CN106928885A - High-fire-resistance cigarette connects mouth glue and preparation method thereof - Google Patents
High-fire-resistance cigarette connects mouth glue and preparation method thereof Download PDFInfo
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- CN106928885A CN106928885A CN201710193864.3A CN201710193864A CN106928885A CN 106928885 A CN106928885 A CN 106928885A CN 201710193864 A CN201710193864 A CN 201710193864A CN 106928885 A CN106928885 A CN 106928885A
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- Prior art keywords
- fire
- parts
- mouth glue
- cigarette
- connects
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Mouth glue technical field is connect the invention belongs to cigarette, and in particular to a kind of high fire-retardance cigarette connects mouth glue.The high-fire-resistance cigarette connects mouth glue, is made up of following mass parts raw material：750 850 parts of vinyl acetate resin ethylene copolymer, 80 120 parts of polyvinyl alcohol water solution, 35 parts of surfactant, 10 20 parts of fire retardant, 0.5 1.0 parts of defoamer, 0.5 1.0 parts of NaOH, 50 100 parts of the deionized water that mass fraction is 15%.Cigarette burns to the cigarette for scribbling the application and connects equal automatic distinguishing at the tipping paper of mouth glue, can effectively suppress cigarette Ignition phenomenon, so as to eliminate fire safety evaluating hidden danger；Cigarette meets mouth glue limited oxygen index ＞ 28%, meets fire resistance requirement；Cigarette connects mouth glue Dynamic Rheological Properties good stability, and anti-shearing force performance is good.
Description
Technical field
Mouth glue technical field is connect the invention belongs to cigarette, and in particular to a kind of high fire-retardance cigarette meets mouth glue and its preparation side
Method.
Background technology
It is important cigarette material in cigarette industry that cigarette connects mouth glue, is the important cigarette material of cigarette connection filter tip,
After cigarette has been burnt, be burned at filter tip tipping paper, cigarette automatic distinguishing, its structural behaviour cigarette has been burnt after cigarette end
The fire resistance and fire savety important of (cigarette filter).
However, the fire resistance that existing cigarette connects mouth glue is not good.
The content of the invention
In view of this, mouth glue is connect it is an object of the invention to provide a kind of high-fire-resistance cigarette, is used to be coated on a fixed width
On the cigarette tipping paper of degree, inhibiting tape is formed.The cigarette of mouth glue is connect using fire-retardant cigarette, cigarette is contributed at burning to inhibiting tape
Extinguish.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of high-fire-resistance cigarette connects mouth glue, is made up of following mass parts raw material：Vinyl acetate resin-ethylene copolymer 750-
850 parts, 80-120 parts of the polyvinyl alcohol water solution that mass fraction is 15%, surfactant 3-5 parts, fire retardant 10-20 parts, disappear
Infusion 0.5-1.0 parts, NaOH 0.5-1.0 parts, deionized water 50-100 parts.
The mass fraction is that 15% polyvinyl alcohol water solution is referred to polyvinyl alcohol as solute, and water is solvent, and
The mass fraction of polyvinyl alcohol is 15% solution.
Further, the surfactant is by polyethylene glycol and C16-18The monoether and polyethylene glycol and C of alcohol generation12-14It is secondary
The ether of alcohol generation is according to 1-2:The mass ratio composition of 2-3.
Further, the degree of polymerization of the polyethylene glycol is 2-6.
Further, the fire retardant is the condensation polymers of the phosphoric acid and pentaerythritol.
The condensation polymers of the phosphoric acid and pentaerythritol fire retardant integrates acid source, carbon source, source of the gas, for pushing away is carbonized during by fire, is formed
Foamed char, it is fire-retardant during main play condensation product fire retardant mechanism.
Further, the defoamer is made up of White Mineral Oil and dimethyl silicone polymer.
Further, the defoamer is the Airase4500 defoamers of air chemical company of the U.S..
The present invention also aims to protect the high-fire-resistance cigarette to connect the preparation method of mouth glue, comprise the following steps：
A. above-mentioned mass parts fire retardant is dispersed in above-mentioned deionized water, and pH value is adjusted to 5 with NaOH, it is standby；
B. above-mentioned mass parts vinyl acetate resin-ethylene copolymer and above-mentioned mass parts polyvinyl alcohol water are put into a kettle.
