CN101200596B - Powdered styrene-butadiene rubber polymer modified asphalt and preparation method thereof - Google Patents
Powdered styrene-butadiene rubber polymer modified asphalt and preparation method thereof Download PDFInfo
- Publication number
- CN101200596B CN101200596B CN2006101650159A CN200610165015A CN101200596B CN 101200596 B CN101200596 B CN 101200596B CN 2006101650159 A CN2006101650159 A CN 2006101650159A CN 200610165015 A CN200610165015 A CN 200610165015A CN 101200596 B CN101200596 B CN 101200596B
- Authority
- CN
- China
- Prior art keywords
- butadiene rubber
- temperature
- styrene
- raw material
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 136
- 229920003048 styrene butadiene rubber Polymers 0.000 title claims abstract description 134
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 229920000642 polymer Polymers 0.000 title abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 98
- 229920001971 elastomer Polymers 0.000 claims abstract description 77
- 239000005060 rubber Substances 0.000 claims abstract description 77
- 239000000843 powder Substances 0.000 claims abstract description 64
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 38
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 238000011049 filling Methods 0.000 claims abstract description 10
- 239000003208 petroleum Substances 0.000 claims abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000084 colloidal system Substances 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 3
- 239000011593 sulfur Substances 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 56
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 48
- 238000003756 stirring Methods 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- 238000002156 mixing Methods 0.000 claims description 31
- 239000003921 oil Substances 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 20
- 230000035484 reaction time Effects 0.000 claims description 18
- 230000003197 catalytic effect Effects 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 7
- 239000005864 Sulphur Substances 0.000 claims description 4
- 238000004523 catalytic cracking Methods 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 238000005194 fractionation Methods 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 32
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- 239000003607 modifier Substances 0.000 abstract description 5
- 239000011159 matrix material Substances 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000005204 segregation Methods 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 45
- 230000035515 penetration Effects 0.000 description 19
- 238000004519 manufacturing process Methods 0.000 description 18
- 239000011295 pitch Substances 0.000 description 18
- 239000002174 Styrene-butadiene Substances 0.000 description 17
- 239000010409 thin film Substances 0.000 description 17
- 239000002245 particle Substances 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 14
- 239000000126 substance Substances 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 238000005336 cracking Methods 0.000 description 6
- 238000010907 mechanical stirring Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 4
- 239000012452 mother liquor Substances 0.000 description 4
- 230000002929 anti-fatigue Effects 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000011301 petroleum pitch Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000010074 rubber mixing Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical class NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000003541 multi-stage reaction Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to an asphalt product which uses powder styrene butadiene rubber high molecular polymer as modifier to modify the matrix asphalt and a preparation method thereof, the asphalt product comprises 3-15 wt% of aromatic base rubber filling oil, 2-10 wt% of powder styrene butadiene rubber modifier and the balance of road asphalt, the aromatic base rubber filling oil is furfural extract oil with aromatic hydrocarbon content of 60-95% and heavy rubber filling oil, the road petroleum asphalt is asphaltene and naphthenic base thick oil asphalt with sulfur content of less than 0.5% and colloid content of more than 45%, the modifier is styrene butadiene rubber with molecular weight of 20-30 ten thousand, and styrene 21.5-35.0% is combined, the process is simple, the operation is convenient, the investment is less, and the energy consumption is low. Meanwhile, in the preparation process, the materials do not corrode equipment, the preparation process does not generate three wastes, the environment is not polluted, the intermiscibility among the raw materials is good, and the prepared product has stable performance and does not generate segregation phenomenon.
Description
Affiliated field
The present invention relates to a kind of polymer modified asphalt and preparation method thereof, specifically relate to a kind of powder styrene butadiene rubber high molecular polymer carries out modification to matrix pitch as properties-correcting agent asphaltic products. and preparation method thereof that utilizes.
Background technology
By introducing in " production of petroleum pitch and application " book that people such as Zhang Deqin write, Sinopec press publishes, domestic production styrene butadiene rubber modified asphalt technology mainly contains three kinds at present.The one, solvent method: solid styrene-butadiene rubber(SBR) is cut into small pieces, joins in the benzene class organic solvents such as toluene and dissolve, solvent is steamed after miscible with heated bitumen again, produce styrene butadiene rubber modified asphalt.The 2nd, emulsion method: styrene butadiene rubber latex is joined in the heated bitumen by mechanical stirring directly miscible, again moisture is steamed, produce styrene butadiene rubber modified asphalt; The 3rd, the calendering process method: by mixing facilities or two roller mill slice, the preparation masterbatch, and by the high speed shear mixing tank SBR blob of viscose directly is blended into and produces styrene butadiene rubber modified asphalt in the heated bitumen.
