CN104911572B - A kind of electrician's copper soft whipping wire antirust agent - Google Patents
A kind of electrician's copper soft whipping wire antirust agent Download PDFInfo
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- CN104911572B CN104911572B CN201510206879.XA CN201510206879A CN104911572B CN 104911572 B CN104911572 B CN 104911572B CN 201510206879 A CN201510206879 A CN 201510206879A CN 104911572 B CN104911572 B CN 104911572B
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Abstract
The present invention provides a kind of electrician's copper soft whipping wire antirust agent, and the antirust agent includes the chemical composition of following percentage by weight：Anti-incrustation corrosion inhibitor：15 ~ 30%, benzotriazole：12 ~ 20%, sodium molybdate：1 ~ 5%, zinc salt：2 ~ 6%, monoethanolamine：15 ~ 30%, ethanol：5 ~ 10%, dodecenylsuccinic acid：4 ~ 8%, inositol hexaphosphate：3 ~ 6%, sodium citrate：0.5 ~ 2%, remaining is water.The antirust agent is nontoxic, environmentally friendly; after copper wire annealing cooling, one layer of uniform, densification can be produced on copper wire surface and is difficult to the protective film to come off so that copper wire has good Anti- tarnishing ability, oxidation resistance; the effectively pot-life of lifting copper wire and service life, reduce production cost.
Description
Technical field
The invention belongs to electrical equipment, electronic component connection line to protect field, and in particular, to a kind of ultra-fine electrician's copper
Litzendraht wire antioxidant.
Background technology
In the industry of intermetallic composite coating now, the share that the market of copper material processing is occupied is increasing, particularly in electricity
The industries such as plating, spraying, cable, wiring board, CNC, mould, punching press hardware, powder metallurgy, the proportion occupied become in what is risen year by year
Gesture.
Industry goes from strength to strength, and the quality requirements of product are also constantly improved, but during Copper fabrication, copper and
Copper alloy after processing is cleaned, the problem of aoxidizing an always disadvantage in the industry, particularly for electrical equipment, electricity
Copper wire, copper litz wire and the electrician's copper soft whipping wire of subcomponent connection, after copper wire is made, surface easily aoxidizes, and aoxidizes
Situation it is extremely widespread, often there is oxidation stain in a few houres after cleaning, drying, verdigris can be generated under normal temperature oxidation, both alkali formula
Copper carbonate, for green；Or cuprous oxide may be oxidized to, it is brick-red, oxidizing slag is played after a few days.Copper material is originally somewhat expensive
The metal of weight, plus present expensive processing cost and labour cost, allows the producer of many to look at the product that a pile aoxidizes and worries,
How handling the product delivery of oxidation must solve the problems, such as into many producers are anxious.
The content of the invention
Above-mentioned to solve the problems, such as, it is an object of the invention to provide a kind of electrician's copper soft whipping wire antirust agent, nothing
It is malicious, environmentally friendly, after copper wire annealing cooling, one layer of uniform, densification can be produced on copper wire surface and is difficult to the protective film to come off so that
Copper wire has good Anti- tarnishing ability, oxidation resistance, effectively lifts pot-life and the service life of copper wire, reduces production
Cost.
To reach above-mentioned purpose, the technical scheme is that：
A kind of electrician's copper soft whipping wire antirust agent, the antirust agent include the chemical composition of following percentage by weight：Scale inhibition
Corrosion inhibiter：15 ~ 30%, benzotriazole：12 ~ 20%, sodium molybdate：1 ~ 5%, zinc salt：2 ~ 6%, monoethanolamine：15 ~ 30%, ethanol：5~
10%, dodecenylsuccinic acid：4 ~ 8%, inositol hexaphosphate：3 ~ 6%, sodium citrate：0.5 ~ 2%, remaining is water.
Preferably, the antirust agent includes the chemical composition of following percentage by weight：Anti-incrustation corrosion inhibitor：20 ~ 25%, benzo
Triazole：15 ~ 18%, sodium molybdate：2 ~ 3%, zinc salt：4 ~ 5%, monoethanolamine：25 ~ 28%, ethanol：7 ~ 9%, dodecenylsuccinic acid：6~
8%, inositol hexaphosphate：5 ~ 6%, sodium citrate：1 ~ 1.6%, remaining is water.
