CN101457051B - Printing ink and preparation method thereof - Google Patents
Printing ink and preparation method thereof Download PDFInfo
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- CN101457051B CN101457051B CN 200710301825 CN200710301825A CN101457051B CN 101457051 B CN101457051 B CN 101457051B CN 200710301825 CN200710301825 CN 200710301825 CN 200710301825 A CN200710301825 A CN 200710301825A CN 101457051 B CN101457051 B CN 101457051B
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Abstract
The invention provides a printing ink which comprises an acrylic resin, a polyamide resin/cyclorubber, a solvent, a packing material, a plasticizer, a dispersant and a pigment; wherein, the ink also comprises nano-silica and corundum powders. The invention also provides a preparation method of the printing ink. By adding the nano-silica and corundum powders in the ink, the printing ink improves the brightness of the ink and greatly promotes the wearing property and water resistance of the printed ink.
Description
Technical field
The invention relates to a kind of printing-ink and preparation method thereof.
Background technology
The stock of printing is very extensive, can be metal, plastics, pottery, glass, paper, leather, rubber, enamel, timber, textiles and non-woven fabrics etc.According to the different properties of stock and the different field of application, when printing, need use the printing ink that is complementary with it.
When on plastics, pottery and metal, printing, need printing ink to have higher sticking power, for example, CN1063705A discloses a kind of screen printing ink for polytrimethylene, and the composition of this printing ink comprises the Chlorinated Polypropylene III of 4-5 weight %, the acrylic resin of 20-30 weight %, the rosin modified phenolic resin of 4-8 weight %, the filler of 20-30 weight %, the pigment of 4-20 weight %, the auxiliary agent of 4-5 weight % and the solvent of 18-20 weight %.Though this ink adhesion can reach requirement, its shortcoming is that glossiness is relatively poor behind this ink printing, and wear resisting property and fire performance are relatively poor, has limited the application of this printing ink on wear-resisting and refractory materials.
Summary of the invention
The objective of the invention is to overcome existing printing-ink and have printing back low in glossiness, and the shortcoming of wear resisting property and fire performance difference, a kind of printing is provided, and afterwards glossiness is good, and wear resisting property and fire performance also can meet the requirements of printing-ink.
The present inventor has carried out careful research to existing printing-ink, the unexpected glossiness of finding in printing ink, to add after nano silicon can significantly improve ink printing, and in printing ink, add wear resisting property and the fire performance that the corundum powder can significantly improve printing ink.
The invention provides a kind of printing-ink, this printing ink contains acrylic resin, polyamide resin and/or thermoprene, molten profit, stopping composition, softening agent, dispersion agent and pigment, and wherein, this printing ink also contains nano silicon and corundum powder.
The present invention also provides the preparation method of described printing ink, and wherein, this method comprises and joins acrylic resin, polyamide resin and/or thermoprene in the solvent and stir; Add stopping composition, softening agent, pigment, nano silicon and corundum powder afterwards and stir, add dispersion agent then and grind, obtain printing ink.
The present invention is by adding nano silicon and corundum powder in printing ink, significantly improved the glossiness behind the ink printing and the wear resisting property and the fire performance of printing ink.
Embodiment
The invention provides a kind of printing-ink, this printing ink contains acrylic resin, polyamide resin and/or thermoprene, solvent, stopping composition, softening agent, dispersion agent and pigment, and wherein, this printing ink also contains nano silicon and corundum powder.
According to the present invention, the average particle diameter of described nano silicon and corundum powder can in very large range change; Under the preferable case, the average particle diameter of described nano silicon is the 1-100 nanometer; The average particle diameter of described corundum powder is the 0.1-10 micron; More preferably, the average particle diameter of described nano silicon is the 20-60 nanometer; The average particle diameter of described corundum powder is the 0.5-3 micron, glossiness is better after using the nano silicon of the average particle diameter in the above-mentioned scope and corundum powder can make ink printing, can also further improve the wear resisting property and the fire performance of printing ink simultaneously; The corundum powder that meets above-mentioned condition can be commercially available, the corundum powder produced of the anti-material of sharp second micro mist of Zhengzhou moral company limited for example, the nano silicon that meets above-mentioned condition can be commercially available, for example the HN serial nano silicon-dioxide of Zibo Hai Nagaoke Materials Co., Ltd production.
Among the present invention, described acrylic resin, polyamide resin and/or thermoprene, solvent, stopping composition, softening agent, dispersion agent, pigment, the content of nano silicon and corundum powder can in very large range change, under the preferable case, gross weight with printing ink is a benchmark, the content of described acrylic resin is 20-50 weight %, the content of described polyamide resin and/or thermoprene is 2-10 weight %, the content of described solvent is 20-60 weight %, the content of described stopping composition is 3-10 weight %, the content of described softening agent is 2-15 weight %, the content of described dispersion agent is 0.2-1 weight %, the content of described pigment is 5-15 weight %, the content of described nano silicon is 1-5 weight %, and the content of described corundum powder is 0.5-2 weight %; More preferably, gross weight with printing ink is a benchmark, the content of described acrylic resin is 25-45 weight %, the content of described polyamide resin and/or thermoprene is 4-8 weight %, the content of described solvent is 25-50 weight %, the content of described stopping composition is 4-8 weight %, the content of described softening agent is 5-10 weight %, the content of described dispersion agent is 0.5-0.8 weight %, the content of described pigment is 8-12 weight %, the content of described nano silicon is 2-4 weight %, and the content of described corundum powder is 0.8-1.5 weight %.
Among the present invention, described acrylic resin can be commercially available for the acrylic resin that is used for printing-ink of various routines, for example, and the acrylic resin (B838) that Nanjing DSM resin company limited produces.
According to the present invention, described polyamide resin can be commercially available for the polyamide resin that is used for printing-ink of various routines, for example, and the polyamide resin (650) that bright chemical plant, Wuxi company limited produces.
Among the present invention, described thermoprene can be commercially available for the thermoprene that is used for printing-ink of various routines, for example, and the thermoprene that scientific ﹠ trading Co., Ltd. provides in the palm fibre of Shanghai (CK514).
Among the present invention, described solvent can be the solvent of the various routines that are used for printing ink, and for example, described solvent can be in alcoholic solvent, ester solvent, ketone solvent and the ether solvents one or more; Described alcoholic solvent can be in ethanol, Virahol and the butanols one or more; Described ester solvent can be in ethyl acetate, butylacetate and the n-Butyl lactate one or more; Described ketone solvent can be in pimelinketone, acetone and the butanone one or more; Described ether solvents can be in ethylene glycol ethyl ether, the butyl glycol ether one or more.
Under the preferable case, described solvent is the mixed solvent of alcoholic solvent, ester solvent and ketone solvent, in the described mixed solvent, the content of alcoholic solvent, ester solvent and ketone solvent can in very large range change, more preferably, with respect to the alcoholic solvent of 100 weight parts, the content of described ester solvent is the 100-200 weight part, and the content of described ketone solvent is the 100-250 weight part.The solvent that use meets above-mentioned condition can improve the printing effect of printing ink and have quick-drying characteristic.
According to the present invention, described stopping composition can be the stopping composition of the various routines that are used for printing ink, and for example, described stopping composition can be in lime carbonate, barium sulfate, talcum powder and the mica powder one or more.
Described softening agent can be the softening agent of the various routines that are used for printing ink, for example, described softening agent can be in dimethyl phthalate, butyl benzyl phthalate and the di(2-ethylhexyl)phosphate phenyl monooctyl ester one or more, the softening agent that meets above-mentioned requirements can be commercially available, for example, the butyl benzyl phthalate (Santicizer 160) and the di(2-ethylhexyl)phosphate phenyl monooctyl ester (Santicizer 141) of the production of FERRO company.
The kind of described dispersion agent is conventionally known to one of skill in the art, for example, and BYK2000 dispersion agent, BYK110 dispersion agent, BYK180 dispersion agent and BYK104 dispersion agent that BYK company produces.