All there is certain defective in above-mentioned preceding two kinds of technologies: introduce noxious solvents such as toluene when solvent method is produced in the system, can cause serious environmental to pollute and to operator's murder by poisoning, and still contain a small amount of aromatic solvent in the product after reclaiming, influence the high temperature performance of product, cause the various diseases on road surface easily; Emulsion method can produce a large amount of water vapors when producing, cause " bumping " still that overflows easily, production endangers safety, simultaneously, latex stops up shower nozzle, etching apparatus easily, make troubles to production, and residual moisture can influence the high temperature performance of modifying asphalt in the product, has weakened the adhesivity with building stones, influences the pavement performance of product; When producing, calendering process need use mixing facilities or two roller mill and high speed shear mixing tank, the equal more complicated of production technique and equipment, production cost height.
Related article is analyzed:
" SBR modifying asphalt production application research ":
[author] Wang Jinqin [1] Luo Qiang [2] etc. [periodical name] petroleum pitch .2004,18 (1) .-35-38
[mechanism] [1] oil-refining chemical research institute of Kelamayi petro-chemical corporation, [2] Kelamayi petro-chemical corporation lubricating oil workshop
[digest] SBR modifying asphalt has good low-temperature performance, is widely used in the making of advanced road.Set forth the production technique Status of development of SBR modifying asphalt, introduced the process characteristic that SBR latex and rubber powder are produced modifying asphalt.With the fine road bitumen is raw material, is properties-correcting agent with the SBR rubber powder, goes out stable performance fine SBR modified bitumen product by " masterbatch is compound " explained hereafter.
Article is the exploration of carrying out at the subject study initial stage, and the technology in the article is inequality with the technology of being applied for a patent." masterbatch recombining process " in the article produced the SBR modifying asphalt and was divided into for two steps.The first step is to adopt the asphalt stock and the pre-consolute of SBR rubber powder of big penetration number, and under certain temperature and mechanical stirring processing condition, the SBR rubber powder is grown in pitch, held and expands, and is configured to masterbatch; Second step was that masterbatch is mixed with matrix pitch under certain process conditions, can produce satisfactory SBR modified bitumen product.What adopt in this technology is " asphalt stock of big penetration number " and the pre-consolute of SBR rubber powder, needs the SBR rubber powder to be dissolved away fully through long consolute, so the production cycle is long; And this patent " powder styrene butadiene rubber mother liquor dispersing and mixing technology " mixed a part of road bitumen and rich aromatic component before this, added the styrene-butadiene rubber(SBR) rubber powder under certain temperature and mechanical stirring, formed styrene-butadiene rubber(SBR) rubber cement mother liquor; And then the road bitumen of remainder joined in the styrene-butadiene rubber(SBR) masterbatch that configures, " miscible " produces satisfactory styrene butadiene rubber modified asphalt product under certain temperature and mechanical stirring.Adopt in this technology be " road bitumen and rich aromatic component mix back " again with SBR rubber powder consolute, rich aromatic component and SBR have consistency preferably, so solute effect is good, can shorten the production cycle greatly.
Relevant patent analyses:
＜application number〉90106343.6 disclosed styrene butadiene rubber modified asphalt and method for makings, have following characteristics: form by a certain percentage by petroleum pitch, styrene-butadiene rubber(SBR), solubility promoter, Polyolefin and sulphur; Styrene-butadiene rubber(SBR) is low temperature copolymerization, random linear glue, and solubility promoter is high aromatic hydrocarbons petroleum cuts.Modifying asphalt of the present invention has system stability and higher thermotolerance and low temperature flexibility is arranged.By its modified asphalt felt of making, can be used for building roof waterproof, the penetration degree 10-80 of this invention modifying asphalt, 100 ℃-120 ℃ of softening temperatures, brittle point-35 ℃.The present invention compares with the patent that we declare and has 3 differences: raw material is different, end-use difference, product index difference.＜application number〉92108804.3 disclosed rubber modified asphalt and the method for makings that are used for waterproof roll.The present invention is a kind of rubber modified asphalt and preparation method who is used to prepare the adhesive waterproof coil of cold construction, rubber modified asphalt is by pitch 40%～60% (m/m), SBR3%～15% (m/m), SBS2%～10% (m/m), mineral oil 20%～50% (m/m) is formed.The patent difference that this invention and we declare is bigger: adopt the SBR-SBS composite modifier, product is mainly used in adhesive waterproof coil, contains mineral oil 20%～50% in the composition.
＜application number〉02114801.5 disclosed rubber modified asphalt material for road and preparation method thereof, this material adopts organic grafts and/or cross-linked composite to carry out chemical modification and forms, wherein organic grafts is selected from organic ethylenic unsaturation alkylene dicarboxylate and ester, acid anhydrides or the mixture between them, and cross-linked composite is the mixture of vulcanizing agent and vulcanization aid.A kind of method for making of this material is that rubber solutions adds organic grafts reaction earlier, adds the pitch mixing, adds the cross-linked composite reaction again and forms; Another method for making is earlier rubber to be scattered in the pitch, adds the reaction of organic grafts and cross-linked composite again and forms.This invention is bigger with the patent difference that we declare: raw material is different, reaction mechanism difference, technology difference.
