CN104921406A - Preparation method for antifungal and deodorized insole - Google Patents
Preparation method for antifungal and deodorized insole Download PDFInfo
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- CN104921406A CN104921406A CN201510391353.3A CN201510391353A CN104921406A CN 104921406 A CN104921406 A CN 104921406A CN 201510391353 A CN201510391353 A CN 201510391353A CN 104921406 A CN104921406 A CN 104921406A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 230000000843 anti-fungal effect Effects 0.000 title abstract 3
- 229940121375 antifungal agent Drugs 0.000 title abstract 3
- 239000000839 emulsion Substances 0.000 claims abstract description 49
- 239000000341 volatile oil Substances 0.000 claims abstract description 49
- 239000003094 microcapsule Substances 0.000 claims abstract description 34
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 19
- 238000001035 drying Methods 0.000 claims abstract description 17
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 16
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 15
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 12
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical class O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000000243 solution Substances 0.000 claims description 32
- 239000003431 cross linking reagent Substances 0.000 claims description 30
- 230000002421 anti-septic effect Effects 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 16
- 244000131522 Citrus pyriformis Species 0.000 claims description 14
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 13
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 13
- 241001479543 Mentha x piperita Species 0.000 claims description 13
- 235000001050 hortel pimenta Nutrition 0.000 claims description 13
- 230000001857 anti-mycotic effect Effects 0.000 claims description 11
- 239000002543 antimycotic Substances 0.000 claims description 11
- 241000675108 Citrus tangerina Species 0.000 claims description 10
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 8
- 230000000845 anti-microbial effect Effects 0.000 claims description 8
- 239000004599 antimicrobial Substances 0.000 claims description 8
- 238000004108 freeze drying Methods 0.000 claims description 8
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 claims description 8
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 238000003828 vacuum filtration Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 4
- 239000004744 fabric Substances 0.000 abstract description 7
- 241000233866 Fungi Species 0.000 abstract description 6
- 230000003115 biocidal effect Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract 6
- 239000003205 fragrance Substances 0.000 abstract 3
- 238000005096 rolling process Methods 0.000 abstract 2
- 244000248349 Citrus limon Species 0.000 abstract 1
- 239000001116 FEMA 4028 Substances 0.000 abstract 1
- 235000006679 Mentha X verticillata Nutrition 0.000 abstract 1
- 235000002899 Mentha suaveolens Nutrition 0.000 abstract 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 abstract 1
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 abstract 1
- 235000011175 beta-cyclodextrine Nutrition 0.000 abstract 1
- 229960004853 betadex Drugs 0.000 abstract 1
- 239000011162 core material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 208000014770 Foot disease Diseases 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- 208000002474 Tinea Diseases 0.000 description 1
- 241000130764 Tinea Species 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 206010047601 Vitamin B1 deficiency Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 208000002894 beriberi Diseases 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 210000000106 sweat gland Anatomy 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Abstract
Provided is a preparation method for an antifungal and deodorized insole. The preparation method comprises the steps that firstly, essential oils of lemon fragrance, mint fragrance and orange fragrance are selected to serve as core materials, beta-cyclodextrin is selected as wall materials, fragrant microcapsules are prepared by using a wrapping method, and a preparation technology of the microcapsules is optimized; secondly, antibiotic finish is performed on a cotton fabric insole by utilizing organosilicon quaternary ammonium salt through a finishing technology with twice immersing and twice rolling at the temperature ranging from 110 DEG C to 120 DEG C; thirdly, the finished antibacterial cotton fabric insole is immersed in fragrant emulsion for two to three minutes, and through the mode of twice immersing and twice rolling, predrying is firstly performed on the cotton fabric, and then high-temperature drying is performed on the cotton fabric; finally, the antifungal and deodorized cotton fabric insole is obtained. The prepared cotton fabric insole can resist fungi and bacteria, and meanwhile has the different fragrant functions and the advantages of being good in antibacterial and deodorized effect.
Description
Technical field
The invention belongs to the preparing technical field of functional insole, particularly a kind of preparation method of antimycotic Antibromic shoe pads.
