CN104981446A - Amino acid fertiliser from which unpleasant foul smells have been removed, and production method for same - Google Patents
Amino acid fertiliser from which unpleasant foul smells have been removed, and production method for same Download PDFInfo
- Publication number
- CN104981446A CN104981446A CN201380072858.2A CN201380072858A CN104981446A CN 104981446 A CN104981446 A CN 104981446A CN 201380072858 A CN201380072858 A CN 201380072858A CN 104981446 A CN104981446 A CN 104981446A
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- amino acid
- acid fertilizer
- fertilizer
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- sugar
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Botany (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
In the present invention, the foul smell and the fishy smell that constitute disadvantages of amino acid fertilisers are given a familiar smell trusted by people, such as a savoury smell or potato smell, by means of a Maillard reaction between a reducing sugar and a sulphur-containing amino acid, thereby giving the outstanding advantage of providing a production method for a novel amino acid fertiliser able to eliminate aversion on the part of people handling the fertiliser while at the same time promoting plant physiological activity via the sulphur-containing amino acid.
Description
Technical field
The stench that the present invention relates to a kind of shortcoming as animality amino acid fertilizer is removed and is added with the preparation method of the amino acid fertilizer to the effective sulfur-containing amino acid of Promoting plant growth.
Background technology
The preparation of existing amino acid fertilizer is that the feather etc. of blood meal by producing in slaughtering process the liquid by-product of amino acid fermentation produced when generating food flavouring and poultry carries out enzymic fermentation or hydrolysis etc. to prepare.Unlike this, in No. 10-980595th, Korean Patent No, disclose the amino acid liquid fertilizer of the blood utilizing domestic animal, in No. 10-284976th, Korean Patent No, disclose the preparation method of the aminoacids complex fertilizer utilizing chicken feather.
Described animality amino acid fertilizer, although can be variant according to the treating processes Sum decomposition method of raw material, all has the unpleasant taste bringing and repel sense, therefore, the problem that the situation of headache etc. uses occurs after there is fertilising.Disclosed in No. 10-241336th, Korean Patent No, by prepared by acidolysis containing amino acid whose solution be used as fertilizer time, acid proof equipment is needed in order to neutralization solution, not only need a lot of installation cost, and can topsoil be caused, therefore, in normal circumstances, prepared by the method for most employing enzymolysis or alkaline hydrolysis, but compared with acidolysis, smell and allow people be sick in the stomach, therefore, obstinate headache can be caused after using or feel the stress, therefore there is the problem needing it to be carried out to improvement in time.
In addition, extract from the protein deriving from animal and prepare the method for the CYSTINE of sulfur-bearing, being disclosed in No. 10-1023538th, the Korean Patent No that the present inventor publishes.
Summary of the invention
The technical problem solved
Therefore, the object of the invention is to, familiar and strong by utilizing Maillard reaction (maillard reaction) technology adopted in food preparation section to give people
fragrance, and by regulating in Maillard reaction the amount of the sulfur-containing amino acid added, thus a kind of facilitation effect to plant-growth can be provided excellent, and eliminate the novel amino fertilizer of the stench allowing people be sick in the stomach.
Technical scheme
The present invention achieves above-mentioned purpose by Maillard reaction.Specifically by the amino of amino acid, peptide and protein and ketone, aldehyde, especially react with reducing sugar, to remove all unpleasant stenches containing amino acid whose fertilizer material, thus generate strong fragrance and brown pigment, and have nothing to do with the decomposition method such as the kind of the raw material such as blood meal, feather and acid, alkali or enzyme.