＜application number〉manufacture method of 02114800.7 1 kinds of rubber modified asphalts.A kind of manufacture method comprises (1), earlier rubber and pitch is made the modifying asphalt condensation product by 100: 50～500 weight ratio banburying; (2), in heated bitumen, add the modifying asphalt condensation product of step (1), admixture stablizer aromatic hydrocarbons and/or hydrocarbon with condensed rings, dispersed with stirring is after milling treatment of colloid.Another kind of manufacture method comprises (a), part rubber modifier and pitch is refined into the modifying asphalt condensation product; (b), all the other pitches and rubber stirred be warming up to 150 ℃～200 ℃, make the abundant swelling of rubber; (c), the modifying asphalt condensation product of (a) step is dropped in the rubber asphalt of (b) step, add stablizer aromatic hydrocarbons and/or hydrocarbon with condensed rings, dispersed with stirring is after milling treatment of colloid.This invention needs through equipment such as Banbury mixer, colloidal mill, complex process, loaded down with trivial details.
＜application number〉preparation method of 03135004.6 waste rubber powder modified asphalt.The present invention adopts two step process to prepare rubber powder modified asphalt masterbatch and rubber powder/polymer composite modified asphalt, at first, 140 ℃-250 ℃ of temperature, under the high speed shear condition, preparation high density rubber powder modified asphalt masterbatch, rubber powder content＞20%, then, 140 ℃-230 ℃ of temperature, under the high speed shear condition, masterbatch is diluted to desired concn, adds polymkeric substance and linking agent, preparation rubber powder/polymer composite modified asphalt.This invents used properties-correcting agent is shoddy, need just can finish modification by high speed shear, and there is some difference with patent that we declare.
＜application number〉the styrene butadiene rubber modified asphalt preparation method of 03150929.0 high temperature storage stable.The inventive method is passed through styrene-butadiene rubber(SBR), filler (carbon black) and processing aid (aromatic hydrocarbon oil, naphthenic oil, pitch) two roller mill slices earlier, obtains the modifying asphalt masterbatch, and then by the high speed shear mixing tank this masterbatch fully is distributed in the matrix pitch.Styrene-butadiene rubber(SBR) in this invention is the synthetic rubber of industrial general, and production unit will be used two roller mills, high speed shear mixing tank etc., and technology is complicated; In addition in the product owing to add carbon black, carbon black is easily separated out in the heating use, influences the actual use properties of product.
＜application number〉02116763 make the method for the thermoplastic olefine polymer modified asphalt have good stability.The present invention has announced that a kind of is the method that properties-correcting agent is made modifying asphalt with thermoplastic olefin polymer SBS or SBR unvulcanized rubber, present method has added one package stabilizer when with SBS or SBR pitch being carried out modification, and this one package stabilizer is made up of density of aromatic hydrocarbon conditioning agent, zinc oxide, sulphur, N-replacement 2-[4-morpholinodithio sulphenamide, zinc salt of dithiocarbamate, Ursol D class.The patent that this invention and we declare is distinguished bigger on raw material.
＜application number〉production technique of 01,133,679 1 kinds of polymer modified asphalts.The present invention relates to a kind of production technique of polymer modified asphalt, the steps include: that (1) is warming up to the 140-210 degree with 100 parts of pitches; (2) in the described pitch of step (1), add the properties-correcting agent of 2-20 part, and carry out agitation cycle; (3) in the mixture of step (2), add 0.1-2 part stablizer; (4) levigate finished product.Properties-correcting agent accounts for 2-20 part in this invention, has added stablizer in preparation process, also needs finished product levigate.The patent that this and we declare is bigger in difference.
＜application number〉preparation method of 99,116,033 1 kinds of polymer modified asphalts.The invention provides a kind of preparation method of polymer modified asphalt, this law is from improving the consistency of polymkeric substance pitch and reducing the bituminous temperature sensitivity and start with, select that the rubber rubber mixing machine of high shear force is prefabricated to contain a small amount of bituminous modified master, solve pitch and polymkeric substance and be difficult to the uniform mixing problem.The proportioning of modified master is polymkeric substance 100 weight parts, pitch 100～200 weight parts, aromatic resin 5～50 weight parts, carbon black 2～20 weight parts, anti-aging agent 0～1 weight part; Place whipping appts to mix simultaneously with modified master 8～40 weight parts pitch 100 weight parts that are heated to 155～160 ℃, promptly make modifying asphalt.Comprise resin, carbon black, anti-aging agent etc. in the raw material of this invention, also will use the rubber mixing machine of high shear force, the patent difference of declaring with us is bigger.
Summary of the invention:
One of purpose of the present invention is to provide a kind of powder styrene butadiene rubber modified bitumen product, this constant product quality, can residual organic solvent and moisture in the product, guaranteed the adhesion property good with the road surface, high temperature performance is good, satisfies bituminous pavement high temperature resistance rut, anti-cold cracking and the requirement of antifatigue cracking performance fully.
