CN103805074B - Nano palygorskite-modified flame-retardant adhesive - Google Patents
Nano palygorskite-modified flame-retardant adhesive Download PDFInfo
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- CN103805074B CN103805074B CN201410057022.1A CN201410057022A CN103805074B CN 103805074 B CN103805074 B CN 103805074B CN 201410057022 A CN201410057022 A CN 201410057022A CN 103805074 B CN103805074 B CN 103805074B
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- palygorskite
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 27
- 230000001070 adhesive Effects 0.000 title claims abstract description 15
- 239000000853 adhesive Substances 0.000 title claims abstract description 14
- DGMCGTFMFPEQLT-UHFFFAOYSA-M aluminum;magnesium;silicon;hydroxide;tetradecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.[OH-].[Mg].[Mg].[Al].[Al].[Si].[Si].[Si].[Si] DGMCGTFMFPEQLT-UHFFFAOYSA-M 0.000 claims abstract description 15
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 12
- 229920000570 polyether Polymers 0.000 claims abstract description 12
- 229920005862 polyol Polymers 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 7
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- HPSUPGAVFFFPMQ-UHFFFAOYSA-N 1,2,3,4,6,7,10-heptachlorododecane Chemical compound CCC(Cl)CCC(Cl)C(Cl)CC(Cl)C(Cl)C(Cl)CCl HPSUPGAVFFFPMQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000005576 amination reaction Methods 0.000 claims abstract description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052796 boron Inorganic materials 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims abstract description 4
- 239000010433 feldspar Substances 0.000 claims abstract description 4
- 239000011521 glass Substances 0.000 claims abstract description 4
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 4
- 239000003549 soybean oil Substances 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 4
- 150000003918 triazines Chemical class 0.000 claims abstract description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 230000004048 modification Effects 0.000 claims description 17
- 238000006011 modification reaction Methods 0.000 claims description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRZGZGXXONWBRA-UHFFFAOYSA-N 1,4-bis(ethenyl)benzene;2-(phenylmethoxymethyl)oxirane;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=C(C=C)C=C1.C1OC1COCC1=CC=CC=C1 KRZGZGXXONWBRA-UHFFFAOYSA-N 0.000 claims description 6
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N furane Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- 229960001735 pentaerythritol Drugs 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000001264 neutralization Effects 0.000 claims description 3
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N tributyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 15
- 231100000053 low toxicity Toxicity 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 3
- 239000000779 smoke Substances 0.000 abstract description 2
- 230000001629 suppression Effects 0.000 abstract description 2
- 230000003712 anti-aging Effects 0.000 abstract 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- 239000007849 furan resin Substances 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 abstract 1
- 238000004513 sizing Methods 0.000 description 14
- 235000019504 cigarettes Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- -1 2 parts Substances 0.000 description 1
- 101710042989 SHMT2 Proteins 0.000 description 1
- 230000003078 antioxidant Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000004450 types of analysis Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Abstract
The invention discloses a nano palygorskite-modified flame-retardant adhesive which consists of the following raw materials in parts by weight: 100-150 parts of styrene, 50-80 parts of ethyl methacrylate, 10-15 parts of pentaerythritol, 5-8 parts of furan resin, 10-15 parts of epoxypropane butyl ether, 10-15 parts of chloroprene rubber, 1-3 parts of boron powder, 5-10 parts of bisphenol A epoxy resin, 5-8 parts of epoxidized soybean oil, 15-20 parts of nano palygorskite, 8-10 parts of nano feldspar powder, 2-4 parts of titanium dioxide, 2-3 parts of chlorinated paraffin, 1-3 parts of glass powder, 2-3 parts of magnesium oxide, 15-20 parts of flame-retardant polyether polyol, 5-8 parts of lignin, 3-5 parts of amination triazine salt, 0.5-0.8 part of dibutyltin dilaurate, 0.3-0.5 part of phosphoric acid, 1-2 parts of antioxidant 1076, 2-3 parts of anti-aging agent MB, 1-2 parts of accelerant CBS, 3-5 parts of titanate coupling agent and 3-5 parts of modified tree ash. The adhesive disclosed by the invention has the advantages of excellent adhesion, flame retardance, smoke suppression, low toxicity, good storage stability and the like.
