CN104877454A - Fireproof ink for wallpaper and preparation method of fireproof ink - Google Patents
Fireproof ink for wallpaper and preparation method of fireproof ink Download PDFInfo
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- CN104877454A CN104877454A CN201510337308.XA CN201510337308A CN104877454A CN 104877454 A CN104877454 A CN 104877454A CN 201510337308 A CN201510337308 A CN 201510337308A CN 104877454 A CN104877454 A CN 104877454A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a fireproof ink for wallpaper and a preparation method of the fireproof ink. The fireproof ink comprises the following components in part by weight: 7-17 parts of organic pigment, 7-19 parts of cellulose nitrate, 4-10 parts of sepiolite fiber, 1-5 parts of dioctyl phthalate, 5-15 parts of of phenolic resin, 2-7 parts of ethylene propylene diene terpolymer rubber, 32-46 parts of isopropanol, 10-20 parts of rosin pentaerythrityl ester, 3-7 parts of toluene, 4-12 parts of gummy oil, 1-4 parts of polyethylene microcrystalline wax, 0.5-2.5 parts of tin tetrachloride, 3-8 parts of melamine phosphate, 5-13 parts of polytetrafluoroethylene micropowder, 0.2-0.8 parts of methyl hydroquinone. The fireproof ink provided by the invention has excellent fire, moisture, corrosion and abrasion resistance.
Description
Technical field
The present invention relates to decorative materials technology, particularly relate to a kind of wallpaper fire prevention ink and preparation method thereof.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application indoor hardware fitting quite widely.Because it is various that wallpaper has color, pattern enriches, the feature that other house decorative material multiple such as luxurious style, safety and environmental protection, easy construction, affordable is incomparable, therefore obtains the universal of certain degree.Wallpaper is divided into a lot of class, as overlay film wallpaper, coating wallpaper, embossed wall paper etc.Usually produce body paper with bleached wood pulp, then through the processing treatment of different operation, cover as coating, printing, embossing or surface and mould, dispatch from the factory after cutting, packing.Wallpaper has certain intensity, toughness, appearance attractive in appearance and good water repelling property because of it, is widely used in the interior decoration etc. in house, office, hotel, hotel.
The fire prevention of current existing Ink for wallpaper, protection against the tide, crocking resistance are poor, make the work-ing life of wallpaper short, easy to wear and not fire-resistant.Such as Chinese invention patent (the patent No. 201110155073.4, applying date 2011.06.10) disclose anti-yellowing high-temperature resistant wallpaper printing ink, be made up of the following following component according to weight percent meter: water-borne acrylic resin 40%-60%, toner 8%-10%, heat resistance accessory 1%-3%, organic solvent 30%-50%.Ink formulations of the present invention adopts water-borne acrylic resin, has the advantage of environmental protection, anti-yellowing change, and is added with heat resistance accessory in ink, can stand the high temperature of 200-220 DEG C, be applicable to the printing of high-grade wallpaper.
Summary of the invention
the technical problem solved:for the shortcoming of the fire prevention of existing Ink for wallpaper, protection against the tide, crocking resistance difference, the invention provides a kind of wallpaper fire prevention ink and preparation method thereof.
technical scheme:a kind of wallpaper fire prevention ink, in mass parts containing following composition: pigment dyestuff 7 ~ 17 parts, 7 ~ 19 parts, nitrocellulose, sepiolite fibre 4 ~ 10 parts, o-phthalic acid dibutyl ester 1 ~ 5 part, 5 ~ 15 parts, resol, terpolymer EP rubber 2 ~ 7 parts, Virahol 32 ~ 46 parts, pentalyn 10 ~ 20 parts, toluene 3 ~ 7 parts, gummy oil 4 ~ 12 parts, polyethylene Microcrystalline Wax 1 ~ 4 part, tin tetrachloride 0.5 ~ 2.5 part, melamine phosphate 3 ~ 8 parts, superfine powder of polytetrafluoroethylene 5 ~ 13 parts, methyl hydroquinone 0.2 ~ 0.8 part.