Another object of the present invention is to provide a kind of preparation method of powder styrene butadiene rubber modified bitumen product, compared with prior art preparation technology is simpler for it, overcome traditional contaminate environment that solvent method caused in process of production, poisoned operator ' s health, influenced the defectives such as high temperature performance of product, avoid numerous and diverse recovery dissolving agent process simultaneously, can not cause equipment corrosion and environmental pollution.
" mother liquor disperses blending " of the present invention, preparation technology in two steps.Before this a part of road bitumen and aromatic base rubber filling oil were mixed, under certain temperature and mechanical stirring, added the styrene-butadiene rubber(SBR) rubber powder, formed styrene-butadiene rubber(SBR) rubber cement mother liquor; And then the basic asphalt of remainder joined in the styrene-butadiene rubber(SBR) masterbatch that configures, " miscible " produces satisfactory styrene butadiene rubber modified asphalt product under certain temperature and mechanical stirring.The product that present method is produced has good low temperature extension performance, low temperature anti-cracking performance, antifatigue cracking performance and better weather energy, can improve the bituminous pavement use properties effectively and increase the service life.The product of this explained hereafter meets the technical requirements of styrene butadiene rubber modified asphalt among the JTG F40-2004 " asphalt highway construction technique normalizing ".
Technical scheme of the present invention realizes by following measure: will account for raw material gross weight 3%～15%, temperature earlier and be 60 ℃～80 ℃ aromatic base rubber filling oil and account for that the raw material gross weight is 27%～43%, temperature is that 130 ℃～150 ℃ wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 100 ℃～150 ℃ temperature condition; Then in the above-mentioned feed liquid that mixes, slowly adding the powder styrene butadiene rubber polymeric properties-correcting agent that accounts for raw material gross weight 2%～10% while stirring dissolves, 120 ℃～150 ℃ of control reaction temperature are disperseed the miscible styrene-butadiene rubber(SBR) masterbatch liquid that becomes even light fully until rubber powder; The road bitumen that is 130 ℃～150 ℃ with temperature at last, accounts for the remainder of raw material gross weight 32%～68% joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 140 ℃～160 ℃ of temperature of reaction, in 2～7 hours reaction times, obtain the styrene butadiene rubber polymeric modified asphalt product.
In the above-mentioned styrene butadiene rubber polymeric modified asphalt, the furfural extract oil that petroleum fractions that described aromatic base rubber filling oil is the cycloalkyl viscous crude or the petroleum fractions of paraffinic crude after solvent dewaxing obtain through furfural treatment, the turning oil of catalytic cracking unit or catalytic slurry are through pulling out a fractionation, concocting the heavy rubber filling oil of making, and its aromaticity content is 60%～95%.Or the suitable product of character of other petroleum chemical enterprise's production.
In the above-mentioned styrene butadiene rubber polymeric modified asphalt, described road bitumen is 70#, 90# or 110# heavy traffic paving asphalt, or the suitable bi tumenf orr oad product of character that adopts other petroleum chemical enterprise to produce.This bi tumenf orr oad is that bituminous matter and sulphur content less than 0.5%, gum level are up to the low bituminous matter more than 45%, high colloid, low-sulfur cycloalkyl heavy oil asphalt.
In the above-mentioned styrene butadiene rubber polymeric modified asphalt, described properties-correcting agent is molecular weight 200,000～300,000, the styrene-butadiene rubber(SBR) of combined styrene 21.5～35.0%, and granularity is in 20 orders, crude rubber Mooney viscosity ML
1+4 100 ℃Be 38～68, its styrene-butadiene rubber(SBR) or other disclosed styrene-butadiene rubber(SBR) that is applicable to that asphalt modification is used that asphalt modification is used that is applicable to for selling on the market.
The styrene butadiene rubber modified asphalt product that adopts powder styrene butadiene rubber to produce, its low-temperature performance is outstanding, 5 ℃ of ductilities of residue behind the rotating thin film baking oven are greater than 100cm, have characteristics such as good low temperature extension performance, low temperature anti-cracking performance, antifatigue cracking performance and better weather energy, can improve the bituminous pavement use properties effectively and prolong road work-ing life; The binder that obtains after product of the present invention and building stones mix and stir shows good water stability and high low-temperature stability, and especially low-temperature performance has clear superiority; Because the present invention is except that properties-correcting agent styrene-butadiene rubber(SBR), the main raw material that is adopted is the high aromatic hydrocarbon content component of producing in the road bitumen that derives from crude oil and the petroleum refining process, therefore intermiscibility is good between each raw material, and the product performance of preparing are stable, can not produce segregation phenomenon.
The preparation method of product of the present invention only need adopt common whipping device can finish the hybrid reaction process, need not mixing roll and high-speed shearing equipment, so technology is simple, and is easy to operate, less investment, and energy consumption is low.In the preparation process, material is etching apparatus not simultaneously, and preparation technology does not produce the three wastes, environmentally safe.