Description
Technical field
The present invention relates to sizing agent technical field, particularly relate to a kind of flame-retardant adhesive of nanometer palygorskite modification.
Background technology
Along with the high stratification of building, automotive light weight technology, electrical equipment high zinc foods, furniture are superior, the development of industrial large-sizedization, sizing agent has obtained and has applied increasingly widely in modern industry field and daily life, but most of sizing agent is more inflammable, there is fire hazard, simultaneously, also can produce smog and poison gas during sizing agent burning, environment and the person are all impacted.Existing market being in great demand for flame-retardant adhesive, for the research in this field or little, sizing agent belongs to macromolecular compound, meets the general condition of superpolymer burning, if without fire-retardant finish, just cannot use some special dimension.Therefore, research and development have fire-retardant, press down cigarette, one of low toxicity or the nontoxic sizing agent focus direction having become development of new sizing agent.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of very strong adhesiveproperties, fire-retardant of having is provided
Property, press down the flame-retardant adhesive of nanometer palygorskite modification of cigarette, low toxicity, excellent storage stability.
The present invention adopts following technical scheme to achieve these goals:
A kind of flame-retardant adhesive of nanometer palygorskite modification, be made up of the raw material of following weight part: vinylbenzene 100-150 part, β-dimethyl-aminoethylmethacrylate 50-80 part, tetramethylolmethane 10-15 part, furane resin 5-8 part, epoxy propane butyl ether 10-15 part, chloroprene rubber 10-15 part, boron powder 1-3 part, bisphenol A epoxide resin 5-10 part, epoxy soybean oil 5-8 part, nanometer palygorskite 15-20 part, nanometer Feldspar Powder 8-10 part, titanium dioxide 2-4 part, clorafin 2-3 part, glass powder 1-3 part, magnesium oxide 2-3 part, flame retardant polyether polyol 15-20 part, xylogen 5-8 part, amination triazine salt 3-5 part, dibutyl tin laurate 0.5-0.8 part, phosphoric acid 0.3-0.5 part, antioxidant 1076 1-2 part, antioxidant MB 2-3 part, accelerator CBS 1-2 part, titanate coupling agent 3-5 part, modification tree ash 3-5 part.
Described flame retardant polyether polyol be halogenated polyether polyvalent alcohol, phenol polyvalent alcohol one or both.
Described modification tree ash is prepared by following methods: first use 10-15% salt acid soak tree ash 3-5h, then clean with deionized water wash, 3-5h is soaked again with 10-13% sodium hydroxide solution, with deionized water wash to neutral, dry, add be equivalent to tree ash weight 2-4% wooden sodium sulfonate, the peregal of 1-3%, the tributyl citrate of 2-4%, high speed 1300-1500 rev/min stir 1-3h, pulverize grind to form ultrafine powder.
The preparation method of the flame-retardant adhesive of described nanometer palygorskite modification, comprises the following steps:
(1) by above-mentioned weight ratio, vinylbenzene, β-dimethyl-aminoethylmethacrylate, tetramethylolmethane, furane resin, epoxy propane butyl ether, chloroprene rubber, bisphenol A epoxide resin, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid are added reactor and are heated to 100-120 DEG C, high-speed stirring 1-2h;
(2) other material is mixed with reactant in step (1), stir 30-50min, be cooled to normal temperature, obtain finished product, pack.
