CN107022925B - A kind of maceration extract and its height of preparation quantify transparency paper and the quickly method of the high quantitative transparency paper of preparation - Google Patents

A kind of maceration extract and its height of preparation quantify transparency paper and the quickly method of the high quantitative transparency paper of preparation Download PDF

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CN107022925B
CN107022925B CN201710265469.1A CN201710265469A CN107022925B CN 107022925 B CN107022925 B CN 107022925B CN 201710265469 A CN201710265469 A CN 201710265469A CN 107022925 B CN107022925 B CN 107022925B
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paper
transparency
maceration extract
preparation
compound
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CN107022925A (en
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陈港
朱朋辉
张俊奇
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South China University of Technology SCUT
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    • DTEXTILES; PAPER
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    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
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    • D21H17/47Condensation polymers of aldehydes or ketones
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Abstract

The invention discloses a kind of maceration extracts and its height of preparation to quantify transparency paper and the quickly method of the high quantitative transparency paper of preparation.Maceration extract of the invention includes clarifier, surfactant, water repellent agent, lubricant.The fast preparation method are as follows: multiple low basis weight body paper are placed in maceration extract and impregnates, is compound, takes out, is put among two thin-film materials, squeeze out extra maceration extract, then dipping paper is separated with thin-film material, drying, press polish processing obtain high quantitative transparency paper.Maceration extract raw material of the invention is simple, abundance, easily prepared, the preparation method operating procedure of the quantitative transparency paper of height is easy, easy to industrialized production, the height of preparation quantifies transparency paper with good transparency and tensile strength, quantifies 20-40 g/m in body paper2, tightness 0.4-0.8 g/cm3When, it is 50-80% by the paper transparency that 2-6 low basis weights impregnate the compound preparation of paper, tensile strength is 60-150 MPa.

Description

A kind of maceration extract and its height of preparation quantify transparency paper and quickly preparation it is high quantitative saturating The method of bright paper
Technical field
The invention belongs to transparency paper technical field more particularly to a kind of high quantitative transparency paper and its quick preparation sides Method.
Background technique
Cellophane paper as a kind of emerging high-performance substrate have sustainable development, raw material be easy to get with copy paper it is convenient, Biocompatibility and degradability, conducive to the advantages such as roll-to-roll printing production, excellent optics, mechanics and barrier property, It is widely used in the fields such as food packaging, map, peelable label paper, high-grade packaging, mounting.In recent years, in flexible electronic device Part is such as: Flied emission transistor, electronic console, organic solar batteries and supercapacitor are also seen in report in succession, cause The extensive concern of government, scientific research institution and enterprise.
Currently, the transparency paper of industrialized production is mainly to be manufactured paper with pulp using the natural fiber of high beating degree, this side Fado is used in the production of translucent drawing paper.The conventional method of domestic production translucent drawing paper at present is the sulfate wood pulp by bleaching, and is passed through High viscosity mashing, is then glued, then manufacture paper with pulp on long mesh paper making machine.But energy consumption is high for this method, at high cost, Wu Fashi The large-scale production of existing high quantitative transparency paper.Thus, limit its application in requirements at the higher level field.
Therefore, a kind of high quantitatively transparency paper and its fast preparation method are developed, is existed in the prior art for solving Energy consumption is high by preparation process, technological deficiency at high cost, cannot achieve high quantitative transparency paper large-scale production, becomes this field skill Art personnel's urgent problem to be solved.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of maceration extracts, are used to prepare high quantitative transparency paper, the leaching Stain liquid has the characteristics that raw material simple, abundance, easily prepared.
The present invention also provides a kind of height using maceration extract preparation to quantify transparency paper and its fast preparation method. The preparation method has operating procedure simplicity, advantage easy to industrialized production, and the paper of preparation has good transparency, together When also there is excellent tensile strength.In the quantification of 20-40 g/m of body paper2, tightness is 0.4-0.8 g/cm3When, pass through 2-6 The transparency that low basis weight impregnates the paper of the compound preparation of paper is 50-80%, and tensile strength is 60-150 MPa.
The present invention is achieved through the following technical solutions.
A kind of maceration extract, comprising: clarifier, surfactant, water repellent agent and lubricant.
Preferably, in terms of mass parts, the maceration extract includes 100 parts of clarifier, 0.3-0.8 parts of surfactant, water resistant 0.5-1.0 parts of agent, 0.8-1.8 parts of lubricant.
Preferably, the clarifier is epoxy resin, phenolic resin, Lauxite, melamine resin, acrylic acid tree One of rouge, butadiene styrene resin and aqueous polyurethane are a variety of.
Preferably, the surfactant is alkyl alcohol ether carboxylate, alkyl phosphorus carboxylate, sodium alkyl sulfonate, secondary alkyl Sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfate sodium, secondary alkyl sulphate sodium, sulfamic acid sodium, higher aliphatic alcohol sulfuric ester, Fatty glyceride, fatty acid sorbitan, polysorbate, sucrose ester, sulfated castor oil, fatty alcohol polyoxyethylene ether, alkyl Phenol polyethenoxy ether, Negel, succinic acid alkyl ester sulfonate sodium, alcohol compound, phosphate compounds, ketone Close one of object and ether compound or a variety of.
Preferably, the water repellent agent is Lauxite, melamine resin, zirconium carbonate ammonium, polyamide polyamines epoxy One of chloropropane resin and poly- peptamine uramit resin are a variety of.
Preferably, the lubricant is calcium stearate, ammonium stearate, odium stearate, potassium oleate, sulfated castor oil, sulphur It is acidified in oleic acid, fatty acid, paraffin, polyethylene glycol oxide wax, synthesis paraffin, polyethylene glycol, polyglycol ether and soybean lecithin It is one or more.
A method of high quantitative transparency paper is quickly prepared using the maceration extract, is included the following steps:
Multiple low basis weight body paper are placed in maceration extract and are impregnated, then by the low basis weight dipping paper after dipping in maceration extract In be closely combined with each other, take out compound dipping paper and be put among two thin-film materials, will be extra using pressurizing unit Maceration extract squeeze out, compound dipping paper is separated with thin-film material then, is dried, press polish processing, obtain it is described it is high quantitatively Transparency paper.
Preferably, the low basis weight body paper is bleaching needle-point leaf pulp, bleached hardwood pulp, the non-wood pulp of bleaching, bleached waste paper Paper made of slurry, Time of Fluff Slurry and cotton pulp are manufactured paper with pulp, including translucent drawing paper, wrapping paper, writing paper made from bamboo, flat envelope, writing paper, duplicating One of paper, facing paper or air filter paper.
Preferably, the quantification of 20-40 g/m of the low basis weight body paper2, tightness is 0.4-0.8 g/cm3
Preferably, the solid content of the maceration extract is 10-40%.
Preferably, the time of the dipping is 5-30 s, impregnation increment 20-100%.
Preferably, compound quantity of the low basis weight dipping paper in maceration extract is 2-6.
Preferably, the thin-film material is copper foil, polyethylene terephthalate high molecular film material, aluminium foil, gathers One of Polypropylene film, polyethylene film, leaching membrane paper, BOPP and nylon film.
Preferably, the pressurizing unit is one of hydraulic press, roller extruder.
Preferably, the mode of the drying is one of heated-air drying, infra-red drying, cylinder dried, the temperature of drying It is 70-120 DEG C.
Preferably, the pressure of the press polish processing is 2-10 MPa.
Height made from the preparation method as described in any of the above-described quantifies transparency paper, transparency 50-80%, tensile strength For 60-150 MPa.
Compared with prior art, the invention has the advantages that and the utility model has the advantages that
(1) maceration extract of the invention has the characteristics that raw material simple, abundance, easily prepared;
(2) method of the high quantitative transparency paper of present invention preparation has operating procedure easy, easy to industrialized production excellent Gesture;
(2) height of the invention quantifies transparency paper with good transparency, while also having excellent tensile strength, The quantification of 20-40 g/m of body paper2, tightness is 0.4-0.8 g/cm3When, the compound prepared paper of paper is impregnated by 2-6 low basis weights The transparency opened is 50-80%, and tensile strength is 60-150 MPa.
Specific embodiment
In order to which the present invention is described in more detail, technical solution of the present invention is further described below with reference to embodiment.
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Transparency paper is quantified the present invention provides a kind of maceration extract and its height of preparation and prepares high quantitative transparency paper Method, for solve to exist in the prior art preparation process energy consumption is high, it is at high cost, cannot achieve high quantitative transparency paper scale The technological deficiency of production.
Maceration extract of the invention includes clarifier, surfactant, water repellent agent and lubricant, and the preparation method of maceration extract is such as Under: 100 parts of clarifiers, 0.3-0.8 parts of surfactants, 0.5-1.0 parts of water repellent agents and 0.8-1.8 parts of lubricants are mutually mixed It closes, 20-30 min is stirred under 300-600 rpm revolving speed, obtains maceration extract.
The fast preparation method of transparency paper of the present invention, its step are as follows:
(1) initial body paper is provided;
(2) maceration extract is prepared;
(3) multiple low basis weight body paper are placed in maceration extract and impregnate and carry out compound, be then tensioned compound impregnated paper It is close to be fitted among two thin-film materials, extra maceration extract is squeezed out using pressurizing unit;
(4) compound dipping paper is separated with thin-film material, further press polish processing after compound dipping paper drying, Obtain high quantitative transparency paper.