Embodiment
Further illustrate implementation of the present invention and characteristics below in conjunction with embodiment, but the present invention is not subjected to the restriction of following embodiment, can determines concrete embodiment according to technical scheme of the present invention and practical situation.
The used aromatic component feedstock property that is rich in of following examples sees Table 1.
Several feedstock properties of table 1
Embodiment 1:
To account for raw material gross weight 3.0%, temperature earlier and be 60 ℃ pull out the turning oil after the head blending and account for that the raw material gross weight is 27.0%, temperature is that 130 ℃ the 90# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 130 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 2.0% while stirring and be 14 orders, molecular weight and be 280,000, styrene content is 28%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 42 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 131 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 68.0%, temperature at last and be 130 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 143 ℃ of temperature of reaction, 3.5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 78 (0.1mm), (25 ℃ is greater than 100cm 5cm/min) to ductility, 50.8 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 60cm.
Embodiment 2:
To account for raw material gross weight 7.0%, temperature earlier and be 62 ℃ catalytic slurry and account for that the raw material gross weight is 41.3%, temperature is that 150 ℃ the 90# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 150 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 2.3% while stirring and be 20 orders, molecular weight and be 200,000, styrene content is 28%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 49 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 132 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 49.4%, temperature at last and be 150 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 160 ℃ of temperature of reaction, 2 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 103 (0.1mm), (25 ℃ is greater than 110cm 5cm/min) to ductility, 46.1 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 80cm.
Embodiment 3:
To account for raw material gross weight 8.0%, temperature earlier and be 80 ℃ through the extraction oil KA8030 of furfural treatment and account for that the raw material gross weight is 38.7%, temperature is that 134 ℃ the 70# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 128 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 2.5% while stirring and be 5 orders, molecular weight and be 300,000, styrene content is 21.5%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 48 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 130 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 50.8%, temperature at last and be 134 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 144 ℃ of temperature of reaction, 3.4 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 102 (0.1mm), (25 ℃ is greater than 110cm 5cm/min) to ductility, 47.0 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 80cm.
Embodiment 4:
To account for raw material gross weight 8.0%, temperature earlier and be 67 ℃ catalytic slurry and account for that the raw material gross weight is 36.8%, temperature is that 138 ℃ the 90# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 125 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 2.5% while stirring and be 5 orders, molecular weight and be 250,000, styrene content is 21.5%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 51 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 134 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 52.7%, temperature at last and be 138 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 147 ℃ of temperature of reaction, 3.5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 95 (0.1mm), (25 ℃ is greater than 120cm 5cm/min) to ductility, 48.6 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 80cm.
Embodiment 5:
To account for raw material gross weight 8.0%, temperature earlier and be 65 ℃ turning oil and account for that the raw material gross weight is 34.6%, temperature is that 140 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 113 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 2.5% while stirring and be 5 orders, molecular weight and be 260,000, styrene content is 21.5%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 38 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 136 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 54.9%, temperature at last and be 140 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 152 ℃ of temperature of reaction, 5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 106 (0.1mm), (25 ℃ is greater than 120cm 5cm/min) to ductility, 46.0 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 80cm.
Embodiment 6:
To account for raw material gross weight 9.0%, temperature earlier and be 69 ℃ through the extraction oil KA8030 of furfural treatment and account for that the raw material gross weight is 37.5%, temperature is that 143 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 120 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 3.0% while stirring and be 10 orders, molecular weight and be 240,000, styrene content is 31%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 55 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 140 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 50.5%, temperature at last and be 143 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 145 ℃ of temperature of reaction, 4.2 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 108 (0.1mm), (25 ℃ is greater than 130cm 5cm/min) to ductility, 46.3 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 100cm.
Embodiment 7:
To account for raw material gross weight 9.0%, temperature earlier and be 70 ℃ turning oil and account for that the raw material gross weight is 36.5%, temperature is that 150 ℃ the 70# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 115 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 3.5% while stirring and be 10 orders, molecular weight and be 220,000, styrene content is 26%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 58 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 138 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 51.0%, temperature at last and be 150 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 156 ℃ of temperature of reaction, 3.6 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 82 (0.1mm), (25 ℃ is greater than 100cm 5cm/min) to ductility, 48.8 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 80cm.
Embodiment 8:
To account for raw material gross weight 10.0%, temperature earlier and be 75 ℃ turning oil and account for that the raw material gross weight is 29.6%, temperature is that 145 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 105 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 4.0% while stirring and be 16 orders, molecular weight and be 210,000, styrene content is 28%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 60 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 142 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 56.4%, temperature at last and be 145 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 155 ℃ of temperature of reaction, 3 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 102 (0.1mm), (25 ℃ is greater than 150cm 5cm/min) to ductility, 46.0 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 100cm.
Embodiment 9:
To account for raw material gross weight 9.0%, temperature earlier and be 73 ℃ catalytic slurry and account for that the raw material gross weight is 35%.0, temperature is that 147 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 118 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 3.5% while stirring and be 6 orders, molecular weight and be 230,000, styrene content is 35%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 66 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 129 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 52.5%, temperature at last and be 147 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 157 ℃ of temperature of reaction, 2.5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 105 (0.1mm), (25 ℃ is greater than 120cm 5cm/min) to ductility, 45.9 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 100cm.
Embodiment 10:
To account for raw material gross weight 10.0%, temperature earlier and be 77 ℃ catalytic slurry and account for that the raw material gross weight is 27%.0, temperature is that 131 ℃ the 70# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 100 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 4.0% while stirring and be 8 orders, molecular weight and be 270,000, styrene content is 25%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 64 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 129 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 59.0%, temperature at last and be 131 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 146 ℃ of temperature of reaction, 3.4 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 62 (0.1mm), (25 ℃ is greater than 100cm 5cm/min) to ductility, 51.9 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 60cm.
Embodiment 11:
To account for raw material gross weight 10.0%, temperature earlier and be 71 ℃ through the extraction oil KA8520 of furfural treatment and account for that the raw material gross weight is 43.0%, temperature is that 148 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 110 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 5.0% while stirring and be 15 orders, molecular weight and be 300,000, styrene content is 33%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 68 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 150 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 42.0%, temperature at last and be 148 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 158 ℃ of temperature of reaction, 4.5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 96 (0.1mm), (25 ℃ is greater than 130cm 5cm/min) to ductility, 48.2 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 100cm.
Embodiment 12:
To account for raw material gross weight 6.5%, temperature earlier and be 76 ℃ through furfural treatment subtract four lines extract oil out and account for that the raw material gross weight is 40.0%, temperature is that 142 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 140 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 5.5% while stirring and be 20 orders, molecular weight and be 250,000, styrene content is 28%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 61 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 145 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 48.0%, temperature at last and be 142 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 155 ℃ of temperature of reaction, 5.5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 87 (0.1mm), (25 ℃ is greater than 150cm 5cm/min) to ductility, 49.2 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 100cm.
Embodiment 13:
To account for raw material gross weight 7.5%, temperature earlier and be 80 ℃ turning oil and account for that the raw material gross weight is 29.8%, temperature is that 135 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 135 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 6.7% while stirring and be 18 orders, molecular weight and be 230,000, styrene content is 31%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 62 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 147 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 56.0%, temperature at last and be 135 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 140 ℃ of temperature of reaction, 7 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 76 (0.1mm), (25 ℃ is greater than 150cm 5cm/min) to ductility, 53.2 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 150cm.
Embodiment 14:
To account for raw material gross weight 8.5%, temperature earlier and be 80 ℃ catalytic slurry and account for that the raw material gross weight is 27.0%, temperature is that 137 ℃ the 110# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 130 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 7.3% while stirring and be 12 orders, molecular weight and be 270,000, styrene content is 26%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 56 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 128 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 57.2%, temperature at last and be 137 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 142 ℃ of temperature of reaction, 6.5 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 99 (0.1mm), (25 ℃ is greater than 150cm 5cm/min) to ductility, 48.6 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 150cm.
Embodiment 15:
To account for raw material gross weight 9.5%, temperature earlier and be 65 ℃ catalytic slurry and account for that the raw material gross weight is 41.0%, temperature is that 140 ℃ the 90# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 123 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 8.7% while stirring and be 16 orders, molecular weight and be 300,000, styrene content is 28%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 59 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 125 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 40.8%, temperature at last and be 140 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 150 ℃ of temperature of reaction, 6 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 102 (0.1mm), (25 ℃ is greater than 150cm 5cm/min) to ductility, 49.1 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 150cm.
Embodiment 16:
To account for raw material gross weight 15.0%, temperature earlier and be 70 ℃ catalytic slurry and account for that the raw material gross weight is 43.0%, temperature is that 146 ℃ the 70# of wherein first part road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 145 ℃ of temperature condition; Then in the above-mentioned feed liquid that mixes, slowly add the mean particle size that accounts for raw material gross weight 10.0% while stirring and be 18 orders, molecular weight and be 200,000, styrene content is 28%, crude rubber Mooney viscosity ML
1+4 100 ℃Be that 38 powder styrene butadiene rubber polymeric properties-correcting agent dissolves, 120 ℃ of control reaction temperature become the styrene-butadiene rubber(SBR) masterbatch of even light after the rubber powder complete reaction; The road bitumen that will account for raw material gross weight 32.0%, temperature at last and be 146 ℃ remainder joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 160 ℃ of temperature of reaction, 4 hours reaction times prepared the styrene butadiene rubber polymeric modified asphalt product, (25 ℃ of its penetration degrees, 100g, 5s) be 104 (0.1mm), (25 ℃ is greater than 150cm 5cm/min) to ductility, 48.3 ℃ of softening temperatures, 5 ℃ of ductilities of the residue behind the rotating thin film baking oven are greater than 150cm.
Claims (5)
1. the preparation method of a powder styrene butadiene rubber polymeric modified asphalt, it is characterized in that: will account for raw material gross weight 3%～15%, temperature earlier and be 60 ℃～80 ℃ aromatic base rubber filling oil and account for that the raw material gross weight is 27%～43%, temperature is that 130 ℃～150 ℃ road bitumen joins in the reactor, it is even to be stirred well to two kinds of raw material thorough mixing under 100 ℃～150 ℃ temperature condition; Then in the above-mentioned feed liquid that mixes, slowly adding the powder styrene butadiene rubber polymeric properties-correcting agent that accounts for raw material gross weight 2%～10% while stirring dissolves, 120 ℃～150 ℃ of control reaction temperature are disperseed the miscible styrene-butadiene rubber(SBR) masterbatch liquid that becomes even light fully until rubber powder; The road bitumen that is 130 ℃～150 ℃ with temperature at last, accounts for raw material total weight percent residual content joins in the styrene-butadiene rubber(SBR) masterbatch that has prepared while stirring, 140 ℃～160 ℃ of temperature of reaction, in 2～7 hours reaction times, prepare styrene butadiene rubber polymeric modified asphalt.
2. according to the preparation method of the described powder styrene butadiene rubber polymeric modified asphalt of claim 1, it is characterized in that: the aromatic base rubber filling oil is the turning oil of the petroleum fractions of cycloalkyl viscous crude or furfural extract oil that the petroleum fractions of paraffinic crude after solvent dewaxing obtains through furfural treatment, catalytic cracking unit or catalytic slurry through pulling out the heavy rubber filling oil that a fractionation, blending are made, and its aromaticity content is 60%～95%.
3. according to the preparation method of the described powder styrene butadiene rubber polymeric modified asphalt of claim 1, it is characterized in that: road bitumen is 70#, 90# or 110# heavy traffic paving asphalt, or character identical bi tumenf orr oad, this bi tumenf orr oad is bituminous matter and sulphur content＜0.5%, the low bituminous matter of gum level＞45%, high colloid, low-sulfur cycloalkyl heavy oil asphalt.
4. according to the preparation method of the described powder styrene butadiene rubber polymeric modified asphalt of claim 1, it is characterized in that: properties-correcting agent is molecular weight 200,000～300,000, the styrene-butadiene rubber(SBR) of combined styrene 21.5～35.0%, and granularity is in 20 orders, crude rubber Mooney viscosity ML
1+4 100 ℃Be 38～68.
5. powder styrene butadiene rubber polymeric modified asphalt is characterized in that: it is preparation method's preparation according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006101650159A CN101200596B (en) | 2006-12-12 | 2006-12-12 | Powdered styrene-butadiene rubber polymer modified asphalt and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006101650159A CN101200596B (en) | 2006-12-12 | 2006-12-12 | Powdered styrene-butadiene rubber polymer modified asphalt and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101200596A CN101200596A (en) | 2008-06-18 |
| CN101200596B true CN101200596B (en) | 2010-09-08 |
Family
ID=39515971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006101650159A Active CN101200596B (en) | 2006-12-12 | 2006-12-12 | Powdered styrene-butadiene rubber polymer modified asphalt and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101200596B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475341B (en) * | 2009-01-12 | 2012-01-25 | 华北建设集团有限公司 | Asphalt pavement pit repairing binder |
| CN102816447B (en) * | 2012-09-03 | 2015-04-22 | 唐晓旭 | Production and application methods of ductility-enhancing modifier for road asphalt |
| CN105017782A (en) * | 2015-07-30 | 2015-11-04 | 华南理工大学 | High-grade road asphalt and preparation method thereof |
| CN109401344B (en) * | 2018-10-16 | 2021-06-29 | 北京东方雨虹防水技术股份有限公司 | Coating material, preparation method thereof and modified asphalt waterproof coiled material |
| CN110003672B (en) * | 2019-04-17 | 2021-05-04 | 山东显元化工研究院有限公司 | SBR (styrene butadiene rubber) modified asphalt and preparation method thereof |
| CN110016234B (en) * | 2019-04-17 | 2021-06-04 | 山东显元化工研究院有限公司 | SBR (styrene butadiene rubber) latex for modified emulsified asphalt and preparation method thereof |
| CN111718586A (en) * | 2020-06-12 | 2020-09-29 | 广东石油化工学院 | Preparation method of aromatic oil special for radial tires |
| CN114075432B (en) * | 2020-08-20 | 2023-04-28 | 中国石油化工股份有限公司 | Deep plugging control system and steam steering method for thickened oil thermal recovery well |
| CN114426411B (en) * | 2020-10-29 | 2023-05-16 | 中国石油化工股份有限公司 | Pavement repair material and preparation method and application thereof |
