CN104893623A - Paper tube adhesive and production method thereof - Google Patents
Paper tube adhesive and production method thereof Download PDFInfo
- Publication number
- CN104893623A CN104893623A CN201510369904.6A CN201510369904A CN104893623A CN 104893623 A CN104893623 A CN 104893623A CN 201510369904 A CN201510369904 A CN 201510369904A CN 104893623 A CN104893623 A CN 104893623A
- Authority
- CN
- China
- Prior art keywords
- add
- parts
- paper tube
- mangrove bark
- production method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 30
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 35
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 21
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 8
- 235000004936 Bromus mango Nutrition 0.000 claims abstract description 4
- 240000007228 Mangifera indica Species 0.000 claims abstract description 4
- 235000014826 Mangifera indica Nutrition 0.000 claims abstract description 4
- 235000009184 Spondias indica Nutrition 0.000 claims abstract description 4
- 240000002044 Rhizophora apiculata Species 0.000 claims description 27
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 20
- 239000004159 Potassium persulphate Substances 0.000 claims description 19
- 235000019394 potassium persulphate Nutrition 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 238000004880 explosion Methods 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 10
- 239000007858 starting material Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 239000008213 purified water Substances 0.000 claims description 5
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 40
- 239000003292 glue Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- 241000237502 Ostreidae Species 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 235000020636 oyster Nutrition 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical group [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a paper tube adhesive and a production method thereof. The paper tube adhesive is made by, by weight, 32-38 parts of vinyl acetate and 8-10 parts of mango peel, 7-9 parts of poval, 2-3 parts of glycol, 0.5-1.5 parts of polyacrylamide, 0.5-1.5 parts of dibutyl phthalate, 0.5-1.5 parts of emulsifier, 0.5 part of potassium persulfate and 110-130 parts of pure water. The paper tube adhesive produced by the method is high in initial adhesiveness, short in initial adhesive time, high in adhesive strength, high in fluidity and storage stability and free of adhesive warping.
Description
Technical field
The invention belongs to tamanori technical field, be specifically related to paper tube adhesive and production method thereof.
Background technology
Paper tube (paper tuber) sticks with glue agent and is commonly called as paper tube adhesive, paper web glue etc., is a kind of special-purpose adhesive making various paper tube, fiber drum, paper can and relevant paper product.The deformable sheet materials such as paper, cloth, plastic film, tinsel, conventional paper web (paper tube) reels bundled, makes paper tube core web-like finished product.These paper webs are generally roll with kraft paper or other raw material paper machinery, be bonded, and tamanori used is called paper web glue.
Along with the fast development of China's economy, paper tube is increasing in the requirement in daily necessities, weaving, light industry, packaging, leather etc. field.As reel package paper tubes such as toiler roll inner core paper web, weaving spool, cloth, paper product, leather, plastics film etc.Paper tube (cylinder) glue that tradition is commonly used mainly contains gelatin, pasted starch (comprising Sumstar 190 and treated starch), polyvinyl formal liquid (107) tackiness agent, polyvinyl acetate emulsion (white glue with vinyl), PVA solution etc.Wherein gelatin, starch adhesive because bonding strength is low, staging life shortly do not use substantially; The maximum shortcoming of polyvinyl alcohol adhesive is exactly poor water resistance, and paper tube compressive strength increases with the shelf-time and significantly declines, and improves, but still can not meet the demands although can obtain part after acetalation; The water tolerance of polyvinyl acetate emulsion is all better than front several tackiness agent, but the compressive strength of low, the bonding rear paper tube of initial bonding strength and creep resistance difference are its main drawbacks.The paper tube adhesive of development of new meets the demand in market.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of initial bonding strength good, just the sticky time is short, and bonding strength is high, mobility and excellent storage stability, bonds without the paper tube adhesive of the premium propertiess such as warpage, the invention still further relates to the production method of this paper tube adhesive.
