CN107686710A - A kind of high speed cigarette connects mouth glue and preparation method with antibacterial - Google Patents
A kind of high speed cigarette connects mouth glue and preparation method with antibacterial Download PDFInfo
- Publication number
- CN107686710A CN107686710A CN201710798716.4A CN201710798716A CN107686710A CN 107686710 A CN107686710 A CN 107686710A CN 201710798716 A CN201710798716 A CN 201710798716A CN 107686710 A CN107686710 A CN 107686710A
- Authority
- CN
- China
- Prior art keywords
- high speed
- antibacterial
- antiseptic
- preparation
- mouth glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of high speed cigarette mouth glue and preparation method are connect with antibacterial, the present invention is used as material of main part using VAE emulsions, the loaded modified zeolite molecular sieve of potassium diformate is antiseptic, pass through the modification removal of impurity to micro-pore zeolite and heavy metal element, molecular sieve crystal formation is complete, there is provided more mesoporous, into cubic, total BET specific surface area can also be increased simultaneously, its absorption property is set to meet as antiseptic matrix requirement, and it is uniformly dispersed in polymer emulsion and is not easy to reunite, effectively solves the problems, such as the antibacterial that tradition connects mouth glue, use it for high speed cigarette, glue will not be flown under high speed shear, and the wet viscosity of product is good, when high-speed production, it is not in sudden and violent lip reflex.
Description
Technical field
The present invention relates to cigarette field of adhesive technology, and in particular to a kind of high speed cigarette connects mouth glue and preparation with antibacterial
Method.
Background technology
With the development of tobacco science and technology, " smoking and the safety " and " smoking and health " that tobacco is advocated turns into a kind of trend
And main contents.Consider from health, it is desirable to which the tobacco auxiliary material feature of environmental protection is constantly lifted, and cigarette is by the use of connecing mouth glue as must in production of cigarettes
Indispensable material, but also be organic chemical industry's material, strict regulations are carried out to its feature of environmental protection, security, as high speed is rolled up
The continuous introduction of cigarette unit, the speed of cigarette machine have brought up to 15000-20000 from 5000-10000 branch/minute before
Branch/minute, correspondingly, cigarette adhesive just allow for the requirement for meeting high speed cigarette, such as have certain tack, dry
Speed is fast, and cohesive force is strong etc..
In recent years, with urbanization process quickening and industrial development acceleration, environmental pollution getting worse, so as to cause
Haze phenomenon getting worse and frequently, coverage is also increasing, inside haze containing various harmful fine graineds,
Noxious material directly can enter bronchus, or even lung, so as to easily trigger respiratory tract disease up to kind more than 20 by respiratory system
The diseases such as disease, cranial vascular disease, nasal cavity inflammation, meanwhile, during haze weather, air pressure reduction, Inhalable Particulate abruptly increase,
Air flow property is poor, and harmful bacteria and virus slow to what surrounding spread, cause virus concentration in air to increase, and disease passes
The risk broadcast is very high.
The High-speed Cigarette Adhesives for Filter Tipping refers in high speed cigarette produces, and is applied on tipping paper, is hinged with for cigarette and filter tip
A kind of cigarette glue, because cigarette stem filter tip is directly to be contacted with face, during smoking, virus and bacterium in surrounding air etc. have
Evil thing enters human body easily by face, brings potential safety hazard.Thus the High-speed Cigarette Adhesives for Filter Tipping needs that there is certain antibacterial to kill
Bacterium property, and traditional the High-speed Cigarette Adhesives for Filter Tipping is only capable of basic viscosity and the rate of drying for meeting high speed cigarette requirement.
The content of the invention
Mouth glue and preparation method are connect with antibacterial it is an object of the invention to provide a kind of high speed cigarette, to overcome prior art
Deficiency.
The object of the present invention is achieved like this：
A kind of high speed cigarette connects mouth glue with antibacterial, it is characterised in that using VAE emulsions as matrix, adds a certain amount of antiseptic, institute
It is 1.5-2wt.% to state antiseptic addition.
Described VAE emulsion solid contents are 55-60%.
