterised in that described MOF material is MOF-Fe, MOF-
One or more in Mn or MOF-Zn.
5. cigarette paper according to claim 4, it is characterised in that described MOF material with including including wood pulp, filler
Raw material obtains the cigarette paper with real-time pore function by being beaten papermaking.
6. cigarette paper according to claim 5, it is characterised in that the wood pulp is made up of softwood pulp and hardwood pulp,
Softwood pulp accounts for the 9%～22% of cigarette paper weight, and hardwood pulp accounts for the 22%～37% of cigarette paper quality.
7. cigarette paper according to claim 5, it is characterised in that described filler is calcium carbonate, calcium carbonate accounts for cigarette paper weight
The 23%～53% of amount.
8. cigarette paper according to claim 5, it is characterised in that add in cigarette paper further and account for cigarette paper weight
2%～4% combustion adjuvant.
9. cigarette paper according to claim 8, it is characterised in that the combustion adjuvant is in potassium citrate or sodium citrate
One or two.
10. the preparation method of the cigarette paper described in any one of claim 1-9, it is characterised in that by wood pulp, MOF material and fill out
Material mixing, carries out being beaten, papermaking, then adds combustion adjuvant, obtains final product cigarette paper.
11. preparation methods according to claim 10, it is characterised in that described combustion adjuvant in the form of a solution, in applying glue
It is added on cigarette paper in operation.
The purposes of the real-time pore cigarette paper described in a kind of 12. any one of claim 1-9, which is used for reducing cigarette mainstream flue gas
HCN burst size.
The purposes of the real-time pore cigarette paper described in a kind of 13. any one of claim 1-9, in the suction quality for not affecting cigarette
Under, it is simultaneously used for reducing cigarette mainstream flue gas HCN burst size.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510494538.7A CN105002784B (en) | 2015-08-12 | 2015-08-12 | A kind of real-time pore cigarette paper and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510494538.7A CN105002784B (en) | 2015-08-12 | 2015-08-12 | A kind of real-time pore cigarette paper and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105002784A CN105002784A (en) | 2015-10-28 |
| CN105002784B true CN105002784B (en) | 2017-03-08 |
Family
ID=54375628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510494538.7A Active CN105002784B (en) | 2015-08-12 | 2015-08-12 | A kind of real-time pore cigarette paper and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105002784B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912340B (en) * | 2018-07-20 | 2021-04-20 | 河南中烟工业有限责任公司 | Moisture-retaining cigarette paper and preparation method thereof |
| CN109012606B (en) * | 2018-07-20 | 2021-05-18 | 河南中烟工业有限责任公司 | MOF-Zn @ molecular sieve composite material, preparation method thereof and application thereof in cigarettes |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6817365B2 (en) * | 2001-11-15 | 2004-11-16 | Philip Morris Usa Inc. | Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles |
| US9307790B2 (en) * | 2011-08-01 | 2016-04-12 | Massachusetts Institute Of Technology | Porous catalytic matrices for elimination of toxicants found in tobacco combustion products |
| CN104418315A (en) * | 2013-08-22 | 2015-03-18 | 苏州奥索特新材料有限公司 | Preparation method of ordered mesoporous carbon material with high specific surface area by using metal organic skeleton |
| CN103882778B (en) * | 2014-04-02 | 2016-08-17 | 湖南中烟工业有限责任公司 | A kind of reduce the preparation method of the pore cigarette paper of the harmful substance burst size such as CO in cigarette mainstream flue gas |
-
2015
- 2015-08-12 CN CN201510494538.7A patent/CN105002784B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105002784A (en) | 2015-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104053369B (en) | Paper filled with tobacco particle | |
| CN102217783B (en) | Thin sheet for cigarette, preparation method thereof and cigarette | |
| CN104428466B (en) | There is the cigarette paper of the breathability of improvement | |
| CN105002784B (en) | A kind of real-time pore cigarette paper and its preparation method and application | |
| CN105019298B (en) | A kind of real-time pore cigarette paper and its application in main flume CO and releasing content of coke tar is reduced | |
| CN106723282A (en) | A kind of heating of amount of smoke high is not burnt the preparation method of tobacco product | |
| CN106376968A (en) | Cigarette with recreated cut tobacco leaves and cut stems as cut tobacco and filter tip containing nano granular material | |
| DE102010032814B4 (en) | Cigarette paper with high diffusion capacity during thermal decomposition, cigarette, process for producing a cigarette paper and use of a water-soluble salt | |
| CN101775759A (en) | Cigarette paper additive, preparation method and application thereof | |
| CN103882778B (en) | A kind of reduce the preparation method of the pore cigarette paper of the harmful substance burst size such as CO in cigarette mainstream flue gas | |
| CN113550175B (en) | Cigarette paper, preparation method thereof and cigarette product | |
| CN103556541B (en) | A kind of cigarette paper and application thereof with variable diffusivity and pore structure | |
| CN102587198B (en) | Functional cigarette paper | |
| CN104188090A (en) | Method for reducing carbonic oxide emission of paper-making reconstituted tobacco | |
| CN103082395A (en) | Method for reducing releasing quantity of carbon monoxide (CO) paper-making process reproducing tobacco leaf smoke | |
| US9675104B2 (en) | Cigarette paper additive having harm reduction function and application thereof | |
| US9775378B2 (en) | Cigarette paper comprising flaky filler | |
| CN101792987A (en) | Cigarette paper and preparation method thereof | |
| CN107927899A (en) | A kind of method for reducing carbon monoxide release amount of papermaking reconstituted tobacco | |
| CN102217792A (en) | Tobacco sheet and cigarette | |
| Cvetkovic et al. | Catalytic reduction of NO and NOx content in tobacco smoke | |
| CN107080287A (en) | A kind of activated carbon dipping method of modifying and application | |
| CN103462211A (en) | Ignitable smoking tobacco substitute capable of reducing tar yield and hazardous substance content of cigarettes and preparation method thereof | |
| CN105064119A (en) | Cigarette with low CO and tar release amount | |
| CN105064120A (en) | Application of renewable plant fiber, cigarette paper with hole forming function through thermal cracking, and preparation method and application of cigarette paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |