CN104981446B - Remove the amino acid fertilizer and preparation method thereof of stench - Google Patents
Remove the amino acid fertilizer and preparation method thereof of stench Download PDFInfo
- Publication number
- CN104981446B CN104981446B CN201380072858.2A CN201380072858A CN104981446B CN 104981446 B CN104981446 B CN 104981446B CN 201380072858 A CN201380072858 A CN 201380072858A CN 104981446 B CN104981446 B CN 104981446B
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- amino acid
- acid fertilizer
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- fragrance
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The present invention provides a kind of method preparing novel amino fertilizer, the method by the Maillard reaction of sulfur-containing amino acid and reduced sugar come to being used as amino acid fertilizer the shortcomings that stench and fishy smell assign strong fragrance, potato fragrance etc. and make one to smell known fragrance, so as to eliminate the rejection feeling of fertilising person, physiologically active of plant can be promoted by using sulfur-containing amino acid simultaneously, therefore there is effect outstanding.
Description
Technical field
A kind of stench for the shortcomings that the present invention relates to amino acid fertilizers as animality is removed and added with to promoting to plant
Object grows the preparation method of the amino acid fertilizer of effective sulfur-containing amino acid.
Background technology
The preparation of existing amino acid fertilizer is by the liquid by-product of amino acid fermentation to being generated when generation seasoning to Tu
Feather of blood meal and poultry generated in the process etc. is killed to carry out enzyme fermentation or hydrolysis etc. to prepare.Unlike this, in South Korea
The amino acid liquid fertilizer using the blood of domestic animal is disclosed in patent gazette the 10-980595th, in Korean patent publication No.
The preparation method of the compound amino acid fertilizer using chicken feather is disclosed in No. 10-284976.
The animality amino acid fertilizer, although can be variant according to the processing procedure of raw material and decomposition method,
With the unpleasant taste for bringing rejection feeling, therefore, can be asked using upper in the presence of there is a situation where headaches etc. after fertilising
Topic.As disclosed in Korean patent publication No. 10-241336, the solution containing amino acid that will be prepared by acidolysis is used
When making fertilizer, acid proof equipment is needed to neutralize solution, not only needs many installation costs, but also air can be caused dirty
Dye, therefore, in normal circumstances, mostly uses greatly the method for enzymolysis or alkaline hydrolysis to prepare, but compared with acidolysis, smells and allow
People is sick in the stomach, and therefore, after use can cause obstinate headache or feel the stress, therefore exists and need to improve it in time
The problem of.
In addition, the method that the l-cysteine of sulfur-bearing is extracted and prepared from from the protein of animal, it has been disclosed that at this
In the Korean patent publication No. 10-1023538 that inventor publishes.
Invention content
Technical problems to be solved
Therefore, it is an object of the present invention to by using the Maillard reaction used in food preparation section
(maillard reaction) technology is familiar and strong to assignFragrance, and pass through adjust it is beautiful
The amount of the sulfur-containing amino acid added in Maillard reaction, it is excellent so as to provide a kind of facilitation effect to plant growth, and
And eliminate the novel amino fertilizer for the stench for allowing people to be sick in the stomach.
Technical solution
The present invention realizes above-mentioned purpose by Maillard reaction.Specifically by the amino of amino acid, peptide and protein
With ketone, aldehyde, especially reacted with reduced sugar, to remove the unpleasant stench of all fertilizer materials containing amino acid, to
Generate strong fragrance and brown pigment, and it is unrelated with the decomposition methods such as the type and acid of the raw materials such as blood meal, feather, alkali or enzyme.
More specifically, the present invention is realized by following steps.By as the cysteine of sulfur-containing amino acid, cystine,
Methionine and acetylcysteine, N- acetyl thios proline, Acetylmethionine and carbohydrate as its derivative are added to ammonia
In base acid fertilizer material liquid, wherein the carbohydrate refers to all carbohydrates such as monosaccharide and disaccharide and polysaccharide, and preferred carbohydrate is Portugal
Grape sugar (glucose), fructose (fructose) etc., are then heated 1~8 hour at 60~120 DEG C；Either from keratin
The animal acidic amino acid that remaining 1kg after l-cysteine is extracted in (being usually the feather and blood meal of hair or poultry) is discarded
The xylose of the methionine and 8g of 4g is put into liquid, and after heat 2 hours at 95~110 DEG C, stirring 12 is small at 30~35 DEG C
When；Either put into from the animal acidic amino acid exhaust gas liquid for extracting remaining 1kg after l-cysteine in the keratin
The cysteine of 8g and the xylose of 8g after pH is adjusted to 4~8 with calcium carbonate, heat 2 hours, and 30 at 95~110 DEG C
After being stirred 12 hours at~35 DEG C, pH is adjusted to 3~4 with citric acid.In addition, for the present invention, pass through following specific implementations
Example is explicitly stated to carry out.
Advantageous effect
The present invention provides a kind of amino acid fertilizer of new concept, and the amino acid fertilizer can improve existing animality ammonia
While the stench of base acid fertilizer material liquid, assigned by adding sulfur-containing amino acid and the sugar of physiologically active of plant prominent function
Potato fragrance and beef flavor, to enable niff to remove, and it is also helpful to plant.
Specific implementation mode
Amino acid fertilizer in the present invention indicates to assign the amino of the new concept of strong fragrance by Maillard reaction
Sour fertilizer, the Maillard reaction is unrelated with the raw material of fertilizer or preparation method, is realized by following steps.Made by adding
For the cysteine of sulfur-containing amino acid, cystine, methionine and acetylcysteine, N- acetyl thio dried meat as its derivative
Propylhomoserin, Acetylmethionine and monosaccharide and disaccharide as carbohydrate and polysaccharide etc. most preferably add glucose, xylose (xylose), sugarcane
Sugared (sucrose), maltose (maltose) and fructose etc., and heated 1~8 hour at 60~120 DEG C.Hereinafter, by preferred
Embodiment be described in detail.
In the present invention, sulfur-containing amino acid is related with Maillard reaction, but does not react, and remaining amino acid promotes to plant
The physiological activity of object and growth to improve due to a lack of sunshine amount, and become the recovery of tender plants cell because damaging to plants caused by sudden drop in temperature
Power, using the elongation of root and root becomes excellent, and will be own as plant physiology due to having the effect of extension survival period
Active material effectively acts on plant, and this effect is confirmed that by implementing crops cultivation experiment result.
Hereinafter, the present invention will be more specifically described by embodiment, but the interest field of the present invention is not limited to
These embodiments.
Embodiment 1：Assign the preparation of the amino acid fertilizer of potato fragrance
Divide in the keratin animality amino acid fertilizer material liquid of remaining 1Kg after extracting l-cysteine from hair
Not Tou Ru the methionine of 4g and the xylose of 8g mixed, and after being heated 2 hours at 95~110 DEG C, stirred at 30~35 DEG C
It mixes 12 hours, to prepare having strong potato fragrance and being 3.5 with the pH of crineous color and luster is revealed for 1,010g
Amino acid fertilizer.
Embodiment 2：The preparation of increased amino acid fertilizer is obtained with strong fragrance and keeping quality
It is put into respectively in the animality amino acid fertilizer material liquid of remaining 1Kg after extracting l-cysteine from hair
The cysteine of 8g and the xylose of 8g are mixed, and pH is then adjusted to 5.0 with calcium carbonate, are added at 95~110 DEG C later
Heat 2 hours, then stirs 12 hours at 30~35 DEG C, pH is adjusted to 3~4 with citric acid later, to prepare 1,
The keeping quality of 016g is prominent and the amino acid fertilizer with crineous color and luster with strong fragrance.
Embodiment 3：The removal of the unpleasant taste of alkaline hydrolysis amino acid fertilizer
While the chicken feather of the drying of 1kg is put into hydrolytic tank, the water of 3L is added and is stirred, by the conduct of 250g
The sodium bicarbonate of hydrolytic reagent, 20g as the vulcanized sodium of reducing agent, 10mL as the monomethyl amine of amine compounds and the hydrazine of 10mL
It is blended in the water of 1L, and is added in hydrolytic tank, then will be obtained by the method for embodiment 1 and embodiment 2
What the amino acid fertilizer feed liquid with potato fragrance and strong fragrance for eliminating foul odour was separated to 1Kg respectively is maintaining 90
~100 DEG C and by 11 hours alkaline hydrolysis amino acid fertilizer material liquid in, to prepare the amino acid fertilizer of pH3.5 and pH5.0
Material.
Use the arable farming result (experiment of 1 and 2 amino acid fertilizer obtained of embodiment according to the present invention
Group) as described in Table 1.
Table 1 (tests the time using crop (cucumber) the cultivation result of amino acid fertilizer：2011)
(note) every 10 plants of cucumber for 1 arithmetic mean of instantaneous value.
(panel is tested come the expert group of the amino acid fertilizer prepared for through the embodiment of the present invention 1 and embodiment 2
Test) result is as shown in table 2.The peasant of 10 40 years old age brackets is randomly selected as panel member, them is allowed to hear taste
It gives a mark behind road, and is carried out recording (10 points after arithmetic average：It is extremely strong, 5 points：Medium level, 1 point：It is faint, 0
Point：Nothing).
2 expert group of table tests test result
| Classification | Stench | Potato fragrance | Strong fragrance |
| It is prepared by embodiment 1 | 0 | 10 | 1 |
| It is prepared by embodiment 2 | 0 | 1 | 10 |
| It is prepared by embodiment 3 | 0 | 10 | 10 |
| Existing liquid fertilizer | 10 | 0 | 0 |
Industrial applicibility
The present invention provides a kind of method preparing novel amino fertilizer, amino acid and reduction of the method by sulfur-bearing
The stench and fishy smell for the shortcomings that Maillard reaction of sugar is come to as amino acid fertilizer assign strong fragrance, potato fragrance etc.
It makes one to smell known fragrance, it, can by using sulfur-containing amino acid while rejection feeling so as to eliminate fertilising person
Promote physiologically active of plant, there is effect outstanding, therefore there is high industrial applicibility.
Claims (4)
1. a kind of method preparing amino acid fertilizer, which is characterized in that the method is by extracting L- Guangs from hair
Methionine and xylose are put into after propylhomoserin in remaining animality amino acid fertilizer material liquid, and is heated 2 hours at 95~110 DEG C
Afterwards, 12 hours are stirred at 30~35 DEG C to assign potato fragrance.
2. a kind of method preparing amino acid fertilizer, which is characterized in that the method is by extracting L- Guangs from hair
Cysteine and xylose are put into after propylhomoserin in remaining animality amino acid fertilizer material liquid, after adjusting pH with calcium carbonate, 95
It is heated 2 hours at~110 DEG C, and after being stirred 12 hours at 30~35 DEG C, pH is adjusted to 3~4 come imparting body with citric acid
Strongly fragrant fragrance.
3. a kind of method preparing amino acid fertilizer, which is characterized in that the method is by adding water in dry chicken feather
After while be stirred, sodium bicarbonate, vulcanized sodium, monomethyl amine and hydrazine are mixed in water, and is added in hydrolytic tank,
Then addition amino acid and sugar carry out U.S. drawing in maintaining 90~100 DEG C and amino acid fertilizer material liquid by 11 hours alkaline hydrolysis
Moral reaction assigns potato fragrance or strong fragrance.
4. a kind of amino acid fertilizer of the not stench of crineous shape, which is characterized in that the fertilizer passes through claims 1 to 3
Any one of described in method be made.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130014823A KR101331253B1 (en) | 2013-02-12 | 2013-02-12 | Amino acid fertilizer without sickening ordor and method of manufacturing the same |
| KR10-2013-0014823 | 2013-02-12 | ||
| PCT/KR2013/008008 WO2014126313A1 (en) | 2013-02-12 | 2013-09-05 | Amino acid fertiliser from which unpleasant foul smells have been removed, and production method for same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104981446A CN104981446A (en) | 2015-10-14 |
| CN104981446B true CN104981446B (en) | 2018-10-12 |
Family
ID=49858107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380072858.2A Active CN104981446B (en) | 2013-02-12 | 2013-09-05 | Remove the amino acid fertilizer and preparation method thereof of stench |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101331253B1 (en) |
| CN (1) | CN104981446B (en) |
| WO (1) | WO2014126313A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101507345B1 (en) | 2014-11-20 | 2015-03-31 | (주)지에스티 | Hydrolysis apparatus of organic waste using hydraulic crushing effect |
| AU2018278219B2 (en) * | 2017-05-30 | 2024-03-07 | Mars, Incorporated | Methods for producing feather-based food products |
| KR102205590B1 (en) | 2019-02-14 | 2021-01-20 | 전주대학교산학협력단 | Amino acid fermentation material with improved preservability using chicken feathers and manufacturing method thereby |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000050722A (en) * | 1999-01-14 | 2000-08-05 | 이은국 | Process for the preparation of a c0mposite amino acid fertilizer by using the feathers of fowls |
| KR20080069463A (en) * | 2007-01-23 | 2008-07-28 | 경상대학교산학협력단 | Method of preparing a natural flavoring comprising pearl oyster muscle extract with enhancing flavor |
| CN102381891A (en) * | 2011-07-23 | 2012-03-21 | 天津北洋百川生物技术有限公司 | Method for producing organic fertilizer by using activated sludge |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR850005393A (en) * | 1984-01-23 | 1985-08-24 | 이기선 | Manufacturing method of synthetic amino acid fertilizer |
| KR100241336B1 (en) | 1997-10-21 | 2000-02-01 | 하기성 | Fertilizer composition containing water-solubilized sulfur-containing amino acids and preparation thereof |
| JP2003160391A (en) * | 2001-11-21 | 2003-06-03 | Kazuhiro Aida | Plant activating agent obtained from animal fiber and method for producing the same, and plant growing method using the same |
| KR100998656B1 (en) * | 2007-11-20 | 2010-12-07 | 대상 주식회사 | Method For Manufacturing Salmon Frame Extract |
| KR101023538B1 (en) | 2009-01-22 | 2011-03-21 | (주)해림파메틱 | A method of producing L-Cystine |
-
2013
- 2013-02-12 KR KR1020130014823A patent/KR101331253B1/en active IP Right Grant
- 2013-09-05 WO PCT/KR2013/008008 patent/WO2014126313A1/en active Application Filing
- 2013-09-05 CN CN201380072858.2A patent/CN104981446B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20000050722A (en) * | 1999-01-14 | 2000-08-05 | 이은국 | Process for the preparation of a c0mposite amino acid fertilizer by using the feathers of fowls |
| KR20080069463A (en) * | 2007-01-23 | 2008-07-28 | 경상대학교산학협력단 | Method of preparing a natural flavoring comprising pearl oyster muscle extract with enhancing flavor |
| CN102381891A (en) * | 2011-07-23 | 2012-03-21 | 天津北洋百川生物技术有限公司 | Method for producing organic fertilizer by using activated sludge |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101331253B1 (en) | 2013-11-19 |
| WO2014126313A1 (en) | 2014-08-21 |
| CN104981446A (en) | 2015-10-14 |
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