CN106699344A - Chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and preparation method thereof - Google Patents
Chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and preparation method thereof Download PDFInfo
- Publication number
- CN106699344A CN106699344A CN201611056247.0A CN201611056247A CN106699344A CN 106699344 A CN106699344 A CN 106699344A CN 201611056247 A CN201611056247 A CN 201611056247A CN 106699344 A CN106699344 A CN 106699344A
- Authority
- CN
- China
- Prior art keywords
- calcium
- oyster shell
- fertilizer
- chelated calcium
- alcohol effluent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/005—Fertilisers made from animal corpses, or parts thereof from meat-wastes or from other wastes of animal origin, e.g. skins, hair, hoofs, feathers, blood
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to a chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and a preparation method thereof. The chelated calcium fertilizer is characterized by being prepared from the following raw materials in parts by weight: 5-20 parts of oyster shell powder, 60-90 parts of alcohol slop, 10-20 parts of potassium permanganate solution and 5-15 parts of concentrated nitric acid. The chelated calcium fertilizer prepared by the invention supplements calcium nutrition to plants, and the small molecule water-soluble organic chelated calcium is more beneficial to plant absorption; when the chelated calcium is applied into soil, the soil can be improved, and soil hardening is improved; the chelated calcium increases the fertilizer utilization ratio, can improve the crop rhizosphere environment, increases the beneficial bacterium content and enables a root system to be stout; and the chelated calcium promotes nutrient absorption, improves the fruit quality and increases the yield.
Description
Technical field
The present invention relates to a kind of chelating calcium with oyster shell and alcohol effluent as Material synthesis and preparation method thereof, belong to agriculture
Medicine technical field of fertilizers.
Background technology
Oyster is the first big cultivated shellfish in the world, after oyster meat is extracted, a large amount of oyster shells be but taken as waste and
Abandon, this not only land occupation resource, pollution environment, while also resulting in a large amount of wastes of marine resources.Oyster shell it is main into
It is calcium carbonate to divide, and its calcium carbonate content is up to more than 95%, additionally contains 17 kinds of ammonia such as cystine, glycine, isoleucine
Trace element in 24 kinds of base acid and iron, zinc, selenium, silicon, strontium etc..Oyster shell is made up of cuticula, prismatic layer, nacre, passes through
Modified, it has certain absorption, exchange, the ability of catalysis.
Cane sugar industry waste water is mainly molasses alcohol waste liquid, and cane sugar manufacture per ton about produces 25-30kg blackstrap, per 4-
4.2 tons of blackstrap can produce 1 ton of alcohol, while producing 9.5-10.5 tons of alcohol effluent.The treatment of alcohol effluent is always influence
Industry development, urgent need to resolve.Containing 13 kinds of amino acid such as aspartic acid, threonine, serine, glutamic acid in alcohol effluent,
Containing organic matter more than 28%, by degraded, plant nutrition liquid can be done.
Calcium be plant growth necessary to moderate-element, the metabolism and development of major regulatory plant are plant cell walls and thin
After birth structural material.In addition, calcium also has great importance to improving fruit quality and increasing Storage etc..Chelating calcium is biological
Active organic calcium, its electric charge tends to neutral, and during foliage-spray, chelating calcium passes through the speed of blade cuticula than inorganic calcium ion
Hurry up, utilization rate is high；Additionally, chelating calcium stability in soil is high, it is difficult to be fixed；In plant, organic chelated calcium is not only
Solubility is larger, and with obvious mobile advantage, overcomes calcium ion and be difficult to the drawbacks of being transported in bast.
As can be seen here, developing a kind of technology can effectively combine oyster shell and alcohol effluent both " rubbish ", become useless
It is treasured, synthesizes organic chelated calcareous fertilisers, it will produces great economic benefit and social benefit.
CN200610122709.4 prepares slow release fertilizer there is provided one kind oyster shell, and the preparation technology of the fertilizer is：(1)
By oyster shell through 200 DEG C~250 DEG C of high temperature activation process 12 hours；(2) chemical fertilizer, deionized water wiring solution-forming；(3) (1)
In preparation absorb (2) in the aqueous solution, stand 3 days or so, drying and packaging.
CN201410348050.9 provides a kind of tartaric acid chelating calcium product and method prepared as raw material with shell, with shellfish
Shell is raw material, and the water-insoluble calcium of shell is first fully converted into water soluble ion calcium using acid solution, and separation of solid and liquid goes removal of impurities
Matter, then control the concentration and mol ratio of pH value, temperature and citrate, malate and the calcium ion of filtrate, chelating calcium from
After son is allowed to precipitation, tartaric acid chelating calcium product is processed into.
