CN104926359A - Production method of non-sintered artificial pelelith - Google Patents
Production method of non-sintered artificial pelelith Download PDFInfo
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- CN104926359A CN104926359A CN201510310598.9A CN201510310598A CN104926359A CN 104926359 A CN104926359 A CN 104926359A CN 201510310598 A CN201510310598 A CN 201510310598A CN 104926359 A CN104926359 A CN 104926359A
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- volcanized rock
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 78
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 44
- 238000000034 method Methods 0.000 claims abstract description 32
- 230000008569 process Effects 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003381 stabilizer Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 238000005520 cutting process Methods 0.000 claims abstract description 7
- 238000005266 casting Methods 0.000 claims abstract description 6
- 239000011435 rock Substances 0.000 claims description 51
- 239000002893 slag Substances 0.000 claims description 35
- 239000002131 composite material Substances 0.000 claims description 33
- 239000004088 foaming agent Substances 0.000 claims description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000004411 aluminium Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 13
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 13
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 13
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 13
- 239000001110 calcium chloride Substances 0.000 claims description 13
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 13
- 239000004571 lime Substances 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 238000012423 maintenance Methods 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 239000004575 stone Substances 0.000 claims description 12
- 239000004568 cement Substances 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- -1 Zhong Shui Substances 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000002699 waste material Substances 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000002351 wastewater Substances 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 239000012267 brine Substances 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000010893 paper waste Substances 0.000 claims description 2
- 239000013618 particulate matter Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000008399 tap water Substances 0.000 claims description 2
- 235000020679 tap water Nutrition 0.000 claims description 2
- 238000005187 foaming Methods 0.000 abstract description 11
- 238000001723 curing Methods 0.000 abstract description 7
- 238000005245 sintering Methods 0.000 abstract description 5
- 238000009826 distribution Methods 0.000 abstract description 3
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000012779 reinforcing material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 14
- 239000002994 raw material Substances 0.000 description 7
- 239000003245 coal Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
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- 239000002002 slurry Substances 0.000 description 4
- 239000002594 sorbent Substances 0.000 description 4
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000004131 Bayer process Methods 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002519 antifouling agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000021321 essential mineral Nutrition 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000004537 pulping Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000029058 respiratory gaseous exchange Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- NJWIMFZLESWFIM-UHFFFAOYSA-N 2-(chloromethyl)pyridine Chemical compound ClCC1=CC=CC=N1 NJWIMFZLESWFIM-UHFFFAOYSA-N 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 229910004762 CaSiO Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000019739 Dicalciumphosphate Nutrition 0.000 description 1
- 208000035126 Facies Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- RWCMCDZEZZLVHL-UHFFFAOYSA-L S(=O)(=O)([O-])[O-].[Na+].C(=C)OC=C.[Na+] Chemical compound S(=O)(=O)([O-])[O-].[Na+].C(=C)OC=C.[Na+] RWCMCDZEZZLVHL-UHFFFAOYSA-L 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910002800 Si–O–Al Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- AGWMJKGGLUJAPB-UHFFFAOYSA-N aluminum;dicalcium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Ca+2].[Ca+2].[Fe+3] AGWMJKGGLUJAPB-UHFFFAOYSA-N 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HOOWDPSAHIOHCC-UHFFFAOYSA-N dialuminum tricalcium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[Al+3].[Al+3].[Ca++].[Ca++].[Ca++] HOOWDPSAHIOHCC-UHFFFAOYSA-N 0.000 description 1
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
- 229940038472 dicalcium phosphate Drugs 0.000 description 1
- 229910000390 dicalcium phosphate Inorganic materials 0.000 description 1
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000010855 food raising agent Nutrition 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 235000016768 molybdenum Nutrition 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 229910021534 tricalcium silicate Inorganic materials 0.000 description 1
- 235000019976 tricalcium silicate Nutrition 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000005335 volcanic glass Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a production method of non-sintered artificial pelelith, and aims to overcome the defects that natural pelelith is less in resource and non-uniform in distribution and the conventional artificial pelelith process needs sintering. The production method comprises the following steps; mixing a compound gel material, a reinforcing material, an exciting agent and process water in proportion, re-adding modified polyethoxylated silicone (MPS) as a foam stabilizer, stirring for 1 min, finally, adding a gas former, then stirring for 1-3 min, and casting, foaming, curing and cutting to produce the artificial pelelith. Compared with the prior art, the production method provided by the invention does not need high-temperature sintering and is low in cost and easy for industrial production, and the obtained product is stable in performance and adjustable in both color and gas pore size, and is a favorable substitute of natural pelelith.