The antiseptic is the loaded modified zeolite molecular sieve of potassium diformate, and its preparation method is：
（1）Micro-pore zeolite is taken to add aqueous slkali according to solid-to-liquid ratio 1: 20, at room temperature ultrasonic disperse 30-40min；
（2）According to solid-to-liquid ratio 1: 10 to step（1）Aqueous isopropanol is added in material, it is small to be warming up to 55-60 DEG C of ultrasonic disperse 2-3
When, filtration washing simultaneously dries to obtain alkali process zeolite；
（3）Above-mentioned alkali process zeolite is added in 15% hydrochloric acid solution according to solid-to-liquid ratio 1: 3 and stirred and evenly mixed, is warming up to 80-90 DEG C
Ultrasonic disperse 1-2 hours, filtration washing to neutrality simultaneously dry to obtain mesoporous-microporous zeolite molecular sieve；
（4）Mesoporous-microporous zeolite molecular sieve obtained above is added in potassium diformate solution according to solid-to-liquid ratio 1: 20, normal temperature
Lower magnetic agitation reacts 2-3 hours, filters, washs and dry, obtains the loaded modified zeolite molecular sieve of potassium diformate.
Step（1）Described in aqueous slkali be selected from NaOH the or KOH aqueous solution, concentration 1-2mol/L.
Step（4）The initial concentration of described potassium diformate solution is 40mg/mL, and control ph is 6- in course of reaction
6.5, washed product is in 60 DEG C of drying.
A kind of described high speed cigarette connects the preparation method of mouth glue with antibacterial, it is characterised in that comprises the following steps：
（1）By VAE emulsions and polyvinyl alcohol input reactor, 20min is stirred with 30 turns/min speed；
（2）Add antiseptic while stirring, 30min stirred with 60 turns/min speed, be warming up to 75-85 DEG C, then with 80 turns/
Min speed stirring 30min, is cooled to room temperature ultrasonic disperse 20-30min；
（3）Defoamer is finally slowly added to while stirring, and stirring 10 minutes, discharging are continued with 30 turns/min speed.
Step（1）The dosage of described polyvinyl alcohol is the 15-18% of VAE quality of the emulsion.
Step（3）Described defoamer is mineral oil defoaming agent, and dosage is the 0.1-0.2% of VAE quality of the emulsion.
The present invention has following beneficial effect：The present invention is using VAE emulsions as material of main part, the loaded modified zeolite of potassium diformate
Molecular sieve is antiseptic, complete by the modification removal of impurity to micro-pore zeolite and heavy metal element, molecular sieve crystal formation, there is provided
It is more mesoporous, into cubic, while total BET specific surface area can also be increased, its absorption property is met as antibacterial
The requirement of agent matrix, and be uniformly dispersed in polymer emulsion and be not easy to reunite, effectively solve the problems, such as the antibacterial that tradition connects mouth glue, by it
For high speed cigarette, glue will not be flown under high speed shear, and the wet viscosity of product is good, when high-speed production, be not in
Sudden and violent lip reflex.
Embodiment
A kind of high speed cigarette connects mouth glue with antibacterial, it is characterised in that using VAE emulsions as matrix, adds a certain amount of antibacterial
Agent, the antiseptic addition are 2wt.%.
Described VAE emulsion solid contents are 55-60%.
The antiseptic is the loaded modified zeolite molecular sieve of potassium diformate, and its preparation method is：
（1）Micro-pore zeolite is taken to add aqueous slkali according to solid-to-liquid ratio 1: 20, at room temperature ultrasonic disperse 30-40min；
（2）According to solid-to-liquid ratio 1: 10 to step（1）Aqueous isopropanol is added in material, it is small to be warming up to 55-60 DEG C of ultrasonic disperse 2-3
When, filtration washing simultaneously dries to obtain alkali process zeolite；
（3）Above-mentioned alkali process zeolite is added in 15% hydrochloric acid solution according to solid-to-liquid ratio 1: 3 and stirred and evenly mixed, is warming up to 80-90 DEG C
Ultrasonic disperse 1-2 hours, filtration washing to neutrality simultaneously dry to obtain mesoporous-microporous zeolite molecular sieve；
（4）Mesoporous-microporous zeolite molecular sieve obtained above is added in potassium diformate solution according to solid-to-liquid ratio 1: 20, normal temperature
Lower magnetic agitation reacts 2-3 hours, filters, washs and dry, obtains the loaded modified zeolite molecular sieve of potassium diformate.
