CN104893144A - Special PVC resin paste material for wallpaper and preparation method of special PVC resin paste material - Google Patents
Special PVC resin paste material for wallpaper and preparation method of special PVC resin paste material Download PDFInfo
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- CN104893144A CN104893144A CN201510272130.5A CN201510272130A CN104893144A CN 104893144 A CN104893144 A CN 104893144A CN 201510272130 A CN201510272130 A CN 201510272130A CN 104893144 A CN104893144 A CN 104893144A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Paper (AREA)
Abstract
The invention discloses a special PVC resin paste material for wallpaper. The special PVC resin paste material comprises the following components in parts by weight: 30-50 parts of PVC resin, 2-6 parts of nanometer silicon nitride, 1-3 parts of nanometer titanium carbide, 5-10 parts of herba elsholtziae powder, 6-12 parts of bagasse, 10-20 parts of mullite, 5-10 parts of polypropylene fibers, 2-6 parts of a lubricating agent, 1-4 parts of a plasticizer and 2-3 parts of a stabilizer. The invention also discloses a preparation method of the PVC resin paste material. The special PVC resin paste material for wallpaper, provided by the invention, is strong in adhesive force, good in wear resistance, high in strength, scratch-resistant, safe and nontoxic, pollution-free, good in antibacterial property, simple in preparation method and capable of greatly improving the mechanical property of the wallpaper.
Description
Technical field:
The present invention relates to technical field of wallpaper, be specifically related to the polyvinyl chloride resin thickener that a kind of wallpaper is special.
Background technology:
Wallpaper, also referred to as wallpaper, it is a kind of widely used house decorative material.Because the feature that other house decorative materials multiple such as wallpaper has changing style, color is various, pattern enriches, safety and environmental protection, easy construction are incomparable, obtain the universal of certain degree at developed countries and regions.Along with the deduction of our people's standard of living, wallpaper is because of the diversity of its color and style, and extensively by the favor of human consumer, especially polyvinyl chloride resin, good decorating effect, obtains the favor of people.
Traditional PVC wallpaper, especially foam wallpaper, there is difference of hardness, stressedly easily to cave in, the shortcoming such as not scratch-resistant, and its development receives very large restriction.The polymerization degree of mainly polyvinyl chloride resin of tracing it to its cause is lower, and usually adds mineral filler in conventional P VC resin thickener, but to add mineral filler particle diameter too large, poor with the consistency of resin, the mechanical property of PVC system is declined greatly.
Summary of the invention:
The object of this invention is to provide the polyvinyl chloride resin thickener that a kind of wallpaper is special, its strong adhesion, wear resistance is good, and intensity is large, scratch-resistant, its safety non-toxic, and pollution-free, germ resistance is good, and its preparation method is simple, greatly can improve the mechanical property of wallpaper.
Another object of the present invention is to provide the preparation method of this wallpaper PVC resin specially thickener.
For achieving the above object, the present invention is by the following technical solutions:
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 30-50 part, nano-silicon nitride 2-6 part,
Nano titanium carbide 1-3 part, elscholtiza powder 5-10 part,
Bagasse 6-12 part, mullite 10-20 part,
Polypropylene fibre 5-10 part, lubricant 2-6 part,
Softening agent 1-4 part, stablizer 2-3 part.
Preferred as technique scheme, the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that, with parts by weight, comprises following component:
Polyvinyl chloride resin 45 parts, nano-silicon nitride 6 parts,
Nano titanium carbide 3 parts, 8 parts, elscholtiza powder,
Bagasse 10 parts, mullite 18 parts,
Polypropylene fibre 6 parts, lubricant 5 parts,
3 parts, softening agent, stablizer 3 parts.
Preferred as technique scheme, described polyvinyl chloride resin is XS-3 type polyvinyl chloride resin.
Preferred as technique scheme, the size of described nano-silicon nitride is 20-30nm, and the size of described nano titanium carbide is 20-50nm.
Preferred as technique scheme, the size of described mullite is 500-800 order.
Preferred as technique scheme, described polypropylene fibre length is 1-2 μm.
Preferred as technique scheme, described lubricant is one or more mixing in epoxy soybean oil, clorafin, polyethylene wax.
Preferred as technique scheme, described softening agent is one or both mixing in dioctyl phthalate (DOP), dibutyl phthalate.
A preparation method for the polyvinyl chloride resin thickener that wallpaper is special, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, 20-30min is stirred under the state of 3000-5000 rev/min, add the mixed powder that step (1) obtains, under the state of 4000-6000 rev/min, stir 20-60min; Continue to add lubricant, softening agent, stablizer, under the state of 6000-10000 rev/min, stir 1-3h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
The present invention has following beneficial effect:
The present invention adds the Nano filling such as nano-silicon nitride, nano titanium carbide in PVC matrix resin, considerably increase wear-resisting, the scratch-resistant performance of wallpaper, water-repellancy also increases greatly, add elscholtiza powder, bagasse simultaneously, not only increase the anti-microbial property of wallpaper, also improve the humidity resistance of wallpaper, hardness also increases greatly;
Polyvinyl chloride resin thickener provided by the invention, tack is good, adopts raw material environment-protecting asepsis, and preparation method is simple, and cost is low.