Description
Technical field
The present invention relates to a kind of production method of non-sintered artificial volcanized rock, belong to comprehensive utilization of resources and New Building Materials technical field.
Background technology
Natural volcanized rock is commonly called as float stone or porous basalt, is a kind of functional type environment-friendly materials, is the porous stone material by volcanic glass, mineral and bubble formation after volcanic explosion.Natural mineral kind and content depend on circumferentially shell structure, generally containing tens kinds of mineral substance and trace elements such as sodium, magnesium, aluminium, silicon, calcium, titanium, manganese, iron, nickel, cobalt and molybdenums, have far-infrared magnetic wave property radiationless.Natural volcanized rock outward appearance takes on a red color, black, Steel Gray, blueness etc., and its color is by the structures shape of its mineral composition, also relevant to its proportion, thus purposes also difference to some extent.Along with the raising of people's living standard, natural volcanized rock Application Areas constantly expands, and as building, water conservancy, grinding, filter material, Landscape, charcoal for roasting, soilless culture, ornamental article etc., plays irreplaceable effect, also has following characteristics simultaneously:
1, volcanics stone property superior, except there is the general characteristic of common stone material, also there is self individual style and specific function.Compared with the stone materials such as grouan, the low-activity of basalt stone material, makes it to be used safely in human lives and to live place, and the anxiety of no radioactivity pollute.
2, volcanics stone material weathering resistance, weather, durable in use; Sqouynd absorption lowering noise is conducive to improving acoustic environments; Primitive simplicity and nature avoids dazzle, is of value to and improves visual environment; The anti-skidding thermal resistance that absorbs water is of value to improves body sense environment: unique " breathing " function can adjusting air humidity, improves the ecological environment, can meet current era people and in construction and decoration, pursue primitive simplicity and nature, advocate the new fashion of environmental protection.
3, volcanic rock matter is hard, can in order to produce ultrathin stone slab, after the fine grinding of surface, glossiness can reach more than 85 degree, bright in color is pure, outward appearance is elegant serious, is widely used in various decorating outer wall of building, the ground pavement of town road square, residential quarters, the first-selected stone material of all kinds of building in the style of the ancients, European Architecture, garden architecture, is loved by the people and welcomes especially.
4, volcanic rock glass-ceramic tubre has fabulous wear-resistant, corrosion resistance, can be used as the lining of the tubing system of department's strengths such as electric power, chemical industry, metallurgy, mine, coal or Hydraulic transportation erosion corrosion material and slurry.The fiber made as utilized basalt, tubing, sheet, netted and flocculence finished product, can make fire prevention, flame-retardant textile, automotive brake, pipeline, insulation, heat insulation absorption of noise material, has the features such as lightweight, corrosion-resistant, work-ing life.
5, the metaling of volcanic rock after fragmentation (0.5 ~ 2 centimetre) is widely used in the foundation construction of the occasions such as road, bridge, building, dykes and dams seawall, there is the characteristic of unique high strength, high abrasion, high rigidity, be particularly useful for the roadbed cast of motorway and airfield runway, greatly can improve the property indices such as the load-bearing on road basis, resistance to compression, wear-resistant, antifatigue, be construction project unit and the architectural design department first-selected stone material when determining engineering materials.
At present, volcanized rock is mainly derived from natural recovery, due to the good characteristic that it has, and the focus having become people to pay close attention to of volcanized rock application and synthetic thereof.
CN 203924566 U relates to a kind of imitative volcanized rock decorative paint production board; comprise prime coat, volcanized rock coating base layer, the moulding of volcanized rock coating and protective paint layer; described prime coat, volcanized rock coating base layer, volcanized rock coating moulding layer and protective paint layer set gradually from top to bottom; compared with prior art, there is effective, low cost and other advantages.