Further, the antirust agent includes the chemical composition of following percentage by weight：Anti-incrustation corrosion inhibitor：20%, three nitrogen of benzo
Azoles：15%, sodium molybdate：2.5%, zinc salt：5%, monoethanolamine：25%, ethanol：8%, dodecenylsuccinic acid：7%, inositol hexaphosphate：
5%, sodium citrate：1.5%, remaining is water.
In addition, the zinc salt is ZnSO4Or ZnCl2。
Separately have, the anti-incrustation corrosion inhibitor is selected from 1-hydroxy ethylidene-1,1-diphosphonic acid, poly-epoxy succinic acid, poly-aspartate, ethylenediamine
One or more in four methene Alendronates.
Again, electrician's copper soft whipping wire is formed by the stranded copper wire braiding of a diameter of 0.03 ~ 0.05mm.
The beneficial effects of the present invention are：
Anti-incrustation corrosion inhibitor can form stable complex compound with copper ion, can dissolve the oxide of metal surface.Copper wire and institute
State antirust agent and generate insoluble and fine and close sull, thus prevent the anodic solution of copper wire, promote the passivation of copper wire, from
And suppress the rust corrosion of copper wire.Copper line surface can generate the salt of indissoluble with antioxidant, so that copper wire and corrosive medium
Isolation, from corrosion.Benzotriazole can generate chelate Cu (C with copper wire6H4N3)2, protect the surface of copper wire not oxidized.
Embodiment
Following embodiments are used to illustrate the present invention, but cannot be used for limiting the scope of the invention.The reality used in embodiment
The condition of applying can be for further adjustments according to the condition of producer, and unaccounted implementation condition is usually conventional laboratory conditions.
A kind of electrician's copper soft whipping wire antirust agent provided by the present invention, the antirust agent include following percentage by weight
Chemical composition：Anti-incrustation corrosion inhibitor：15 ~ 30%, benzotriazole：12 ~ 20%, sodium molybdate：1 ~ 5%, zinc salt：2 ~ 6%, monoethanolamine：15~
30%, ethanol：5 ~ 10%, dodecenylsuccinic acid：4 ~ 8%, inositol hexaphosphate：3 ~ 6%, sodium citrate：0.5 ~ 2%, remaining is
Water.
Preferably, the antirust agent includes the chemical composition of following percentage by weight：Anti-incrustation corrosion inhibitor：20 ~ 25%, benzo
Triazole：15 ~ 18%, sodium molybdate：2 ~ 3%, zinc salt：4 ~ 5%, monoethanolamine：25 ~ 28%, ethanol：7 ~ 9%, dodecenylsuccinic acid：6~
8%, inositol hexaphosphate：5 ~ 6%, sodium citrate：1 ~ 1.6%, remaining is water.
Further, the antirust agent includes the chemical composition of following percentage by weight：Anti-incrustation corrosion inhibitor：20%, three nitrogen of benzo
Azoles：15%, sodium molybdate：2.5%, zinc salt：5%, monoethanolamine：25%, ethanol：8%, dodecenylsuccinic acid：7%, inositol hexaphosphate：
5%, sodium citrate：1.5%, remaining is water.
In addition, the zinc salt is ZnSO4Or ZnCl2。
Separately have, the anti-incrustation corrosion inhibitor is selected from 1-hydroxy ethylidene-1,1-diphosphonic acid, poly-epoxy succinic acid, poly-aspartate, ethylenediamine
One or more in four methene Alendronates.
Again, electrician's copper soft whipping wire is formed by the stranded copper wire braiding of a diameter of 0.03 ~ 0.05mm.
Embodiment 1
Take 20wt% 1-hydroxy ethylidene-1,1-diphosphonic acids, 15wt% benzotriazole, 2.5wt% sodium molybdates, 5wt% ZnCl2, 25wt% second
Hydramine, 8wt% ethanol, 7wt% dodecenylsuccinic acids, 5wt% inositol hexaphosphates, 1.5wt% sodium citrates, remaining is water.
