CN105178105A - Flame-retardant corrugated paperboard - Google Patents
Flame-retardant corrugated paperboard Download PDFInfo
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- CN105178105A CN105178105A CN201510545824.1A CN201510545824A CN105178105A CN 105178105 A CN105178105 A CN 105178105A CN 201510545824 A CN201510545824 A CN 201510545824A CN 105178105 A CN105178105 A CN 105178105A
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Abstract
The invention relates to a corrugated paperboard and provides a flame-retardant corrugated paperboard with insusceptibility to moisture absorption, good flame-retardant effect and high degree of stiffness. The flame-retardant corrugated paperboard comprises a corrugated paperboard body, wherein the corrugated paperboard body comprises the following raw materials by weight: 300 to 400 parts of corrugated paper, 10 to 18 parts of sodium carbonate, 25 to 30 parts of aromatic epoxy resin, 13 to 20 parts of an epoxy resin curing agent, 20 to 30 parts of zinc borate, 3 to 7 parts of acetyl triethyl citrate, 50 to 60 parts of asbestos powder, 70 to 80 parts of polyvinyl chloride, 10 to 20 parts of polyethylene wax, 20 to 25 parts of starch, 10 to 15 parts of sodium dodecylbenzene sulfonate, 10 to 15 parts of silicone oil, 12 to 17 parts of rosin and 18 to 22 parts of talcum powder.
Description
Technical field
The present invention relates to a kind of corrugated board, particularly relate to a kind of fire-retarded corrugated paper plate.
Background technology
Corrugated paper is the plate object be bonded by sheet lining and the corrugated paper of waveform being processed by corrugated roller and formed, generally be divided into single wall corrugated board and double-layer corrugated cardboard two class, and corrugated paper has, and cost is low, quality light, processing is easy, intensity is large, printing adaptability sample is excellent, store the advantages such as convenient in carrying.At present, corrugated paper on the market all can not carry out effectively fire-retardant with fire prevention, in external environment, corrugated paper is easy to again, because of fortuitous event, the phenomenons such as on fire or spontaneous combustion occur, especially be in the environment of high temperature at corrugated paper, have especially and very large may occur corrugated paper combustion phenomena, increase the use safety of corrugated paper greatly, be unfavorable for the use of user to corrugated paper.
Along with the progress of science and technology, people have carried out further research to the fire retardant performance of corrugated paper, both at home and abroad main research two aspects, first flame retardant effect, as cardboard afterflame time, continuously burn time, char length and all will be up to state standards; Its two be the carton humidity resistance with flame retardant effect to reach be applicable to producing, application aspect.Show according to data at home and abroad, Many researchers solves first problem, the fire resistant fluid of good flame retardation effect has a lot, can be well fire-retardant, but the displays such as experiment and data, they all can not meet the condition of second aspect, by these products application to corrugated board all can occur at high humidity the performance of (more than 70%) cardboard very large receive impact, there is the phenomenon of the serious moisture absorption, the moisture sucked almost can be extruded with hand, does not meet China's climate characteristic.
Summary of the invention
Therefore, for above content, the invention provides a kind of not easily moisture absorption, good flame retardation effect, fire-retarded corrugated paper plate that deflection is high.
For achieving the above object, the present invention is achieved by the following technical solutions: a kind of fire-retarded corrugated paper plate, comprise corrugated board body, described corrugated board body comprises each raw material of following weight portion: corrugated paper 300 ~ 400 weight portion, sodium carbonate 10 ~ 18 weight portion, aromatic epoxy resin 25 ~ 30 weight portion, epoxy curing agent 13 ~ 20 weight portion, Firebrake ZB 20 ~ 30 weight portion, acetyl triethyl citrate 3 ~ 7 weight portion, flake asbestos 50 ~ 60 weight portion, polyvinyl chloride 70 ~ 80 weight portion, Tissuemat E 10 ~ 20 weight portion, starch 20 ~ 25 weight portion, neopelex 10 ~ 15 weight portion, silicone oil 10 ~ 15 weight portion, rosin 12 ~ 17 weight portion, talcum powder 18 ~ 22 weight portion.