CN 102962092 A relates to a kind of modification volcanized rock sorbent material and electroplating effluent treatment method, it is characterized in that sorbent preparation method is as follows: be added in toluene by volcanized rock powder and tosic acid, 10 ~ 14h is stirred under room temperature, 200 ~ 300rpm, then 55 ~ 65 DEG C are warming up to, 180 ~ 220mL tetraethoxy is added again with the speed of 8 ~ 12mL/min, continue to be stirred to solution and become solid phase, weight is solid to distilled water wash, at 100 ~ 120 DEG C, dry 1.5 ~ 2.5h, obtains modification volcanized rock gel; By 2-chloromethylpyridine, modification volcanized rock gel and methanol mixed, 60 ~ 70 DEG C, stir 18 ~ 22h under 200 ~ 300rpm, grinding, sieve granularity at 80 ~ 100 order particles, be modification volcanized rock sorbent material, when its goods are for adsorbing the chromium in electroplating wastewater, adsorption rate can reach more than 99%, and treatment effect is stablized.
As CN 102491730 A mono-kind utilizes Bayer process red mud to produce the method for artificial volcanized rock building block, take Bayer process red mud as main raw, through slurrying of milling, add fine coal powder, leavening agent, whipping agent, binding agent base, drying are burnt till and the step such as cooling is prepared from.The artificial volcanized rock that the method is produced has rule and irregular micropore, aperture, macropore, thus the artificial volcanized rock building block of the porcelainization forming similar sponge type, this product sqouynd absorption lowering noise can not only improve acoustic environments, and " breathing " function of its uniqueness can regulate air themperature, improve the ecological environment, can be widely used in constructing, building ground and wall decoration etc., be a kind of building and ornament materials of desirable environmental protection and energy saving.
It take coal gangue as the method for the artificial volcanized rock building block of raw material production that CN 102491732 A discloses a kind of, comprises the following steps: A, mill; B, batching; C, base; D, drying; E, to burn till; F, cooling.Adopting provided by the invention is that the method for raw material production artificial volcanized rock building block processes existing coal gangue slag with coal gangue, coal gangue slag is recycled, solve environmental issue, and have the remarkable advantage that environment-friendly high-efficiency, speed are fast, energy consumption is low, effective.Article of manufacture physicochemical property is stablized, and reaches the requirement of building material industry standard (JCT945-2005), can be widely used in building block, building ground, wall decoration etc., in addition, also has the advantage that investment is little, technique simple, be convenient to control grasp.
In sum, copy volcano slabstone, volcanized rock sorbent material and sintering process with coating for main material and produce the existing research of artificial volcanized rock, but also do not have patent application or reported in literature by foaming, the non-sintered artificial volcanized rock of casting production.
Summary of the invention
The object of the invention is with cement clinker, industrial slag prepares composite gelled material, the slag pulverized and sieved or phosphorus slag make strongthener, lime, calcium chloride, sodium-chlor is composite makes exciting agent, silicone resin polyethers emulsion makes suds-stabilizing agent, foaming agent is made with varigrained aluminium powder, through stirring, casting, maintenance, artificial volcanized rock is produced in cutting, decorative material for wall surface can be widely used as, walkway building materials, heat preserving and insulating material, the uses such as sound absorbent material, there is lightweight, anti-skidding, noise reduction, heat insulation, the effects such as decoration, excellent natural volcanized rock substitute products.
1, technology contents of the present invention is as follows:
1.1 non-sintered artificial volcano main raw material(s) and requirements
Described artificial volcanized rock forms primarily of composite gelled material, strongthener, exciting agent, suds-stabilizing agent, foaming agent and process water.
(1) composite gelled material
Composite gelled material take cement clinker as base material, and admixtion is slag, phosphorus slag, and wherein each constituent and mass percent are grog 50 ~ 60%, slag 20 ~ 30%, phosphorus slag 10 ~ 20%;
Composite gelled material is measured in proportion respectively by cement clinker, slag, phosphorus slag, and mix rear ball milling and obtain, granularity requirements was that 200 order square hole sieve screen over-sizes are less than 5%, and each dispensing requirements is as follows:
Cement clinker: with Wingdale, clay, ferriferous raw material for main raw material, through broken, batching, levigately makes raw material, is fired to part or all of melting, the work in-process obtained through cooling in cement kiln; Essential mineral consists of tricalcium silicate, Dicalcium Phosphate (Feed Grade), tricalcium aluminate and tetracalcium aluminoferrite, and its physicochemical property meets GB/T 21372-2008 requirement.
Phosphorus slag: the shrend solid waste produced in electric furnace process phosphorus production process, main component is CaSiO
3, mineral facies, based on vitreum, have lateral reactivity.