The production method of paper tube adhesive of the present invention, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight part: vinyl-acetic ester 32-38 part, mangrove bark 8-10 part, polyvinyl alcohol 7-9 part, ethylene glycol 2-3 part, polyacrylamide 0.5-1.5 part, dibutyl phthalate 0.5-1.5 part, emulsifying agent 0.5-1.5 part, Potassium Persulphate 0.5 part, pure water 110-130 part;
2) to the process of mangrove bark:
1. autoclaving: by mangrove bark chopping or after pulverizing, put into pressure pan, be forced into 20-30MPa, make its pressure uniform, and keep 10-20min, recover normal pressure;
2. steam explosion: steam explosion tank put into by material step 1. obtained, burstpressures 3.0-3.5Mpa, the dwell time maintains 150-200s;
3. decoct, decolour: material step 1. obtained the heavy pure water such as to add and decocts 2 times, each 1 hour, obtains extracting solution, filters, united extraction liquid, filtrate is concentrated into the medicinal extract that relative density is 1.30 (surveying when 70 DEG C); Add activated carbon decolorizing in medicinal extract, filter;
3) add a small amount of water in retort, be warming up to 60 DEG C, stir 0.5h, then add polyvinyl alcohol, polyacrylamide, emulsifying agent and purified water remainder;
4) continue to be warming up to 90-95 DEG C, keep until polyvinyl alcohol all dissolves;
5) be cooled to 69-71 DEG C, filter, add 3/4 Potassium Persulphate, and slowly drip vinyl-acetic ester;
6) temperature 69-71 DEG C is kept, reaction 6-7h;
7) temperature is risen to 85-90 DEG C, add remaining 1/4 Potassium Persulphate, reaction 0.5-1h;
8) be cooled to 75 DEG C, add step 2) the mangrove bark filtrate that obtains, reaction 1-2h;
9) be cooled to 55 DEG C, add dibutyl phthalate and ethylene glycol, stir 0.5h, be cooled to room temperature, filtration, discharging.
Step 1 of the present invention) described in get the raw materials ready, the starting material of preferred following weight part: vinyl-acetic ester 35 parts, mangrove bark 10 parts, polyvinyl alcohol 8 parts, ethylene glycol 2.5 parts, polyacrylamide 1 part, dibutyl phthalate 1 part, emulsifying agent 1 part, Potassium Persulphate 0.5 part, pure water 120 parts; The preferred fresh mango skin of described mangrove bark.
Step 2) described in the preferred 3-5% of activated carbon dosage (w/v).
Step 5) described in add Potassium Persulphate, preferably a small amount of repeatedly, described slow dropping vinyl-acetic ester, preferably at least drips 1h.
The invention still further relates to the paper tube adhesive adopting aforementioned production method to obtain, is the even thickness glue of oyster white.
Compared to existing technology, the invention has the advantages that:
1, the paper tube adhesive that the present invention obtains is the product of the novel high-performance be made up of high molecular polymer, has initial bonding strength good, and just the sticky time is short, and bonding strength is high, mobility and excellent storage stability, and bonding is without premium propertiess such as warpages.Currently available products is generally 3-4 month storage period, product chambers of the present invention is gentle put more than 6 months not stratified, never degenerate.
2, the present invention does not use the material such as W-Gum and thickening material, but adds the performance that mangrove bark improves product.The fiber of mangrove bark have good thickening effectiveness, but the fiber in mangrove bark vegetable cell is bondd by lignin, not easy fracture, product can be caused to lump, precipitation, the present invention adopts steam explosion, under high temperature, high pressure steam effect, cellulose crystallity improves, and the polymerization degree declines, and hemicellulose fraction is degraded, lignin softens, horizontal strength of connection declines, even softening plastic, when being full of the material sudden pressure reduction of pressure steam, gas play in hole is expanded, produce " explosion " effect, partly can peel off lignin, and raw material is torn as fiber fines.By such process, the Mierocrystalline cellulose in mangrove bark can be utilized well.Add plant constituent in product, meet environmental protection, natural theory.
