CN105018004A - Holder adhesive for cellulose acetate cigarette tipping paper - Google Patents
Holder adhesive for cellulose acetate cigarette tipping paper Download PDFInfo
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- CN105018004A CN105018004A CN201510361968.1A CN201510361968A CN105018004A CN 105018004 A CN105018004 A CN 105018004A CN 201510361968 A CN201510361968 A CN 201510361968A CN 105018004 A CN105018004 A CN 105018004A
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- tipping paper
- cellulose acetate
- cigarette tipping
- mouth glue
- glue
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Abstract
The invention discloses a holder adhesive for cellulose acetate cigarette tipping paper. The holder adhesive is prepared from 70-90% of a VAE emulsion and 10-30% of an additive, and the additive comprises polyvinyl alcohol, a plasticizer, a tackifier, an antifoaming agent and a bactericide. The holder adhesive has the characteristics of environmental protection, no boric acid, excellent wet viscosity, excellent in-machine stability, and realization of clean running of a machine.
Description
Technical field
The present invention relates to a kind of cigarette tipping paper and connect mouth glue technical field, particularly relating to a kind of cellulose acetate cigarette tipping paper with connecing mouth glue.
Background technology
Tipping paper is a kind of volume smoking material, for the filter-tip external parcel of cigarette, connects the effect that mouth glue plays bonding filter tip, cigarette and tipping paper.
The development of domestic tobacco industry has driven the development of relevant raw and auxiliary material, the application on cigarette of novel material, novel process is had higher requirement to cigarette glue, wherein cellulose acetate cigarette tipping paper is exactly an example, cellulose acetate cigarette tipping paper with the difference of original cigarette tipping paper is: this tipping paper is made up of cellulose acetate, and common tipping paper is natural plant fibre processes; This tipping paper smooth surface, present transparent or semitransparent shape, as plastics film shape, fiber is fine and close, the contact angle of this tipping paper and water base adhesive greatly and glue be difficult to penetrate in paper, end-to-end jointing nozzle glue proposes very high requirement.
Original problem connecing mouth glue and run into when bonding cellulose acetate cigarette tipping paper: machine operating speed is very low or cannot be bonding, when machine operating speed is slightly high, can produce that rubbing is bad, the phenomenon such as bubble wrinkle and gas leakage; Secondly, bonding rear wait glue complete drying after, tipping paper easily produces buckling phenomena, and this is owing to permeating uneven after this kind of technique tipping paper gluing and the hardness of paper large, causes tipping paper to be out of shape to cause in glue dries process.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind ofly has environmental protection, characteristic without boric acid, have simultaneously excellent wet viscosity, upper machine stability and machines clean can be made to run cellulose acetate cigarette tipping paper with connecing mouth glue.
For solving the problem, the present invention adopts following technical scheme:
A kind of cellulose acetate cigarette tipping paper is with connecing mouth glue, and be made up of following raw material: VAE emulsion and additive, described additive includes polyvinyl alcohol, softening agent, tackifier, defoamer, sterilant; Described raw material is frequently made up of following weight percent: VAE emulsion 70-90% and additive 10%-30%.
Further, the second-order transition temperature of described emulsion is 0 DEG C-20 DEG C, and solid content is 50%-60%.
Further, described polyvinyl alcohol alcoholysis degree is 80-90%, polymerization degree 500-2000.
Further, described softening agent is made up of 2,2,4-trimethylammonium-1,3-pentanediol diisobutyrate, vanay, epoxy soybean oil and triethyl citrate.
Further, described tackifier are made up of ester gum, polyvalent alcohol hydrogenated wood rosin glycerol ester and guar gum.
Further, described defoamer is mineral oil antifoam agent and silicone antifoam agent.
Further, described sterilant is made up of 1,2-benzisothiazole base-3 (2H)-one, 2-methyl-3 (2H)-isothiazolinone and 5-chloro-2-methyl-2H-isothiazoline-3-ketone.
Further, described cellulose acetate cigarette tipping paper is applicable to the tipping of cellulose acetate cigarette tipping paper and the cigarette machine of roller coating gluing with connecing mouth glue.