CN201010237006.2 provides a kind of chelated calcium preparation method of collagen, is divided into from Animal Skin and shell-lime
Primary raw material, Animal Skin is collagen through enzyme hydrolysis, and shell ashing obtains ash content, and ash content obtains calcium chloride solution through acidolysis, passes through
Chelating, separation, purifying can chelate calcium product.
CN201510687552.9 provides a kind of preparation method of amino acid chelated calcium, and the method is soaked by hydrochloric acid solution
Bubble egg shell, with egg shell reaction, produces inorganic calcium source, adds a certain amount of egg and is well mixed, and is hydrolyzed by protein
Enzyme is digested, and produces amino acid, then adds zinc acetate, under microwave and the auxiliary of energization, produces amino acid chelated calcium
Crude product, then by filtering, refined, dry prepared amino acid chelated calcium.
CN201510262267.2 provides a kind of compound amino acid chelate calcium prepared as raw material with oyster, the method life
Product process is：(1) oyster living is purified 48 hours, separating shell and meat；(2) oyster shell is first soaked 4 hours with running water, then is used
0.5% salt acid soak 1 hour, then soaks rinsing for several times with purified water, reaches neutrality；Oyster shell after cleaning passes through
100 DEG C dry 1 hour, crush 100 mesh sieves, obtain oyster shell powder；The hydrochloric acid of 3mol/L, mixing are added in ostreae testa pulverata；In temperature
Spend to be acted on 2 hours under conditions of 110 DEG C, filtering is concentrated under reduced pressure, it is 28.08% that spray drying is prepared into solubility calcium content
Denaturation oyster shell powder；(3) oyster meat high temperature cooked, sterilized, ground, digested, filtered, desalination, concentration, spray drying；(4)
Desciccate and denaturation oyster shell reaction；(5) product centrifugation, filtrate decompression concentration, wash, filter, and dry to obtain product.
The content of the invention
It is an object of the invention to overcome prior art problem, effectively solve discarded oyster shell and take up an area, alcohol effluent difficulty
A kind of great number of issues such as reason, there is provided fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis and preparation method thereof.I.e. with
Oyster shell and alcohol effluent are raw material, synthetic fluid fertilizer of chelated calcium.Fertilizer of chelated calcium prepared by the present invention supplements calcium nutrition for plant,
The molten organic chelated calcium of micromolecular water is more beneficial for plant absorption；In being manured into soil, can improved soil, improvement soil hardening；Improve
Utilization rate of fertilizer, can improve crop rhizosphere environment, increase beneficial bacterial content, make root system sturdy；Promote Nutrient Absorption, improve fruit
Quality, increases yield.
To reach above-mentioned purpose, the present invention uses following technical proposals：
A kind of fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis, it is characterised in that the fertilizer of chelated calcium is by male
Oyster shells, alcohol effluent, liquor potassic permanganate and concentrated nitric acid are made, wherein oyster shell powder, alcohol effluent, liquor potassic permanganate and
The weight ratio of concentrated nitric acid is：(1-4)：(12-16)：(2-4)：(1-3).
The content of organic matter accounts for alcohol waste material percentage by weight for 20%-35% in the alcohol effluent.
Free aminoacid content 30g/L-100g/L in the alcohol effluent.
Present invention also offers a kind of liquor potassic permanganate preparation method, the liquor potassic permanganate is main by weight portion meter
The following raw material be made：2-8 parts of potassium permanganate solid, water 25-58 parts, fully concentrated nitric acid 1-5 parts, dissolving.
The concentrated nitric acid concentration presses mass fraction for 48%-75%.
Present invention also offers a kind of preparation method of the fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis, bag
Include following steps：
(1) raw material is prepared according to proportioning；
(2) oyster shell pretreatment：Discarded oyster shell is cleaned, 100 DEG C of drying are crushed to 50-100 mesh and obtain final product oyster shell
Powder；
(3) preparation of activated ionic calcium：Oyster shell powder, concentrated nitric acid and water are placed in reactor, normal-temperature reaction 20min-
40min, filtering, filtrate is activated ionic calcium；The oyster shell powder presses solid-to-liquid ratio 1 with concentrated nitric acid addition：(1-2), dense nitre
Acid and the addition of water by volume 1:(0.5-1)；
(4) alcohol effluent oxidative degradation：Alcohol effluent, liquor potassic permanganate is taken to react 1-3 hours, 50 DEG C of reaction temperature-
80 DEG C, you can obtain the organic carbon solution of small molecule；
(5) chelated calcium preparation：By the activity in the organic carbon solution of the step (3) small molecular and the step (3)
Ion calcium solution hybrid reaction, reaction time 1-2 hours, 60 DEG C -80 DEG C of reaction temperature, you can obtain liquid chelating calcium.