Described pigment is conventionally known to one of skill in the art, and for example, described pigment can be in carbon black, titanium dioxide, azo pigment and the blue or green pigment of phthalein one or more.
The present invention also provides the preparation method of described printing ink, and wherein, this method comprises and joins acrylic resin, polyamide resin and/or thermoprene in the solvent and stir; Add stopping composition, softening agent, pigment nano silicon and corundum powder afterwards and stir, add dispersion agent then and grind, obtain printing ink.
Among the present invention, the average particle diameter of described nano silicon and corundum powder can in very large range change; Under the preferable case, the average particle diameter of described nano silicon is the 1-100 nanometer; The average particle diameter of described corundum powder is the 0.1-10 micron; More preferably, the average particle diameter of described nano silicon is the 20-60 nanometer; The average particle diameter of described corundum powder is the 0.5-3 micron, glossiness is better after using the nano silicon of the average particle diameter in the above-mentioned scope and corundum powder can make ink printing, can also further improve the wear resisting property and the fire performance of printing ink simultaneously.
Among the present invention, the consumption of described acrylic resin, polyamide resin and/or thermoprene, solvent, stopping composition, softening agent, dispersion agent, pigment, nano silicon and corundum powder can in very large range change; Under the preferable case, with the gross weight that obtains printing ink is benchmark, the consumption of described acrylic resin is 20-50 weight %, the consumption of described polyamide resin and/or thermoprene is 2-10 weight %, the consumption of described solvent is 20-50 weight %, the consumption of described stopping composition is 3-10 weight %, described plasticizer dosage is 2-15 weight %, the consumption of described dispersion agent is 0.2-1 weight %, the consumption of described pigment is 5-15 weight %, the consumption of described nano silicon is 1-5 weight %, and the consumption of described corundum powder is 0.5-2 weight %; More preferably, with the gross weight that obtains printing ink is benchmark, the consumption of described acrylic resin is 25-45 weight %, the consumption of described polyamide resin and/or thermoprene is 4-8 weight %, the consumption of described solvent is 25-50 weight %, the consumption of described stopping composition is 4-8 weight %, described plasticizer dosage is 5-10 weight %, the consumption of described dispersion agent is 0.5-0.8 weight %, the consumption of described pigment is 8-12 weight %, the consumption of described nano silicon is 2-4 weight %, and the consumption of described corundum powder is 0.8-1.5 weight %.
The kind of described acrylic resin, polyamide resin, thermoprene, solvent, stopping composition, softening agent, dispersion agent and pigment is described in detail hereinbefore, no longer applies at this and states.
According to the present invention, the equipment of described stirring and condition are conventionally known to one of skill in the art, for example, the JSF-400 type stirrer that can use Jiangyin City company of diligent industry chemical machinery company limited to produce stirs, the temperature of described stirring is 40-70 ℃, the rotating speed of described stirring is 300-800 rev/min, and the time of described stirring is 0.5-1.5 hour; The equipment of described grinding and condition are conventionally known to one of skill in the art, for example, can grind in sand mill, and used grinding medium is the zirconium glass pearl, and diameter is the 0.4-0.8 millimeter, and the time of described grinding is 1-2 hour.
Below by specific embodiment the present invention is described in more details.
Embodiment 1
Present embodiment is used to illustrate printing-ink provided by the invention and preparation method thereof.