The invention has the beneficial effects as follows: the tipping being applicable to cellulose acetate tipping paper; Be applicable to the cigarette equipment of roller coating gluing, equipment comprises: Protos 70, the Protos 1-8 of German Hao Ni company, Protos 90E, Protos 2-2; The GD-121 of GD company of Italy; The PASSIM 7000 and 8000 of Pa Ximu company of Britain; ZJ17, ZJ112, ZJ116 and ZJ118 of Changde Yan Ji company limited.This connects mouth glue and meets the relevant regulations of tobacco industry to water base cigarette glue.Original mouth glue Dichlorodiphenyl Acetate Mierocrystalline cellulose cigarette tipping paper that connects is difficult to wetting, and glue is very large to the contact angle of this tipping paper, and glue is difficult to sprawl on tipping paper surface; By the adjusting and optimizing to formula, this cellulose acetate tipping paper can be good at soaking with connecing mouth glue Dichlorodiphenyl Acetate Mierocrystalline cellulose tipping paper, and contact angle diminishes, and makes bonding more firm.Connect mouth glue compared to original, this cellulose acetate tipping paper is larger with the wet viscous force connecing mouth glue, makes after tipping paper gluing, before the non-drying of glue, tipping paper and filter tip also can be made to have good bonding force, thus ensure that the operation of machine.This cellulose acetate tipping paper is stronger with the anti-shear ability connecing mouth glue, and under high shear, running roller band glue is stablized, and glue does not splash, whirl coating, and gluing is even.This cellulose acetate tipping paper is faster with connecing mouth glue rate of drying, and after glue drying, particle is comparatively hard, is easy to be brushed by the brush on machine from tipping paper cutter and drum, thus ensure that the clean operation of machine.
Embodiment
Embodiment 1
Prepare polyvinyl alcohol water solution, join in stirring tank, start stirring by 800 grams of water, slowly added wherein by polyvinyl alcohol 200 grams, be stirred to and mix, be heated to 85-90 DEG C and keep this temperature 2 hours, cooling discharge, obtains polyvinyl alcohol water solution.VAE emulsion 850 grams is added in stirring tank, then start stirring, add defoamer 3 grams, stir 15 minutes, then above ready-made polyvinyl alcohol water solution 80 grams is added, after stirring half an hour, add 30 grams, softening agent, stir 1 hour, then tackifier 50 grams are added, stir after 1 hour, add 0.1 gram, sterilant and stir after half an hour, adjusting viscosity is to the scope discharging set.
The formula of embodiment 1 is as follows:
| Starting material title | Usage quantity/% |
| VAE emulsion | 81.2 |
| Polyvinyl alcohol | 3.6 |
| 2,2,4-trimethylammonium-1,3-pentanediol diisobutyrate | 1.2 |
| Vanay | 0.8 |
| Epoxy soybean oil | 1.0 |
| Triethyl citrate | 0.8 |
| Ester gum | 3.8 |
| Polyvalent alcohol hydrogenated wood rosin glycerol ester | 2.5 |
| Guar gum | 0.5 |
| Polydimethylsiloxane | 0.1 |
| White mineral oil | 0.2 |
| 1,2-benzisothiazole base-3 (2H)-one | 0.003 |
| 2-methyl-3 (2H)-isothiazolinone | 0.001 |
| 5-chloro-2-methyl-2H-isothiazoline-3-ketone | 0.001 |
| Water | 4.3 |
The conventional index wherein connecing mouth glue is as follows:
| Conventional sense project | Detected result |
| Outward appearance | White uniformity emulsion |
| Viscosity | 5520 |
| Evaporation residuum (%) | 52.7 |
| PH value | 4.4 |
Embodiment 2
Prepare polyvinyl alcohol water solution, join in stirring tank, start stirring by 400 grams of water, slowly added wherein by polyvinyl alcohol 100 grams, be stirred to and mix, be heated to 85-90 DEG C and keep this temperature 2 hours, cooling discharge, obtains polyvinyl alcohol water solution.VAE emulsion 800 grams is added in stirring tank, then start stirring, add defoamer 2.5 grams, stir 15 minutes, then above ready-made polyvinyl alcohol water solution 60 grams is added, after stirring half an hour, add 26 grams, softening agent, stir 1 hour, then tackifier 35 grams are added, stir after 1 hour, add 0.1 gram, sterilant and stir after half an hour, adjusting viscosity is to the scope discharging set.
