CN104934291B - A kind of method for handling abnormal chip - Google Patents

A kind of method for handling abnormal chip Download PDF

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Publication number
CN104934291B
CN104934291B CN201410105748.8A CN201410105748A CN104934291B CN 104934291 B CN104934291 B CN 104934291B CN 201410105748 A CN201410105748 A CN 201410105748A CN 104934291 B CN104934291 B CN 104934291B
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Prior art keywords
polyimides
chip
abnormal chip
abnormal
etching
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CN104934291A (en
Inventor
杨国威
樊佩申
曹存朋
朱晓峥
杨晓松
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Semiconductor Manufacturing International Shanghai Corp
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Semiconductor Manufacturing International Shanghai Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31127Etching organic layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31127Etching organic layers
    • H01L21/31133Etching organic layers by chemical means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31127Etching organic layers
    • H01L21/31133Etching organic layers by chemical means
    • H01L21/31138Etching organic layers by chemical means by dry-etching

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  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Drying Of Semiconductors (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)

Abstract

The present invention provides a kind of method for handling abnormal chip, and the method for the abnormal chip of processing includes at least the step of removing wafer surface cured polyimides, which includes at least:There is provided has the abnormal chip of protection zone, formed with cured polyimides on the protection zone;Positive photoresist is applied on the abnormal chip and polyimide surface;The positive photoresist is exposed by the first mask plate, the polyimides on the protection zone is exposed after development;The polyimides of the exposure is removed using etching technics etching;Remove the positive photoresist.The mode for removing polyimides is changed to etch by the present invention by traditional cleaning, and the cured polyimides of abnormal wafer surface can be fallen with thorough cleaning;Positive photoresist plays barrier effect in etching processing, and protection chip surface is injury-free, carries out reworked processing so as to fulfill to the abnormal chip after polyimide curing, avoids wafer scrap;And the present invention need not change manufacturing process and bench structure, industrial cost is low.