Further improvement is: described corrugated board body comprises each raw material of following weight portion: corrugated paper 350 weight portion, sodium carbonate 12 ~ 18 weight portion, aromatic epoxy resin 27 ~ 30 weight portion, epoxy curing agent 19 ~ 20 weight portion, Firebrake ZB 26 ~ 30 weight portion, acetyl triethyl citrate 5 ~ 7 weight portion, flake asbestos 57 ~ 60 weight portion, polyvinyl chloride 77 ~ 80 weight portion, Tissuemat E 18 ~ 20 weight portion, starch 21 ~ 25 weight portion, neopelex 12 ~ 15 weight portion, silicone oil 13 ~ 15 weight portion, rosin 14 ~ 17 weight portion, talcum powder 19 ~ 22 weight portion.
Further improvement is: described corrugated board body comprises each raw material of following weight portion: corrugated paper 400 weight portion, sodium carbonate 15 weight portion, aromatic epoxy resin 28 weight portion, epoxy curing agent 20 weight portion, Firebrake ZB 27 weight portion, acetyl triethyl citrate 6 weight portion, flake asbestos 58 weight portion, polyvinyl chloride 78 weight portion, Tissuemat E 19 weight portion, starch 25 weight portion, neopelex 14 weight portion, silicone oil 14 weight portion, rosin 15 weight portion, talcum powder 20 weight portion.
A kind of preparation method of fire-retarded corrugated paper plate, the leaching one corrugated board being carried out in long vehicle groove a normal temperature is rolled, formula in described groove is: with corrugated board body 300 ~ 400 parts by weight, sodium carbonate 12 ~ 18 weight portion, aromatic epoxy resin 27 ~ 30 weight portion, epoxy curing agent 19 ~ 20 weight portion, Firebrake ZB 26 ~ 30 weight portion, acetyl triethyl citrate 5 ~ 7 weight portion, flake asbestos 57 ~ 60 weight portion, polyvinyl chloride 77 ~ 80 weight portion, Tissuemat E 18 ~ 20 weight portion, starch 21 ~ 25 weight portion, neopelex 12 ~ 15 weight portion, silicone oil 13 ~ 15 weight portion, rosin 14 ~ 17 weight portion, talcum powder 19 ~ 22 weight portion, the speed of a motor vehicle of described long vehicle controls at 10 ~ 20m/min, then carries out baking and curing process to padding the corrugated board processed.
Further improvement is: described drying and processing temperature controls at 160 ~ 168 DEG C.
By adopting preceding solution, the invention has the beneficial effects as follows: fire-retarded corrugated paper plate of the present invention, comprise corrugated board body, process is rolled by the leaching one corrugated board body being carried out in long vehicle groove a normal temperature, corrugated board body is made to wrap each material of flame-proof damp-proof fully, then carry out baking and curing process again, the obtained corrugated board not easily moisture absorption, good flame retardation effect, deflection is high.The present invention adopts new material as the moisture retardant agent of corrugated board body, each raw material of formula is: corrugated paper 300 ~ 400 weight portion, sodium carbonate 10 ~ 18 weight portion, aromatic epoxy resin 25 ~ 30 weight portion, epoxy curing agent 13 ~ 20 weight portion, Firebrake ZB 20 ~ 30 weight portion, acetyl triethyl citrate 3 ~ 7 weight portion, flake asbestos 50 ~ 60 weight portion, polyvinyl chloride 70 ~ 80 weight portion, Tissuemat E 10 ~ 20 weight portion, starch 20 ~ 25 weight portion, neopelex 10 ~ 15 weight portion, silicone oil 10 ~ 15 weight portion, rosin 12 ~ 17 weight portion, talcum powder 18 ~ 22 weight portion, each raw material components carries out matched combined reaction, thus play effect of flame-proof damp-proof, after tested, at there was dampness in the air degree higher than under the environment of 80%, the corrugated paper that the limit pressure strength ratio of fire-retarded corrugated paper plate of the present invention is common improves 10%, increases the safety in utilization of this corrugated paper greatly.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how application technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technological means adopted in embodiment is well known to those skilled in the art, the reagent adopted and product be also can business obtain.Source, the trade name of agents useful for same and be necessary to list its constituent person, all indicate when occurring first.