Background technology
Moisture content, salt is removed exceptionally, also containing lactic acid and urea in sweat.Because arch of the foot sweat gland is many, easily perspire, under hidrosis condition, the bacterium amount reproduction on pin also decomposes keratoprotein, adds the urea in sweat, lactic acid, will stink like this.If shoes are airtight, atmosphere draught-free, stink will be more long-pending denseer.It is smelly that fungi not only can cause pin to the decomposition of keratoprotein, also can cause foot's disease, as beriberi.
At present, keep foot dry exactly for dispelling the most basic way of footwear cavity foreign flavor, clean, or adhere to that every day steeps pin with some Chinese herbal medicines.In addition, most Antibromic shoe pads is mainly smelly for removal pin, does not have good effect to the suppression of foot fungi with killing.Some antibacterial insoles does not have aromatic function, and antibacterial effect neither be fine, and even some antibacterial shoe is paid somebody's debt and expected repayment later and can be played certain injury to skin.
Summary of the invention
In order to overcome the shortcoming of above-mentioned prior art, the object of the present invention is to provide a kind of preparation method of antimycotic Antibromic shoe pads, obtained bafta shoe-pad both can antimycotic and antibacterium, had again different aromatic functions simultaneously, had antibacterial and feature that is good deodorization effect.
In order to achieve the above object, the technical scheme that the present invention takes is:
A preparation method for antimycotic Antibromic shoe pads, its step is as follows:
Step one: take beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take volatile oil as core, the quality of volatile oil and beta-schardinger dextrin-is 1:7-1:10 than scope, dissolved in ethanol by volatile oil, the volume range of essential oil and ethanol is 1:6-1:10;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 40-50 DEG C, it is stirred, mixing speed is 700-900r/min, mixing time is 2.0-3.5h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 4-10 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 1.5-3.0ml crosslinking agent, the catalyst added and the volume ratio of crosslinking agent are 1:3-1:5, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 4%-6%, first bafta shoe-pad is soaked 2.0-3.0 minute in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%-80%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 110-120 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic is immersed in 2-3 minute in fragrant emulsion, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%-80%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 70-90 DEG C of temperature conditions, then bakes under the temperature conditions of 140-160 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
Described volatile oil is one or more in lemon, Peppermint essential oil, orange essence oil.
Because the present invention adopts organosilicon quaternary ammonium salt as antiseptic, organosilicon quaternary ammonium salt is a class Novel Cationic Surfactants, there is excellent antibacterial bacteriostatic performance, and to human body skin non-stimulated and carcinogenesis, indices all meets the requirement both at home and abroad to antibacterial fabric, it has high temperature resistant, water-fastness, lasting effect, and scope of restraining fungi is wide, can effectively suppress gram-positive bacteria, Gram-negative bacteria, saccharomycete and fungi, adopt cyclodextrin as wall material, beta-schardinger dextrin-is tubular structure, by means of Van der Waals force by drug molecule suitable for some size and shapes (as halogen, volatilization wet goods) be contained in circulus, Application comparison is many in the food industry, beta-schardinger dextrin-is with the space structure of its uniqueness, self just can carry out certain absorption to stink, volatile oil again by embedding in cyclodextrin, can effectively hide pin smelly, reach from two aspects simultaneously and alleviate the smelly effect of pin, the shoe-pad adopting preparation method of the present invention to prepare can play good inhibitory action to foot fungi, pin can be alleviated again smelly, there is certain medical value.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment one:
Step one: take 24.0g beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take 2.4g lemon as core, the mass ratio of lemon and beta-schardinger dextrin-is 1:10, dissolved in ethanol by lemon, the volume ratio of essential oil and ethanol is 1:10;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 50 DEG C, it is stirred, mixing speed is 900r/min, mixing time is 2.5h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 4 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is lemon beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the lemon beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 1.5ml crosslinking agent, namely 36.0ml crosslinking agent is added, the catalyst added and the volume ratio of crosslinking agent are 1:3, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 5%, first bafta shoe-pad is soaked 2.0 minutes in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 75%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 110 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic to be immersed in fragrant emulsion 3.0 minutes, with padding machine, bafta shoe-pad is arranged again, pick-up is 80%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 70 DEG C of temperature conditions, then bakes under the temperature conditions of 160 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
Lemon itself has good deodorizing and antibiotic effect, the antibiotic aromatic shoe-pad of the lemon flavor adopting embodiment one obtained, adopt organosilicon quaternary ammonium salt as antiseptic simultaneously, make prepared shoe-pad both have antibacterium function, also there is antimycotic function.
