CN104946107A - Anti-flaming anti-bacteria coating - Google Patents
Anti-flaming anti-bacteria coating Download PDFInfo
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- CN104946107A CN104946107A CN201510414854.9A CN201510414854A CN104946107A CN 104946107 A CN104946107 A CN 104946107A CN 201510414854 A CN201510414854 A CN 201510414854A CN 104946107 A CN104946107 A CN 104946107A
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Abstract
The invention relates anti-flaming anti-bacteria coating. The anti-flaming anti-bacteria coating comprises the following materials, by mass, 6-10 parts furfuryl alcohol resin, 15-30 parts of butylated hydroxyanisole, 8-16 parts of polyhexamethylene guanidine, 10-25 parts of zirconite powder bodies, 8-10 parts of trimethoprim lactate, 4-10 parts of bismaleimide resin, 12-20 parts of antimonous oxide, 0.5-1 part of cobalt blue, 0.1-0.5 part of chlorothalonil, 5-15 parts of magnesium stearate, 1-3 parts of isophorone diisocyanate and 30-100 parts of deionized water. The preparation process of the anti-flaming anti-bacteria coating is conducted under normal temperature, no new equipment is needed to be added, the technology is simple, and the cost is low. After the anti-flaming anti-bacteria coating is used, not only can the antibacterial property on the surface of a material be effectively improved, but also the anti-flaming property is good.
Description
Technical field
The present invention relates to technical field of coatings, be specifically related to a kind of flame-proof antibiotic coating.
Background technology
Along with the fast development of economy, people's living standard improves greatly, and health perception constantly strengthens, especially in recent years
The outburst of various diseases and popular, the serious harm that the various transmissible diseases making people more and more pay attention to being caused by harmful levels of pathogens, disease cause human health.This series products industrialized does not have antibacterial at present.Along with the raising of people's living standard and the reinforcement of health consciousness, will inevitably to antimicrobial product.In addition, some coating have better effects to fire-retardant, convenient better fire-retardant, improve the security that coating uses.
Summary of the invention
The object of the present invention is to provide a kind of flame-proof antibiotic coating, to realize coating flame-proof antibiotic function, and provide this preparation method for coating.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of flame-proof antibiotic coating, is made up of following mass component material: furfuryl alcohol resin 6 ~ 10 parts, butylated hydroxy anisole 15 ~ 30 parts, polyhexamethylene guanidine 8 ~ 16 parts, zircon powder 10 ~ 25 parts, Trimethoprim lactate 8 ~ 10 parts, bimaleimide resin 4 ~ 10 parts, antimonous oxide 12 ~ 20 parts, cobalt blue 0.5 ~ 1 part, m-tetrachlorophthalodinitrile 0.1 ~ 0.5 part, Magnesium Stearate 5 ~ 15 parts, isoflurane chalcone diisocyanate 1 ~ 3 part, deionized water 30 ~ 100 parts.
Further degree, above-mentioned flame-proof antibiotic coating, is made up of following mass component material: furfuryl alcohol resin 8 parts, butylated hydroxy anisole 23 parts, polyhexamethylene guanidine 12 parts, zircon powder 12 parts, Trimethoprim lactate 9 parts, bimaleimide resin 7 parts, antimonous oxide 16 parts, cobalt blue 0.8 part, m-tetrachlorophthalodinitrile 0.3 part, Magnesium Stearate 10 parts, isoflurane chalcone diisocyanate 2 parts, deionized water 65 parts.
Further, above-mentioned flame-proof antibiotic preparation method for coating comprises the steps:
(1) butylated hydroxy anisole of above-mentioned mass fraction is added in deionized water, then furfuryl alcohol resin, polyhexamethylene guanidine, Trimethoprim lactate, bimaleimide resin, antimonous oxide, m-tetrachlorophthalodinitrile, Magnesium Stearate, the isoflurane chalcone diisocyanate of above-mentioned mass fraction is added successively, high speed dispersion;
(2) the zircon powder of above-mentioned mass fraction is added, high speed dispersion;
(3) add the cobalt blue of above-mentioned mass fraction, high-speed mixing evenly, filter, regulate pH value to be 8 ~ 10, obtained solid content is 30 ~ 60% flame-proof antibiotic coating.
Further, in above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 3800 ~ 4800r/min in step (1), jitter time is 25 ~ 50min.
Further, in above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 3000 ~ 3800r/min in step (2), jitter time is 15 ~ 35min.
Further, in above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 1500 ~ 2500r/min in step (3), jitter time is 10 ~ 20min.