A kind of wallpaper fire prevention ink described above, in mass parts containing following composition: pigment dyestuff 9 ~ 15 parts, 8 ~ 17 parts, nitrocellulose, sepiolite fibre 5 ~ 9 parts, o-phthalic acid dibutyl ester 1.5 ~ 4 parts, 7 ~ 13 parts, resol, terpolymer EP rubber 3 ~ 6.5 parts, Virahol 35 ~ 44 parts, pentalyn 12 ~ 18 parts, toluene 4 ~ 6.5 parts, gummy oil 5 ~ 11 parts, polyethylene Microcrystalline Wax 1.7 ~ 3.4 parts, tin tetrachloride 0.8 ~ 2.2 part, melamine phosphate 4 ~ 7 parts, superfine powder of polytetrafluoroethylene 6 ~ 11 parts, methyl hydroquinone 0.3 ~ 0.7 part.
A kind of wallpaper fire prevention ink described above, in mass parts containing following composition: pigment dyestuff 11 parts, 10 parts, nitrocellulose, sepiolite fibre 6 parts, o-phthalic acid dibutyl ester 2.3 parts, 9 parts, resol, terpolymer EP rubber 4 parts, Virahol 38 parts, pentalyn 14 parts, toluene 4.8 parts, gummy oil 7 parts, polyethylene Microcrystalline Wax 2.2 parts, tin tetrachloride 1.2 parts, melamine phosphate 5 parts, superfine powder of polytetrafluoroethylene 7 parts, methyl hydroquinone 0.4 part.
A kind of wallpaper fire prevention ink described above, in mass parts containing following composition: pigment dyestuff 12 parts, 12 parts, nitrocellulose, sepiolite fibre 7 parts, o-phthalic acid dibutyl ester 2.6 parts, 10 parts, resol, terpolymer EP rubber 4.8 parts, Virahol 40 parts, pentalyn 15 parts, toluene 5.2 parts, gummy oil 8 parts, polyethylene Microcrystalline Wax 2.5 parts, tin tetrachloride 1.5 parts, melamine phosphate 5.5 parts, superfine powder of polytetrafluoroethylene 8.5 parts, methyl hydroquinone 0.5 part.
The preparation method of a kind of wallpaper fire prevention ink described above, the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 10 ~ 20 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 1 ~ 2h, leaves standstill 2 ~ 4h, and namely discharging obtains wallpaper fire prevention ink.
The fineness that is ground in second step described above is 15 μm.
Stirring 1h in the 3rd step described above, leaves standstill 3h.
Stirring 2h in the 3rd step described above, leaves standstill 4h.
beneficial effect:a kind of wallpaper fire prevention ink provided by the invention and preparation method thereof, this ink has excellent fire prevention, protection against the tide, anticorrosion and crocking resistance, the long service life of wallpaper, not easy to wear, not easily mouldy, ink run into external substance be infected with can not variable color, scatter, meanwhile, its fire resistance reaches 1 grade.
Embodiment
embodiment 1
A kind of wallpaper fire prevention ink, in mass parts containing following composition: pigment dyestuff 7 parts, 7 parts, nitrocellulose, sepiolite fibre 4 parts, o-phthalic acid dibutyl ester 1 part, 5 parts, resol, terpolymer EP rubber 2 parts, Virahol 32 parts, pentalyn 10 parts, toluene 3 parts, gummy oil 4 parts, polyethylene Microcrystalline Wax 1 part, tin tetrachloride 0.5 part, melamine phosphate 3 parts, superfine powder of polytetrafluoroethylene 5 parts, methyl hydroquinone 0.2 part.
A preparation method for wallpaper fire prevention ink, the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 10 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 1h, leaves standstill 2h, and namely discharging obtains wallpaper fire prevention ink.
embodiment 2
A kind of wallpaper fire prevention ink, in mass parts containing following composition: pigment dyestuff 17 parts, 19 parts, nitrocellulose, sepiolite fibre 10 parts, o-phthalic acid dibutyl ester 5 parts, 15 parts, resol, terpolymer EP rubber 7 parts, Virahol 46 parts, pentalyn 20 parts, toluene 7 parts, gummy oil 12 parts, polyethylene Microcrystalline Wax 4 parts, tin tetrachloride 2.5 parts, melamine phosphate 8 parts, superfine powder of polytetrafluoroethylene 13 parts, methyl hydroquinone 0.8 part.
A preparation method for wallpaper fire prevention ink, the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 20 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 2h, leaves standstill 4h, and namely discharging obtains wallpaper fire prevention ink.
embodiment 3
A kind of wallpaper fire prevention ink, in mass parts containing following composition: pigment dyestuff 9 parts, 8 parts, nitrocellulose, sepiolite fibre 5 parts, o-phthalic acid dibutyl ester 1.5 parts, 7 parts, resol, terpolymer EP rubber 3 parts, Virahol 35 parts, pentalyn 12 parts, toluene 4 parts, gummy oil 5 parts, polyethylene Microcrystalline Wax 1.7 parts, tin tetrachloride 0.8 part, melamine phosphate 4 parts, superfine powder of polytetrafluoroethylene 6 parts, methyl hydroquinone 0.3 part.