Embodiment one
A kind of fire-retarded corrugated paper plate, comprise corrugated board body, described corrugated board body comprises each raw material of following weight portion: corrugated paper 300 weight portion, sodium carbonate 10 weight portion, aromatic epoxy resin 25 weight portion, epoxy curing agent 13 weight portion, Firebrake ZB 20 weight portion, acetyl triethyl citrate 3 weight portion, flake asbestos 50 weight portion, polyvinyl chloride 70 weight portion, Tissuemat E 10 weight portion, starch 20 weight portion, neopelex 10 weight portion, silicone oil 10 weight portion, rosin 12 weight portion, talcum powder 18 weight portion.
Its preparation method is, the leaching one corrugated board being carried out in long vehicle groove a normal temperature is rolled, formula in described groove is: with corrugated board body 300 parts by weight, sodium carbonate 10 weight portion, aromatic epoxy resin 25 weight portion, epoxy curing agent 13 weight portion, Firebrake ZB 20 weight portion, acetyl triethyl citrate 3 weight portion, flake asbestos 50 weight portion, polyvinyl chloride 70 weight portion, Tissuemat E 10 weight portion, starch 20 weight portion, neopelex 10 weight portion, silicone oil 10 weight portion, rosin 12 weight portion, talcum powder 18 weight portion; The speed of a motor vehicle of described long vehicle controls at 10m/min, and then carry out baking and curing process to padding the corrugated board processed, described baking and curing treatment temperature controls at 160 ~ 168 DEG C.
Embodiment two
A kind of fire-retarded corrugated paper plate, comprise corrugated board body, described corrugated board body comprises each raw material of following weight portion: described corrugated board body comprises each raw material of following weight portion: corrugated paper 350 weight portion, sodium carbonate 12 weight portion, aromatic epoxy resin 27 weight portion, epoxy curing agent 19 weight portion, Firebrake ZB 26 weight portion, acetyl triethyl citrate 5 weight portion, flake asbestos 57 weight portion, polyvinyl chloride 77 weight portion, Tissuemat E 18 weight portion, starch 21 weight portion, neopelex 12 weight portion, silicone oil 13 weight portion, rosin 14 weight portion, talcum powder 19 weight portion.
Its preparation method, the leaching one corrugated board being carried out in long vehicle groove a normal temperature is rolled, formula in described groove is: with corrugated board body 350 parts by weight, sodium carbonate 12 weight portion, aromatic epoxy resin 27 weight portion, epoxy curing agent 19 weight portion, Firebrake ZB 26 weight portion, acetyl triethyl citrate 5 weight portion, flake asbestos 57 weight portion, polyvinyl chloride 77 weight portion, Tissuemat E 18 weight portion, starch 21 weight portion, neopelex 12 weight portion, silicone oil 13 weight portion, rosin 14 weight portion, talcum powder 19 weight portion; The speed of a motor vehicle of described long vehicle controls at 15m/min, and then carry out baking and curing process to padding the corrugated board processed, described drying and processing temperature controls at 164 DEG C.
Embodiment three
A kind of fire-retarded corrugated paper plate, comprise corrugated board body, described corrugated board body comprises each raw material of following weight portion: corrugated paper 400 weight portion, sodium carbonate 15 weight portion, aromatic epoxy resin 28 weight portion, epoxy curing agent 20 weight portion, Firebrake ZB 27 weight portion, acetyl triethyl citrate 6 weight portion, flake asbestos 58 weight portion, polyvinyl chloride 78 weight portion, Tissuemat E 19 weight portion, starch 25 weight portion, neopelex 14 weight portion, silicone oil 14 weight portion, rosin 15 weight portion, talcum powder 20 weight portion.
Its preparation method is, the leaching one corrugated board being carried out in long vehicle groove a normal temperature is rolled, formula in described groove is: with corrugated board body 400 parts by weight, sodium carbonate 15 weight portion, aromatic epoxy resin 28 weight portion, epoxy curing agent 20 weight portion, Firebrake ZB 27 weight portion, acetyl triethyl citrate 6 weight portion, flake asbestos 58 weight portion, polyvinyl chloride 78 weight portion, Tissuemat E 19 weight portion, starch 25 weight portion, neopelex 14 weight portion, silicone oil 14 weight portion, rosin 15 weight portion, talcum powder 20 weight portion; The speed of a motor vehicle of described long vehicle controls at 18m/min, and then carry out baking and curing process to padding the corrugated board processed, described drying and processing temperature controls at 166 DEG C.