3, the paper tube adhesive that the present invention obtains is applicable to various high, medium and low all kinds of paper tube machinery production and application, also can be used for fiber drum and produces, replace the paper tube such as white glue with vinyl, polyvinyl alcohol bonding glue.The paper tube intensity made is high, stiffness good, not embrittlement, and the paper tube using the present invention adhesion-molded increases by 35%, more than 45% than prior art respectively in hardness, intensity.Meanwhile, glued membrane moisture resistivity is good, improves more than 35% compared to existing technology, can meet the requirement of various paper tube moisture resistivity completely.Can not only significantly improve hardness and the intensity of paper tube, can greatly reduce costs again, be a kind of novel low-cost, the high-performance paper tube adhesive that replace traditional paper tube adhesive.
Embodiment
With embodiment, the invention will be further described below, but the present invention is not limited to these embodiments.
Embodiment 1:
The production method of paper tube adhesive, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight part: vinyl-acetic ester 32 parts, dry mangrove bark 10 parts, polyvinyl alcohol 7 parts, ethylene glycol 3 parts, polyacrylamide 0.5 part, dibutyl phthalate 1.5 parts, emulsifying agent 0.5 part, Potassium Persulphate 0.5 part, pure water 130 parts;
2) to the process of mangrove bark:
1. autoclaving: by mangrove bark chopping or after pulverizing, put into pressure pan, be forced into 30MPa, make its pressure uniform, and keep 10min, recover normal pressure;
2. steam explosion: steam explosion tank put into by material step 1. obtained, burstpressures 3.5Mpa, the dwell time maintains 200s;
3. decoct, decolour: material step 1. obtained the heavy pure water such as to add and decocts 2 times, each 1 hour, obtains extracting solution, filters, united extraction liquid, filtrate is concentrated into the medicinal extract that relative density is 1.30 (surveying when 70 DEG C); Add activated carbon decolorizing in medicinal extract, filter;
3) add a small amount of water in retort, be warming up to 60 DEG C, stir 0.5h, then add polyvinyl alcohol, polyacrylamide, emulsifying agent and purified water remainder;
4) continue to be warming up to 95 DEG C, keep until polyvinyl alcohol all dissolves;
5) be cooled to 69 DEG C, filter, add 3/4 Potassium Persulphate, on a small quantity repeatedly, and slowly drip vinyl-acetic ester, at least drip 1h;
6) temperature 71 DEG C is kept, reaction 7h;
7) temperature is risen to 85 DEG C, add remaining 1/4 Potassium Persulphate, reaction 1h;
8) be cooled to 75 DEG C, add step 2) the mangrove bark filtrate that obtains, reaction 1h;
9) be cooled to 55 DEG C, add dibutyl phthalate and ethylene glycol, stir 0.5h, be cooled to room temperature, filtration, discharging.
Embodiment 2:
The production method of paper tube adhesive, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight part: vinyl-acetic ester 38 parts, mangrove bark 8 parts, polyvinyl alcohol 9 parts, ethylene glycol 2 parts, polyacrylamide 1.5 parts, dibutyl phthalate 0.5 part, emulsifying agent 1.5 parts, Potassium Persulphate 0.5 part, pure water 110 parts;
2) to the process of mangrove bark:
1. autoclaving: by mangrove bark chopping or after pulverizing, put into pressure pan, be forced into 30MPa, make its pressure uniform, and keep 15min, recover normal pressure;
2. steam explosion: steam explosion tank put into by material step 1. obtained, burstpressures 3.0Mpa, the dwell time maintains 180s;
3. decoct, decolour: material step 1. obtained the heavy pure water such as to add and decocts 2 times, each 1 hour, obtains extracting solution, filters, united extraction liquid, filtrate is concentrated into the medicinal extract that relative density is 1.30 (surveying when 70 DEG C); Add activated carbon decolorizing in medicinal extract, filter;
3) add a small amount of water in retort, be warming up to 60 DEG C, stir 0.5h, then add polyvinyl alcohol, polyacrylamide, emulsifying agent and purified water remainder;
4) continue to be warming up to 90 DEG C, keep until polyvinyl alcohol all dissolves;
5) be cooled to 71 DEG C, filter, add 3/4 Potassium Persulphate, on a small quantity repeatedly, and slowly drip vinyl-acetic ester, at least drip 1h;
6) temperature 69 DEG C is kept, reaction 6h;
7) temperature is risen to 90 DEG C, add remaining 1/4 Potassium Persulphate, reaction 0.5h;
8) be cooled to 75 DEG C, add step 2) the mangrove bark filtrate that obtains, reaction 2h;
9) be cooled to 55 DEG C, add dibutyl phthalate and ethylene glycol, stir 0.5h, be cooled to room temperature, filtration, discharging.