Embodiment 2
Take 30wt% ethylene diamine tetra methylene phosphonic acid sodium, 12wt% benzotriazole, 1wt% sodium molybdates, 2wt% ZnSO4, 15wt%
Monoethanolamine, 6wt% ethanol, 4wt% dodecenylsuccinic acids, 6wt% inositol hexaphosphates, 2wt% sodium citrates, remaining is water.
Embodiment 3
Take 20wt% poly-epoxy succinic acids, 15wt% benzotriazole, 4wt% sodium molybdates, 4wt% ZnSO4, 20wt% ethanol
Amine, 5wt% ethanol, 8wt% dodecenylsuccinic acids, 5wt% inositol hexaphosphates, 1wt% sodium citrates, remaining is water.
Embodiment 4
Take 25wt% poly-epoxy succinic acids, 13wt% benzotriazole, 2wt% sodium molybdates, 6wt% ZnCl2, 20wt% ethanol
Amine, 7wt% ethanol, 4wt% dodecenylsuccinic acids, 3wt% inositol hexaphosphates, 0.5wt% sodium citrates, remaining is water.
Embodiment 5
Take the mixture of 17wt% 1-hydroxy ethylene-1,1-diphosphonics and poly-epoxy succinic acid, 12wt% benzotriazole, 5wt% sodium molybdates,
6wt% ZnCl2, 30wt% monoethanolamines, 5wt% ethanol, 8wt% dodecenylsuccinic acids, 3wt% inositol hexaphosphates, 0.5wt% lemons
Lemon acid sodium, remaining is water.
Embodiment 6
Take 30wt% poly-aspartates, 18wt% benzotriazole, 3wt% sodium molybdates, 4wt% ZnSO4, 16wt% monoethanolamines,
5wt% ethanol, 8wt% dodecenylsuccinic acids, 3wt% inositol hexaphosphates, 0.5wt% sodium citrates, remaining is water.
Embodiment 7
Take the mixture of 15wt% poly-aspartates and ethylene diamine tetra methylene phosphonic acid sodium, 15wt% benzotriazole, 5wt% molybdenums
Sour sodium, 6wt% ZnCl2, 30wt% monoethanolamines, 5wt% ethanol, 8wt% dodecenylsuccinic acids, 3wt% inositol hexaphosphates,
0.5wt% sodium citrates, remaining is water.
Embodiment 8
Take 18wt% 1-hydroxy ethylidene-1,1-diphosphonic acid things, 17wt% benzotriazole, 1wt% sodium molybdates, 4wt% ZnSO4, 20wt% second
Hydramine, 6wt% ethanol, 6wt% dodecenylsuccinic acids, 5wt% inositol hexaphosphates, 1wt% sodium citrates, remaining is water.
The preparation method of electrician's copper soft whipping wire antirust agent is as follows：
Mixing of weighing is carried out according to percentage by weight described in embodiment 1 ~ 8 respectively, is put into reactor, stirs 10 ~ 30 points
Clock, you can obtain ultra-fine electrician's copper litz wire antioxidant.
Application method of the electrician's copper soft whipping wire antirust agent provided by the present invention in copper wire annealing technique is as follows：
It will be sent into by the copper wire of a diameter of 0.03 ~ 0.05mm after constant speed wheel constant speed in baking oven, interior 400 DEG C of the use of baking oven-
500 DEG C of vapor baking copper wire, the copper wire after baking enter in water tank, and electrician's copper soft whipping wire antirust agent is added in water tank
（Use ratio：1:800 times are watered use）, you can realize the anti-oxidant treatment to the copper wire, 5 ~ 60s of processing time, temperature
25 ~ 50 DEG C, electrician's copper soft whipping wire is can obtain after the copper wire that is disposed is superimposed.
The copper soft whipping wire that copper wire after being handled using antirust agent provided by the present invention is formed, preservation time averagely can reach
3 years.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, can be to the technology of invention
Scheme technical scheme is modified or replaced equivalently, without departing from the scope of technical solution of the present invention, it should all cover the power in the present invention
In sharp claimed range.