Embodiment four
A kind of fire-retarded corrugated paper plate, comprise corrugated board body, described corrugated board body comprises each raw material of following weight portion: corrugated paper 400 weight portion, sodium carbonate 18 weight portion, aromatic epoxy resin 30 weight portion, epoxy curing agent 20 weight portion, Firebrake ZB 30 weight portion, acetyl triethyl citrate 7 weight portion, flake asbestos 60 weight portion, polyvinyl chloride 80 weight portion, Tissuemat E 20 weight portion, starch 25 weight portion, neopelex 15 weight portion, silicone oil 15 weight portion, rosin 17 weight portion, talcum powder 22 weight portion.
Its preparation method, the leaching one corrugated board being carried out in long vehicle groove a normal temperature is rolled, formula in described groove is: with corrugated board body 400 parts by weight, sodium carbonate 18 weight portion, aromatic epoxy resin 30 weight portion, epoxy curing agent 20 weight portion, Firebrake ZB 30 weight portion, acetyl triethyl citrate 7 weight portion, flake asbestos 60 weight portion, polyvinyl chloride 80 weight portion, Tissuemat E 20 weight portion, starch 25 weight portion, neopelex 15 weight portion, silicone oil 15 weight portion, rosin 17 weight portion, talcum powder 22 weight portion; The speed of a motor vehicle of described long vehicle controls at 20m/min, and then carry out baking and curing process to padding the corrugated board processed, described drying and processing temperature controls at 168 DEG C.
Fire-retarded corrugated paper plate of the present invention, comprise corrugated board body, process is rolled by the leaching one corrugated board body being carried out in long vehicle groove a normal temperature, corrugated board body is made to wrap each material of flame-proof damp-proof fully, then carry out baking and curing process again, the obtained corrugated board not easily moisture absorption, good flame retardation effect, deflection is high.The present invention adopts new material as the moisture retardant agent of corrugated board body, each raw material of formula is: corrugated paper 300 ~ 400 weight portion, sodium carbonate 10 ~ 18 weight portion, aromatic epoxy resin 25 ~ 30 weight portion, epoxy curing agent 13 ~ 20 weight portion, Firebrake ZB 20 ~ 30 weight portion, acetyl triethyl citrate 3 ~ 7 weight portion, flake asbestos 50 ~ 60 weight portion, polyvinyl chloride 70 ~ 80 weight portion, Tissuemat E 10 ~ 20 weight portion, starch 20 ~ 25 weight portion, neopelex 10 ~ 15 weight portion, silicone oil 10 ~ 15 weight portion, rosin 12 ~ 17 weight portion, talcum powder 18 ~ 22 weight portion, each raw material components carries out matched combined reaction, thus play effect of flame-proof damp-proof, after tested, at there was dampness in the air degree higher than under the environment of 80%, the corrugated paper that the limit pressure strength ratio of fire-retarded corrugated paper plate of the present invention is common improves 10%, increases the safety in utilization of this corrugated paper greatly.
Above, be only the embodiment utilizing this origination techniques content, the modification that any those skilled in the art use this creation to do, change, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (5)
1. a fire-retarded corrugated paper plate, comprise corrugated board body, it is characterized in that, described corrugated board body comprises each raw material of following weight portion: corrugated paper 300 ~ 400 weight portion, sodium carbonate 10 ~ 18 weight portion, aromatic epoxy resin 25 ~ 30 weight portion, epoxy curing agent 13 ~ 20 weight portion, Firebrake ZB 20 ~ 30 weight portion, acetyl triethyl citrate 3 ~ 7 weight portion, flake asbestos 50 ~ 60 weight portion, polyvinyl chloride 70 ~ 80 weight portion, Tissuemat E 10 ~ 20 weight portion, starch 20 ~ 25 weight portion, neopelex 10 ~ 15 weight portion, silicone oil 10 ~ 15 weight portion, rosin 12 ~ 17 weight portion, talcum powder 18 ~ 22 weight portion.
2. fire-retarded corrugated paper plate according to claim 1, it is characterized in that: described corrugated board body comprises each raw material of following weight portion: corrugated paper 350 weight portion, sodium carbonate 12 ~ 18 weight portion, aromatic epoxy resin 27 ~ 30 weight portion, epoxy curing agent 19 ~ 20 weight portion, Firebrake ZB 26 ~ 30 weight portion, acetyl triethyl citrate 5 ~ 7 weight portion, flake asbestos 57 ~ 60 weight portion, polyvinyl chloride 77 ~ 80 weight portion, Tissuemat E 18 ~ 20 weight portion, starch 21 ~ 25 weight portion, neopelex 12 ~ 15 weight portion, silicone oil 13 ~ 15 weight portion, rosin 14 ~ 17 weight portion, talcum powder 19 ~ 22 weight portion.