The application that the present invention also provides a kind of utilization oyster shell and alcohol effluent is the fertilizer of chelated calcium for synthesizing, is characterised by,
The fertilizer of chelated calcium is applied to the plantation of crops, fruit tree or Chinese medicine.
Beneficial effect
Compared with prior art, the present invention has the advantages that：
(1) fertilizer of chelated calcium prepared by the present invention is that, using discarded oyster shell and alcohol effluent, cost of material is low, economy effect
It is beneficial high.
(2) preparation process is simple of the present invention, low production cost, can be mass-produced.
(3) the chelating calcium plant absorption that prepared by the present invention is good, and instant effect can improve fruit quality, extend storage time.
(4) alcohol effluent degradation solution prepared by the present invention contains a large amount of small molecule amino acid, can effectively supplement plant carbon
Nutrition, improves utilization rate of fertilizer.
(5) the chelating calcium and the small molecule alcohol effluent degradation solution of addition that prepared by the present invention can produce cooperative effect, change
Kind crop rhizosphere environment, increases beneficial microbe content, makes well developed root system, increases yield.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with case study on implementation, to this hair
It is bright to be further elaborated, but the scope of protection of present invention is not limited to the scope of embodiment expression.
Embodiment 1
A kind of preparation method of fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis, comprises the following steps：
(1) oyster shell pretreatment：
Discarded oyster shell is rinsed with water, 30min is dried in 100 DEG C of baking ovens, be crushed to 80 mesh, obtain oyster shell powder；
(2) preparation of activated ionic calcium：
Oyster shell powder, concentrated nitric acid and water 50kg being taken respectively to be placed in reactor, normal-temperature reaction 20min, being filtered, filtrate is
Activated ionic calcium；
(3) alcohol effluent oxidative degradation：
10% acid permanganate soln 50kg is prepared, and is mixed with 150kg alcohol effluents, reacted 2 hours at 60 DEG C,
Reaction solution is the organic carbon solution of small molecule；
(4) chelated calcium preparation：
By the organic carbon solution of above-mentioned small molecule and active ion calcium solution hybrid reaction, 1 hour reaction time, reaction temperature
70 DEG C, products obtained therefrom is liquid chelating calcium.
Embodiment 2
A kind of preparation method of fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis, comprises the following steps：
(1) oyster shell pretreatment：
Discarded oyster shell is rinsed with water, 30min is dried in 100 DEG C of baking ovens, be crushed to 60 mesh, obtain oyster shell powder；
(2) preparation of activated ionic calcium：
Take oyster shell powder 50kg, concentrated nitric acid 60kg and water 40kg to be placed in reactor, normal-temperature reaction 30min, filter, filtrate
As activated ionic calcium；
(3) alcohol effluent oxidative degradation：
8% acid permanganate soln 60kg is prepared, and is mixed with 200kg alcohol effluents, reacted 2 hours at 70 DEG C,
Reaction solution is the organic carbon solution of small molecule；
(4) chelated calcium preparation：
By the organic carbon solution of above-mentioned small molecule and active ion calcium solution hybrid reaction, 1 hour reaction time, reaction temperature
70 DEG C, products obtained therefrom is liquid chelating calcium.
Embodiment 3
A kind of preparation method of fertilizer of chelated calcium with oyster shell and with glycine as Material synthesis, comprises the following steps：
(1) oyster shell pretreatment：
Discarded oyster shell is rinsed with water, 30min is dried in 100 DEG C of baking ovens, be crushed to 80 mesh, obtain oyster shell powder；
(2) preparation of activated ionic calcium：
Take oyster shell powder 50kg, concentrated nitric acid 60kg and water 40kg to be placed in reactor, normal-temperature reaction 30min, filter, filtrate
As activated ionic calcium；
(3) chelated calcium preparation：
By 10kg glycine and above-mentioned active ion calcium solution hybrid reaction, 1 hour reaction time, 70 DEG C of reaction temperature,
Products obtained therefrom is liquid chelating calcium.
