CN104987733A - Biology binding material modified asphalt material used for road engineering and preparing method thereof - Google Patents
Biology binding material modified asphalt material used for road engineering and preparing method thereof Download PDFInfo
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- CN104987733A CN104987733A CN201510344673.3A CN201510344673A CN104987733A CN 104987733 A CN104987733 A CN 104987733A CN 201510344673 A CN201510344673 A CN 201510344673A CN 104987733 A CN104987733 A CN 104987733A
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- bioconjugation
- modified asphalt
- petroleum pitch
- binding material
- road engineering
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Abstract
The invention discloses a biology binding material modified asphalt material used for road engineering and a preparing method thereof. A raw material is formed by matching of a biology binding material and petroleum asphalt, and the biology binding material modified asphalt material comprises, by weight, 5%-35% of the biology binding material and 65%-95% of the asphalt. The preparing method of the biology binding material modified asphalt material comprises the following specific steps that firstly, the biology binding material and the petroleum asphalt are heated to be at a temperature of 115 DEG C to 145 DEG C; secondly, the biology binding material and the petroleum asphalt in the first step are weighed; thirdly, the temperature of a mixture of the biology binding material and the petroleum asphalt is maintained to range from 130 DEG C to 190 DEG C by a constant temperature heating device, a high-speed cutting emulsifying device is adopted, the mixture is cut for 15 min to 60 min at a high rotating speed ranging from 500 rpm to 4000 rpm, the mixture is made to continue to develop through a stirring method until bubbles of the mixture basically disappear, and a finished product is obtained. The preparing technology is simple, and according to the produced biology binding material modified asphalt, the asphalt low-temperature ductility performance can be improved, the cost is low, sources are abundant, the yield is sufficient, and the environment is protected.
Description
Technical field
The invention belongs to pavement construction material field, relate to a kind of preparation technology and preparation method of road engineering bioconjugation material modified asphalt material.
Background technology
At present, the petroleum pitch of the binder used in bituminous pavement mostly for refining from crude oil, due to overexploitation and use, petroleum resources will be petered out.The present situation of petroleum resources and environmental development problem force the equivalent material of the continuous search for oil asphaltic binder of road investigator.Due to bioenergy comparatively fossil energy compared the features such as recyclability, the feature of environmental protection and economy, generally believe that bioenergy solves energy starved main method from now on both at home and abroad.Compared with petroleum pitch, bioconjugation material is similarly the product of the biological material course of processing, is refuse and the residue of biological industry, is obtained by complete processings such as the distillation of biological material, extraction, blending and oxidations.Bioconjugation material and petroleum pitch character close, using bioconjugation material as petroleum pitch substitute or material modified, both can realize the recycling of new forms of energy chemical field waste material, again for new developing direction opened up by road novel material.
Pitch is typically used as paves the way and water-proof material, belongs to a kind of thermoplastic material in essence.The road surface of asphalt paving used now by this property list, during summer high-temperature season, under heavy lift effect easily there is rut in road surface, easily warm plastic forming is there is during cold season in winter, along with the raising of road quality classification and the generally employing of Large-span Steel Box Beam structural bridge, very high requirement is proposed to the intensity of pavement material, deformation stability and fatigue durability etc., in use properties, also been proposed high agglutinating value(of coal) and the particular requirement such as waterproof simultaneously.As the important component part of bridge car system, the quality of deck paving directly has influence on the security of driving, comfortableness, bridge durability and economic benefit of investment.Obviously, so high performance requriements is that plain asphalt institute is incompetent, must use modifying asphalt.Although most of bioconjugation material has certain plasticity-and cohesiveness, and supporting capacity is general.
The bioconjugation material of usual employing derives from sawdust and the agroforestry such as stalk, rice husk by product or waste, although the Biological asphalt prepared to a certain extent can petroleum replacing pitch, but because in these waste materials, heavy ingredient is more, can affect greatly aspects such as the petroleum pitch low-temperature performancies mixed with it.This is very disadvantageous for this kind of Materials.Chinese patent CN1276820A discloses the made paraffin modification pitch of employing expense-holder synthesis method, but the shortcoming of this method to be the low-temperature performance of modifying asphalt bad, its use is subject to great limitation.Chinese patent 01126386.5 reports and adopts the filler of nucleocapsid structure independent or composite with polymkeric substance, as asphalt modifier to prepare the modifying asphalt of shelf-stable, but this method complicated process of preparation, production cost is high.