More specifically, the present invention is realized by following steps.Using as the halfcystine of sulfur-containing amino acid, Gelucystine, methionine(Met) and add in amino acid fertilizer stock liquid as the acetylcysteine of its derivative, N-acetyl thio proline(Pro), Thiomedon and carbohydrate, wherein, described carbohydrate refers to the carbohydrate that monosaccharide and disaccharide and polysaccharide etc. are all, preferred carbohydrate is glucose (glucose), fructose (fructose) etc., then heats 1 ~ 8 hour at 60 ~ 120 DEG C; Or after extract CYSTINE from Keratin sulfate (being generally feather and the blood meal of hair or poultry) remaining 1kg animality amino acid waste liquid in drop into the methionine(Met) of 4g and the wood sugar of 8g, and heat at 95 ~ 110 DEG C after 2 hours, stir 12 hours at 30 ~ 35 DEG C; Or after extract CYSTINE from described Keratin sulfate remaining 1kg animality amino acid waste gas liquid in drop into the halfcystine of 8g and the wood sugar of 8g, be after 4 ~ 8 by pH regulator with calcium carbonate, heat 2 hours at 95 ~ 110 DEG C, and stir after 12 hours at 30 ~ 35 DEG C, be 3 ~ 4 with citric acid by pH regulator.In addition, for the present invention, undertaken explicitly bright by following specific embodiment.
Beneficial effect
The invention provides a kind of amino acid fertilizer of new ideas, while described amino acid fertilizer can improve the stench of existing animality amino acid fertilizer stock liquid, potato fragrance and beef flavor is given by the sulfur-containing amino acid and sugar that add physiologically active of plant prominent function, thus niff is removed, and also helpful to plant.
Embodiment
Amino acid fertilizer in the present invention represents the amino acid fertilizer of the new ideas of being given strong fragrance by Maillard reaction, and the raw material of described Maillard reaction and fertilizer or preparation method have nothing to do, and are realized by following steps.By adding as the halfcystine of sulfur-containing amino acid, Gelucystine, methionine(Met) and as the acetylcysteine of its derivative, N-acetyl thio proline(Pro), Thiomedon and as the monosaccharide and disaccharide of carbohydrate and polysaccharide etc., most preferably add glucose, wood sugar (xylose), sucrose (sucrose), maltose (maltose) and fructose etc., and heat 1 ~ 8 hour at 60 ~ 120 DEG C.Below, be described in detail by preferred embodiment.
In the present invention, sulfur-containing amino acid is relevant with Maillard reaction, but do not react, and residual amino acid promotes physiologically active and the growth of plant, thus improve for want of sunshine amount, and the restorer of tender plants cell is become because damaging to plants caused by sudden drop in temperature, the elongation of using root and root becomes excellent, and because of the effect with prolongation survival time, himself is acted on plant effectively as physiologically active of plant material, this effect obtains confirmation by implementing crops cultivation experiment result.
Below, the present invention will be more specifically described by embodiment, but interest field of the present invention is not limited to these embodiments.
Embodiment 1: the preparation of giving the amino acid fertilizer of potato fragrance
After extracting CYSTINE from hair remaining 1Kg Keratin sulfate animality amino acid fertilizer stock liquid in drop into 4g respectively the wood sugar of methionine(Met) and 8g mix, and heat at 95 ~ 110 DEG C after 2 hours, stir 12 hours at 30 ~ 35 DEG C, thus prepare 1,010g to have strong potato fragrance and have the pH revealing dun color and luster be the amino acid fertilizer of 3.5.
Embodiment 2: there is strong fragrance and keeping quality obtains the preparation of amino acid fertilizer that increases
After extracting CYSTINE from hair remaining 1Kg animality amino acid fertilizer stock liquid in drop into 8g respectively the wood sugar of halfcystine and 8g mix, then be 5.0 with calcium carbonate by pH regulator, heat 2 hours at 95 ~ 110 DEG C afterwards, then stir 12 hours at 30 ~ 35 DEG C, be 3 ~ 4 with citric acid by pH regulator afterwards, thus the keeping quality preparing 1,016g is given prominence to and is had the amino acid fertilizer with dun color and luster of strong fragrance.
Embodiment 3: the removal of the unpleasant taste of alkaline hydrolysis amino acid fertilizer
The chicken feather of the drying of 1kg is put in hydrolytic tank, add 3L water and while carrying out stirring, using the sodium bicarbonate as hydrolytic reagent of 250g, the sodium sulphite as reductive agent of 20g, 10mL is blended in the water of 1L as the Monomethylamine of amine compound and the hydrazine of 10mL, and added in hydrolytic tank, then the amino acid fertilizer feed liquid with potato fragrance and strong fragrance the eliminating foul odour method by embodiment 1 and embodiment 2 obtained be separated to respectively 1Kg maintenance 90 ~ 100 DEG C and in the amino acid fertilizer stock liquid of 11 hours alkaline hydrolysis, thus prepare the amino acid fertilizer of pH3.5 and pH5.0.
The arable farming result (test group) of the amino acid fertilizer using embodiment 1 and 2 according to the present invention obtained as described in Table 1.
Table 1 uses the crop of amino acid fertilizer (cucumber) to cultivate result (test time: 2011)
(note) every 10 strain cucumber for 1 arithmetical av.
It is as shown in table 2 that expert group for the amino acid fertilizer prepared by the embodiment of the present invention 1 and embodiment 2 tests (panel test) result.The peasant of random selecting 10 40 years old age brackets, as panel member, gives a mark after allowing them hear taste, and records after being carried out arithmetical mean (10 points: extremely strong, 5 points: medium level, 1 point: faint, 0 point: nothing).
Table 2 expert group test test result
| Classification | Stench | Potato fragrance | Strong fragrance |
| Prepared by embodiment 1 | 0 | 10 | 1 |
| Prepared by embodiment 2 | 0 | 1 | 10 |
| Prepared by embodiment 3 | 0 | 10 | 10 |
| Existing liquid fertilizer | 10 | 0 | 0 |
Industrial applicibility
The invention provides a kind of method preparing novel amino fertilizer, described method gives strong fragrance, potato fragrance etc. by the amino acid of sulfur-bearing and the Maillard reaction of reducing sugar to the stench of the shortcoming as amino acid fertilizer and fishy smell makes people smell familiar fragrance, thus while the repulsion sense of fertilising person can be eliminated, physiologically active of plant can be promoted by using sulfur-containing amino acid, there is outstanding effect, therefore there is high industrial applicibility.
Claims (7)
1. the removed amino acid fertilizer of stench, is characterized in that, described amino acid fertilizer add in remaining animality amino acid fertilizer stock liquid after extract CYSTINE from Keratin sulfate amino acid and sugar and obtained by Maillard reaction.
2. the removed amino acid fertilizer of stench as claimed in claim 1, it is characterized in that, described amino acid is sulfur-containing amino acid.
3. the removed amino acid fertilizer of stench as claimed in claim 1, it is characterized in that, described sugar is any one in monosaccharide and disaccharide, polysaccharide.
4. the method for a Preparation of amino acid fertilizer, it is characterized in that, described method is by dropping into methionine(Met) and wood sugar in animality amino acid fertilizer stock liquid remaining after extracting CYSTINE from hair, and heat after 2 hours at 95 ~ 110 DEG C, to stir at 30 ~ 35 DEG C and within 12 hours, give potato fragrance.
5. the method for a Preparation of amino acid fertilizer, it is characterized in that, described method is by dropping into halfcystine and wood sugar in animality amino acid fertilizer stock liquid remaining after extracting CYSTINE from hair, after regulating pH with calcium carbonate, heat 2 hours at 95 ~ 110 DEG C, and stir after 12 hours at 30 ~ 35 DEG C, be 3 ~ 4 give strong fragrance by pH regulator with citric acid.
6. the method for a Preparation of amino acid fertilizer, it is characterized in that, described method is by while carrying out stirring after add water in the chicken feather of drying, sodium bicarbonate, sodium sulphite, Monomethylamine and hydrazine are blended in water, and added in hydrolytic tank, then in the amino acid fertilizer stock liquid of 11 hours alkaline hydrolysis, add amino acid and sugar carry out Maillard reaction to give potato fragrance or strong fragrance maintenance 90 ~ 100 DEG C.