Compared with the prior art, beneficial effect of the present invention is as follows:
The present invention is by adding nanometer palygorskite and flame retardant polyether polyol in sizing agent, and adjustment formula, significantly improves the flame retardant properties of sizing agent, smoke suppressing, carry out modification simultaneously to tree ash, improves sizing agent group
The dispersing uniformity divided, obviously improves the bonding strength of sizing agent, and significantly improves the package stability of sizing agent.Sizing agent of the present invention has very strong cementability, flame retardant resistance, presses down the advantages such as cigarette, low toxicity, excellent storage stability.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment:
A kind of flame-retardant adhesive of nanometer palygorskite modification, be made up of the raw material of following weight part: vinylbenzene 130 parts, β-dimethyl-aminoethylmethacrylate 70 parts, tetramethylolmethane 10 parts, furane resin 6 parts, epoxy propane butyl ether 12 parts, chloroprene rubber 12 parts, 2 parts, boron powder, bisphenol A epoxide resin 8 parts, epoxy soybean oil 7 parts, nanometer palygorskite 20 parts, nanometer Feldspar Powder 8 parts, titanium dioxide 2 parts, clorafin 2 parts, 2 parts, glass powder, 2 parts, magnesium oxide, halogenated polyether polyvalent alcohol 15 parts, 7 parts, xylogen, amination triazine salt 4 parts, dibutyl tin laurate 0.6 part, phosphoric acid 0.4 part, antioxidant 1,076 2 parts, antioxidant MB 2 parts, accelerator CBS 2 parts, titanate coupling agent 4 parts, modification tree ash 5 parts.
Wherein, described modification tree ash is prepared by following methods: first use 15% salt acid soak tree ash 4h, then clean with deionized water wash, 4h is soaked again with 13% sodium hydroxide solution, with deionized water wash to neutral, dry, add be equivalent to tree ash weight 3% wooden sodium sulfonate, the peregal of 2%, the tributyl citrate of 3%, 1500 revs/min are stirred 2h at a high speed, pulverize and grind to form ultrafine powder.
The preparation method of the flame-retardant adhesive of described nanometer palygorskite modification, comprises the following steps:
(1) by above-mentioned weight ratio, vinylbenzene, β-dimethyl-aminoethylmethacrylate, tetramethylolmethane, furane resin, epoxy propane butyl ether, chloroprene rubber, bisphenol A epoxide resin, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid are added reactor and is heated to 120 DEG C, high-speed stirring 1h;
(2) other material is mixed with reactant in step (1), stir 50min, be cooled to normal temperature, obtain finished product, pack.
Carry out thermal analyses to it after sizing agent solidification in the embodiment of the present invention, the temperature starting to decompose is 292.05 DEG C.
Claims (3)
1. the flame-retardant adhesive of a nanometer palygorskite modification, it is characterized in that: be made up of the raw material of following weight part: vinylbenzene 100-150 part, β-dimethyl-aminoethylmethacrylate 50-80 part, tetramethylolmethane 10-15 part, furane resin 5-8 part, epoxy propane butyl ether 10-15 part, chloroprene rubber 10-15 part, boron powder 1-3 part, bisphenol A epoxide resin 5-10 part, epoxy soybean oil 5-8 part, nanometer palygorskite 15-20 part, nanometer Feldspar Powder 8-10 part, titanium dioxide 2-4 part, clorafin 2-3 part, glass powder 1-3 part, magnesium oxide 2-3 part, flame retardant polyether polyol 15-20 part, xylogen 5-8 part, amination triazine salt 3-5 part, dibutyl tin laurate 0.5-0.8 part, phosphoric acid 0.3-0.5 part, antioxidant 1076 1-2 part, antioxidant MB 2-3 part, accelerator CBS 1-2 part, titanate coupling agent 3-5 part, modification tree ash 3-5 part,
Described modification tree ash is prepared by following methods: first use 10-15% salt acid soak tree ash 3-5h, then clean with deionized water wash, 3-5h is soaked again with 10-13% sodium hydroxide solution, with deionized water wash to neutral, dry, add be equivalent to tree ash weight 2-4% wooden sodium sulfonate, the peregal of 1-3%, the tributyl citrate of 2-4%, high speed 1300-1500 rev/min stir 1-3h, pulverize grind to form ultrafine powder.