Summary of the invention
First object of the present invention is the deficiency that non-renewable petroleum pitch resource is petered out in order to solve, waste and scrap recycles problem and common Biological asphalt low-temperature performance aspect, and provides a kind of road engineering bioconjugation material modified asphalt material.
Second object of the present invention is to provide that a kind of preparation method is simple, the preparation method of the road engineering bioconjugation material modified asphalt material of handling ease.
For reaching above object, the present invention adopts following technical scheme to realize.
Raw material of the present invention is formed with parts by weight proportioning by bioconjugation material and petroleum pitch, and wherein, bioconjugation material weight percent is 5%--35%, and the weight percent of pitch is 65%--95%.
Bioconjugation material source is cottonseed and soybean, by resistates after refining grease through chemical technologies such as distillation, oxidations, and the appurtenant of acquisition.
The SBS modifying asphalt that petroleum pitch model is No. AH50, be matrix pitch modification with No. 70 pitches.
The road engineering preparation method of bioconjugation material modified asphalt material, specifically comprises the steps:
Step 1, respectively bioconjugation material and petroleum pitch are heated to 115-145 DEG C, make bioconjugation material and petroleum pitch have good mobility.
Step 2, take bioconjugation material and petroleum pitch in step 1.Carry out proportioning according to weight, wherein, bioconjugation material weight percent is 5%--35%, and the weight percent of petroleum pitch is 65%--95%.
Step 3, by thermostatically heating equipment, the blend temperature of bioconjugation material and petroleum pitch is maintained within the scope of 130--190 DEG C, adopt high speed shear emulsifying device with the blend 15--60min of the rotating speed high speed shear bioconjugation material of 500rpm--4000rpm and petroleum pitch, the blend of bioconjugation material and petroleum pitch is made to continue to grow by the mode stirred again, until the bubble mixed in blend disappears substantially, obtain finished product.
The mode stirred can be mechanical stirring equipment stirring at low speed, high-speed shearing equipment stirring at low speed or artificial Keep agitation or be manually interrupted.
The present invention has following useful technique effect:
1) preparation technology of the present invention is simple, the bioconjugation material modifying asphalt produced can improve the low-temperature ductility of petroleum pitch, effectively improve the antifreeze resistance to cleavage of petroleum pitch under low temperature environment, can partly replace road petroleum pitch, the consumption of non-renewable petroleum pitch can be slowed down to a certain extent;
2) bioconjugation material of the present invention derives from the waste material in industrial production, cheap, effectively can realize waste material recycling,
3) the bioconjugation material adopted in the present invention, its starting material are reproducible Biological resources, abundance, and output is sufficient, environmental protection.
Accompanying drawing explanation
Fig. 1 is a kind of road engineering bioconjugation material modified asphalt material preparation technology schema.
Embodiment
Below in conjunction with accompanying drawing 1, the present invention is described.
Embodiment 1:
One, bioconjugation material source is cottonseed and soybean, by resistates after refining grease through chemical technologies such as distillation, oxidations, and the appurtenant of acquisition; Respectively bioconjugation material and petroleum pitch are heated to 135 DEG C, make bioconjugation material and petroleum pitch have good mobility.
Two, the bioconjugation material 50g in step one is taken, AH50 model petroleum pitch 450g.
Three, by thermostatically heating equipment, the blend temperature of bioconjugation material and petroleum pitch is maintained 170 DEG C, adopt high speed shear emulsifying device with the blend 60min of the rotating speed high speed shear bioconjugation material of 4000rpm and petroleum pitch, the bioconjugation material made with 500rpm stirring at low speed by mechanical stirring equipment again and the blend of petroleum pitch continue to grow, until the bubble in the blend of bioconjugation material and petroleum pitch disappears substantially, obtain finished product.