3. fire-retarded corrugated paper plate according to claim 1, is characterized in that: described corrugated board body comprises each raw material of following weight portion: corrugated paper 400 weight portion, sodium carbonate 15 weight portion, aromatic epoxy resin 28 weight portion, epoxy curing agent 20 weight portion, Firebrake ZB 27 weight portion, acetyl triethyl citrate 6 weight portion, flake asbestos 58 weight portion, polyvinyl chloride 78 weight portion, Tissuemat E 19 weight portion, starch 25 weight portion, neopelex 14 weight portion, silicone oil 14 weight portion, rosin 15 weight portion, talcum powder 20 weight portion.
4. the preparation method of a fire-retarded corrugated paper plate, it is characterized in that: the leaching one corrugated board being carried out in long vehicle groove a normal temperature is rolled, formula in described groove is: with corrugated board body 300 ~ 400 parts by weight, sodium carbonate 12 ~ 18 weight portion, aromatic epoxy resin 27 ~ 30 weight portion, epoxy curing agent 19 ~ 20 weight portion, Firebrake ZB 26 ~ 30 weight portion, acetyl triethyl citrate 5 ~ 7 weight portion, flake asbestos 57 ~ 60 weight portion, polyvinyl chloride 77 ~ 80 weight portion, Tissuemat E 18 ~ 20 weight portion, starch 21 ~ 25 weight portion, neopelex 12 ~ 15 weight portion, silicone oil 13 ~ 15 weight portion, rosin 14 ~ 17 weight portion, talcum powder 19 ~ 22 weight portion, the speed of a motor vehicle of described long vehicle controls at 10 ~ 20m/min, then carries out baking and curing process to padding the corrugated board processed.
5. the preparation method of fire-retarded corrugated paper plate according to claim 4, is characterized in that: described baking and curing treatment temperature controls at 160 ~ 168 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510545824.1A CN105178105A (en) | 2015-08-31 | 2015-08-31 | Flame-retardant corrugated paperboard |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510545824.1A CN105178105A (en) | 2015-08-31 | 2015-08-31 | Flame-retardant corrugated paperboard |
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| CN105178105A true CN105178105A (en) | 2015-12-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510545824.1A Pending CN105178105A (en) | 2015-08-31 | 2015-08-31 | Flame-retardant corrugated paperboard |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106320055A (en) * | 2016-08-29 | 2017-01-11 | 苏州市炫之彩包装有限公司 | Formula of environment-friendly packaging box |
| CN107604744A (en) * | 2017-08-26 | 2018-01-19 | 蚌埠申徽彩色印刷包装有限公司 | A kind of corrugated paper additives used for producing and preparation method thereof |
| CN107858864A (en) * | 2017-10-29 | 2018-03-30 | 贵州铜仁华毅新型材料科技有限公司 | A kind of fire-retardant honeycomb paper core and preparation method thereof |
| CN110804896A (en) * | 2019-11-13 | 2020-02-18 | 鲍双铭 | Corrugated paper pulp with waterproof and fireproof characteristics |
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| US20030215602A1 (en) * | 2002-02-26 | 2003-11-20 | Anders Andersson | Method and device for producing a multi-ply web of flexible material, such as paper and nonwoven, and multi-ply material and product produced by the method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106320055A (en) * | 2016-08-29 | 2017-01-11 | 苏州市炫之彩包装有限公司 | Formula of environment-friendly packaging box |
| CN107604744A (en) * | 2017-08-26 | 2018-01-19 | 蚌埠申徽彩色印刷包装有限公司 | A kind of corrugated paper additives used for producing and preparation method thereof |
| CN107858864A (en) * | 2017-10-29 | 2018-03-30 | 贵州铜仁华毅新型材料科技有限公司 | A kind of fire-retardant honeycomb paper core and preparation method thereof |
| CN110804896A (en) * | 2019-11-13 | 2020-02-18 | 鲍双铭 | Corrugated paper pulp with waterproof and fireproof characteristics |
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Application publication date: 20151223 |