Solution, stirring, it is 5-7 to be adjusted to pH value with NaOH, adds above-mentioned mass parts defoamer and above-mentioned mass of surface activating agent, then will
The mixture that step A is obtained is slowly added into reactor emulsion, continues to stir, and filtering obtains final product the high-fire-resistance cigarette and connects mouth
Glue.
Further, in step B, above-mentioned mass parts vinyl acetate resin-ethylene copolymer and above-mentioned matter are put into a kettle.
Amount part polyvinyl alcohol water solution, in being stirred 100-140 minutes under 28 ± 0.5Hz frequencies, it is 5-7 to be adjusted to pH value with NaOH, is added
In above-mentioned mass parts defoamer and above-mentioned mass of surface activating agent, then the mixture addition reactor emulsion that step A is obtained,
In being stirred 50-70 minutes under 28 ± 0.5Hz frequencies, filtering obtains final product the high-fire-resistance cigarette and connects mouth glue.
Further, in step B, the filtering refers to the filter-cloth filtering of use >=80 mesh.
Cigarette burns to scribbling flame retardant type cigarette obtained in the application and connects equal automatic distinguishing, energy at the tipping paper of mouth glue
Effectively suppress cigarette Ignition phenomenon, eliminate fire safety evaluating hidden danger.Cigarette obtained in the application connects mouth glue suitable for ultrahigh speed cigarette
Unit (16000/min).
The beneficial effects of the present invention are：
(1) Cigarette burns to the cigarette for scribbling the application and connects equal automatic distinguishing at the tipping paper of mouth glue, can effectively press down
Cigarette Ignition phenomenon processed, so as to eliminate fire safety evaluating hidden danger；(2) cigarette meets mouth glue limited oxygen index ＞ 28%, meets anti-flammability
Can require；(3) cigarette connects mouth glue Dynamic Rheological Properties good stability, and anti-shearing force performance is good.
Brief description of the drawings
Fig. 1 is the rheological property stability test result figure that cigarette obtained in embodiment 3 connects mouth glue；
Fig. 2 is the anti-shearing force the performance test results figure that cigarette obtained in embodiment 3 connects mouth glue.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is unreceipted in preferred embodiment
The experimental technique of actual conditions, generally according to normal condition.
Following defoamer is the Airase4500 defoamers of air chemical company of the U.S..
Embodiment 1
A kind of high-fire-resistance cigarette connects mouth glue, consisting of：Vinyl acetate resin-ethylene copolymer 750g, mass fraction are
15% polyvinyl alcohol water solution 80g, the polyethylene glycol and C that the degree of polymerization is 2-616-18The monoether 1g of alcohol generation, the degree of polymerization are 2-6
Polyethylene glycol and C12-14Ether 2g, the condensation polymers of the phosphoric acid and pentaerythritol 10g, defoamer 1.0g, the NaOH 0.5- of secondary alcohol generation
1.0g, deionized water 50g.
The preparation method that the high-fire-resistance cigarette connects mouth glue is：
A. 10g the condensation polymers of the phosphoric acid and pentaerythritol is dispersed in 50g deionized waters, and pH value is adjusted to 5 with NaOH, it is standby
With；
B. input 750g vinyl acetate resins-ethylene copolymer and 80g polyvinyl alcohol water solutions in a kettle., in 28 ±
Stirred 100 minutes under 0.5Hz frequencies, it is 5 to be adjusted to pH value with NaOH, it is the poly- second two of 2-6 to add 1.0g defoamers, the 1g degree of polymerization
Alcohol and C16-18The monoether and the 2g degree of polymerization of alcohol generation are the polyethylene glycol and C of 2-612-14The ether of secondary alcohol generation, then step A is obtained
To mixture be slowly added into reactor emulsion, under 28 ± 0.5Hz frequencies stir 50 minutes, with the filter cloth mistake of >=80 mesh
Filter, obtains final product the high-fire-resistance cigarette and connects mouth glue.