Description

A kind of method for handling abnormal chip
Technical field
The present invention relates to technical field of manufacturing semiconductors, is related to a kind of method for handling abnormal chip, more particularly to one The method that kind removes the cured polyimides of abnormal wafer surface.
Background technology
Polyimides(Polyimide)It is widely used, is being made in microelectronics industry with the performance that its is excellent Make the passivation protection that can be used as all kinds of devices in industry and inter-level dielectric etc..Protective layer of the polyimides as microelectronic component, A- particles can be shielded, the soft error of abatement device, reduces influence of the environment to device, can improve microelectronic component and resist badly The ability of environment.Polyimides or a kind of negative photoresist, itself had not only played photoresist but also is dielectric material, was preparing Without applying extra photoresist in polyimide surface during polyimide covercoat, process is substantially reduced.
In integrated circuit fabrication process, can firmly it be attached to after polyimide curing shaping on device, to device Play a protective role, still, chip can usually be found various abnormal conditions, for example go out during test after the completion of preliminary manufacture Existing electrical property is abnormal, residual particles are too many etc..Once exception occurs in chip, then need to carry out reworked processing to abnormal chip.
The first step of reworked processing is to remove the protective layer polyimides of abnormal wafer surface, but the polyamides after curing Imines has the characteristics such as antiacid anticorrosive high temperature resistant, and good with the adhesiveness of chip, causes the polyamides after curing molding sub- Amine is difficult to remove.Until current chip abnormality processing is still the problem of industry, chip is done over again, and success rate is very low, and scrappage reaches More than 95%, enterprises' loss is serious, and cost increases substantially.
In the prior art if it find that chip can be carried out by the way that polyimides is cleaned multiple times extremely after polyimide curing Reworked processing, but the polyimides that the chip after doing over again still has large area remains, and carries out by force after technique is cleaned multiple times, on chip Polyimides residual still receives on a small quantity, but chip surface can be serious due to cleaning damage, and abnormal chip can still be scrapped.
Therefore it provides a kind of method that method of the abnormal chip of improved processing especially removes polyimides is this area Technical staff needs the problem solved.
The content of the invention
In view of the foregoing deficiencies of prior art, it is an object of the invention to provide a kind of side for handling abnormal chip Method, is not thorough for solving to remove when cleaning in the prior art removes abnormal wafer surface cured polyimides, removes polyamides The problem of abnormal wafer surface causes abnormal wafer scrap is damaged during imines.
In order to achieve the above objects and other related objects, the present invention provides a kind of method for handling abnormal chip, the place The method of the abnormal chip of reason includes at least the step of removing wafer surface cured polyimides, which includes at least:
There is provided has the abnormal chip of protection zone, formed with cured polyimides on the protection zone;
Positive photoresist is applied on the abnormal chip and polyimide surface;
The positive photoresist is exposed by the first mask plate, the polyamides on the protection zone is exposed after development Imines;
The polyimides of the exposure is removed using etching technics etching;
Remove the positive photoresist.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, the exception chip are served as a contrast including semiconductor Bottom and the circuit structure for being formed in the semiconductor substrate surface.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, forms cured on the protection zone The step of polyimides, includes:
First, the coating polyimide on the semiconductor substrate structure;Secondly, by the second mask plate to the polyamides Imines is exposed, and the polyimides is formed on the protection zone of semiconductor substrate structure after development;Finally, on protection zone Polyimides carry out baking-curing.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, first mask plate and the second mask Plate is same mask plate.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, the thickness range of the polyimides are 10~90 μm.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, the model of the positive photoresist PFI58 or AR89.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, using dry or wet etch technique pair The polyimides performs etching.
As a kind of prioritization scheme of the method for the abnormal chip of processing of the present invention, etched using wet-etching technology described in Polyimides, etching liquid use hydrofluoric acid.
As a kind of prioritization scheme of the method for the abnormal chip of processing of the present invention, etched using dry etch process described in Polyimides, the gas of etching use fluoro-gas.
A kind of prioritization scheme of the method for the abnormal chip of processing as the present invention, the fluoro-gas is CF4、CHF3Or C3F8
As described above, the method for the abnormal chip of the processing of the present invention, including remove the cured polyimides of wafer surface Step, the step include at least:There is provided has the abnormal chip of protection zone, sub- formed with cured polyamides on the protection zone Amine;Positive photoresist is applied on the abnormal chip and polyimide surface;By the first mask plate to the positive-tone photo Glue is exposed and develops, and exposes the polyimides on the protection zone;The exposure is removed using etching technics etching Polyimides;Remove the positive photoresist.The mode for removing polyimides is changed to etch by the present invention by traditional cleaning, can The cured polyimides of abnormal wafer surface is fallen with thorough cleaning;Positive photoresist plays barrier effect in etching processing, protects Shield chip surface is injury-free, carries out reworked processing so as to fulfill to the abnormal chip after polyimide curing, avoids chip report It is useless;And the present invention need not change manufacturing process and bench structure, industrial cost is low.
Brief description of the drawings
Fig. 1 is the process flow diagram of the method for the abnormal chip of present invention processing.
Fig. 2~Fig. 4 is the structure diagram that cured polyimides is formed in the method for the abnormal chip of present invention processing.
Fig. 5~Fig. 9 is to remove cured polyimides schematic diagram in the method for the abnormal chip of present invention processing.
Component label instructions
1 abnormal chip
11 Semiconductor substrates
12 circuit structures
2 polyimides
3 second mask plates
4 positive photoresists
5 first mask plates
Embodiment
Illustrate embodiments of the present invention below by way of specific instantiation, those skilled in the art can be by this specification Disclosed content understands other advantages and effect of the present invention easily.The present invention can also pass through in addition different specific realities The mode of applying is embodied or practiced, the various details in this specification can also be based on different viewpoints with application, without departing from Various modifications or alterations are carried out under the spirit of the present invention.
Refer to attached drawing.It should be noted that only explanation is of the invention in a schematic way for the diagram provided in the present embodiment Basic conception, only the display component related with the present invention rather than component count, shape during according to actual implementation in schema then Shape and size are drawn, and kenel, quantity and the ratio of each component can be a kind of random change during its actual implementation, and its component cloth Office's kenel may also be increasingly complex.