Embodiment 3:
The production method of paper tube adhesive, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight part: vinyl-acetic ester 35 parts, fresh mango skin 10 parts, polyvinyl alcohol 8 parts, ethylene glycol 2.5 parts, polyacrylamide 1 part, dibutyl phthalate 1 part, emulsifying agent 1 part, Potassium Persulphate 0.5 part, pure water 120 parts;
2) to the process of mangrove bark:
1. autoclaving: by mangrove bark chopping or after pulverizing, put into pressure pan, be forced into 25MPa, make its pressure uniform, and keep 20min, recover normal pressure;
2. steam explosion: steam explosion tank put into by material step 1. obtained, burstpressures 3.5Mpa, the dwell time maintains 150s;
3. decoct, decolour: material step 1. obtained the heavy pure water such as to add and decocts 2 times, each 1 hour, obtains extracting solution, filters, united extraction liquid, filtrate is concentrated into the medicinal extract that relative density is 1.30 (surveying when 70 DEG C); Add activated carbon decolorizing in medicinal extract, filter;
3) add a small amount of water in retort, be warming up to 60 DEG C, stir 0.5h, then add polyvinyl alcohol, polyacrylamide, emulsifying agent and purified water remainder;
4) continue to be warming up to 92 DEG C, keep until polyvinyl alcohol all dissolves;
5) be cooled to 70 DEG C, filter, add 3/4 Potassium Persulphate, on a small quantity repeatedly, and slowly drip vinyl-acetic ester, at least drip 1h;
6) temperature 70 C is kept, reaction 7h;
7) temperature is risen to 88 DEG C, add remaining 1/4 Potassium Persulphate, reaction 1h;
8) be cooled to 75 DEG C, add step 2) the mangrove bark filtrate that obtains, reaction 1h;
9) be cooled to 55 DEG C, add dibutyl phthalate and ethylene glycol, stir 0.5h, be cooled to room temperature, filtration, discharging.
Step 1 of the present invention) described in get the raw materials ready, the starting material of preferred following weight part:.
Result: quality standard:
(1) outward appearance: the even thickness glue of oyster white
(2) quality index meets following table requirement:
Claims (5)
1. the production method of paper tube adhesive, is characterized in that, comprises the steps:
1) get the raw materials ready: the starting material preparing following weight part: vinyl-acetic ester 32-38 part, mangrove bark 8-10 part, polyvinyl alcohol 7-9 part, ethylene glycol 2-3 part, polyacrylamide 0.5-1.5 part, dibutyl phthalate 0.5-1.5 part, emulsifying agent 0.5-1.5 part, Potassium Persulphate 0.5 part, pure water 110-130 part;
2) to the process of mangrove bark:
1. autoclaving: by mangrove bark chopping or after pulverizing, put into pressure pan, be forced into 20-30MPa, make its pressure uniform, and keep 10-20min, recover normal pressure;
2. steam explosion: steam explosion tank put into by material step 1. obtained, burstpressures 3.0-3.5Mpa, the dwell time maintains 150-200s;
3. decoct, decolour: material step 1. obtained the heavy pure water such as to add and decocts 2 times, each 1 hour, obtains extracting solution, filters, united extraction liquid, filtrate is concentrated into the medicinal extract that relative density is 1.30 (surveying when 70 DEG C); Add activated carbon decolorizing in medicinal extract, filter;
3) add a small amount of water in retort, be warming up to 60 DEG C, stir 0.5h, then add polyvinyl alcohol, polyacrylamide, emulsifying agent and purified water remainder;
4) continue to be warming up to 90-95 DEG C, keep until polyvinyl alcohol all dissolves;
5) be cooled to 69-71 DEG C, filter, add 3/4 Potassium Persulphate, and slowly drip vinyl-acetic ester;
6) temperature 69-71 DEG C is kept, reaction 6-7h;
7) temperature is risen to 85-90 DEG C, add remaining 1/4 Potassium Persulphate, reaction 0.5-1h;
8) be cooled to 75 DEG C, add step 2) the mangrove bark filtrate that obtains, reaction 1-2h;
9) be cooled to 55 DEG C, add dibutyl phthalate and ethylene glycol, stir 0.5h, be cooled to room temperature, filtration, discharging.