With 20 parts by weight of acrylic resins (Nanjing DSM resin company limited, B838), the polyamide resin of 10 weight parts (bright chemical plant, Wuxi company limited, 650), the pimelinketone of 30 weight parts, the ethanol of 10 weight parts, the lime carbonate of 10 weight parts, the dimethyl phthalate of 2 weight parts, the BYK110 dispersion agent of 1 weight part (BYK company), the carbon black of 14 weight parts (Degussa China Investment Ltd., FW200), the nano silicon of 1 weight part (Zibo Hai Nagaoke Materials Co., Ltd, HN, average particle diameter is 80 nanometers) and the corundum powder of 2 weight parts (the anti-material of sharp second micro mist of Zhengzhou moral company limited, average particle diameter is 10 microns) (Jiangyin City's duty is chemical machinery company limited already to put into stirrer, JSF-400) stir in, the temperature that stirs is 50 ℃, the rotating speed that stirs is 500 rev/mins, the time of stirring is 1 hour, is stirred the mixture; Stirring the mixture of to obtaining afterwards is put into sand mill, and (the dynamo-electric company limited of Chongqing HTC chemical industry grinds in SWM20), and used grinding medium is that diameter is 0.5 millimeter a zirconium glass pearl, and the time of grinding is 1 hour, obtains printing-ink A1.
Comparative Examples 1
With 20 parts by weight of acrylic resins (Nanjing DSM resin company limited, B838), the polyamide resin of 10 weight parts (bright chemical plant, Wuxi company limited, 650), the pimelinketone of 30 weight parts, the ethanol of 10 weight parts, the lime carbonate of 10 weight parts, the dimethyl phthalate of 2 weight parts, carbon black (the Degussa China Investment Ltd. of BYK110 dispersion agent of 1 weight part (BYK company) and 14 weight parts, FW200) put into stirrer (Jiangyin City diligent industry chemical machinery company limited, JSF-400) stir in, the temperature that stirs is 50 ℃, the rotating speed that stirs is 500 rev/mins, the time of stirring is 1 hour, is stirred the mixture; Stirring the mixture of to obtaining afterwards is put into sand mill, and (the dynamo-electric company limited of Chongqing HTC chemical industry grinds in SWM20), and grinding medium is that diameter is 0.5 millimeter a zirconium glass pearl, and the time of grinding is 1 hour, obtains reference printing-ink CA1.
Embodiment 2
Present embodiment is used to illustrate printing-ink provided by the invention and preparation method thereof.
With 50 parts by weight of acrylic resins (Nanjing DSM resin company limited, B838), the thermoprene of 2 weight parts (scientific ﹠ trading Co., Ltd. in the palm fibre of Shanghai, CK514), the ethanol of 10 weight parts, 12.3 the butylacetate of weight part, the butyl benzyl phthalate of 15 weight parts (FERRO company, Santicizer160), 0.2 the BYK180 dispersion agent of weight part (BYK company), the titanium dioxide of 5 weight parts (Ke Meiji company, CR826), the nano silicon of 5 weight parts (Zibo Hai Nagaoke Materials Co., Ltd, HN, average particle diameter is 10 nanometers) and the corundum powder of 0.5 weight part (the anti-material of sharp second micro mist of Zhengzhou moral company limited, average particle diameter is 0.2 micron) (Jiangyin City's duty is chemical machinery company limited already to put into stirrer, JSF-400) stir in, the temperature that stirs is 60 ℃, the rotating speed that stirs is 800 rev/mins, the time of stirring is 1 hour, is stirred the mixture; Stirring the mixture of to obtaining afterwards is put into sand mill, and (the dynamo-electric company limited of Chongqing HTC chemical industry grinds in SWM20), and grinding medium is that diameter is 0.5 millimeter a zirconium glass pearl, and the time of grinding is 1 hour, obtains printing-ink A2.
Embodiment 3
Present embodiment is used to illustrate printing-ink provided by the invention and preparation method thereof.