The present invention provides a kind of method for handling abnormal chip, as shown in Figure 1, the method for the abnormal chip of the processing includes The step of removing wafer surface cured polyimides, which includes at least:
First, there is provided there is the abnormal chip of protection zone, formed with cured polyimides on the protection zone;
Secondly, positive photoresist is applied on the abnormal chip and polyimide surface;
Then, the positive photoresist is exposed by the first mask plate, is exposed after development on the protection zone Polyimides;
Then, the polyimides of the exposure is removed using etching technics etching;
Finally, the positive photoresist is removed.
The method for specifically describing the abnormal chip of processing of the present invention below in conjunction with the accompanying drawings.
Step 1 is first carried out, asks Shenfu Fig. 4, there is provided there is the abnormal chip 1 of protection zone, on the protection zone formed with Cured polyimides 2.
The exception chip 1 includes Semiconductor substrate 11 and the circuit structure for being formed in 11 surface of Semiconductor substrate 12.Wherein, the Semiconductor substrate 11 can be silicon substrate or silicon-on-insulator(SOI), in the present embodiment, the semiconductor lining Bottom 11 is preferably silicon substrate.The circuit structure 12 is that subsequent growth has the function of certain device on the silicon substrate 11 Structure, such as, source electrode, drain electrode, grid and metal interconnecting wires etc. are included in circuit structure.According to the needs of actual wafer, Some circuit structures need to be protected, it is necessary to which those circuit structures protected are defined as protecting in its surface making polyimides 2 Protect area.
Fig. 2~Fig. 4 is referred to, is specially in the step of formation polyimides 2 on the protection zone:
First in abnormal 1 coating polyimide 2 of chip, as shown in Fig. 2, the polyimides 2 covers whole chip 1 Surface;Then the polyimides 2 is exposed by the second mask plate 3, as shown in Figure 3;Due to the polyimides 2 Body is that therefore, the polyimides 2 being exposed will not be dissolved by the developing as a kind of negative photoresist, described poly- after development Acid imide 2 is formed on the protection zone of abnormal chip 1, as shown in Figure 4;Finally, the polyimides 2 on protection zone is toasted It is allowed to cure, the polyimides 2 after curing has very strong adhesiveness with chip, it is possible to achieve the protection to circuit structure.
It should be noted that the polyimides 2 itself can be used as a kind of negative photoresist, therefore, on protection zone It is not required extra photoresist just can directly be patterned to polyimides 2 when making polyimides 2, reduces process, saves Cost.
The thickness of the polyimides 2 formed on the protection zone is in 10~90 μ ms, in the present embodiment, the thickness Degree can be 60 μm.
Secondly step 2 is performed, positive photoresist is applied on the abnormal chip and polyimide surface.
The abnormal chip 1 that surface has formed 2 protective layer of polyimides is being examined by technical staff by various detection means Measure after exception, it is necessary to carry out reworked processing, the polyimides 2 that will be cured removes, with the internal structure to abnormal chip 1 Repaired.
Specifically, positive photoresist 4 is applied on abnormal 2 surface of chip 1 and polyimides by the way of spin coating, Structure after spin coating positive photoresist 4 is as shown in Figure 5.The model of the positive photoresist 4 of spin coating can be PFI58 or AR89. In the present embodiment, using model AR89.Positive photoresist 4.
Then step 3 is performed, the positive photoresist is exposed by the first mask plate, institute is exposed after development State the polyimides on protection zone.
Attached drawing 6 and attached drawing 7 are referred to, the first mask plate 5 and the second mask plate 3 in step 1 used in the step can To be same mask plate, as shown in Figure 6.The positive photoresist 4 on abnormal 1 protection zone of chip is exposed by the mask plate Light, the positive photoresist 4 of exposure remove after developing solution dissolution, are follow-up so as to expose the polyimides 2 on protection zone Polyimides 2 on etching protection zone is prepared.
Then step 4 is performed, the polyimides of the exposure is removed using etching technics etching.
The positive photoresist 2 not being dissolved by the developing in above-mentioned steps three is covered in the area beyond abnormal 1 protection zone of chip Domain, carry out polyimides 2 etch when from barrier effect, can be conducive to protect to avoid damage of the etching technics to wafer surface Hold wafer surface characteristics.
The polyimides 2 can be removed to etch using dry etching or wet-etching technology.
In one embodiment, the polyimides 2 is performed etching using wet-etching technology, the etching liquid used is hydrogen Fluoric acid, etch period is in the range of tens seconds.Specifically, the etching technics is molten as wet etching using diluted hydrofluoric acid Liquid, the concentration range of the hydrofluoric acid solution is 45:1~55:1;The temperature performed etching is in the range of 20~30 DEG C;Wet method is carved The time of erosion is in the range of 8~15 seconds.More specifically, the concentration of the hydrofluoric acid solution is preferably 50:1;The temperature of etching Preferably 23 DEG C;The time of etching is preferably 10 seconds.
In another embodiment, the polyimides 2 is performed etching using dry etch process, it is specifically, described dry Method etching is carried out in etching reaction intracavitary, and using etching gas, the fluoro-gas can be CF for fluorine-containing gas4Or CHF3 Or C3F8.The range of flow of the etching gas is 50~100sccm, and the time for carrying out dry etching is about tens seconds.More have Body, the flow of the etching gas is preferably 80sccm.
It should also be noted that, specifically adopted, it is necessary to the abnormal progress of chip 1 cleaning step after the etching technics The abnormal chip 1 is rinsed with deionized water, the time of flushing is 5~10 minutes, then the abnormal chip 1 is carried out Drying.
Structure after the polyimides 2 of etching removal protection zone is as shown in Figure 8.
Step 5 is finally performed, removes the positive photoresist.
The positive photoresist 4 can be removed by the method for ashing or chemistry.In the present embodiment, using cineration technics The positive photoresist 4 is removed, as shown in Figure 9.
In conclusion the present invention provides a kind of method for handling abnormal chip, this method includes removal wafer surface and consolidates The step of polyimides of change, include at least:There is provided has the abnormal chip of protection zone, formed with cured on the protection zone Polyimides;Positive photoresist is applied on the abnormal chip and polyimide surface;By the first mask plate to it is described just Property photoresist is exposed and develops, and exposes the polyimides on the protection zone;Using described in etching technics etching removal Exposed polyimides;Remove the positive photoresist.The mode for removing polyimides is changed to by the present invention by traditional cleaning Etching, can fall the cured polyimides of abnormal wafer surface with thorough cleaning;Positive photoresist plays stop in etching processing Effect, protection chip surface is injury-free, carries out reworked processing so as to fulfill to the abnormal chip after polyimide curing, avoids Wafer scrap;And the present invention need not change manufacturing process and bench structure, industrial cost is low.
So the present invention effectively overcomes various shortcoming of the prior art and has high industrial utilization.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any ripe Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as Into all equivalent modifications or change, should by the present invention claim be covered.