Slag: the high-temperature molten of discharging from blast furnace when blast furnace slag is manUfaCtUre of pig iron obtains through shrend quenching, and chemical composition is with CaO, SiO
2, Al
2o
3be main, essential mineral is vitreum mutually, and chemical reactivity is good.
(2) strongthener: strongthener refers to that slag or phosphorus slag are through pulverizing, sieving, and its granularity is 0.177 ~ 0.25mm
Between particulate matter.
(3) exciting agent be composite by lime, calcium chloride, sodium-chlor after form through ball milling, wherein in lime, active oxidation calcium contents is greater than 75wt%, and properties of powder performace was that 180 order square hole sieve screen over-sizes are less than 10%, and consumption accounts for 90 ~ 95wt% of exciting agent total amount; Calcium chloride is technical grade, CaCl
2content>=75%, consumption accounts for 4 ~ 6wt% of exciting agent total amount, and sodium-chlor is industry three grades of product, and consumption accounts for 1 ~ 4wt% of exciting agent total amount.
(4) suds-stabilizing agent: silicone resin polyethers emulsion (MPS) suds-stabilizing agent, as sodium lauryl sulphate (K12), poly alkyl alcohol
Oxygen Vinyl Ether sodium sulfate (AES), α-sodium olefin sulfonate (AOS) etc.
(5) foaming agent is made up of varigrained metallic aluminium powder, active aluminium content (in solid part) >=90%, wherein grain
What degree was less than 0.044mm accounts for 10wt%, and 0.044 ~ 0.105mm accounts for 30wt%, and 0.105 ~ 0.147mm accounts for 60wt%.
(6) process water be tap water, Zhong Shui, paper waste, red mud waste liquid, containing any one in alkali waste water, brine waste, processing of stone recycle-water.
1.2 non-sintered artificial volcano proportioning raw materials
Prepare to obtain non-sintered artificial volcanized rock body material after the mixing of composite gelled material, strongthener, exciting agent, composite gelled material, strongthener, the exciting agent butt mass percent in body material is respectively 60 ~ 70%, 20 ~ 30%, 10 ~ 15%; Process water consumption is 50 ~ 55% of body material gross weight, and suds-stabilizing agent consumption is 0.02 ~ 0.04% of body material mixture total weight amount, and foaming agent consumption is 0.06 ~ 0.08% of body material mixture total weight amount.
Take the composite gelled material in body material, exciting agent and strongthener in proportion, pre-mixing is carried out in stirrer, then process water is added, stir, add foaming agent after stirring 1min with suds-stabilizing agent again and stir 1 ~ 3min, casting, the demoulding, maintenance, cut into product as requested.
Described maintenance steam carries out maintenance, and vapor pressure is 0.8 ~ 1.2MPa, and curing time is 8 ~ 12h.
The production method of 1.3 non-sintered artificial volcanized rocks
This production method is prepared by composite gelled material, exciting agent and strongthener, pulping, foaming, leaves standstill the operation compositions such as maintenance, vapor cure, cutting, wherein:
(1) composite gelled material, exciting agent and strongthener preparation
Composite gelled material: by percentage to the quality, by cement clinker 50 ~ 60%, slag 20 ~ 30%, phosphorus slag 10 ~ 20% measures respectively, mix rear ball milling, and gelling material granularity requirements was that 200 order square hole sieve screen over-sizes are less than 5%;
Exciting agent: lime active oxidation calcium contents being greater than 75wt% carries out being milled to 180 sieve screen over-sizes and is less than 10%, by lime 90 ~ 95wt%, calcium chloride 4 ~ 6wt%, sodium-chlor 1 ~ 4wt% mass percent is composite forms, CaCl in industrial calcium chloride
2content>=75%, sodium-chlor be industry three grades of product and more than;
Strongthener: by slag, phosphorus slag through pulverizing, sieving, getting granularity is that 0.177 ~ 0.25mm part makes artificial volcanized rock strongthener;
(2) pulping
Composite gelled material, strongthener, exciting agent are added in stirrer after weighing and carries out pre-mixing, then process water, stirring is added by 50 ~ 55wt% of dry material gross weight, afterwards with suds-stabilizing agent continue stir 1min, then add foaming agent stir 1 ~ 3min make slip;
(3) foaming is left standstill
Slip is poured in mould, leave standstill foaming;
(4) maintenance is left standstill
In physical environment, carry out standing maintenance, curing time can be determined according to natural environmental condition, with intact for foundation during the test specimen demoulding;
(5) vapor cure
Be that 0.8 ~ 1.2MPa steam carries out maintenance by the test specimen pressure after the demoulding, curing time is 8 ~ 12h.