A preparation method for wallpaper fire prevention ink, the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 15 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 1h, leaves standstill 3h, and namely discharging obtains wallpaper fire prevention ink.
embodiment 4
A kind of wallpaper fire prevention ink, in mass parts containing following composition: pigment dyestuff 11 parts, 10 parts, nitrocellulose, sepiolite fibre 6 parts, o-phthalic acid dibutyl ester 2.3 parts, 9 parts, resol, terpolymer EP rubber 4 parts, Virahol 38 parts, pentalyn 14 parts, toluene 4.8 parts, gummy oil 7 parts, polyethylene Microcrystalline Wax 2.2 parts, tin tetrachloride 1.2 parts, melamine phosphate 5 parts, superfine powder of polytetrafluoroethylene 7 parts, methyl hydroquinone 0.4 part.
A preparation method for wallpaper fire prevention ink, the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 15 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 2h, leaves standstill 4h, and namely discharging obtains wallpaper fire prevention ink.
embodiment 5
A kind of wallpaper fire prevention ink, in mass parts containing following composition: pigment dyestuff 12 parts, 12 parts, nitrocellulose, sepiolite fibre 7 parts, o-phthalic acid dibutyl ester 2.6 parts, 10 parts, resol, terpolymer EP rubber 4.8 parts, Virahol 40 parts, pentalyn 15 parts, toluene 5.2 parts, gummy oil 8 parts, polyethylene Microcrystalline Wax 2.5 parts, tin tetrachloride 1.5 parts, melamine phosphate 5.5 parts, superfine powder of polytetrafluoroethylene 8.5 parts, methyl hydroquinone 0.5 part.
A preparation method for wallpaper fire prevention ink, the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 15 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 2h, leaves standstill 4h, and namely discharging obtains wallpaper fire prevention ink.
comparative example 1
Patent of invention publication number is that the patent of CN 102241916 A comprises following component: water-borne acrylic resin 60%; Toner 8%; Heat resistance accessory 2%; Organic solvent 30%.
The above-mentioned technical performance index stating the ink of embodiment 1 ~ embodiment 5 and comparative example 1, its detected result is as follows:
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 |
| Moistureproofness (under humidity is 50-60%RH storage time/h) | 92 | 94 | 92 | 96 | 97 | 58 |
| Rub resistance number of times/time | 212 | 215 | 218 | 224 | 225 | 132 |
| Fire rating/level | 1 | 1 | 1 | 1 | 1 |
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (8)
1. a wallpaper fire prevention ink, to it is characterized in that in mass parts containing following composition: pigment dyestuff 7 ~ 17 parts, 7 ~ 19 parts, nitrocellulose, sepiolite fibre 4 ~ 10 parts, o-phthalic acid dibutyl ester 1 ~ 5 part, 5 ~ 15 parts, resol, terpolymer EP rubber 2 ~ 7 parts, Virahol 32 ~ 46 parts, pentalyn 10 ~ 20 parts, toluene 3 ~ 7 parts, gummy oil 4 ~ 12 parts, polyethylene Microcrystalline Wax 1 ~ 4 part, tin tetrachloride 0.5 ~ 2.5 part, melamine phosphate 3 ~ 8 parts, superfine powder of polytetrafluoroethylene 5 ~ 13 parts, methyl hydroquinone 0.2 ~ 0.8 part.
2. a kind of wallpaper fire prevention ink according to claim 1, to it is characterized in that in mass parts containing following composition: pigment dyestuff 9 ~ 15 parts, 8 ~ 17 parts, nitrocellulose, sepiolite fibre 5 ~ 9 parts, o-phthalic acid dibutyl ester 1.5 ~ 4 parts, 7 ~ 13 parts, resol, terpolymer EP rubber 3 ~ 6.5 parts, Virahol 35 ~ 44 parts, pentalyn 12 ~ 18 parts, toluene 4 ~ 6.5 parts, gummy oil 5 ~ 11 parts, polyethylene Microcrystalline Wax 1.7 ~ 3.4 parts, tin tetrachloride 0.8 ~ 2.2 part, melamine phosphate 4 ~ 7 parts, superfine powder of polytetrafluoroethylene 6 ~ 11 parts, methyl hydroquinone 0.3 ~ 0.7 part.