Claims (8)

  1. A kind of 1. method for handling abnormal chip, it is characterised in that the method for the abnormal chip of processing is brilliant including at least removing The step of polyimides of piece surface cure, the step include at least:
    Abnormal chip with protection zone is provided, is provided with using the exposure of the second mask plate, development and dries on the protection zone The roasting cured polyimides formed, wherein, the polyimides also serves as a kind of negative photoresist;
    Positive photoresist is applied on the abnormal chip and polyimide surface;
    The positive photoresist is exposed by the first mask plate, the polyamides exposed after development on the protection zone is sub- Amine, first mask plate are identical mask plate with second mask plate;
    The polyimides of the exposure is removed using etching technics etching;
    Remove the positive photoresist.
  2. 2. the method for the abnormal chip of processing according to claim 1, it is characterised in that:The exception chip includes semiconductor Substrate and the circuit structure for being formed in the semiconductor substrate surface.
  3. 3. the method for the abnormal chip of processing according to claim 1, it is characterised in that:Formed and cured on the protection zone Polyimides the step of include:
    First, in the surface coating polyimide of the abnormal chip;Secondly, by the second mask plate to the polyimides into Row exposure, the polyimides is formed on the protection zone of abnormal chip after development;Finally, to the polyimides on protection zone into Row baking-curing.
  4. 4. the method for the abnormal chip of processing according to claim 1, it is characterised in that:The thickness of the cured polyimides It is 10~90 μm to spend scope.
  5. 5. the method for the abnormal chip of processing according to claim 1, it is characterised in that:Using dry or wet etch technique The polyimides is performed etching.
  6. 6. the method for the abnormal chip of processing according to claim 5, it is characterised in that:Institute is etched using wet-etching technology Polyimides is stated, etching liquid uses hydrofluoric acid.
  7. 7. the method for the abnormal chip of processing according to claim 5, it is characterised in that:Institute is etched using dry etch process Polyimides is stated, the gas of etching uses fluoro-gas.
  8. 8. according to the method for the abnormal chip of processing described in claim 7, it is characterised in that:The fluoro-gas is CF4、CHF3Or C3F8
CN201410105748.8A 2014-03-20 2014-03-20 A kind of method for handling abnormal chip Active CN104934291B (en)

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CN106128939B (en) * 2016-08-01 2018-10-26 上海华虹宏力半导体制造有限公司 The method of the abnormal MIM capacitor dielectric layer of processing
CN107768232B (en) * 2016-08-23 2020-03-13 中芯国际集成电路制造(上海)有限公司 Method for removing protective layer on surface of device
CN107919267B (en) * 2016-10-10 2021-02-19 中芯国际集成电路制造(上海)有限公司 Semiconductor device and manufacturing method thereof
CN108321085B (en) * 2017-01-17 2021-04-23 中芯国际集成电路制造(上海)有限公司 Method for removing polyimide layer and method for manufacturing semiconductor device

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