Step（1）Described in aqueous slkali be selected from NaOH the or KOH aqueous solution, concentration 1-2mol/L.
Step（4）The initial concentration of described potassium diformate solution is 40mg/mL, and control ph is 6- in course of reaction
6.5, washed product is in 60 DEG C of drying.
A kind of described high speed cigarette connects the preparation method of mouth glue with antibacterial, it is characterised in that comprises the following steps：
（1）By VAE emulsions and polyvinyl alcohol input reactor, 20min is stirred with 30 turns/min speed；
（2）Add antiseptic while stirring, 30min stirred with 60 turns/min speed, be warming up to 75-85 DEG C, then with 80 turns/
Min speed stirring 30min, is cooled to room temperature ultrasonic disperse 20-30min；
（3）Defoamer is finally slowly added to while stirring, and stirring 10 minutes, discharging are continued with 30 turns/min speed.
Step（1）The dosage of described polyvinyl alcohol is the 17% of VAE quality of the emulsion.
Step（3）Described defoamer is mineral oil defoaming agent, and dosage is the 0.1% of VAE quality of the emulsion.
Claims (8)
1. a kind of high speed cigarette connects mouth glue with antibacterial, it is characterised in that using VAE emulsions as matrix, a certain amount of antiseptic is added,
The antiseptic addition is 1.5-2wt.%.
2. a kind of high speed cigarette according to claim 1 connects mouth glue with antibacterial, it is characterised in that described VAE emulsions are consolidated
Content is 55-60%.
3. a kind of high speed cigarette according to claim 1 connects mouth glue with antibacterial, it is characterised in that the antiseptic is diformazan
The sour loaded modified zeolite molecular sieve of potassium, its preparation method are：
（1）Micro-pore zeolite is taken to add aqueous slkali according to solid-to-liquid ratio 1: 20, at room temperature ultrasonic disperse 30-40min；
（2）According to solid-to-liquid ratio 1: 10 to step（1）Aqueous isopropanol is added in material, it is small to be warming up to 55-60 DEG C of ultrasonic disperse 2-3
When, filtration washing simultaneously dries to obtain alkali process zeolite；
（3）Above-mentioned alkali process zeolite is added in 15% hydrochloric acid solution according to solid-to-liquid ratio 1: 3 and stirred and evenly mixed, is warming up to 80-90 DEG C
Ultrasonic disperse 1-2 hours, filtration washing to neutrality simultaneously dry to obtain mesoporous-microporous zeolite molecular sieve；
（4）Mesoporous-microporous zeolite molecular sieve obtained above is added in potassium diformate solution according to solid-to-liquid ratio 1: 20, normal temperature
Lower magnetic agitation reacts 2-3 hours, filters, washs and dry, obtains the loaded modified zeolite molecular sieve of potassium diformate.
4. the preparation method of the antiseptic according to claim 3, it is characterised in that step（1）Described in alkali soluble
Liquid is selected from NaOH the or KOH aqueous solution, concentration 1-2mol/L.
5. the preparation method of the antiseptic according to claim 3, it is characterised in that step（4）Described dioctyl phthalate
The initial concentration of potassium solution is 40mg/mL, and control ph is 6-6.5 in course of reaction, and washed product is in 60 DEG C of drying.
6. a kind of high speed cigarette according to claim 1 connects the preparation method of mouth glue with antibacterial, it is characterised in that including with
Lower step：
（1）By VAE emulsions and polyvinyl alcohol input reactor, 20min is stirred with 30 turns/min speed；
（2）Add antiseptic while stirring, 30min stirred with 60 turns/min speed, be warming up to 75-85 DEG C, then with 80 turns/
Min speed stirring 30min, is cooled to room temperature ultrasonic disperse 20-30min；
（3）Defoamer is finally slowly added to while stirring, and stirring 10 minutes, discharging are continued with 30 turns/min speed.
7. a kind of high speed cigarette according to claim 6 connects the preparation method of mouth glue with antibacterial, it is characterised in that step
（1）The dosage of described polyvinyl alcohol is the 15-18% of VAE quality of the emulsion.