Embodiment 2:
One, bioconjugation material source is cottonseed and soybean, by resistates after refining grease through chemical technologies such as distillation, oxidations, and the appurtenant of acquisition; Respectively bioconjugation material and petroleum pitch are heated to 130 DEG C, make bioconjugation material and petroleum pitch have good mobility.
Two, bioconjugation material 75g in step one is taken, the petroleum pitch 425g of AH50 model.
Three, by thermostatically heating equipment, the blend temperature of bioconjugation material and petroleum pitch is maintained 150 DEG C, adopt high speed shear emulsifying device with the blend 30min of the rotating speed high speed shear bioconjugation material of 3000rpm and petroleum pitch, continue to grow with the blend that 500rpm stirring at low speed makes with high speed shear emulsifying device again, until the bubble of the blend of bioconjugation material and petroleum pitch disappears substantially, obtain finished product.
Embodiment 3:
One, bioconjugation material source is cottonseed and soybean, by resistates after refining grease through chemical technologies such as distillation, oxidations, and the appurtenant of acquisition; Respectively bioconjugation material and petroleum pitch are heated to 140 DEG C, make bioconjugation material and petroleum pitch have good mobility.
Two, bioconjugation material 100g in step one is taken, SBS modifying asphalt 400g.
Three, by thermostatically heating equipment, the blend temperature of bioconjugation material and petroleum pitch is maintained 160 DEG C, adopt high speed shear emulsifying device with the blend 45min of the rotating speed high speed shear bioconjugation material of 2000rpm and petroleum pitch, the bioconjugation material made by the mode of hand mixing again and the blend of petroleum pitch continue to grow, until the bubble of the blend of bioconjugation material and petroleum pitch disappears substantially, obtain finished product.
The product adopting JTG E20-2011 " highway engineering pitch and Asphalt Mixture Experiment code " to prepare above-described embodiment respectively carries out the test of 25 DEG C of penetration degrees, 10 DEG C of ductilities.
Adopt U.S. PG classification technique index to carry out pitch test to embodiment in addition, test result is as shown in table 1.
After starting material and processing units meet related request of the present invention, the processing carrying out modifying asphalt can be started, the mode of instant processing is adopted to produce, namely process within ten hours before the use, produce horse back to use, stored under avoiding long-time (more than 24 hours) high temperature (more than 160 DEG C) as far as possible.
Claims (7)
1. a road engineering bioconjugation material modified asphalt material, it is characterized in that: raw material is formed with parts by weight proportioning by bioconjugation material and petroleum pitch, wherein, bioconjugation material weight percent is 5%--35%, the weight percent of pitch is 65%--95%.
2. a road engineering preparation method for bioconjugation material modified asphalt material, is characterized in that:
Step 1, respectively bioconjugation material and petroleum pitch are heated to 115-145 DEG C, make bioconjugation material and petroleum pitch have good mobility;
Step 2, take bioconjugation material and petroleum pitch in step 1, carry out proportioning according to weight according to claim 1;
Step 3, by thermostatically heating equipment, the blend temperature of bioconjugation material and petroleum pitch is maintained within the scope of 130--190 DEG C, adopt the blend 15--60min of high speed shear emulsifying device high speed shear bioconjugation material and petroleum pitch, the blend of bioconjugation material and petroleum pitch is made to continue to grow by the mode stirred again, until the bubble in the blend of bioconjugation material and petroleum pitch disappears substantially, obtain finished product.
3. the preparation method of road engineering bioconjugation material modified asphalt material according to claim 2, is characterized in that: described bioconjugation material is that the resistates after cottonseed and soybean refine grease passes through distillation, oxidation, the appurtenant of acquisition.
4. the preparation method of road engineering bioconjugation material modified asphalt material according to claim 2, is characterized in that: described pitch model is No. AH50, the SBS modifying asphalt that is matrix pitch modification with No. 70 pitches.
5. the preparation method of road engineering bioconjugation material modified asphalt material according to claim 2, is characterized in that: the rotating speed of high speed shear emulsifying device is 500rpm--4000rpm.