In above-mentioned material used, there is following characteristic:
(1) furfuryl alcohol resin: this resin is a kind of thermoset furane resin, good mechanical performance, and with iron, wood, brick, cohesive strength is high, good heat resistance, maximum operating temperature can reach 190 ° of C, and water resistance is good, the corrosion of all organic solvents can be resisted, can be acidproof, alkaline-resisting.
(2) butylated hydroxy anisole: be a kind of good antioxidant.
(3) polyhexamethylene guanidine: environment-friendly type macromolecule polymkeric substance disinfection sanitizer, has broad-spectrum; Effective concentration is low; Speed of action is fast; Stable in properties; For a long time antibacterial, have no side effect; Non-corrosiveness; Colourless, odorless; Nontoxic; Do not fire, not quick-fried, use safety; Moderate; Convenient transportation, can be described as best sterilant.
(4) zircon powder: zircon is used for refractory materials and (claims zirconia refractory, as zircon corundum brick, zirconium matter refractory fibre), casting industry casting mold is with sand (precision casting molding sand), accurate enamel utensil, in the production in addition also for glass, metal (zirconium sponge) and zirconium compounds (zirconium dioxide, basic zirconium chloride, sodium zirconate, potassium fluozirconate, zirconium sulfate etc.).
(5) Trimethoprim lactate: present germicidal action, and the generation that can also reduce Resistant strain.Can strengthen the anti-microbial effect of tsiklomitsin, penicillin, erythromycin, gentamicin etc., with berberine drug combination, berberine anti-microbial effect obviously strengthens, and is the non-selective antimicrobial drug of wide spectrum.
(6) bimaleimide resin: excellent thermotolerance, electrical insulating property, wave, radiation hardness, flame retardant resistance, good mechanical property and dimensional stability, moulding process is similar to the features such as epoxy resin, be widely used in the industrial circles such as Aeronautics and Astronautics, machinery, electronics, the resin matrix of advanced composite material, high-temperature insulation material and tackiness agent etc.There is the performances such as excellent electrical property, chemical resistance and radiation hardness.
(7) antimonous oxide: as fire retardant, can be widely used in the fire-retardant of the materials such as polyethylene, polypropylene, polystyrene, polyvinyl chloride, nylon, engineering plastics (ABS), rubber, paint, coating, synthetic resins, paper.
(8) cobalt blue: heat-resisting, fast light, acidproof, alkaline-resisting.For glass processed and pottery, also for drawing and coating etc.Excellent outdoor photostabilization, weather resisteant, high thermal resistance; Good acidproof, alkaline-resisting, resistance to all kinds of SOLVENTS and chemical corrosivity; And have without oozing property, nonmigratory; And with most of thermoplasticity, thermosetting resin, there is excellent compatibility.
(9) m-tetrachlorophthalodinitrile: m-tetrachlorophthalodinitrile is wide spectrum, protective fungicide.The mechanism of action can be had an effect with the glyceraldehyde 3-phosphate dehydrogenase in fungal cell, combines, thus destroy this enzymic activity, the metabolism of fungal cell is damaged and the power that loses one's life with the protein containing halfcystine in this enzyme.
(10) Magnesium Stearate: be mainly used as lubricant, antisticking agent, glidant, also can be used as flocculating aids, finings and drips infusion, and the suspending agent of liquid preparation, thickening material.
(11) isoflurane chalcone diisocyanate: have outstanding resistance to optical stabilization and chemical proofing, is generally used for and manufactures high-grade adhesive for polyurethane.
This beneficial effect of the invention is: flame-proof antibiotic dope preparing process of the present invention carries out at normal temperatures and pressures, does not need to add new equipment, and technique is simple, and production cost is low.Flame-proof antibiotic coating of the present invention can not only effectively improve material surface anti-microbial property, and have good flame retardant properties after using.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
embodiment 1
Flame-proof antibiotic coating in the present embodiment, is made up of following mass component material: furfuryl alcohol resin 6 parts, butylated hydroxy anisole 15 parts, polyhexamethylene guanidine 8 parts, zircon powder 10 parts, Trimethoprim lactate 8 parts, bimaleimide resin 4 parts, antimonous oxide 12 parts, cobalt blue 0.5 part, m-tetrachlorophthalodinitrile 0.1 part, Magnesium Stearate 5 parts, isoflurane chalcone diisocyanate 1 part, deionized water 30 parts.