The formula of embodiment 2 is as follows:
| Starting material title | Usage quantity/% |
| VAE emulsion | 81.4 |
| Polyvinyl alcohol | 3.7 |
| 2,2,4-trimethylammonium-1,3-pentanediol diisobutyrate | 1.0 |
| Vanay | 1.0 |
| Epoxy soybean oil | 1.0 |
| Triethyl citrate | 0.8 |
| Ester gum | 3.0 |
| Polyvalent alcohol hydrogenated wood rosin glycerol ester | 3.1 |
| Guar gum | 0.7 |
| Polydimethylsiloxane | 0.1 |
| White mineral oil | 0.2 |
| 1,2-benzisothiazole base-3 (2H)-one | 0.003 |
| 2-methyl-3 (2H)-isothiazolinone | 0.001 |
| 5-chloro-2-methyl-2H-isothiazoline-3-ketone | 0.001 |
| Water | 4.0 |
The conventional index connecing mouth glue of embodiment 2 is as follows:
| Conventional sense project | Detected result |
| Outward appearance | White uniformity emulsion |
| Viscosity | 5340 |
| Evaporation residuum | 52.9 |
| PH value | 4.3 |
The invention has the beneficial effects as follows: the tipping being applicable to cellulose acetate tipping paper; Be applicable to the cigarette equipment of roller coating gluing, equipment comprises: Protos 70, the Protos 1-8 of German Hao Ni company, Protos 90E, Protos 2-2; The GD-121 of GD company of Italy; The PASSIM 7000 and 8000 of Pa Ximu company of Britain; ZJ17, ZJ112, ZJ116 and ZJ118 of Changde Yan Ji company limited.This connects mouth glue and meets the relevant regulations of tobacco industry to water base cigarette glue.Original mouth glue Dichlorodiphenyl Acetate Mierocrystalline cellulose cigarette tipping paper that connects is difficult to wetting, and glue is very large to the contact angle of this tipping paper, and glue is difficult to sprawl on tipping paper surface; By the adjusting and optimizing to formula, this cellulose acetate tipping paper can be good at soaking with connecing mouth glue Dichlorodiphenyl Acetate Mierocrystalline cellulose tipping paper, and contact angle diminishes, and makes bonding more firm.Connect mouth glue compared to original, this cellulose acetate tipping paper is larger with the wet viscous force connecing mouth glue, makes after tipping paper gluing, before the non-drying of glue, tipping paper and filter tip also can be made to have good bonding force, thus ensure that the operation of machine.This cellulose acetate tipping paper is stronger with the anti-shear ability connecing mouth glue, and under high shear, running roller band glue is stablized, and glue does not splash, whirl coating, and gluing is even.This cellulose acetate tipping paper is faster with connecing mouth glue rate of drying, and after glue drying, particle is comparatively hard, is easy to be brushed by the brush on machine from tipping paper cutter and drum, thus ensure that the clean operation of machine.
The above, be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, and any change of expecting without creative work or replacement, all should be encompassed in the new protection domain of this practicality and be as the criterion.
Claims (8)
1. cellulose acetate cigarette tipping paper is with connecing a mouth glue, it is characterized in that: be made up of following raw material: VAE emulsion and additive, and described additive includes polyvinyl alcohol, softening agent, tackifier, defoamer, sterilant; Described raw material is frequently made up of following weight percent: VAE emulsion 70-90% and additive 10%-30%.
2. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: the second-order transition temperature of described emulsion is 0 DEG C-20 DEG C, and solid content is 50%-60%.
3. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: described polyvinyl alcohol alcoholysis degree is 80-90%, polymerization degree 500-2000.
4. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: described softening agent is made up of 2,2,4-trimethylammonium-1,3-pentanediol diisobutyrate, vanay, epoxy soybean oil and triethyl citrate.
5. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: described tackifier are made up of ester gum, polyvalent alcohol hydrogenated wood rosin glycerol ester and guar gum.
6. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: described defoamer is mineral oil antifoam agent and silicone antifoam agent.
7. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: described sterilant is made up of 1,2-benzisothiazole base-3 (2H)-one, 2-methyl-3 (2H)-isothiazolinone and 5-chloro-2-methyl-2H-isothiazoline-3-ketone.
8. a kind of cellulose acetate cigarette tipping paper as claimed in claim 1 is with connecing mouth glue, it is characterized in that: described cellulose acetate cigarette tipping paper is applicable to the tipping of cellulose acetate cigarette tipping paper and the cigarette machine of roller coating gluing with connecing mouth glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510361968.1A CN105018004A (en) | 2015-06-25 | 2015-06-25 | Holder adhesive for cellulose acetate cigarette tipping paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510361968.1A CN105018004A (en) | 2015-06-25 | 2015-06-25 | Holder adhesive for cellulose acetate cigarette tipping paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105018004A true CN105018004A (en) | 2015-11-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510361968.1A Pending CN105018004A (en) | 2015-06-25 | 2015-06-25 | Holder adhesive for cellulose acetate cigarette tipping paper |