2. the flame-retardant adhesive of nanometer palygorskite modification according to claim 1, is characterized in that: described flame retardant polyether polyol be halogenated polyether polyvalent alcohol, phenol polyvalent alcohol one or both.
3. a preparation method for the flame-retardant adhesive of nanometer palygorskite modification as claimed in claim 1, is characterized in that: comprise the following steps:
(1) by above-mentioned weight ratio, vinylbenzene, β-dimethyl-aminoethylmethacrylate, tetramethylolmethane, furane resin, epoxy propane butyl ether, chloroprene rubber, bisphenol A epoxide resin, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid are added reactor and are heated to 100-120 DEG C, high-speed stirring 1-2h;
(2) other material is mixed with reactant in step (1), stir 30-50min, be cooled to normal temperature, obtain finished product, pack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057022.1A CN103805074B (en) | 2014-02-20 | 2014-02-20 | Nano palygorskite-modified flame-retardant adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057022.1A CN103805074B (en) | 2014-02-20 | 2014-02-20 | Nano palygorskite-modified flame-retardant adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103805074A CN103805074A (en) | 2014-05-21 |
| CN103805074B true CN103805074B (en) | 2015-06-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410057022.1A Expired - Fee Related CN103805074B (en) | 2014-02-20 | 2014-02-20 | Nano palygorskite-modified flame-retardant adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN103805074B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315527A (en) * | 2015-11-23 | 2016-02-10 | 苏州盖德精细材料有限公司 | Neoprene-based UL yellow adhesive and preparation method thereof |
| CN106751502A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of neo-epoxy resin composition |
| CN107739577A (en) * | 2017-11-17 | 2018-02-27 | 刘青 | A kind of anti-flammability adhesive |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4997709A (en) * | 1988-11-07 | 1991-03-05 | The Kendall Company | Novel adhesives and tapes including same |
| CN101298509A (en) * | 2008-06-18 | 2008-11-05 | 西北师范大学 | Nanometer grade paligorskite-flame retardant epoxide resin composite material |
| CN102533161A (en) * | 2011-12-19 | 2012-07-04 | 庄晓曦 | Flame-retarding pressure-sensitive adhesive and preparation method thereof |
| CN102965036A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-wollastonite modified adhesive for packaging |
| CN102977799A (en) * | 2012-11-15 | 2013-03-20 | 合肥帝奥木业有限公司 | Preparing method of high-strength woodworking adhesives |
| CN103013389A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Special bonding agent containing rice hull ash for surface composite woven shell fabric of automotive upholstery |
| CN103265917A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing nano attapulgite for packaging and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY142518A (en) * | 2001-01-10 | 2010-12-15 | Hitachi Chemical Co Ltd | Dihydrobenzoxazine ring-containing resin, phenolic-triazine-aldehyde condensate and epoxy resin |
-
2014
- 2014-02-20 CN CN201410057022.1A patent/CN103805074B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4997709A (en) * | 1988-11-07 | 1991-03-05 | The Kendall Company | Novel adhesives and tapes including same |
| CN101298509A (en) * | 2008-06-18 | 2008-11-05 | 西北师范大学 | Nanometer grade paligorskite-flame retardant epoxide resin composite material |
| CN102533161A (en) * | 2011-12-19 | 2012-07-04 | 庄晓曦 | Flame-retarding pressure-sensitive adhesive and preparation method thereof |
| CN102965036A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-wollastonite modified adhesive for packaging |
| CN102977799A (en) * | 2012-11-15 | 2013-03-20 | 合肥帝奥木业有限公司 | Preparing method of high-strength woodworking adhesives |
| CN103013389A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Special bonding agent containing rice hull ash for surface composite woven shell fabric of automotive upholstery |
| CN103265917A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing nano attapulgite for packaging and preparation method thereof |
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| CN103805074A (en) | 2014-05-21 |
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