Above-mentioned flame-proof antibiotic preparation method for coating comprises the steps:
(1) butylated hydroxy anisole of above-mentioned mass fraction is added in deionized water, then furfuryl alcohol resin, polyhexamethylene guanidine, Trimethoprim lactate, bimaleimide resin, antimonous oxide, m-tetrachlorophthalodinitrile, Magnesium Stearate, the isoflurane chalcone diisocyanate of above-mentioned mass fraction is added successively, high speed dispersion;
(2) the zircon powder of above-mentioned mass fraction is added, high speed dispersion;
(3) add the cobalt blue of above-mentioned mass fraction, high-speed mixing evenly, filter, regulate pH value to be 8, obtained solid content is 30% flame-proof antibiotic coating.
In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 3800r/min in step (1), jitter time is 50min.In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 3000r/min in step (2), jitter time is 35min.In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 1500r/min in step (3), jitter time is 20min.
embodiment 2
Flame-proof antibiotic coating in the present embodiment, is made up of following mass component material: furfuryl alcohol resin 10 parts, butylated hydroxy anisole 30 parts, polyhexamethylene guanidine 16 parts, zircon powder 25 parts, Trimethoprim lactate 10 parts, bimaleimide resin 10 parts, antimonous oxide 20 parts, cobalt blue 1 part, m-tetrachlorophthalodinitrile 0.5 part, Magnesium Stearate 15 parts, isoflurane chalcone diisocyanate 3 parts, deionized water 100 parts.
Above-mentioned flame-proof antibiotic preparation method for coating comprises the steps:
(1) butylated hydroxy anisole of above-mentioned mass fraction is added in deionized water, then furfuryl alcohol resin, polyhexamethylene guanidine, Trimethoprim lactate, bimaleimide resin, antimonous oxide, m-tetrachlorophthalodinitrile, Magnesium Stearate, the isoflurane chalcone diisocyanate of above-mentioned mass fraction is added successively, high speed dispersion;
(2) the zircon powder of above-mentioned mass fraction is added, high speed dispersion;
(3) add the cobalt blue of above-mentioned mass fraction, high-speed mixing evenly, filter, regulate pH value to be 10, obtained solid content is 60% flame-proof antibiotic coating.
In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 4800r/min in step (1), jitter time is 25min.In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 3800r/min in step (2), jitter time is 15min.In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 2500r/min in step (3), jitter time is 10min.
embodiment 3
Flame-proof antibiotic coating in the present embodiment, is made up of following mass component material: furfuryl alcohol resin 8 parts, butylated hydroxy anisole 18 parts, polyhexamethylene guanidine 12 parts, zircon powder 13 parts, Trimethoprim lactate 9 parts, bimaleimide resin 12 parts, antimonous oxide 16 parts, cobalt blue 0.75 part, m-tetrachlorophthalodinitrile 0.3 part, Magnesium Stearate 10 parts, isoflurane chalcone diisocyanate 2 parts, deionized water 65 parts.
Above-mentioned flame-proof antibiotic preparation method for coating comprises the steps:
(1) butylated hydroxy anisole of above-mentioned mass fraction is added in deionized water, then furfuryl alcohol resin, polyhexamethylene guanidine, Trimethoprim lactate, bimaleimide resin, antimonous oxide, m-tetrachlorophthalodinitrile, Magnesium Stearate, the isoflurane chalcone diisocyanate of above-mentioned mass fraction is added successively, high speed dispersion;
(2) the zircon powder of above-mentioned mass fraction is added, high speed dispersion;
(3) add the cobalt blue of above-mentioned mass fraction, high-speed mixing evenly, filter, regulate pH value to be 9, obtained solid content is 45% flame-proof antibiotic coating.
In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 4500r/min in step (1), jitter time is 35min.In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 3500r/min in step (2), jitter time is 20min.In above-mentioned flame-proof antibiotic preparation method for coating, the rate of dispersion 2000r/min in step (3), jitter time is 15min.
Carry out flame-proof antibiotic performance measurement for the coating in embodiment 1, embodiment 2 and embodiment 3 and certain commercial coating, measured data are as shown in table 1.Flame retardant rating test adopts UL94 standard.
Table 1 flame-proof antibiotic the performance test results
Visible, material of the present invention has fire-retardant and anti-microbial property preferably.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (6)
1. a flame-proof antibiotic coating, is characterized in that: be made up of following mass component material: furfuryl alcohol resin 6 ~ 10 parts, butylated hydroxy anisole 15 ~ 30 parts, polyhexamethylene guanidine 8 ~ 16 parts, zircon powder 10 ~ 25 parts, Trimethoprim lactate 8 ~ 10 parts, bimaleimide resin 4 ~ 10 parts, antimonous oxide 12 ~ 20 parts, cobalt blue 0.5 ~ 1 part, m-tetrachlorophthalodinitrile 0.1 ~ 0.5 part, Magnesium Stearate 5 ~ 15 parts, isoflurane chalcone diisocyanate 1 ~ 3 part, deionized water 30 ~ 100 parts.