| CN116063857B (en) * | 2021-10-29 | 2024-06-04 | 中国石油化工股份有限公司 | Polymer mother liquor and preparation method thereof, and No. 50A grade asphalt and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053438A (en) * | 1990-12-21 | 1991-07-31 | 齐鲁石油化工公司研究院 | Styrene butadiene rubber modified asphalt and preparation method thereof |
| CN1105371A (en) * | 1993-12-28 | 1995-07-19 | 中国石化齐鲁石油化工公司 | Novel styrene butadiene rubber asphalt modifier |
| CN1443825A (en) * | 2002-03-12 | 2003-09-24 | 尹中平 | Asphalt pavement crack-filling agent and its preparation method |
| CN1519277A (en) * | 2003-01-22 | 2004-08-11 | 中国石油化工股份有限公司北京燕山分 | Modified compsn. of asphaltum and preparation method |
| CN1584211A (en) * | 2004-06-09 | 2005-02-23 | 吉林省交通科学研究所 | High-performance road surface fissures cementing materials and preparing process |
-
2006
- 2006-12-12 CN CN2006101650159A patent/CN101200596B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053438A (en) * | 1990-12-21 | 1991-07-31 | 齐鲁石油化工公司研究院 | Styrene butadiene rubber modified asphalt and preparation method thereof |
| CN1105371A (en) * | 1993-12-28 | 1995-07-19 | 中国石化齐鲁石油化工公司 | Novel styrene butadiene rubber asphalt modifier |
| CN1443825A (en) * | 2002-03-12 | 2003-09-24 | 尹中平 | Asphalt pavement crack-filling agent and its preparation method |
| CN1519277A (en) * | 2003-01-22 | 2004-08-11 | 中国石油化工股份有限公司北京燕山分 | Modified compsn. of asphaltum and preparation method |
| CN1584211A (en) * | 2004-06-09 | 2005-02-23 | 吉林省交通科学研究所 | High-performance road surface fissures cementing materials and preparing process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101200596A (en) | 2008-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101200596B (en) | Powdered styrene-butadiene rubber polymer modified asphalt and preparation method thereof | |
| CN101616997B (en) | Rejuvenating agent and process for recycling of asphalt | |
| US10479892B2 (en) | Functional group asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making | |
| CN100567399C (en) | A kind of rubber powder modified asphalt and working method thereof | |
| Kalantar et al. | A review of using waste and virgin polymer in pavement | |
| CN102051056B (en) | Styrene-butadiene rubber modified asphalt composition and preparation method thereof | |
| CN101235172B (en) | Asphalt pavement rubber plastic composite anti-rut agent and preparation method thereof | |
| CN102131857B (en) | Bitumen composition | |
| US11142667B2 (en) | Asphalt additive compositions and methods of making and using thereof | |
| US10487209B2 (en) | Micronized asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making | |
| US8758597B2 (en) | Reclaimed asphalt pavement | |
| US10294370B2 (en) | Polyolefin asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making | |
| CN105419355B (en) | A kind of nano material composite modified pitch of fine waste Crumb rubber and preparation method thereof | |
| KR20130067292A (en) | Method for producing agglomerates having rubber and wax, agglomerates produced according to said method, and use of said agglomerates in asphalts or bitumen masses | |
| US9944796B1 (en) | Recycled oil- and rubber-modified asphalt and method of use | |
| CN105110685A (en) | High visco-elastic warming mixing modifying agent for asphalt road and production method and application of high visco-elastic warming mixing modifying agent | |
| Agudelo et al. | Ground tire rubber and bitumen with wax and its application in a real highway | |
| CN102337035A (en) | Waste plastic modified asphalt and preparation method thereof | |
| US20150105495A1 (en) | Polymeric asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making | |
| EP3249017A1 (en) | A bitumen composition comprising a wax mixture consisting of a petroleum slack wax and a fischer-tropsch wax, the use of the wax mixture in bitumen compositions, the use of the bitumen composition in asphalt compositions, asphalt compositions comprising the bitumen composition and the method of producing asphalt pavements thereof | |
| CN104693823A (en) | Direct-vat type high-adhesion bituminous mixture modifier and preparation method thereof | |
| CN109384989A (en) | A kind of environment-friendly type anti-rutting asphalt mixture that wet-dry change combines | |
| CN105802263B (en) | A kind of high glue pitch and preparation method thereof | |
| CN101985524A (en) | Compound SBS modified asphalt and preparation method thereof | |
| Ge | The Laboratory Performance and Aging Characteristics of Rubber Modified Asphalt Mixture Using a Dry Process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180718 Address after: 100007 Dongzhimen North Street, Dongcheng District, Dongcheng District, Beijing Co-patentee after: CNPC KARAMAY PETROCHEMICAL CO.,LTD. Patentee after: PetroChina Company Limited Address before: 100011 Beijing city Dongcheng District No. 16 Andrew intercontinental building Patentee before: PetroChina Company Limited |