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| Country | Link |
|---|---|
| CN (1) | CN105018004A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419686A (en) * | 2015-12-11 | 2016-03-23 | 重庆江北工农化工有限责任公司 | Preparation method of emulsion glue |
| CN105419685A (en) * | 2015-12-11 | 2016-03-23 | 重庆江北工农化工有限责任公司 | Emulsion glue |
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
| CN106189938A (en) * | 2016-08-30 | 2016-12-07 | 华威粘结材料（上海）股份有限公司 | A kind of aqueous, environmental protective logistic label glue composition and preparation method thereof |
| CN106928885A (en) * | 2017-03-28 | 2017-07-07 | 湖南珠峰科技有限公司 | High-fire-resistance cigarette connects mouth glue and preparation method thereof |
| CN107267090A (en) * | 2017-07-09 | 2017-10-20 | 云南中烟工业有限责任公司 | A kind of cellulose acetate cigarette tipping paper is with connecing mouth glue |
| CN107686710A (en) * | 2017-09-07 | 2018-02-13 | 滁州市光威化工有限公司 | A kind of high speed cigarette connects mouth glue and preparation method with antibacterial |
| CN110373947A (en) * | 2019-08-19 | 2019-10-25 | 玉溪接装纸制造有限公司 | A kind of antiseepage pearl oil paint and preparation method thereof for quick-fried pearl type tipping paper |
| CN111607339A (en) * | 2020-06-02 | 2020-09-01 | 长沙乐远化工科技有限公司 | Nozzle adhesive for anti-permeation tipping paper and preparation method thereof |
| CN112011292A (en) * | 2020-08-25 | 2020-12-01 | 郑州神火胶剂有限公司 | Water-based high-speed nozzle connecting adhesive and preparation method thereof |
| CN112574698A (en) * | 2019-09-27 | 2021-03-30 | 北京长润化工有限公司 | Eurytopic cigarette packaging adhesive and preparation method thereof |
| CN112574694A (en) * | 2019-09-27 | 2021-03-30 | 北京长润化工有限公司 | Eurytopic packaging adhesive additive and application thereof |
| CN113015446A (en) * | 2018-11-14 | 2021-06-22 | 日本烟草产业株式会社 | Tobacco-containing segment and method of making same, non-combustion heated smoking article, and non-combustion heated smoking system |
-
2015
- 2015-06-25 CN CN201510361968.1A patent/CN105018004A/en active Pending
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419685A (en) * | 2015-12-11 | 2016-03-23 | 重庆江北工农化工有限责任公司 | Emulsion glue |
| CN105419686A (en) * | 2015-12-11 | 2016-03-23 | 重庆江北工农化工有限责任公司 | Preparation method of emulsion glue |
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
| CN106189938A (en) * | 2016-08-30 | 2016-12-07 | 华威粘结材料（上海）股份有限公司 | A kind of aqueous, environmental protective logistic label glue composition and preparation method thereof |
| CN106189938B (en) * | 2016-08-30 | 2018-06-01 | 华威粘结材料（上海）股份有限公司 | A kind of aqueous, environmental protective logistic label glue composition and preparation method thereof |
| CN106928885A (en) * | 2017-03-28 | 2017-07-07 | 湖南珠峰科技有限公司 | High-fire-resistance cigarette connects mouth glue and preparation method thereof |
| CN107267090A (en) * | 2017-07-09 | 2017-10-20 | 云南中烟工业有限责任公司 | A kind of cellulose acetate cigarette tipping paper is with connecing mouth glue |
| CN107686710A (en) * | 2017-09-07 | 2018-02-13 | 滁州市光威化工有限公司 | A kind of high speed cigarette connects mouth glue and preparation method with antibacterial |
| CN113015446A (en) * | 2018-11-14 | 2021-06-22 | 日本烟草产业株式会社 | Tobacco-containing segment and method of making same, non-combustion heated smoking article, and non-combustion heated smoking system |
| EP3881686A4 (en) * | 2018-11-14 | 2022-08-10 | Japan Tobacco Inc. | Tobacco-containing segment and method for producing same, noncombustible heating-smoking article and noncombustible heating-smoking system |
| CN110373947A (en) * | 2019-08-19 | 2019-10-25 | 玉溪接装纸制造有限公司 | A kind of antiseepage pearl oil paint and preparation method thereof for quick-fried pearl type tipping paper |
| CN110373947B (en) * | 2019-08-19 | 2021-11-16 | 玉溪接装纸制造有限公司 | Anti-seepage bead oil coating for bead blasting type tipping paper and preparation method thereof |
| CN112574698A (en) * | 2019-09-27 | 2021-03-30 | 北京长润化工有限公司 | Eurytopic cigarette packaging adhesive and preparation method thereof |
| CN112574694A (en) * | 2019-09-27 | 2021-03-30 | 北京长润化工有限公司 | Eurytopic packaging adhesive additive and application thereof |
| CN111607339B (en) * | 2020-06-02 | 2022-01-04 | 长沙乐远化工科技有限公司 | Nozzle adhesive for anti-permeation tipping paper and preparation method thereof |
| CN111607339A (en) * | 2020-06-02 | 2020-09-01 | 长沙乐远化工科技有限公司 | Nozzle adhesive for anti-permeation tipping paper and preparation method thereof |
| CN112011292A (en) * | 2020-08-25 | 2020-12-01 | 郑州神火胶剂有限公司 | Water-based high-speed nozzle connecting adhesive and preparation method thereof |
| CN112011292B (en) * | 2020-08-25 | 2022-03-08 | 郑州神火胶剂有限公司 | Water-based high-speed nozzle connecting adhesive and preparation method thereof |
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Application publication date: 20151104 |
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