6. the preparation method of road engineering bioconjugation material modified asphalt material according to claim 2, is characterized in that: high speed shear emulsifying device is high-shear mixer or colloidal mill.
7. the preparation method of road engineering bioconjugation material modified asphalt material according to claim 2, is characterized in that: the mode of described stirring is: mechanical stirring equipment stirring at low speed, high-speed shearing equipment stirring at low speed, artificial Keep agitation or artificial occasional agitation.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105885442A (en) * | 2016-04-26 | 2016-08-24 | 哈尔滨工业大学 | Preparation method of chemically modified mixed biological asphalt |
CN107345073A (en) * | 2017-03-10 | 2017-11-14 | 东南大学 | A kind of asphalt pavement regeneration sealant and preparation method based on bioconjugation material |
CN108034269A (en) * | 2017-12-27 | 2018-05-15 | 山东理工大学 | A kind of nano biological modified pitch and preparation method thereof |
CN111665214A (en) * | 2020-07-23 | 2020-09-15 | 江西省交通科学研究院 | Method for measuring respective mixing amounts of SBS (styrene butadiene styrene) modifier and SBR (styrene butadiene rubber) modifier in modified asphalt |
Citations (5)
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CN102485800A (en) * | 2010-12-01 | 2012-06-06 | 周仁福 | Preparation method of modified biological tar asphalt |
CN102766340A (en) * | 2012-08-13 | 2012-11-07 | 交通运输部公路科学研究所 | Modified biological asphalt material, biological asphalt mixture, preparation method thereof and applications |
CN103497521A (en) * | 2013-09-18 | 2014-01-08 | 交通运输部公路科学研究所 | Vegetable oil modified asphalt composite and preparation method thereof |
CN103525100A (en) * | 2013-08-30 | 2014-01-22 | 银禧工程塑料(东莞)有限公司 | Asphalt modifier with low-temperature resistance and modified asphalt |
CN104109397A (en) * | 2013-04-19 | 2014-10-22 | 厦门大学 | Preparation for fiber composite powder and new technology of fiber composite powder as addition composition of modified asphalt |
-
2015
- 2015-06-19 CN CN201510344673.3A patent/CN104987733B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102485800A (en) * | 2010-12-01 | 2012-06-06 | 周仁福 | Preparation method of modified biological tar asphalt |
CN102766340A (en) * | 2012-08-13 | 2012-11-07 | 交通运输部公路科学研究所 | Modified biological asphalt material, biological asphalt mixture, preparation method thereof and applications |
CN104109397A (en) * | 2013-04-19 | 2014-10-22 | 厦门大学 | Preparation for fiber composite powder and new technology of fiber composite powder as addition composition of modified asphalt |
CN103525100A (en) * | 2013-08-30 | 2014-01-22 | 银禧工程塑料(东莞)有限公司 | Asphalt modifier with low-temperature resistance and modified asphalt |
CN103497521A (en) * | 2013-09-18 | 2014-01-08 | 交通运输部公路科学研究所 | Vegetable oil modified asphalt composite and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105885442A (en) * | 2016-04-26 | 2016-08-24 | 哈尔滨工业大学 | Preparation method of chemically modified mixed biological asphalt |
CN107345073A (en) * | 2017-03-10 | 2017-11-14 | 东南大学 | A kind of asphalt pavement regeneration sealant and preparation method based on bioconjugation material |
CN108034269A (en) * | 2017-12-27 | 2018-05-15 | 山东理工大学 | A kind of nano biological modified pitch and preparation method thereof |
CN111665214A (en) * | 2020-07-23 | 2020-09-15 | 江西省交通科学研究院 | Method for measuring respective mixing amounts of SBS (styrene butadiene styrene) modifier and SBR (styrene butadiene rubber) modifier in modified asphalt |
CN111665214B (en) * | 2020-07-23 | 2023-03-28 | 江西省交通科学研究院 | Method for measuring respective mixing amounts of SBS (styrene butadiene styrene) modifier and SBR (styrene butadiene rubber) modifier in modified asphalt |
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