2. the production method of paper tube adhesive according to claim 1, it is characterized in that: step 1) described in get the raw materials ready, starting material for following weight part: vinyl-acetic ester 35 parts, mangrove bark 10 parts, polyvinyl alcohol 8 parts, ethylene glycol 2.5 parts, polyacrylamide 1 part, dibutyl phthalate 1 part, emulsifying agent 1 part, Potassium Persulphate 0.5 part, pure water 120 parts, described mangrove bark is fresh mango skin.
3. the production method of paper tube adhesive according to claim 1, is characterized in that: step 2) described in activated carbon dosage be 3-5%.
4. the production method of paper tube adhesive according to claim 1, is characterized in that: step 5) described in add Potassium Persulphate, on a small quantity repeatedly, described slow dropping vinyl-acetic ester, at least drips 1h.
5. the paper tube adhesive that obtains of method according to any one of claim 1-4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510369904.6A CN104893623B (en) | 2015-06-29 | 2015-06-29 | Paper tube adhesive and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510369904.6A CN104893623B (en) | 2015-06-29 | 2015-06-29 | Paper tube adhesive and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104893623A true CN104893623A (en) | 2015-09-09 |
| CN104893623B CN104893623B (en) | 2017-03-08 |
Family
ID=54026598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510369904.6A Expired - Fee Related CN104893623B (en) | 2015-06-29 | 2015-06-29 | Paper tube adhesive and its production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104893623B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238281A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Flame-retardant soundproof fiber adhesive |
| CN105238279A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Antibacterial soundproof damping adhesive |
| CN105238282A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Corrosion-resistant soundproof adhesive containing quartz powder |
| CN105238278A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Polymer damping sound-insulation glue |
| CN105238309A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Oil-resistant nano damping adhesive |
| CN105238308A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Impact-resistant soundproof adhesive containing glass bead filling |
| CN109468105A (en) * | 2018-10-01 | 2019-03-15 | 深圳日高胶带新材料有限公司 | A kind of biodegradable pressure sensitive adhesive and preparation method thereof |
| CN110041861A (en) * | 2019-03-27 | 2019-07-23 | 广州市白云区钟落潭家立美塑料制品厂 | A kind of high-stability type paper tube adhesive |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102372885A (en) * | 2010-08-24 | 2012-03-14 | 中国石油化工集团公司 | High viscosity polyvinyl acetate emulsion and preparation method thereof |
| CN103254840A (en) * | 2013-04-28 | 2013-08-21 | 南京林业大学 | Wood adhesive active filler and using method thereof |
| CN103923582A (en) * | 2013-01-14 | 2014-07-16 | 上海吉妮乳胶厂 | Production method of modified emulsified binder |
| CN104231977A (en) * | 2013-06-24 | 2014-12-24 | 鲍震 | Method for producing white latex |
-
2015
- 2015-06-29 CN CN201510369904.6A patent/CN104893623B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102372885A (en) * | 2010-08-24 | 2012-03-14 | 中国石油化工集团公司 | High viscosity polyvinyl acetate emulsion and preparation method thereof |
| CN103923582A (en) * | 2013-01-14 | 2014-07-16 | 上海吉妮乳胶厂 | Production method of modified emulsified binder |
| CN103254840A (en) * | 2013-04-28 | 2013-08-21 | 南京林业大学 | Wood adhesive active filler and using method thereof |
| CN104231977A (en) * | 2013-06-24 | 2014-12-24 | 鲍震 | Method for producing white latex |
Non-Patent Citations (2)
| Title |
|---|
| 张洪涛等: "《聚合物胶乳配方与应用》", 31 January 2008, 化学工业出版社 * |