8. a kind of high speed cigarette according to claim 6 connects the preparation method of mouth glue with antibacterial, it is characterised in that step
（3）Described defoamer is mineral oil defoaming agent, and dosage is the 0.1-0.2% of VAE quality of the emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710798716.4A CN107686710A (en) | 2017-09-07 | 2017-09-07 | A kind of high speed cigarette connects mouth glue and preparation method with antibacterial |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710798716.4A CN107686710A (en) | 2017-09-07 | 2017-09-07 | A kind of high speed cigarette connects mouth glue and preparation method with antibacterial |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107686710A true CN107686710A (en) | 2018-02-13 |
Family
ID=61156068
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710798716.4A Pending CN107686710A (en) | 2017-09-07 | 2017-09-07 | A kind of high speed cigarette connects mouth glue and preparation method with antibacterial |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107686710A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102210665A (en) * | 2011-03-24 | 2011-10-12 | 桂林理工大学 | Method for preparing feed antibacterial agent by absorbing and grafting potassium diformate on epidesmine molecular screen |
| CN105018004A (en) * | 2015-06-25 | 2015-11-04 | 云南中烟工业有限责任公司 | Holder adhesive for cellulose acetate cigarette tipping paper |
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
-
2017
- 2017-09-07 CN CN201710798716.4A patent/CN107686710A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102210665A (en) * | 2011-03-24 | 2011-10-12 | 桂林理工大学 | Method for preparing feed antibacterial agent by absorbing and grafting potassium diformate on epidesmine molecular screen |
| CN105018004A (en) * | 2015-06-25 | 2015-11-04 | 云南中烟工业有限责任公司 | Holder adhesive for cellulose acetate cigarette tipping paper |
| CN105567133A (en) * | 2016-01-13 | 2016-05-11 | 华威化工（上海）有限公司 | Ultra-high-speed cigarette mouthpiece adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5204109B2 (en) | High bond strength composite material, process for its production and use in cigarette filters | |
| WO2017122224A4 (en) | A nanobiocomposite formulation for wound healing and a process for the preparation thereof | |
| CN109351165A (en) | It is a kind of indoor except formaldehyde spray | |
| WO2012012989A1 (en) | Functional tobacco sheet and preparation method thereof | |
| CN106167581A (en) | A kind of preparation method of antibacterial polypropylene | |
| CN107686710A (en) | A kind of high speed cigarette connects mouth glue and preparation method with antibacterial | |
| CN109012598A (en) | A kind of preparation method based on manganese dioxide/stannic oxide/graphene nano composite material Ciprofloxacin absorption purifier | |
| CN108485468A (en) | A kind of liquid wallpaper capable of purifying air and preparation method thereof | |
| CN105753368B (en) | A kind of preparation method of refined jasmine oil spacetabs type functional ornamentation material | |
| CN110122924A (en) | Reconstituted tobacoo filter stick, composite filter and its manufacturing method | |
| CN103099777B (en) | Bio-enzyme hydrogel taking porous calcium carbonate as carrier and preparation method of bio-enzyme hydrogel | |
| CN105218662A (en) | A kind of purification of the collagen based on the recyclable nano antibacterial agent of magnetic and anti-corrosion method | |
| CN105165892A (en) | Preparation process of antibacterial composition applicable to hygienic paper | |
| CN111849228A (en) | Inorganic water-based paint and preparation method thereof | |
| CN103518777B (en) | A kind of environment cleaner and preparation method thereof | |
| CN103074801B (en) | Forming paper paint for reducing hazardous substances in cigarette smoke | |
| CN101704719B (en) | Method for preparing medical-grade propylene glycol | |
| JP4021980B2 (en) | Cellulosic particles and method for producing the same | |
| JP2840601B2 (en) | Solid porous silica beads containing metal compound, method for producing the same, and powder deodorant | |
| CN113694247B (en) | Preparation method of multifunctional composite hemostatic sponge | |
| CN106139816B (en) | A kind of application of low viscosity algin | |
| CN108314460A (en) | A kind of moisture-proof wallboard of antibacterial and preparation method thereof | |
| CN105194832A (en) | Air-purifying nanometer wet tissue | |
| CN106390590A (en) | A chemical filter and a chemical filtering material thereof | |
| CN105754274B (en) | A kind of preparation method of Lavender spacetabs type functional ornamentation material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180213 |