Embodiment 4
A kind of preparation method of fertilizer of chelated calcium with oyster shell and citric acid as Material synthesis, comprises the following steps：
(1) oyster shell pretreatment：
Discarded oyster shell is rinsed with water, 35min is dried in 100 DEG C of baking ovens, be crushed to 80 mesh, obtain oyster shell powder；
(2) preparation of activated ionic calcium：
Take oyster shell powder 50kg, concentrated nitric acid 60kg and water 40kg to be placed in reactor, normal-temperature reaction 30min, filter, filtrate
As activated ionic calcium；
(3) chelated calcium preparation：
By 10kg citric acids and above-mentioned active ion calcium solution hybrid reaction, 1 hour reaction time, 70 DEG C of reaction temperature,
Products obtained therefrom is liquid chelating calcium.
Embodiment 5
A kind of preparation method of fertilizer of chelated calcium with calcium nitrate and alcohol effluent as Material synthesis, comprises the following steps：
(1) carbonic acid Calcium preconditioning：
Paris white is broken to 80 mesh, Paris white is obtained；
(2) preparation of activated ionic calcium：
Paris white 50kg, concentrated nitric acid 100kg and water 50kg are placed in reactor, normal-temperature reaction 30min, filtered, filter
Liquid is activated ionic calcium；
(3) alcohol effluent oxidative degradation：
10% acid permanganate soln 50kg is prepared, and is mixed with 200kg alcohol effluents, reacted 2 hours at 80 DEG C,
Reaction solution is the organic carbon solution of small molecule；
(4) chelated calcium preparation：
By the organic carbon solution of above-mentioned small molecule and active ion calcium solution hybrid reaction, 1 hour reaction time, reaction temperature
70 DEG C, products obtained therefrom is liquid chelating calcium.
Specifically used method
Effect example 1
The content for determining calcium in fertilizer of chelated calcium and the stability for having calcium
Used as experimental group, the fertilizer of chelated calcium of domestic certain well-known producer is to for right for the fertilizer of chelated calcium being made of embodiment 1-5
According to group, detect respectively fertilizer of chelated calcium prepare after 1 day, 30 days, 60 days when fertilizer of chelated calcium in calcium content.Experimental result is shown in Table 1.
Calcium content in the different chelating fertilizers of table 1
As shown in Table 1, it is high using calcium content in the fertilizer of chelated calcium of method of the present invention preparation, and calcium content stabilization, no
Easily decompose, it can be seen that, the fertilizer of chelated calcium quality prepared using the method is few, good stability.
Effect example 2
The fertilizer of chelated calcium being made of embodiment 1-5 as experimental group, the fertilizer of chelated calcium of domestic certain well-known producer to for
Control group, the fertilizer of chelated calcium of experimental group and control group is diluted respectively, 1000 times, is fallen Spraying in the flowering stage in cucumber physiology phase, interval
Sprayed after 10 days second, every 50 plants of cucumber are one group, detect cucumber abnormal rate.Experimental result is shown in Table 2.
Prevention effect of the different chelating fertilizers of table 2 to cucumber deformity melon and fruit
| Group | Cucumber sum (individual) | Malformed fruit number (individual) | Abnormal rate (%) |
| Embodiment 1 | 400 | 23 | 5.8 |
| Embodiment 2 | 398 | 29 | 7.3 |
| Embodiment 3 | 405 | 40 | 9.9 |
| Embodiment 4 | 395 | 40 | 10.1 |
| Embodiment 5 | 385 | 37 | 9.6 |
| Control group | 389 | 37 | 9.5 |
As shown in Table 2, the fertilizer of chelated calcium obtained by being prepared using the inventive method, in identical extension rate and identical use
In the case of amount, the abnormal rate of cucumber melon and fruit is lower, illustrates that the anti-malformed fruit effect of fertilizer of chelated calcium prepared by the inventive method is compared
According to organizing.