Embodiment:
For a better understanding of the present invention, below by embodiment, the present invention is further described, and embodiment, only for explaining the present invention, can not form any restriction to the present invention.
Embodiment 1
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 30 parts, nano-silicon nitride 2 parts, nano titanium carbide 1 part,
5 parts, elscholtiza powder, bagasse 6 parts, mullite 10 parts,
Polypropylene fibre 5 parts, lubricant 2 parts,
1 part, softening agent, stablizer 2 parts.
Its preparation method, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, under the state of 3000 revs/min, stir 20min, add the mixed powder that step (1) obtains, under the state of 4000 revs/min, stir 20min; Continue to add lubricant, softening agent, stablizer, under the state of 6000 revs/min, stir 1h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
Embodiment 2
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 50 parts, nano-silicon nitride 6 parts, nano titanium carbide 3 parts,
10 parts, elscholtiza powder, bagasse 12 parts, mullite 20 parts,
Polypropylene fibre 10 parts, lubricant 6 parts,
4 parts, softening agent, stablizer 3 parts.
Its preparation method, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, under the state of 5000 revs/min, stir 30min, add the mixed powder that step (1) obtains, under the state of 6000 revs/min, stir 60min; Continue to add lubricant, softening agent, stablizer, under the state of 10000 revs/min, stir 3h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
Embodiment 3
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 35 parts, nano-silicon nitride 3 parts, nano titanium carbide 1.5 parts,
6 parts, elscholtiza powder, bagasse 7 parts, mullite 12 parts,
Polypropylene fibre 6 parts, lubricant 3 parts,
2 parts, softening agent, stablizer 2.2 parts.
Its preparation method, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, under the state of 3500 revs/min, stir 22min, add the mixed powder that step (1) obtains, under the state of 4500 revs/min, stir 30min; Continue to add lubricant, softening agent, stablizer, under the state of 7000 revs/min, stir 1.5h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
Embodiment 4
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 38 parts, nano-silicon nitride 3.5 parts, nano titanium carbide 1.8 parts,
7 parts, elscholtiza powder, bagasse 8 parts, mullite 14 parts,
Polypropylene fibre 7 parts, lubricant 4 parts,
2.5 parts, softening agent, stablizer 2.4 parts.
Its preparation method, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, under the state of 4000 revs/min, stir 24min, add the mixed powder that step (1) obtains, under the state of 4800 revs/min, stir 40min; Continue to add lubricant, softening agent, stablizer, under the state of 8000 revs/min, stir 2h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
Embodiment 5
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 45 parts, nano-silicon nitride 5 parts, nano titanium carbide 2 parts,
8 parts, elscholtiza powder, bagasse 10 parts, mullite 16 parts,
Polypropylene fibre 8 parts, lubricant 5 parts,
3 parts, softening agent, stablizer 2.6 parts.
Its preparation method, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, under the state of 4500 revs/min, stir 26min, add the mixed powder that step (1) obtains, under the state of 5000 revs/min, stir 50min; Continue to add lubricant, softening agent, stablizer, under the state of 9000 revs/min, stir 2.5h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
Embodiment 6
The polyvinyl chloride resin thickener that wallpaper is special, with parts by weight, comprises following component:
Polyvinyl chloride resin 48 parts, nano-silicon nitride 5.5 parts, nano titanium carbide 3 parts,
9 parts, elscholtiza powder, bagasse 11 parts, mullite 18 parts,
Polypropylene fibre 9 parts, lubricant 5.5 parts,
3 parts, softening agent, stablizer 2.8 parts.
Its preparation method, comprises the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, under the state of 4800 revs/min, stir 28min, add the mixed powder that step (1) obtains, under the state of 5500 revs/min, stir 55min; Continue to add lubricant, softening agent, stablizer, under the state of 9500 revs/min, stir 3h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
By gained polyvinyl chloride resin thickener, be applied to PVC foam wallpaper, and carry out performance test to prepared foaming wallpaper, test result is in table 1.
Table 1
From table 1, wallpaper germ resistance prepared by wallpaper PVC resin specially thickener provided by the invention is good, and intensity is large, scratch-resistant excellent performance.
Claims (9)
1. the polyvinyl chloride resin thickener that wallpaper is special, is characterized in that, with parts by weight, comprises following component:
Polyvinyl chloride resin 30-50 part, nano-silicon nitride 2-6 part,
Nano titanium carbide 1-3 part, elscholtiza powder 5-10 part,
Bagasse 6-12 part, mullite 10-20 part,
Polypropylene fibre 5-10 part, lubricant 2-6 part,
Softening agent 1-4 part, stablizer 2-3 part.
2. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that, with parts by weight, comprises following component:
Polyvinyl chloride resin 45 parts, nano-silicon nitride 6 parts,
Nano titanium carbide 3 parts, 8 parts, elscholtiza powder,
Bagasse 10 parts, mullite 18 parts,
Polypropylene fibre 6 parts, lubricant 5 parts,
3 parts, softening agent, stablizer 3 parts.
3. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that: described polyvinyl chloride resin is XS-3 type polyvinyl chloride resin.
4. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that: the size of described nano-silicon nitride is 20-30nm, and the size of described nano titanium carbide is 20-50nm.
5. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that: the size of described mullite is 500-800 order.
6. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that: described polypropylene fibre length is 1-2 μm.
7. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that: described lubricant is one or more mixing in epoxy soybean oil, clorafin, polyethylene wax.
8. the polyvinyl chloride resin thickener that a kind of wallpaper as claimed in claim 1 is special, is characterized in that: described softening agent is one or both mixing in dioctyl phthalate (DOP), dibutyl phthalate.
9. the preparation method of the polyvinyl chloride resin thickener that a kind of wallpaper as described in as arbitrary in claim 1 to 8 is special, is characterized in that, comprise the following steps:
(1) by nano-silicon nitride, nano titanium carbide, elscholtiza powder, bagasse mixing and stirring, mixed powder is obtained, stand-by;
(2) polyvinyl chloride resin, polypropylene fibre, mullite are joined in stainless steel stirring tank, 20-30min is stirred under the state of 3000-5000 rev/min, add the mixed powder that step (1) obtains, under the state of 4000-6000 rev/min, stir 20-60min; Continue to add lubricant, softening agent, stablizer, under the state of 6000-10000 rev/min, stir 1-3h, obtain the polyvinyl chloride resin thickener that wallpaper is special.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510272130.5A CN104893144A (en) | 2015-05-26 | 2015-05-26 | Special PVC resin paste material for wallpaper and preparation method of special PVC resin paste material |
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| CN201510272130.5A CN104893144A (en) | 2015-05-26 | 2015-05-26 | Special PVC resin paste material for wallpaper and preparation method of special PVC resin paste material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462115A (en) * | 2015-12-24 | 2016-04-06 | 黄山豪泰塑胶有限公司 | Decorative PVC (Polyvinyl Chloride) film |
| CN105504579A (en) * | 2015-12-24 | 2016-04-20 | 黄山豪泰塑胶有限公司 | PVC (polyvinyl chloride) material applied to wallpaper |
| CN108794928A (en) * | 2018-06-22 | 2018-11-13 | 安徽索亚装饰材料有限公司 | A kind of anti-mildew PVC foam Wallpaper paste material |
| CN110878163A (en) * | 2019-06-14 | 2020-03-13 | 安徽鑫豪爵新材料科技有限公司 | Processing technology of scratch self-repairing tablecloth film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850696A (en) * | 2012-09-20 | 2013-01-02 | 吴江市天源塑胶有限公司 | High-toughness polyvinyl chloride tube |
| CN103205133A (en) * | 2013-03-15 | 2013-07-17 | 成钢 | Functional floor tile produced by using waste PVC and agricultural waste |
| CN103740005A (en) * | 2014-01-16 | 2014-04-23 | 黑生贤 | Production formula and process of waste PVC (polyvinyl chloride) wood-plastic composition |
-
2015
- 2015-05-26 CN CN201510272130.5A patent/CN104893144A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850696A (en) * | 2012-09-20 | 2013-01-02 | 吴江市天源塑胶有限公司 | High-toughness polyvinyl chloride tube |
| CN103205133A (en) * | 2013-03-15 | 2013-07-17 | 成钢 | Functional floor tile produced by using waste PVC and agricultural waste |
| CN103740005A (en) * | 2014-01-16 | 2014-04-23 | 黑生贤 | Production formula and process of waste PVC (polyvinyl chloride) wood-plastic composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105462115A (en) * | 2015-12-24 | 2016-04-06 | 黄山豪泰塑胶有限公司 | Decorative PVC (Polyvinyl Chloride) film |
| CN105504579A (en) * | 2015-12-24 | 2016-04-20 | 黄山豪泰塑胶有限公司 | PVC (polyvinyl chloride) material applied to wallpaper |
| CN108794928A (en) * | 2018-06-22 | 2018-11-13 | 安徽索亚装饰材料有限公司 | A kind of anti-mildew PVC foam Wallpaper paste material |
| CN110878163A (en) * | 2019-06-14 | 2020-03-13 | 安徽鑫豪爵新材料科技有限公司 | Processing technology of scratch self-repairing tablecloth film |
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Application publication date: 20150909 |
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