Embodiment 2
A kind of high-fire-resistance cigarette connects mouth glue, consisting of：Vinyl acetate resin-ethylene copolymer 850g, mass fraction are
15% polyvinyl alcohol water solution 120g, the polyethylene glycol and C that the degree of polymerization is 2-616-18The monoether 2g of alcohol generation, the degree of polymerization are 2-
6 polyethylene glycol and C12-14Ether 3g, the condensation polymers of the phosphoric acid and pentaerythritol 20g, defoamer 0.5g, the NaOH 0.5- of secondary alcohol generation
1.0g, deionized water 100g.
The preparation method that the high-fire-resistance cigarette connects mouth glue is：
A. 20g the condensation polymers of the phosphoric acid and pentaerythritol is dispersed in 100g deionized waters, and pH value is adjusted to 5 with NaOH, it is standby
With；
B. input 850g vinyl acetate resins-ethylene copolymer and 120g polyvinyl alcohol water solutions in a kettle., in 28 ±
Stirred 140 minutes under 0.5Hz frequencies, it is 7 to be adjusted to pH value with NaOH, it is the poly- second two of 2-6 to add 0.5g defoamers, the 2g degree of polymerization
Alcohol and C16-18The monoether and the 3g degree of polymerization of alcohol generation are the polyethylene glycol and C of 2-612-14The ether of secondary alcohol generation, then step A is obtained
To mixture be slowly added into reactor emulsion, under 28 ± 0.5Hz frequencies stir 70 minutes, with the filter cloth mistake of >=80 mesh
Filter, obtains final product the high-fire-resistance cigarette and connects mouth glue.
Embodiment 3
A kind of high-fire-resistance cigarette connects mouth glue, consisting of：Vinyl acetate resin-ethylene copolymer 800g, mass fraction are
15% polyvinyl alcohol water solution 90g, the polyethylene glycol and C that the degree of polymerization is 2-616-18The monoether 1.3g of alcohol generation, the degree of polymerization are
The polyethylene glycol and C of 2-612-14Ether 2.7g, the condensation polymers of the phosphoric acid and pentaerythritol 16g, defoamer 0.6g, the NaOH of secondary alcohol generation
0.5-1.0g, deionized water 75g.
The preparation method that the high-fire-resistance cigarette connects mouth glue is：
A. 16g the condensation polymers of the phosphoric acid and pentaerythritol is dispersed in 75g deionized waters, and pH value is adjusted to 5 with NaOH, it is standby
With；
B. input 800g vinyl acetate resins-ethylene copolymer and 90g polyvinyl alcohol water solutions in a kettle., in 28 ±
Stirred 130 minutes under 0.5Hz frequencies, it is 6 to be adjusted to pH value with NaOH, it is the poly- second of 2-6 to add 0.6g defoamers, the 1.3g degree of polymerization
Glycol and C16-18The monoether and the 2.7g degree of polymerization of alcohol generation are the polyethylene glycol and C of 2-612-14The ether of secondary alcohol generation, then by step
The mixture that A is obtained is slowly added into reactor emulsion, in being stirred 60 minutes under 28 ± 0.5Hz frequencies, with the filter cloth of >=80 mesh
Filtering, obtains final product the high-fire-resistance cigarette and connects mouth glue.
Cigarette connects mouth glue performance test
Cigarette obtained in embodiment 1-3 is connect mouth glue according to《GB/T2406-1993 Plastics Combustion method for testing performance oxygen refers to
Number method》Limited oxygen index aspect performance test is carried out, as a result as shown in table 1.
The cigarette of table 1 connects mouth glue limited oxygen index measurement result
Mouth glue is connect to cigarette obtained in embodiment 3 carries out the performance inspection of rheological property stability and anti-shearing force aspect of performance
Survey, as a result as depicted in figs. 1 and 2.
It is false moulding fluid to connect mouth glue, and its viscosity is reduced with the increase of shear rate, increased with the reduction of shear rate
Plus.It will be seen from figure 1 that connecing mouth glue does rheological curve, shear rate：0-8000s-1- 0, two curves are approached after test.Thus
Prove, the cigarette holder of the application connects mouth glue after strong shear, and molecular structure is not destroyed, at high shear rates, this can be kept
Connect the characteristic of mouth glue.