Claims (5)
1. a kind of electrician's copper soft whipping wire antirust agent, it is characterised in that the antirust agent includes the chemistry of following percentage by weight
Component：Anti-incrustation corrosion inhibitor：15 ~ 30%, benzotriazole：12 ~ 20%, sodium molybdate：1 ~ 5%, zinc salt：2 ~ 6%, monoethanolamine：15 ~ 30%,
Ethanol：5 ~ 10%, dodecenylsuccinic acid：4 ~ 8%, inositol hexaphosphate：3 ~ 6%, sodium citrate：0.5 ~ 2%, remaining is water；
Electrician's copper soft whipping wire is formed by the stranded copper wire braiding of a diameter of 0.03 ~ 0.05mm.
2. electrician's copper soft whipping wire antirust agent according to claim 1, it is characterised in that the antirust agent includes following weight
Measure the chemical composition of percentage：Anti-incrustation corrosion inhibitor：20 ~ 25%, benzotriazole：15 ~ 18%, sodium molybdate：2 ~ 3%, zinc salt：4 ~ 5%,
Monoethanolamine：25 ~ 28%, ethanol：7 ~ 9%, dodecenylsuccinic acid：6 ~ 8%, inositol hexaphosphate：5 ~ 6%, sodium citrate：1~
1.6%, remaining is water.
3. electrician's copper soft whipping wire antirust agent according to claim 1, it is characterised in that the antirust agent includes following weight
Measure the chemical composition of percentage：Anti-incrustation corrosion inhibitor：20%, benzotriazole：15%, sodium molybdate：2.5%, zinc salt：5%, monoethanolamine：
25%, ethanol：8%, dodecenylsuccinic acid：7%, inositol hexaphosphate：5%, sodium citrate：1.5%, remaining is water.
4. electrician's copper soft whipping wire antirust agent according to claim 1 or 2 or 3, it is characterised in that the zinc salt is ZnSO4
Or ZnCl2。
5. electrician's copper soft whipping wire antirust agent according to claim 1 or 2 or 3, it is characterised in that the anti-incrustation corrosion inhibitor
One kind in 1-hydroxy ethylidene-1,1-diphosphonic acid, poly-epoxy succinic acid, poly-aspartate, ethylene diamine tetra methylene phosphonic acid sodium or it is a kind of with
On.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510206879.XA CN104911572B (en) | 2015-04-28 | 2015-04-28 | A kind of electrician's copper soft whipping wire antirust agent |
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| CN201510206879.XA CN104911572B (en) | 2015-04-28 | 2015-04-28 | A kind of electrician's copper soft whipping wire antirust agent |
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| CN104911572A CN104911572A (en) | 2015-09-16 |
| CN104911572B true CN104911572B (en) | 2018-05-01 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108624233A (en) * | 2018-06-04 | 2018-10-09 | 合肥汇之新机械科技有限公司 | A kind of special antirust agent of mechanical equipment and preparation method thereof |
| CN114438479B (en) * | 2022-03-03 | 2023-09-26 | 无锡市明星精密线材有限公司 | High-strength heat-resistant copper wire and processing technology thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102797004A (en) * | 2012-08-23 | 2012-11-28 | 李征 | Environmentally-friendly non-ferrous metal surface treating agent and preparation method thereof |
| CN103668257A (en) * | 2013-12-10 | 2014-03-26 | 大连创达技术交易市场有限公司 | Metal surface treatment method |
| CN104213126A (en) * | 2014-09-25 | 2014-12-17 | 无锡康柏斯机械科技有限公司 | Metal surface rust inhibitor and preparation method thereof |
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2015
- 2015-04-28 CN CN201510206879.XA patent/CN104911572B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102797004A (en) * | 2012-08-23 | 2012-11-28 | 李征 | Environmentally-friendly non-ferrous metal surface treating agent and preparation method thereof |
| CN103668257A (en) * | 2013-12-10 | 2014-03-26 | 大连创达技术交易市场有限公司 | Metal surface treatment method |
| CN104213126A (en) * | 2014-09-25 | 2014-12-17 | 无锡康柏斯机械科技有限公司 | Metal surface rust inhibitor and preparation method thereof |
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