With 30 parts by weight of acrylic resins (Nanjing DSM resin company limited, B735), the polyamide resin of 7 weight parts (bright chemical plant, Wuxi company limited, 650), the Virahol of 10 weight parts, the butylacetate of 10 weight parts, the butanone of 20 weight parts, the lime carbonate of 4 weight parts, the dimethyl phthalate of 5 weight parts, 0.5 the BYK180 dispersion agent of weight part, the carbon black of 8 weight parts (Degussa China Investment Ltd., FW200), the nano silicon of 4 weight parts (Zibo Hai Nagaoke Materials Co., Ltd, HN, average particle diameter is 20 nanometers) and the corundum powder of 1.5 weight parts (the anti-material of sharp second micro mist of Zhengzhou moral company limited, average particle diameter is 0.5 micron) (Jiangyin City's duty is chemical machinery company limited already to put into stirrer, JSF-400) stir in, the temperature that stirs is 50 ℃, the rotating speed that stirs is 700 rev/mins, the time of stirring is 1 hour, is stirred the mixture; Stirring the mixture of to obtaining afterwards is put into sand mill, and (the dynamo-electric company limited of Chongqing HTC chemical industry grinds in SWM20), and grinding medium is that diameter is 0.5 millimeter a zirconium glass pearl, and the time of grinding is 1 hour, obtains printing-ink A3.
Embodiment 4
Present embodiment is used to illustrate printing-ink provided by the invention and preparation method thereof.
With 40 parts by weight of acrylic resins (Nanjing DSM resin company limited, B838), the polyamide resin of 2 weight parts (bright chemical plant, Wuxi company limited, 650), the thermoprene of 2 weight parts (scientific ﹠ trading Co., Ltd. in the palm fibre of Shanghai, CK514), the talcum powder of 8 weight parts, the butanols of 6 weight parts, the n-Butyl lactate of 6 weight parts, 10.2 the acetone of weight part, di(2-ethylhexyl)phosphate phenyl monooctyl ester (the FERRO company of 10 weight parts, Santicizer 141), 0.8 the BYK110 dispersion agent of weight part (BYK company), the carbon black of 12 weight parts (Degussa China Investment Ltd., Nerox505), the nano silicon of 2 weight parts (Zibo Hai Nagaoke Materials Co., Ltd, HN, average particle diameter is 60 nanometers) and the corundum powder of 0.8 weight part (the anti-material of sharp second micro mist of Zhengzhou moral company limited, average particle diameter is 3 microns) (Jiangyin City's duty is chemical machinery company limited already to put into stirrer, JSF-400) stir in, the temperature that stirs is 50 ℃, the rotating speed that stirs is 700 rev/mins, the time of stirring is 1 hour, is stirred the mixture; Stirring the mixture of to obtaining afterwards is put into sand mill, and (the dynamo-electric company limited of Chongqing HTC chemical industry grinds in SWM20), and grinding medium is that diameter is 0.5 millimeter a zirconium glass pearl, and the time of grinding is 1 hour, obtains printing-ink A4.
Embodiment 5-8
It is that 145 millimeters, width are that 45 millimeters, thickness are 2 millimeters ABS plastic plate (propylene-butadiene-styrene terpolymer) (Biyadi Co Ltd that the printing-ink A1-A4 that embodiment 1-4 is made is printed on length respectively, 757) on, at room temperature dry 24 hours, detect glossiness, wear resisting property and sticking power after printing ink A1-A4 prints then in accordance with the following methods respectively:
Glossiness detects
Use multi-angle glossiness survey meter (BYK company, A-4430 type) to detect the reflection light quantity of the ABS plastic plate that has printed printing ink A1-A4 respectively, the result is as shown in table 1.
Wear resisting property detects
The come off ratio of area and ink lay area of the surface of the ABS plastic plate that uses 320 order sand paper to rub respectively to have printed printing ink A1-A4 10 times, gauging surface ink lay, the result is as shown in table 1.
The sticking power test
ABS plastic plate sample after 100 printings is placed on the test board, using cutting knife to draw length on the same direction of sample surfaces is that 20 millimeters, spacing are 11 lines of 1 millimeter, and intersecting in 90 degree directions then, to draw length be that 20 millimeters, spacing are 11 lines of 1 millimeter; Adhesive tape (Permacell-99) centre of 75 millimeters long carefully is placed on draws on the good grid and the ruling horizontal direction, make adhesive tape cover grid fully, use the eraser wiping then, adhesive tape is well contacted fully with grid; Whether 30-90 drags adhesive tape from adhesive tape is monolateral rapidly with 180 ° of horizontal directions after second, observe to have to come off, and coming off as nothing illustrates that product is qualified.
Comparative Examples 2
Detect glossiness, wear resisting property and sticking power after the reference printing-ink CA1 printing that Comparative Examples 1 obtains respectively according to the described method of embodiment 5-8, the result is as shown in table 1.
Embodiment 9-12
The printing-ink A1-A4 that embodiment 1-4 is obtained carries out fire performance and detects respectively, and concrete steps are: printing ink is tiled on long 150 millimeters, wide 100 millimeters drawdown sheet, forms thickness and be 2 millimeters thin layer, at room temperature dry 12 hours then; Scrape the next section thin layer, afterwards the thin layer that scrapes is carried out the ignition experiment, the result is as shown in table 2.
Comparative Examples 3
The fire performance that detects the reference printing-ink that Comparative Examples 1 obtains according to the described method of embodiment 9-12 detects, and the result is as shown in table 2.
Table 1
| The embodiment numbering | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Comparative Examples 2 |
| The printing ink numbering | A1 | A2 | A3 | A4 | CA1 |
| Reflection light quantity | 110.5％ | 114.3％ | 117.2％ | 122.6％ | 87％ |
| Wear resisting property | 2% comes off | 2% comes off | 1.5% comes off | 1.6% comes off | 5% comes off |
| The sticking power test | Qualification rate 99% | Qualification rate 99% | Qualification rate 100% | Qualification rate 100% | Qualification rate 99% |
As can be seen from Table 1, compare with the reference printing-ink CA1 that Comparative Examples 1 obtains, the reflection light quantity after the printing-ink A1-A4 printing that embodiment of the invention 1-4 obtains significantly improves, and illustrates that the luminance brightness behind the ink printing provided by the invention is better; In addition, compare with the reference printing-ink CA1 that Comparative Examples 1 obtains, significant raising of wear resisting property and sticking power after the printing-ink A1-A4 printing that embodiment of the invention 1-4 obtains also can reach requirement.
Table 2
| The embodiment numbering | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Comparative Examples 3 |
| The printing ink numbering | A1 | A2 | A3 | A4 | CA1 |
| Fire performance | ◎ | ◎ | ◎ | ◎ | △ |
In the table 2, fire performance:
◎: lighting a fire took fire after 15 seconds, and burning slowly and do not have a flare;
Zero: lighting a fire took fire after 10 seconds, and burning slowly and do not have a flare;
△: lighting a fire took fire in 3 seconds, and burning is violent and flare is vigorous and be accompanied by the sound of whip.
As can be seen from Table 2, compare with the reference printing-ink CA1 that Comparative Examples 1 obtains, the fire performance of the printing-ink A1-A4 that embodiment of the invention 1-4 obtains improves significantly.
Claims (8)
1. printing-ink, this printing ink contains acrylic resin, polyamide resin and/or thermoprene, solvent, stopping composition, softening agent, dispersion agent and pigment, it is characterized in that, this printing ink also contains nano silicon and corundum powder, gross weight with printing ink is a benchmark, the content of described acrylic resin is 20-50 weight %, the content of described polyamide resin and/or thermoprene is 2-10 weight %, the content of described solvent is 20-60 weight %, the content of described stopping composition is 3-10 weight %, the content of described softening agent is 2-15 weight %, the content of described dispersion agent is 0.2-1 weight %, the content of described pigment is 5-15 weight %, and the content of described nano silicon is 1-5 weight %, and the content of described corundum powder is 0.5-2 weight %.
2. printing ink according to claim 1, wherein, gross weight with printing ink is a benchmark, the content of described acrylic resin is 25-45 weight %, the content of described polyamide resin and/or thermoprene is 4-8 weight %, the content of described solvent is 25-50 weight %, the content of described stopping composition is 4-8 weight %, the content of described softening agent is 5-10 weight %, the content of described dispersion agent is 0.5-0.8 weight %, the content of described pigment is 8-12 weight %, and the content of described nano silicon is 2-4 weight %, and the content of described corundum powder is 0.8-1.5 weight %.