(6) cut
Cut by preparing product specification, be the artificial volcanized rock that code is different.
the present invention compared with prior art tool has the following advantages:
(1) compared with natural volcanized rock, artificial volcanized rock pore opening of the present invention, distribution, Color tunable.
(2) compared with existing artificial volcanized rock, artificial volcano of the present invention is without high temperature sintering.
In a word; the present invention is according to natural volcanized rock excellent property, widely used feature; the reality of unified with nature resource-constrained, areal distribution inequality; summing up the high shortcoming of existing artificial volcanized rock employing sintering process energy consumption in production process; take full advantage of composition structure and the chemical property of various material; under exciting agent effect; by improving temperature of reaction; final formation is based on the class ceramic network structure of Si-O-Si tetrahedron, Si-O-Al octahedron; product strength is high, performance is excellent, be easy to large-scale production, is the favorable substitutes of natural volcanized rock.
Accompanying drawing explanation
Fig. 1 is process flow diagram of the present invention.
Embodiment
Below by drawings and Examples, the present invention is described in further detail, but scope is not limited to described content.
Embodiment 1: the production method of this non-sintered artificial volcanized rock, content is as follows:
1, formula composition
(1) composite gelled material: cement clinker 60kg, slag 30kg, phosphorus slag 10kg, be milled to granularity after mixing and cross 200 order square hole sieve screen over-sizes and be less than 5%, composite gelled material consumption is 60% of body material gross weight.
(2) strongthener: slag is pulverized, sieved, and getting granularity is particle between 0.177 ~ 0.25mm, and strongthener consumption is 30% of body material gross weight.
(3) exciting agent is formed by lime, calcium chloride, sodium-chlor mixture, and exciting agent consumption is 10% of body material gross weight, and wherein lime accounts for the 90wt% of exciting agent total amount, and its active oxidation calcium contents is greater than 75%, and granularity was that 180 sieve screen over-sizes are less than 10%; Calcium chloride is technical grade, CaCl
2content>=75%, consumption accounts for the 6wt% of exciting agent total amount, and sodium-chlor is industry three grades of product, and consumption accounts for the 4wt% of exciting agent total amount.
(4) process water: middle water, consumption is 50% of body material gross weight;
(5) suds-stabilizing agent: sodium lauryl sulphate (K12), consumption is 0.02% of body material gross weight;
(6) foaming agent: metallic aluminium powder, foaming agent consumption is 0.06% of body material gross weight, and active aluminium content (in solid part) is 90%, and what wherein granularity was less than 0.044mm accounts for 10%, and 0.044 ~ 0.105mm accounts for 30%, and 0.105 ~ 0.147mm accounts for 60%.
2, technique
Prepare composite gelled material, strongthener, exciting agent and foaming agent by recipe requirements, require according to the above ratio to take composite gelled material, strongthener and exciting agent, in stirrer, carry out pre-mixing; Fully stir after adding process water, then add suds-stabilizing agent continuation stirring 1min, then add foaming agent-aluminium powder and stir 3min slurrying;
Slurry is poured in the mould of 400 × 300 × 600, and leaving standstill foaming, natural curing, is the vapor cure 12h of 0.8MPa with pressure after the demoulding, and cutting is product.
After testing, product strength is 8.22MPa, and unit weight is 830kg/m
3, coefficient of softening is 0.87, and water-intake rate is 12.2%, and hollow rate is 45%.
Embodiment 2: the production method of this non-sintered artificial volcanized rock, content is as follows:
1, formula composition
(1) composite gelled material: grog 50kg, slag 30kg, phosphorus slag 20kg, be milled to granularity after mixing and cross 200 order square hole sieve screen over-sizes and be less than 5%, composite gelled material consumption is 65% of body material gross weight;
(2) strongthener: phosphorus slag is pulverized, sieved, and getting granularity is particle between 0.177 ~ 0.25mm, and strongthener consumption is 20% of body material gross weight;
(3) exciting agent is formed by lime, calcium chloride, sodium-chlor mixture, and exciting agent consumption is 15% of body material gross weight, and wherein lime accounts for the 95wt% of exciting agent total amount, and its active oxidation calcium contents is greater than 75%, and granularity was that 180 sieve screen over-sizes are less than 10%; Calcium chloride is technical grade, CaCl
2content>=75%, consumption accounts for the 4wt% of exciting agent total amount, and sodium-chlor is industry three grades of product, and consumption accounts for the 1wt% of exciting agent total amount;
(4) process water: brine waste, consumption is 52% of body material gross weight;
(5) suds-stabilizing agent: polyoxyethylenated alcohol sodium sulfate (AES), consumption is 0.04% of body material gross weight.