The preparation method that height of the invention quantifies transparency paper is easy, easy to industrialized production etc. excellent with operating procedure Point.Prepared paper has good transparency, while also having excellent tensile strength.In the quantification of 20-40 g/ of body paper m2, tightness is 0.4-0.8 g/cm3When, the transparency that the compound prepared paper of paper is impregnated by 2-6 low basis weights is 50- 80%, tensile strength is 60-150 MPa.
Embodiment 1
Body paper uses quantification of 20 g/m2Wrapping paper, tightness are 0.6 g/cm3
Maceration extract: 500 g of clarifier, 4 g of 1.5 g of surfactant, 2.5 g of water repellent agent and lubricant;The clarifier For acrylic resin, surfactant is fatty alcohol polyoxyethylene ether, and water repellent agent is Lauxite, and lubricant is calcium stearate; Impregnating fluid solid content is 10%.
Preparation step:
Multiple low basis weight body paper are placed in maceration extract and impregnate and carry out compound, dip time 10s, impregnation increment 20%, Compound quantity is 5;Then compound impregnated paper is fitted tightly among two thin-film materials, it will be more using pressurizing unit Remaining maceration extract squeezes out, and the thin-film material used is leaching membrane paper, and the pressurizing unit used is roller extruder;
Compound dipping paper is separated with thin-film material, further press polish processing after compound dipping paper drying, heat Wind drying temperature is 70 DEG C, and the pressure of press polish processing is 2 MPa, obtains high quantitative transparency paper.
The height of preparation quantifies transparency paper after tested, transparency 67.6%, and tensile strength is 110 MPa.
Embodiment 2
Body paper uses quantification of 25 g/m2Translucent drawing paper, tightness are 0.4 g/cm3
Maceration extract: 500 g of clarifier, 5 g of 2.5 g of surfactant, 3.5 g of water repellent agent and lubricant;The clarifier For epoxy resin, surfactant is fatty glyceride, and water repellent agent is zirconium carbonate ammonium, and lubricant is potassium oleate;Maceration extract is solid Content is 25%.
Preparation step:
Multiple low basis weight body paper are placed in maceration extract impregnate and carry out it is compound, dip time be 5 s, impregnation increment 60%, Compound quantity is 3,;Then compound impregnated paper is fitted tightly among two thin-film materials, it will using pressurizing unit Extra maceration extract squeezes out, and the thin-film material used is polyethylene film, and the pressurizing unit used is hydraulic press;
Compound dipping paper is separated with thin-film material, further press polish processing after compound dipping paper drying, heat Wind drying temperature is 80 DEG C, and the pressure of press polish processing is 4 MPa, obtains high quantitative transparency paper.
The height of preparation quantifies transparency paper after tested, transparency 80%, and tensile strength is 60 MPa.
Embodiment 3
Body paper uses quantification of 40 g/m2Writing paper, tightness are 0.8 g/cm3
Maceration extract: 500 g of clarifier, 6 g of 4 g of surfactant, 4 g of water repellent agent and lubricant;The clarifier is urea Urea formaldehyde, surfactant are polysorbate, and water repellent agent is melamine resin, and lubricant is polyethylene glycol;Maceration extract Solid content is 40%.
Preparation step:
Multiple low basis weight body paper are placed in maceration extract and impregnate and carry out compound, dip time is 20 s, and impregnation increment is 80%, compound quantity is 2;Then compound impregnated paper is fitted tightly among two thin-film materials, utilizes pressurizing unit Extra maceration extract is squeezed out, the thin-film material used is BOPP, and the pressurizing unit used is hydraulic press;
Compound dipping paper is separated with thin-film material, further press polish processing after compound dipping paper drying is dried Cylinder drying temperature is 100 DEG C, and the pressure of press polish processing is 8 MPa, obtains high quantitative transparency paper.
The height of preparation quantifies transparency paper after tested, transparency 72.9%, and tensile strength is 76.5 MPa.
Embodiment 4
Body paper uses quantification of 30 g/m2Translucent drawing paper, tightness are 0.5 g/cm3
Maceration extract: 500 g of clarifier, 9 g of 3.5 g of surfactant, 5 g of water repellent agent and lubricant;The clarifier is Acrylic resin, surfactant are alkyl sulfate sodium, and water repellent agent is zirconium carbonate ammonium, and lubricant is sulfated castor oil;Leaching Stain fluid solid content is 30%.
Preparation step:
Multiple low basis weight body paper are placed in maceration extract and impregnate and carry out compound, dip time is 30 s, and impregnation increment is 100%, compound quantity is 6;Then compound impregnated paper is fitted tightly among two thin-film materials, is filled using squeezing It sets and squeezes out extra maceration extract, the thin-film material used is polypropylene film, and the pressurizing unit used is roller extruder;
Compound dipping paper is separated with thin-film material, further press polish processing after compound dipping paper drying is red Outer drying temperature is 120 DEG C, and the pressure of press polish processing is 10 MPa, obtains high quantitative transparency paper.