Embodiment two:
Step one: take 16.8g beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take 2.4g Peppermint essential oil as core, the mass ratio of Peppermint essential oil and beta-schardinger dextrin-is 1:7, Peppermint essential oil dissolved in ethanol, the volume ratio of essential oil and ethanol is 1:8;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 45 DEG C, it is stirred, mixing speed is 700r/min, mixing time is 3.5h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 7 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is Peppermint essential oil beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the Peppermint essential oil beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 2.5ml crosslinking agent, namely 42.0ml crosslinking agent is added, the catalyst added and the volume ratio of crosslinking agent are 1:3.5, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 4%, first bafta shoe-pad is soaked 3.0 minutes in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 120 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic to be immersed in fragrant emulsion 2.0 minutes, with padding machine, bafta shoe-pad is arranged again, pick-up is 75%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 90 DEG C of temperature conditions, then bakes under the temperature conditions of 150 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
The symptoms such as Peppermint essential oil can improve eczema, tinea, skin of releiving is itched, can play certain health-care effect for foot health.
Embodiment three:
Step one: take 19.6g beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take 2.4g tangerine essential oil as core, the mass ratio of tangerine essential oil and beta-schardinger dextrin-is 6:49, dissolved in ethanol by tangerine essential oil, the volume ratio of essential oil and ethanol is 1:6;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 40 DEG C, it is stirred, mixing speed is 800r/min, mixing time is 2.0h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 10 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is tangerine essential oil beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the tangerine essential oil beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 3.0ml crosslinking agent, namely 58.8ml crosslinking agent is added, the catalyst added and the volume ratio of crosslinking agent are 1:4.5, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 6%, first bafta shoe-pad is soaked 2.5 minutes in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 80%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 115 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic to be immersed in fragrant emulsion 2.5 minutes, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 80 DEG C of temperature conditions, then bakes under the temperature conditions of 140 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
Orange essence oil is applicable to the anti-inflammatory of skin, has strong antibiotic effect, and can prevent to infect.Be applied to by orange essence oil in bafta footwear material, can prevent well and alleviate foot's disease, shoe-pad obtained after arranging is a kind of well antibiotic aromatic shoe-pad.
Claims (5)
1. a preparation method for antimycotic Antibromic shoe pads, is characterized in that, step is as follows:
Step one: take beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take volatile oil as core, the quality of volatile oil and beta-schardinger dextrin-is 1:7-1:10 than scope, dissolved in ethanol by volatile oil, the volume range of essential oil and ethanol is 1:6-1:10;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 40-50 DEG C, it is stirred, mixing speed is 700-900r/min, mixing time is 2.0-3.5h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 4-10 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 1.5-3.0ml crosslinking agent, the catalyst added and the volume ratio of crosslinking agent are 1:3-1:5, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 4%-6%, first bafta shoe-pad is soaked 2.0-3.0 minute in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%-80%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 110-120 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic is immersed in 2-3 minute in fragrant emulsion, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%-80%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 70-90 DEG C of temperature conditions, then bakes under the temperature conditions of 140-160 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
2. the preparation method of a kind of antimycotic Antibromic shoe pads according to claim 1, is characterized in that, described volatile oil is one or more in lemon, Peppermint essential oil, orange essence oil.