(6) foaming agent: metallic aluminium powder, consumption is 0.08% of body material gross weight, and active aluminium content (in solid part) is 91.2%, and what wherein granularity was less than 0.044mm accounts for 10%, and 0.044 ~ 0.105mm accounts for 30%, and 0.105 ~ 0.147mm accounts for 60%.
2, technique
Prepare composite gelled material, strongthener, exciting agent and foaming agent by recipe requirements, require according to the above ratio to take composite gelled material, strongthener and exciting agent, in stirrer, carry out pre-mixing; Fully stir after adding process water, then add suds-stabilizing agent continuation stirring 1min, then add foaming agent-aluminium powder and stir 1min slurrying.
Slurry is poured in the mould of 400 × 300 × 600, and leaving standstill foaming, natural curing, is the vapor cure 8h of 1.2MPa with pressure after the demoulding, and cutting is product.
After testing, product strength is 5.10MPa, and unit weight is 570kg/m
3, coefficient of softening is 0.82, and water-intake rate is 15.2%, and hollow rate is 47%.
Embodiment 3: the production method of this non-sintered artificial volcanized rock, content is as follows:
1, formula composition
(1) composite gelled material: grog 55 kg, slag 25 kg, phosphorus slag 20 kg, be milled to granularity after mixing and cross 200 order square hole sieve screen over-sizes and be less than 5%, composite gelled material consumption is 70% of body material gross weight.
(2) strongthener: slag is pulverized, sieved, and getting granularity is particle between 0.177 ~ 0.25mm, and strongthener consumption is 20% of body material gross weight.
(3) exciting agent is formed by lime, calcium chloride, sodium-chlor mixture, and exciting agent consumption is 10% of body material gross weight, and wherein lime accounts for the 93wt% of exciting agent total amount, and its active oxidation calcium contents is greater than 75%, and granularity was that 180 sieve screen over-sizes are less than 10%; Calcium chloride is technical grade, CaCl
2content>=75%, consumption accounts for the 5wt% of exciting agent total amount, and sodium-chlor is industry three grades of product, and consumption accounts for the 2wt% of exciting agent total amount.
(4) process water: containing alkali waste water, consumption is 55% of body material gross weight;
(5) suds-stabilizing agent: α-sodium olefin sulfonate (AOS), consumption is 0.03% of body material gross weight.
(6) foaming agent: metallic aluminium powder, foaming agent consumption is 0.07% of body material gross weight, and active aluminium content (in solid part) is 91.2%, and what wherein granularity was less than 0.044mm accounts for 10%, and 0.044 ~ 0.105mm accounts for 30%, and 0.105 ~ 0.147mm accounts for 60%.
2, technique
Prepare composite gelled material, strongthener, exciting agent and foaming agent by recipe requirements, require according to the above ratio to take composite gelled material, strongthener and exciting agent, in stirrer, carry out pre-mixing; Fully stir after adding process water, then add suds-stabilizing agent continuation stirring 1min, then add foaming agent-aluminium powder and stir 2min slurrying;
Slurry is poured in the mould of 400 × 300 × 600, and leaving standstill foaming, natural curing, is the vapor cure 10h of 1.0MPa with pressure after the demoulding, and cutting is product.
After testing, product strength is 5.42MPa, and unit weight is 650kg/m
3, coefficient of softening is 0.83, and water-intake rate is 16.2%, and hollow rate is 46%.