The height of preparation quantifies transparency paper after tested, transparency 50%, and tensile strength is 150 MPa.
In conclusion the maceration extract includes: clarifier, surfactant, water resistant the present invention provides a kind of maceration extract Agent and lubricant.The present invention also provides a kind of method that above-mentioned maceration extract quickly prepares high quantitative transparency paper, the preparations Method are as follows: multiple low basis weight body paper are placed in maceration extract, it is then that above low basis weight dipping paper is closely multiple in maceration extract It is combined, is put into after taking-up in two thin-film materials, squeezed out extra maceration extract using pressurizing unit, then by impregnated paper It opens and is separated with thin-film material, further press polish handles to obtain transparency paper after dipping paper drying.Provided maceration extract has Raw material is simple, abundance, easily prepared feature.Provided preparation method has operating procedure simplicity, is easy to industrialize The advantage of production.Prepared paper has good transparency, while also having excellent tensile strength.It is quantification of in body paper 20-40 g/m2, tightness is 0.4-0.8 g/cm3When, the transparency of the compound prepared paper of paper is impregnated by 2-6 low basis weights For 50-80%, tensile strength is 60-150 MPa.Solve exist in the prior art preparation process energy consumption is high, is at high cost, can not Realize the technological deficiency of high quantitative transparency paper large-scale production.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (3)

1. a kind of method for quickly preparing high quantitative transparency paper using maceration extract, which comprises the steps of:
Multiple low basis weight body paper are placed in maceration extract and are impregnated, it is then that the low basis weight dipping paper after dipping is tight in maceration extract It is close to be combined with each other, it takes out compound dipping paper and is put among two thin-film materials, using pressurizing unit by extra leaching Stain liquid squeezes out, and then separates compound dipping paper with thin-film material, dries, press polish processing, obtains described high quantitative transparent Paper;
In terms of mass parts, the maceration extract includes 100 parts of clarifier, 0.3-0.8 parts of surfactant, 0.5-1.0 parts of water repellent agent, 0.8-1.8 parts of lubricant;
The clarifier is one of Lauxite, acrylic resin, butadiene styrene resin and aqueous polyurethane or a variety of;
The surfactant is alkyl alcohol ether carboxylate, alkyl phosphorus carboxylate, sodium alkyl sulfonate, sodium secondary alkyl sulfonate, alkyl Benzene sulfonic acid sodium salt, alkyl sulfate sodium, secondary alkyl sulphate sodium, sulfamic acid sodium, higher aliphatic alcohol sulfuric ester, fatty acid glycerine Ester, fatty acid sorbitan, polysorbate, sucrose ester, sulfated castor oil, fatty alcohol polyoxyethylene ether, alkylphenol-polyethenoxy Ether, Negel, succinic acid alkyl ester sulfonate sodium, alcohol compound, phosphate compounds, ketone compounds and ethers One of compound is a variety of;
The water repellent agent be Lauxite, melamine resin, zirconium carbonate ammonium, Polyamide-Polyamsne-Epichlorohydrin resin and One of poly- peptamine uramit resin is a variety of;
The lubricant is calcium stearate, ammonium stearate, odium stearate, potassium oleate, sulfated castor oil, sulphation oleic acid, rouge One of fat acid, paraffin, polyethylene glycol oxide wax, synthesis paraffin, polyethylene glycol, polyglycol ether and soybean lecithin are more Kind;
The thin-film material is copper foil, polyethylene terephthalate high molecular film material, aluminium foil, polypropylene film, gathers One of vinyl film, leaching membrane paper, BOPP and nylon film;The pressurizing unit is hydraulic press, one in roller extruder Kind;The mode of the drying is one of heated-air drying, infra-red drying, cylinder dried, and the temperature of drying is 70-120 DEG C;Institute The pressure for stating press polish processing is 2-10 MPa.
2. the method according to claim 1, wherein the low basis weight body paper is bleaching needle-point leaf pulp, bleaching is wealthy Paper made of leaf wood pulp, the non-wood pulp of bleaching, bleached waste paper slurry, Time of Fluff Slurry and cotton pulp are manufactured paper with pulp, including translucent drawing paper, wrapping paper, One of writing paper made from bamboo, flat envelope, writing paper, copy paper, facing paper or air filter paper, quantification of 20-40 g/m2, tightness For 0.4-0.8 g/cm3;The solid content of the maceration extract is 10-40%;The time of the dipping is 5-30 s, impregnation increment 20- 100%;Compound quantity of the low basis weight dipping paper in maceration extract is 2-6.
3. a kind of height as made from claim 1 ~ 2 described in any item methods quantifies transparency paper, which is characterized in that transparency For 50-80%, tensile strength is 60-150 MPa.
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