3. the preparation method of a kind of antimycotic Antibromic shoe pads according to claim 1 and 2, it is characterized in that, step is as follows:
Step one: take 24.0g beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take 2.4g lemon as core, the mass ratio of lemon and beta-schardinger dextrin-is 1:10, dissolved in ethanol by lemon, the volume ratio of essential oil and ethanol is 1:10;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 50 DEG C, it is stirred, mixing speed is 900r/min, mixing time is 2.5h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 4 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is lemon beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the lemon beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 1.5ml crosslinking agent, namely 36.0ml crosslinking agent is added, the catalyst added and the volume ratio of crosslinking agent are 1:3, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 5%, first bafta shoe-pad is soaked 2.0 minutes in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 75%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 110 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic to be immersed in fragrant emulsion 3.0 minutes, with padding machine, bafta shoe-pad is arranged again, pick-up is 80%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 70 DEG C of temperature conditions, then bakes under the temperature conditions of 160 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
4. the preparation method of a kind of antimycotic Antibromic shoe pads according to claim 1 and 2, it is characterized in that, step is as follows:
Step one: take 16.8g beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take 2.4g Peppermint essential oil as core, the mass ratio of Peppermint essential oil and beta-schardinger dextrin-is 1:7, Peppermint essential oil dissolved in ethanol, the volume ratio of essential oil and ethanol is 1:8;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 45 DEG C, it is stirred, mixing speed is 700r/min, mixing time is 3.5h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 7 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is Peppermint essential oil beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the Peppermint essential oil beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 2.5ml crosslinking agent, namely 42.0ml crosslinking agent is added, the catalyst added and the volume ratio of crosslinking agent are 1:3.5, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 4%, first bafta shoe-pad is soaked 3.0 minutes in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 120 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic to be immersed in fragrant emulsion 2.0 minutes, with padding machine, bafta shoe-pad is arranged again, pick-up is 75%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 90 DEG C of temperature conditions, then bakes under the temperature conditions of 150 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
5. the preparation method of a kind of antimycotic Antibromic shoe pads according to claim 1 and 2, it is characterized in that, step is as follows:
Step one: take 19.6g beta-schardinger dextrin-at ambient temperature as wall material, be prepared into saturated cyclodextrin aqueous solution, solution concentration is 48g/L, take 2.4g tangerine essential oil as core, the mass ratio of tangerine essential oil and beta-schardinger dextrin-is 6:49, dissolved in ethanol by tangerine essential oil, the volume ratio of essential oil and ethanol is 1:6;
Step 2: the volatile oil solution dissolved is poured in saturated cyclodextrin aqueous solution lentamente and is prepared into microcapsule emulsion, at the temperature of 40 DEG C, it is stirred, mixing speed is 800r/min, mixing time is 2.0h, the microcapsule emulsion prepared is left standstill 24.0h in the refrigerator of 10 DEG C, carry out freeze drying after vacuum filtration, the white powdery solids obtained is tangerine essential oil beta-schardinger dextrin-aromatic micro-capsule;
Step 3: the tangerine essential oil beta-schardinger dextrin-aromatic micro-capsule prepared is dissolved in water and makes cyclodextrin emulsion, concentration is 60g/L, be glutaraldehyde and the concentration of 30g/L again using concentration be that 25g/L magnesium chloride hexahydrate joins in cyclodextrin emulsion as crosslinking agent and catalyst, each gram of wall material adds 3.0ml crosslinking agent, namely 58.8ml crosslinking agent is added, the catalyst added and the volume ratio of crosslinking agent are 1:4.5, obtained fragrant emulsion;
Step 4: silicone Quaternary Ammonium Salt Antimicrobial Agent is mixed with the antiseptic solution that volume fraction is 6%, first bafta shoe-pad is soaked 2.5 minutes in the antimicrobial solution, with padding machine, bafta shoe-pad is arranged again, pick-up is 80%, after repeating above padding operation, bafta shoe-pad is put into baking oven heat, heating-up temperature is 115 DEG C, and the heat time is 3.0 minutes;
Step 5: bafta shoe-pad step 4 being put in order antiseptic to be immersed in fragrant emulsion 2.5 minutes, with padding machine, bafta shoe-pad is arranged again, pick-up is 70%, after repeating above padding operation, bafta shoe-pad is first carried out preliminary drying, preliminary drying time 2.5 minutes under 80 DEG C of temperature conditions, then bakes under the temperature conditions of 140 DEG C, bake 5.0 minutes time, finally obtain the bafta shoe-pad of antibacterial and deodouring.
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Effective date of registration: 20240316 Address after: Building 709-3, China Railway Financial Intelligence Center, No. 59 Gongye South Road, High tech Zone, Jinan City, Shandong Province, 250000 Patentee after: Jinan Mr. Foot Clothing Co.,Ltd. Country or region after: China Address before: 710021 Shaanxi province Xi'an Weiyang university campus of Shaanxi University of Science and Technology Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY Country or region before: China |