Claims (5)
1. the production method of a non-sintered artificial volcanized rock, it is characterized in that: composite gelled material, strongthener, exciting agent, process water are fully mixed in proportion, add silicone resin polyethers emulsion again and make suds-stabilizing agent, finally add foaming agent, fully after mixing, artificial volcanized rock is produced in casting, maintenance, cutting;
Wherein said composite gelled material take cement clinker as base material, and admixtion is slag, phosphorus slag, and wherein each constituent and mass percent are cement clinker 50 ~ 60%, slag 20 ~ 30%, phosphorus slag 10 ~ 20%;
Described strongthener refers to that slag or phosphorus slag are through pulverizing, sieving, and its granularity is particulate matter between 0.177 ~ 0.25mm;
Described exciting agent be by lime, calcium chloride, sodium-chlor is composite forms, wherein in lime, active oxidation calcium contents is greater than 75wt%, and granularity was that 180 sieve screen over-sizes are less than 10%, and consumption accounts for 90 ~ 95 wt % of exciting agent total amount; Calcium chloride is technical grade, CaCl
2content>=75%, consumption accounts for 4 ~ 6 wt% of exciting agent total amount, and sodium-chlor is industry three grades of product, and consumption accounts for 1 ~ 4 wt% of exciting agent total amount;
Described process water be tap water, Zhong Shui, paper waste, red mud waste liquid, containing any one in alkali waste water, brine waste, processing of stone recycle-water;
Described foaming agent is made up of varigrained metallic aluminium powder, active aluminium content >=90%, and what wherein granularity was less than 0.044mm accounts for 10wt%, and 0.044 ~ 0.105mm accounts for 30wt%, and 0.105 ~ 0.147mm accounts for 60wt%;
Described silicone resin polyethers emulsion is sodium lauryl sulphate, polyoxyethylenated alcohol sodium sulfate or α-sodium olefin sulfonate.
2. the production method of non-sintered artificial volcanized rock according to claim 1, it is characterized in that: prepare to obtain non-sintered artificial volcanized rock body material after the mixing of composite gelled material, strongthener, exciting agent, wherein each constituent and butt mass percent are respectively 60 ~ 70%, 20 ~ 30%, 10 ~ 15%; Process water consumption is 50 ~ 55% of body material gross weight, and suds-stabilizing agent consumption is 0.02 ~ 0.04% of body material gross weight, 0.06 ~ 0.08% of foaming agent consumption body material gross weight.
3. the production method of non-sintered artificial volcanized rock according to claim 2, it is characterized in that: take the composite gelled material in body material, exciting agent and strongthener in proportion, pre-mixing is carried out in stirrer, then process water is added, stir, add foaming agent after stirring 1min with suds-stabilizing agent again and stir 1 ~ 3min, casting, the demoulding, maintenance, cut into product as requested.
4. the production method of non-sintered artificial volcanized rock according to claim 3, is characterized in that: in composite gelled material, each constituent measures in proportion respectively, and ball milling after mixing, granularity was that 200 order square hole sieve screen over-sizes are less than 5%.
5. the production method of non-sintered artificial volcanized rock according to claim 4, is characterized in that: maintenance steam carries out maintenance, and vapor pressure is 0.8 ~ 1.2MPa, and curing time is 8 ~ 12h.
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| CN105669240A (en) * | 2016-03-01 | 2016-06-15 | 海南兆晟科技发展有限公司 | Volcanic rock structure composite material and preparation method thereof |
| CN109053079A (en) * | 2018-09-12 | 2018-12-21 | 山东科技大学 | A kind of production method of artificial marine habitat |
| CN112694295A (en) * | 2020-12-15 | 2021-04-23 | 昆明理工大学 | Silicate-based artificial volcanic rock and production method thereof |
| CN113277738A (en) * | 2021-06-07 | 2021-08-20 | 昆明理工大学 | Artificial volcanic rock calcined by using red mud and steel slag as main raw materials and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105669240A (en) * | 2016-03-01 | 2016-06-15 | 海南兆晟科技发展有限公司 | Volcanic rock structure composite material and preparation method thereof |
| CN109053079A (en) * | 2018-09-12 | 2018-12-21 | 山东科技大学 | A kind of production method of artificial marine habitat |
| WO2020051870A1 (en) * | 2018-09-12 | 2020-03-19 | 山东科技大学 | Manufacturing method of artificial reef |
| CN112694295A (en) * | 2020-12-15 | 2021-04-23 | 昆明理工大学 | Silicate-based artificial volcanic rock and production method thereof |
| CN112694295B (en) * | 2020-12-15 | 2022-08-02 | 昆明理工大学 | Silicate-based artificial volcanic rock and production method thereof |
| CN113277738A (en) * | 2021-06-07 | 2021-08-20 | 昆明理工大学 | Artificial volcanic rock calcined by using red mud and steel slag as main raw materials and preparation method thereof |
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