Effect example 3
Used as experimental group, the fertilizer of chelated calcium of domestic certain well-known producer is to for right for the fertilizer of chelated calcium being made of embodiment 1-5
According to group, the fertilizer of chelated calcium of experimental group and control group is diluted 500 times respectively, fallen Spraying in the flowering stage in the apple physiology phase, be spaced 10 days
After spray second, every 10 plants of apples are one group, detect apple bitter pit preventive effect and soluble sugar content.Experimental result is shown in Table
2。
Prevention effect of the different fertilizer of chelated calcium of table 3 to apple bitter pit
| Group | Apple sum (individual) | Disease fruit number (individual) | Diseased fruit rate (%) | Soluble sugar content (%) |
| Embodiment 1 | 550 | 29 | 5.2 | 15.4 |
| Embodiment 2 | 544 | 27 | 5.0 | 16.5 |
| Embodiment 3 | 532 | 52 | 9.7 | 12.9 |
| Embodiment 4 | 546 | 50 | 9.2 | 11.7 |
| Embodiment 5 | 533 | 61 | 11.5 | 12.4 |
| Control group | 530 | 56 | 10.6 | 12.5 |
As shown in Table 2, the fertilizer of chelated calcium for being prepared using the inventive method, under identical extension rate, the diseased fruit rate of apple
Significantly lower than control group, soluble sugar content illustrates the anti-apple hardship acne of fertilizer of chelated calcium of present invention preparation apparently higher than control group
The effect and organoleptic quality of disease are better than control group.
The announcement and teaching of book according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and changed.Therefore, the invention is not limited in specific embodiment disclosed and described above, to the one of invention
A little modifications and changes should also be as falling into scope of the claims of the invention.Although additionally, being used in this specification
Some specific terms, but these terms are merely for convenience of description, not to any limitation of this composition.
Claims (7)
1. a kind of fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis, it is characterised in that the fertilizer of chelated calcium is by oyster
Shell powder, alcohol effluent, liquor potassic permanganate and concentrated nitric acid are made, wherein oyster shell powder, alcohol effluent, liquor potassic permanganate and dense
The weight ratio of nitric acid is：(1-4)：(12-16)：(2-4)：(1-3).
2. the fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis according to claim 1, it is characterised in that institute
The content of organic matter accounts for alcohol waste material percentage by weight for 20%-35% in stating alcohol effluent.
3. the fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis according to claim 1, it is characterised in that institute
State free aminoacid content 30g/L-100g/L in alcohol effluent.
4. the fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis according to claim 1, it is characterised in that
The liquor potassic permanganate is mainly made up of the following raw material of weight portion meter：2-8 parts of potassium permanganate solid, water 25-58 parts,
Concentrated nitric acid 1-5 parts, fully dissolving.
5. the fertilizer of chelated calcium with oyster shell and alcohol effluent as Material synthesis according to right 1 or 4, it is characterised in that described
Concentrated nitric acid concentration presses mass fraction for 48%-75%.
6. the preparation side of the fertilizer of chelated calcium according to claim any one of 1-5 with oyster shell and alcohol effluent as Material synthesis
Method, comprises the following steps：
(1) raw material is prepared according to the raw material proportioning in claim 1-5；
(2) oyster shell pretreatment：Discarded oyster shell is cleaned, 100 DEG C of drying are crushed to 50-100 mesh and obtain final product oyster shell powder；
(3) preparation of activated ionic calcium：Oyster shell powder, concentrated nitric acid and water are placed in reactor, normal-temperature reaction 20min-
40min, filtering, filtrate is activated ionic calcium；The oyster shell powder presses solid-to-liquid ratio 1 with concentrated nitric acid addition：(1-2), dense nitre
Acid and the addition of water by volume 1:(0.5-1)；
(4) alcohol effluent oxidative degradation：Take alcohol effluent, liquor potassic permanganate to react 1-3 hours, 50 DEG C -80 DEG C of reaction temperature,
The organic carbon solution of small molecule can be obtained；
(5) chelated calcium preparation：By the active ion in the organic carbon solution of the step (3) small molecular and the step (3)
Calcium solution hybrid reaction, reaction time 1-2 hours, 60 DEG C -80 DEG C of reaction temperature, you can obtain liquid chelating calcium.