It is to be respectively in shear rate in Fig. 2：3000s-1、4000s-1、5000s-1、6000s-1、7000s-1、8000s-1Bar
Each shearing 1min, the data of collection under under part.Figure it is seen that connecing mouth glue in 3000s-1-7000s-1Under shear rate, stick
Degree held stationary, molecular structure stabilized, shear rate is in 8000s-1Under the conditions of, the time in 310s, connect the viscosity of mouth glue drastically
Decline, the network structure of its macromolecular is destroyed, and connects the characteristic that mouth glue loses its adhesive.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
Good embodiment has been described in detail to the present invention, it will be understood by those within the art that, can be to skill of the invention
Art scheme is modified or equivalent, and without deviating from the objective and scope of technical solution of the present invention, it all should cover at this
In the middle of the right of invention.
Claims (8)
1. a kind of high-fire-resistance cigarette connects mouth glue, it is characterised in that be made up of following mass parts raw material：Vinyl acetate resin-ethene
Copolymer 750-850 parts, 80-120 parts of the polyvinyl alcohol water solution that mass fraction is 15%, surfactant 3-5 parts, fire retardant
10-20 parts, defoamer 0.5-1.0 parts, NaOH 0.5-1.0 parts, deionized water 50-100 parts.
2. high-fire-resistance cigarette according to claim 1 connects mouth glue, it is characterised in that the surfactant is by poly- second two
Alcohol and C16-18The monoether and polyethylene glycol and C of alcohol generation12-14The ether of secondary alcohol generation is according to 1-2:The mass ratio composition of 2-3.
3. high-fire-resistance cigarette according to claim 2 connects mouth glue, it is characterised in that the degree of polymerization of the polyethylene glycol is
2-6。
4. high-fire-resistance cigarette according to claim 1 connects mouth glue, it is characterised in that the fire retardant is phosphoric acid Ji Wusi
Alcohol condensation polymer.
5. high-fire-resistance cigarette according to claim 1 connects mouth glue, it is characterised in that the defoamer is by White Mineral Oil and gathers
Dimethyl siloxane is constituted.
6. high-fire-resistance cigarette connects the preparation method of mouth glue described in claim 1, it is characterised in that comprise the following steps：
A. above-mentioned mass parts fire retardant is dispersed in above-mentioned deionized water, and pH value is adjusted to 5 with NaOH, it is standby；
B. above-mentioned mass parts vinyl acetate resin-ethylene copolymer is put into a kettle. and above-mentioned mass parts polyvinyl alcohol is water-soluble
Liquid, stirring, it is 5-7 to be adjusted to pH value with NaOH, adds above-mentioned mass parts defoamer and above-mentioned mass of surface activating agent, then will step
The mixture that rapid A is obtained is added in reactor emulsion, continues to stir, and filtering obtains final product the high-fire-resistance cigarette and connects mouth glue.
7. high-fire-resistance cigarette connects the preparation method of mouth glue according to claim 6, it is characterised in that in step B, in reaction
Above-mentioned mass parts vinyl acetate resin-ethylene copolymer and above-mentioned mass parts polyvinyl alcohol water solution are put into kettle, in 28 ± 0.5Hz
Stirred 100-140 minutes under frequency, it is 5-7 to be adjusted to pH value with NaOH, add above-mentioned mass parts defoamer and above-mentioned mass parts table
In face activating agent, then the mixture addition reactor emulsion that step A is obtained, divide in 50-70 is stirred under 28 ± 0.5Hz frequencies
Clock, filtering, obtains final product the high-fire-resistance cigarette and connects mouth glue.
8. high-fire-resistance cigarette connects the preparation method of mouth glue according to claim 6, it is characterised in that in step B, the mistake
Filter refers to the filter-cloth filtering of use >=80 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710193864.3A CN106928885A (en) | 2017-03-28 | 2017-03-28 | High-fire-resistance cigarette connects mouth glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710193864.3A CN106928885A (en) | 2017-03-28 | 2017-03-28 | High-fire-resistance cigarette connects mouth glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106928885A true CN106928885A (en) | 2017-07-07 |
Family
ID=59425352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710193864.3A Pending CN106928885A (en) | 2017-03-28 | 2017-03-28 | High-fire-resistance cigarette connects mouth glue and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629736A (en) * | 2017-09-07 | 2018-01-26 | 滁州市光威化工有限公司 | A kind of nano-silicon dioxide modified fire-retardant the High-speed Cigarette Adhesives for Filter Tipping of hud typed acrylate and vinyl acetate emulsion and preparation method |
| CN108441142A (en) * | 2018-03-27 | 2018-08-24 | 无锡双锚新材料有限公司 | Fire-retardant white glue |
| CN108753201A (en) * | 2018-06-20 | 2018-11-06 | 滁州市光威化工有限公司 | A kind of environment-friendly type glutinous rice cigarette glue and preparation method thereof |
| CN108753200A (en) * | 2018-06-20 | 2018-11-06 | 滁州市光威化工有限公司 | A kind of environmental-protection flame-retardant cigarette glue and preparation method thereof |
| CN108795328A (en) * | 2018-06-20 | 2018-11-13 | 滁州市光威化工有限公司 | A kind of nano flame retardant starch cigarette glue and preparation method thereof |
| CN108795327A (en) * | 2018-06-20 | 2018-11-13 | 滁州市光威化工有限公司 | A kind of cigarette glue and preparation method thereof containing Chinese medical extract |
| CN108795320A (en) * | 2018-06-20 | 2018-11-13 | 滁州市光威化工有限公司 | A kind of moisture-proof cigarette glue and preparation method thereof |
| CN110628360A (en) * | 2019-09-27 | 2019-12-31 | 常德市芙蓉实业发展有限责任公司 | Cigarette phase change interface adhesive for tipping paper for cigarettes |
| CN114525089A (en) * | 2022-02-21 | 2022-05-24 | 连云港昌瑞科技有限公司 | Environment-friendly flame-retardant cigarette adhesive and preparation method thereof |
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| CN105018004A (en) * | 2015-06-25 | 2015-11-04 | 云南中烟工业有限责任公司 | Holder adhesive for cellulose acetate cigarette tipping paper |
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
| CN106520020A (en) * | 2016-11-17 | 2017-03-22 | 大理新天制胶回收有限公司 | Environmentally friendly high speed cigarette adhesive for filter tipping and preparation method thereof |
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| CN105018004A (en) * | 2015-06-25 | 2015-11-04 | 云南中烟工业有限责任公司 | Holder adhesive for cellulose acetate cigarette tipping paper |
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
| CN106520020A (en) * | 2016-11-17 | 2017-03-22 | 大理新天制胶回收有限公司 | Environmentally friendly high speed cigarette adhesive for filter tipping and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629736A (en) * | 2017-09-07 | 2018-01-26 | 滁州市光威化工有限公司 | A kind of nano-silicon dioxide modified fire-retardant the High-speed Cigarette Adhesives for Filter Tipping of hud typed acrylate and vinyl acetate emulsion and preparation method |
| CN108441142A (en) * | 2018-03-27 | 2018-08-24 | 无锡双锚新材料有限公司 | Fire-retardant white glue |
| CN108753201A (en) * | 2018-06-20 | 2018-11-06 | 滁州市光威化工有限公司 | A kind of environment-friendly type glutinous rice cigarette glue and preparation method thereof |
| CN108753200A (en) * | 2018-06-20 | 2018-11-06 | 滁州市光威化工有限公司 | A kind of environmental-protection flame-retardant cigarette glue and preparation method thereof |
| CN108795328A (en) * | 2018-06-20 | 2018-11-13 | 滁州市光威化工有限公司 | A kind of nano flame retardant starch cigarette glue and preparation method thereof |
| CN108795327A (en) * | 2018-06-20 | 2018-11-13 | 滁州市光威化工有限公司 | A kind of cigarette glue and preparation method thereof containing Chinese medical extract |
| CN108795320A (en) * | 2018-06-20 | 2018-11-13 | 滁州市光威化工有限公司 | A kind of moisture-proof cigarette glue and preparation method thereof |
| CN110628360A (en) * | 2019-09-27 | 2019-12-31 | 常德市芙蓉实业发展有限责任公司 | Cigarette phase change interface adhesive for tipping paper for cigarettes |
| CN114525089A (en) * | 2022-02-21 | 2022-05-24 | 连云港昌瑞科技有限公司 | Environment-friendly flame-retardant cigarette adhesive and preparation method thereof |
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Application publication date: 20170707 |