7. dun shape does not have a cacodorous amino acid fertilizer, and it is characterized in that, described fertilizer is obtained by the method according to any one of claim 4 to 6.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2013-0014823 | 2013-02-12 | ||
| KR1020130014823A KR101331253B1 (en) | 2013-02-12 | 2013-02-12 | Amino acid fertilizer without sickening ordor and method of manufacturing the same |
| PCT/KR2013/008008 WO2014126313A1 (en) | 2013-02-12 | 2013-09-05 | Amino acid fertiliser from which unpleasant foul smells have been removed, and production method for same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104981446A true CN104981446A (en) | 2015-10-14 |
| CN104981446B CN104981446B (en) | 2018-10-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201380072858.2A Active CN104981446B (en) | 2013-02-12 | 2013-09-05 | Remove the amino acid fertilizer and preparation method thereof of stench |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101331253B1 (en) |
| CN (1) | CN104981446B (en) |
| WO (1) | WO2014126313A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110678088A (en) * | 2017-05-30 | 2020-01-10 | 马斯公司 | Method for producing feather-based food products |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101507345B1 (en) | 2014-11-20 | 2015-03-31 | (주)지에스티 | Hydrolysis apparatus of organic waste using hydraulic crushing effect |
| KR102205590B1 (en) | 2019-02-14 | 2021-01-20 | 전주대학교산학협력단 | Amino acid fermentation material with improved preservability using chicken feathers and manufacturing method thereby |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990032892A (en) * | 1997-10-21 | 1999-05-15 | 하기성 | Fertilizer compositions comprising soluble sulfur-containing amino acids and methods for their preparation |
| KR20000050722A (en) * | 1999-01-14 | 2000-08-05 | 이은국 | Process for the preparation of a c0mposite amino acid fertilizer by using the feathers of fowls |
| KR20080069463A (en) * | 2007-01-23 | 2008-07-28 | 경상대학교산학협력단 | Method of preparing a natural flavoring comprising pearl oyster muscle extract with enhancing flavor |
| CN102381891A (en) * | 2011-07-23 | 2012-03-21 | 天津北洋百川生物技术有限公司 | Method for producing organic fertilizer by using activated sludge |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR850005393A (en) * | 1984-01-23 | 1985-08-24 | 이기선 | Manufacturing method of synthetic amino acid fertilizer |
| JP2003160391A (en) * | 2001-11-21 | 2003-06-03 | Kazuhiro Aida | Plant activating agent obtained from animal fiber and method for producing the same, and plant growing method using the same |
| KR100998656B1 (en) * | 2007-11-20 | 2010-12-07 | 대상 주식회사 | Method For Manufacturing Salmon Frame Extract |
| KR101023538B1 (en) | 2009-01-22 | 2011-03-21 | (주)해림파메틱 | A method of producing L-Cystine |
-
2013
- 2013-02-12 KR KR1020130014823A patent/KR101331253B1/en active IP Right Grant
- 2013-09-05 CN CN201380072858.2A patent/CN104981446B/en active Active
- 2013-09-05 WO PCT/KR2013/008008 patent/WO2014126313A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19990032892A (en) * | 1997-10-21 | 1999-05-15 | 하기성 | Fertilizer compositions comprising soluble sulfur-containing amino acids and methods for their preparation |
| KR20000050722A (en) * | 1999-01-14 | 2000-08-05 | 이은국 | Process for the preparation of a c0mposite amino acid fertilizer by using the feathers of fowls |
| KR20080069463A (en) * | 2007-01-23 | 2008-07-28 | 경상대학교산학협력단 | Method of preparing a natural flavoring comprising pearl oyster muscle extract with enhancing flavor |
| CN102381891A (en) * | 2011-07-23 | 2012-03-21 | 天津北洋百川生物技术有限公司 | Method for producing organic fertilizer by using activated sludge |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110678088A (en) * | 2017-05-30 | 2020-01-10 | 马斯公司 | Method for producing feather-based food products |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014126313A1 (en) | 2014-08-21 |
| CN104981446B (en) | 2018-10-12 |
| KR101331253B1 (en) | 2013-11-19 |
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