2. flame-proof antibiotic coating according to claim 1, is characterized in that: described flame-proof antibiotic coating, is made up of following mass component material: furfuryl alcohol resin 8 parts, butylated hydroxy anisole 23 parts, polyhexamethylene guanidine 12 parts, zircon powder 12 parts, Trimethoprim lactate 9 parts, bimaleimide resin 7 parts, antimonous oxide 16 parts, cobalt blue 0.8 part, m-tetrachlorophthalodinitrile 0.3 part, Magnesium Stearate 10 parts, isoflurane chalcone diisocyanate 2 parts, deionized water 65 parts.
3. flame-proof antibiotic coating according to claim 1 and 2, is characterized in that: described flame-proof antibiotic preparation method for coating comprises the steps:
(1) butylated hydroxy anisole of described mass fraction is added in deionized water, then furfuryl alcohol resin, polyhexamethylene guanidine, Trimethoprim lactate, bimaleimide resin, antimonous oxide, m-tetrachlorophthalodinitrile, Magnesium Stearate, the isoflurane chalcone diisocyanate of above-mentioned mass fraction is added successively, high speed dispersion;
(2) the zircon powder of described mass fraction is added, high speed dispersion;
(3) add the cobalt blue of described mass fraction, high-speed mixing evenly, filter, regulate pH value to be about 8 ~ 10, obtained solid content is about 30 ~ 60% flame-proof antibiotic coating.
4. flame-proof antibiotic coating according to claim 3, it is characterized in that: described flame-proof antibiotic preparation method for coating comprises the steps: in above-mentioned flame-proof antibiotic preparation method for coating, rate of dispersion about 3800 ~ 4800r/min in step (1), jitter time is about 25 ~ 50min.
5. flame-proof antibiotic coating according to claim 3, it is characterized in that: described flame-proof antibiotic preparation method for coating comprises the steps: in above-mentioned flame-proof antibiotic preparation method for coating, rate of dispersion 3000 ~ 3800r/min in step (2), jitter time is about 15 ~ 35min.
6. flame-proof antibiotic coating according to claim 3, it is characterized in that: described flame-proof antibiotic preparation method for coating comprises the steps: in above-mentioned flame-proof antibiotic preparation method for coating, rate of dispersion about 1500 ~ 2500r/min in step (3), jitter time is about 10 ~ 20min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510414854.9A CN104946107A (en) | 2015-07-15 | 2015-07-15 | Anti-flaming anti-bacteria coating |
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| CN201510414854.9A CN104946107A (en) | 2015-07-15 | 2015-07-15 | Anti-flaming anti-bacteria coating |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105419495A (en) * | 2015-12-29 | 2016-03-23 | 齐齐哈尔译夫经贸有限公司 | Building paint having flame retardation and antibiosis functions |
| CN105542618A (en) * | 2015-12-23 | 2016-05-04 | 铜陵市肆得科技有限责任公司 | Powder coating with high performance and high stability |
| CN106832418A (en) * | 2016-12-30 | 2017-06-13 | 安徽远征电缆科技有限公司 | A kind of cable fire retardant |
| CN115058182A (en) * | 2022-08-01 | 2022-09-16 | 牡丹江乾元智康环保科技有限公司 | Flame-retardant polyurethane coating capable of releasing negative oxygen ions and synthesis process thereof |
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2015
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Patent Citations (4)
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| US4212909A (en) * | 1979-06-18 | 1980-07-15 | Wausau Homes, Inc. | Fireproof barrier coating compositions |
| CN1508190A (en) * | 2002-12-16 | 2004-06-30 | 吴荣泰 | Flame-retarding resin composition |
| CN102892529A (en) * | 2010-03-08 | 2013-01-23 | 福塞科国际有限公司 | Foundry coating composition |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542618A (en) * | 2015-12-23 | 2016-05-04 | 铜陵市肆得科技有限责任公司 | Powder coating with high performance and high stability |
| CN105419495A (en) * | 2015-12-29 | 2016-03-23 | 齐齐哈尔译夫经贸有限公司 | Building paint having flame retardation and antibiosis functions |
| CN106832418A (en) * | 2016-12-30 | 2017-06-13 | 安徽远征电缆科技有限公司 | A kind of cable fire retardant |
| CN115058182A (en) * | 2022-08-01 | 2022-09-16 | 牡丹江乾元智康环保科技有限公司 | Flame-retardant polyurethane coating capable of releasing negative oxygen ions and synthesis process thereof |
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