7. the utilization oyster shell and alcohol effluent described in a kind of claim 1 are the application of the fertilizer of chelated calcium of synthesis, are characterised by,
The fertilizer of chelated calcium is applied to the plantation of crops, fruit tree or Chinese medicine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611056247.0A CN106699344A (en) | 2016-11-25 | 2016-11-25 | Chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611056247.0A CN106699344A (en) | 2016-11-25 | 2016-11-25 | Chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106699344A true CN106699344A (en) | 2017-05-24 |
Family
ID=58934035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611056247.0A Pending CN106699344A (en) | 2016-11-25 | 2016-11-25 | Chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106699344A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108718586A (en) * | 2018-06-28 | 2018-11-02 | 广东工业大学 | A method of sand being cured by microorganism induction precipitation of calcium carbonate using regeneration calcium source |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050134A (en) * | 2007-05-18 | 2007-10-10 | 吴礼树 | Fertilizer of chelated calcium, and preparation method |
| CN105085051A (en) * | 2015-08-21 | 2015-11-25 | 南宁汉和生物科技有限公司 | Chelated calcium fertilizer prepared from oyster shell, and preparation method and application thereof |
| CN105367167A (en) * | 2014-11-15 | 2016-03-02 | 深圳市芭田生态工程股份有限公司 | Preparation method of trace element-containing organic carbon liquid fertilizer |
-
2016
- 2016-11-25 CN CN201611056247.0A patent/CN106699344A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101050134A (en) * | 2007-05-18 | 2007-10-10 | 吴礼树 | Fertilizer of chelated calcium, and preparation method |
| CN105367167A (en) * | 2014-11-15 | 2016-03-02 | 深圳市芭田生态工程股份有限公司 | Preparation method of trace element-containing organic carbon liquid fertilizer |
| CN105085051A (en) * | 2015-08-21 | 2015-11-25 | 南宁汉和生物科技有限公司 | Chelated calcium fertilizer prepared from oyster shell, and preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| 王业俊 许保玖: "《水和废水技术研究》", 31 March 1992, 中国建筑工业出版社 * |
| 王海芳主编；柴艳芳，侯彬，赵英虎等编: "《环境监测》", 31 August 2014, 国防工业出版社 * |
| 秦浩正总主编: "《中学生学习辞典 化学卷》", 30 September 2012, 世界图书上海出版公司 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108718586A (en) * | 2018-06-28 | 2018-11-02 | 广东工业大学 | A method of sand being cured by microorganism induction precipitation of calcium carbonate using regeneration calcium source |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103524236B (en) | Amino acid chelated trace element foliage fertilizer rich in seaweed extract | |
| CN103193525B (en) | Production method for sargassum liquid fertilizer | |
| CN103626545B (en) | A kind of amino-acid compound fertilizer, preparation method and Agro-ecology circulation development approach | |
| CN1289743A (en) | Composite organic liquid fertilizer | |
| CN106008085A (en) | Water-soluble amino acid fertilizer and preparation method thereof | |
| CN1124784C (en) | Biological Pesticide prepared with the extraction from xianggu mushroom leftover and the preparation process | |
| CN1721371A (en) | Process for preparing bio-organic chelated trace fertilizer | |
| JPH0640786A (en) | Fertilizer containing amino acid and its production | |
| CN102173910A (en) | Marine byproduct fermentation concentration composite fertilizer and production method thereof | |
| JP2006290716A (en) | Manufacturing method of natural amino acid fertilizer derived from gelatin waste | |
| KR20100042824A (en) | Method for producing high concentrated-amino acid liquid fertilizer using animal blood and product by the same | |
| CN1161303C (en) | Process for preparing nourishing agent of plant | |
| CN106699344A (en) | Chelated calcium synthesized by taking oyster shells and alcohol slops as raw materials and preparation method thereof | |
| EP1517873B1 (en) | Process for treating residue of organic material | |
| CN111170767A (en) | Production method of ox bone amino acid organic fertilizer | |
| CN107840705A (en) | One plant nutrient liquor and preparation method thereof | |
| JP2009249239A (en) | Liquid compound fertilizer and method of manufacturing the same | |
| CN107176865A (en) | The sweetened liquid fertilizer method of preparation and use of marine alga earthworm hydrolyzate efficient bio-active | |
| CN107827513A (en) | A kind of preparation method of the water-soluble fertilizer containing amino acid | |
| CN110724211B (en) | High-value comprehensive utilization method of shrimp and crab shells based on reducing sugar catalytic oxidation and application thereof | |
| WO2017042826A1 (en) | "non-gmo wheat gluten derived glutamine rich peptide based biostimulating organic fertilizer and process for preparation thereof'' | |
| JPH0597556A (en) | Production of liquid organic fertilizer | |
| CN112335608A (en) | Earthworm breeding system combined with organic solid waste treatment | |
| KR20190044215A (en) | The Treatment Method of Activated Mineral Group Solution in the shrimp farm | |
| CN114540445B (en) | Preparation method of amino acid polypeptide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170524 |
|
| RJ01 | Rejection of invention patent application after publication |