3. according to the printing ink described in claim 1 or 2, wherein, the average particle diameter of described nano silicon is the 1-100 nanometer; The average particle diameter of described corundum powder is the 0.1-10 micron.
4. according to the printing ink described in claim 1 or 2, wherein, described solvent is one or more in alcoholic solvent, ester solvent, ketone solvent and the ether solvents.
5. printing ink according to claim 4, wherein, described solvent is alcoholic solvent, ester solvent and ketone solvent, and with respect to the alcoholic solvent of 100 weight parts, the content of described ester solvent is the 100-200 weight part, and the content of described ketone solvent is the 100-250 weight part.
6. according to the printing ink described in claim 1 or 2, wherein, described stopping composition is one or more in lime carbonate, barium sulfate, talcum powder and the mica powder; Described softening agent is one or more in dimethyl phthalate, butyl benzyl phthalate and the di(2-ethylhexyl)phosphate phenyl monooctyl ester; Described pigment is one or more in the blue or green pigment of carbon black, titanium dioxide, azo pigment and phthalein.
7. the preparation method of the described printing ink of claim 1 is characterized in that, this method comprises and joins acrylic resin, polyamide resin and/or thermoprene in the solvent and stir; Add stopping composition afterwards, softening agent, pigment, nano silicon and corundum powder also stir, adding dispersion agent then grinds, obtain printing ink, with the gross weight that obtains printing ink is benchmark, the consumption of described acrylic resin is 20-50 weight %, the consumption of described polyamide resin and/or thermoprene is 2-10 weight %, the consumption of described solvent is 20-50 weight %, the consumption of described stopping composition is 3-10 weight %, described plasticizer dosage is 2-15 weight %, the consumption of described dispersion agent is 0.2-1 weight %, the consumption of described pigment is 5-15 weight %, the consumption of described nano silicon is 1-5 weight %, and the consumption of described corundum powder is 0.5-2 weight %.
8. method according to claim 7, wherein, the average particle diameter of described nano silicon is the 1-100 nanometer; The average particle diameter of described corundum powder is the 0.1-10 micron.
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| CN102408779B (en) * | 2010-09-24 | 2013-10-02 | 比亚迪股份有限公司 | Printing ink composition and preparation method thereof and stainless steel workpiece |
| JP6043659B2 (en) | 2013-03-14 | 2016-12-14 | 株式会社リコー | Ink for ink jet recording, ink cartridge using the ink, ink jet recording apparatus, ink jet recording method, and ink recorded matter |
| CN104592809A (en) * | 2015-02-04 | 2015-05-06 | 韦棋 | High-adhesive force printing ink |
| CN108841248A (en) * | 2018-05-25 | 2018-11-20 | 安徽猛牛彩印包装有限公司 | A kind of printing ink of wear resistant fluorescent anti-counterfeiting performance |
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| CN1458207A (en) * | 2003-03-11 | 2003-11-26 | 王崇高 | Water flame-retardant paint |
| EP1634929A1 (en) * | 2004-09-13 | 2006-03-15 | DSM IP Assets B.V. | Objet comprising a non-insulative coating |
| WO2006032778A1 (en) * | 2004-09-21 | 2006-03-30 | Gti Process | Method for making anti-graffiti coatings |
| CN101074340A (en) * | 2007-06-25 | 2007-11-21 | 沈阳市航达科技有限责任公司 | Flexible ceramic coating and preparation method thereof |
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Patent Citations (4)
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|---|---|---|---|---|
| CN1458207A (en) * | 2003-03-11 | 2003-11-26 | 王崇高 | Water flame-retardant paint |
| EP1634929A1 (en) * | 2004-09-13 | 2006-03-15 | DSM IP Assets B.V. | Objet comprising a non-insulative coating |
| WO2006032778A1 (en) * | 2004-09-21 | 2006-03-30 | Gti Process | Method for making anti-graffiti coatings |
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