3. a kind of wallpaper fire prevention ink according to claim 1, to it is characterized in that in mass parts containing following composition: pigment dyestuff 11 parts, 10 parts, nitrocellulose, sepiolite fibre 6 parts, o-phthalic acid dibutyl ester 2.3 parts, 9 parts, resol, terpolymer EP rubber 4 parts, Virahol 38 parts, pentalyn 14 parts, toluene 4.8 parts, gummy oil 7 parts, polyethylene Microcrystalline Wax 2.2 parts, tin tetrachloride 1.2 parts, melamine phosphate 5 parts, superfine powder of polytetrafluoroethylene 7 parts, methyl hydroquinone 0.4 part.
4. a kind of wallpaper fire prevention ink according to claim 1, to it is characterized in that in mass parts containing following composition: pigment dyestuff 12 parts, 12 parts, nitrocellulose, sepiolite fibre 7 parts, o-phthalic acid dibutyl ester 2.6 parts, 10 parts, resol, terpolymer EP rubber 4.8 parts, Virahol 40 parts, pentalyn 15 parts, toluene 5.2 parts, gummy oil 8 parts, polyethylene Microcrystalline Wax 2.5 parts, tin tetrachloride 1.5 parts, melamine phosphate 5.5 parts, superfine powder of polytetrafluoroethylene 8.5 parts, methyl hydroquinone 0.5 part.
5. the preparation method of a kind of wallpaper fire prevention ink as claimed in claim 1, is characterized in that the preparation process of the method is as follows:
The first step: first pigment dyestuff and nitrocellulose are put into agitator and stir, drops in decollator;
Second step: Virahol, pentalyn, toluene, sepiolite fibre, terpolymer EP rubber are dropped in the decollator in the first step, resol, o-phthalic acid dibutyl ester, polyethylene Microcrystalline Wax, gummy oil, superfine powder of polytetrafluoroethylene is added after stirring, dispersed with stirring mixes rear discharging, grind, being ground to fineness is 10 ~ 20 μm, then drops in agitator;
3rd step: add tin tetrachloride, melamine phosphate, methyl hydroquinone in the agitator in second step, stirs 1 ~ 2h, leaves standstill 2 ~ 4h, and namely discharging obtains wallpaper fire prevention ink.
6. the preparation method of a kind of wallpaper fire prevention ink according to claim 5, is characterized in that: the fineness that is ground in described second step is 15 μm.
7. the preparation method of a kind of wallpaper fire prevention ink according to claim 5, is characterized in that: the stirring 1h in described 3rd step, leaves standstill 3h.
8. the preparation method of a kind of wallpaper fire prevention ink according to claim 5, is characterized in that: the stirring 2h in described 3rd step, leaves standstill 4h.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510337308.XA CN104877454A (en) | 2015-06-18 | 2015-06-18 | Fireproof ink for wallpaper and preparation method of fireproof ink |
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| CN201510337308.XA CN104877454A (en) | 2015-06-18 | 2015-06-18 | Fireproof ink for wallpaper and preparation method of fireproof ink |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105751720A (en) * | 2016-03-29 | 2016-07-13 | 王兆进 | Method for preparing sepiolite digital printing wallpaper |
| CN105774278A (en) * | 2016-03-29 | 2016-07-20 | 王兆进 | Manufacturing method for digitally printing wall picture through diatom ooze |
| CN105839875A (en) * | 2016-03-29 | 2016-08-10 | 王兆进 | Diatom ooze digital printing wallpaper preparation method |
| CN111910469A (en) * | 2019-05-09 | 2020-11-10 | 东莞顺裕纸业有限公司 | High-strength corrugated paper and preparation method thereof |
-
2015
- 2015-06-18 CN CN201510337308.XA patent/CN104877454A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105751720A (en) * | 2016-03-29 | 2016-07-13 | 王兆进 | Method for preparing sepiolite digital printing wallpaper |
| CN105774278A (en) * | 2016-03-29 | 2016-07-20 | 王兆进 | Manufacturing method for digitally printing wall picture through diatom ooze |
| CN105839875A (en) * | 2016-03-29 | 2016-08-10 | 王兆进 | Diatom ooze digital printing wallpaper preparation method |
| CN111910469A (en) * | 2019-05-09 | 2020-11-10 | 东莞顺裕纸业有限公司 | High-strength corrugated paper and preparation method thereof |
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Application publication date: 20150902 |