| 林巧佳等: "再生资源制胶合板胶粘剂的研究", 《福建林学院学报》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105238281A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Flame-retardant soundproof fiber adhesive |
| CN105238279A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Antibacterial soundproof damping adhesive |
| CN105238282A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Corrosion-resistant soundproof adhesive containing quartz powder |
| CN105238278A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Polymer damping sound-insulation glue |
| CN105238309A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Oil-resistant nano damping adhesive |
| CN105238308A (en) * | 2015-09-30 | 2016-01-13 | 安徽静雅声学科技有限公司 | Impact-resistant soundproof adhesive containing glass bead filling |
| CN109468105A (en) * | 2018-10-01 | 2019-03-15 | 深圳日高胶带新材料有限公司 | A kind of biodegradable pressure sensitive adhesive and preparation method thereof |
| CN110041861A (en) * | 2019-03-27 | 2019-07-23 | 广州市白云区钟落潭家立美塑料制品厂 | A kind of high-stability type paper tube adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104893623B (en) | 2017-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104893623A (en) | Paper tube adhesive and production method thereof | |
| CN104927725A (en) | Paper tube adhesive and preparation method thereof | |
| BRPI0720426A8 (en) | METHODS FOR PRODUCING A LAMINATED PAPER PRODUCT COMPRISING AT LEAST TWO LAYERS, LAMINATED PAPER PRODUCTS, AND USE OF A LAMINATED PAPER PRODUCT | |
| RU2019116892A (en) | CORRUGATED PAPERBOARD CONTAINING AN ADHESIVE SUBSTANCE CONTAINING STARCH AND FINE MICROFIBRILLED CELLULOSE | |
| CN102174776B (en) | Surface sizing and dyeing method of environmentally-friendly craft paper | |
| RU2012154890A (en) | CELLULAR BARRIER COMPOSITION, INCLUDING ANION ANIMAL POLYMER | |
| CN104927726A (en) | Paper tube adhesive and preparation method thereof | |
| WO2010066195A1 (en) | Raw paper and production method and application thereof | |
| CN110939009A (en) | Production method of heat-sealing self-adhesive medical dialyzing paper | |
| JP7291776B2 (en) | Smoking article, method for manufacturing paper for packaging smokable material of smoking article | |
| CN103059770A (en) | Starch adhesive as well as preparation method and application thereof | |
| CN112176770A (en) | Method for manufacturing novel medical dialyzing paper | |
| CN104629658A (en) | Non-formaldehyde starch-base vinyl acetate adhesive production method | |
| CN105001812A (en) | Paper tuber adhesive, and production method thereof | |
| CN108162112A (en) | A kind of ternary built dyestuff and the method that high color fastness veneer layer is prepared using the dyestuff | |
| CN104946196B (en) | Environmentally friendly Cottonseed Meal base adhesive of a kind of cross-linking type and preparation method and application | |
| CN106012689A (en) | Paper-based mulching film and manufacturing method thereof | |
| CN107083045A (en) | A kind of method that degradable film for package is prepared by base-material of blue-green algae | |
| CN108749141B (en) | Manufacturing method of double-PLA (polylactic acid) film-coated paper cup | |
| CN108277698A (en) | A kind of preparation method of high strength paper packaging material | |
| CN103254841A (en) | Adhesive for production of corrugated board | |
| CN106758457B (en) | Energy-saving environment-friendly full-regeneration coated white cardboard and preparation method thereof | |
| CN106087532A (en) | A kind of compound paper capable of writing with water and preparation method thereof | |
| CN107022925B (en) | A kind of maceration extract and its height of preparation quantify transparency paper and the quickly method of the high quantitative transparency paper of preparation | |
| CN107418489A (en) | A kind of factory formula of paper tube adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170308 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |