CN104862046A - Lubricant composition for cold spinning lead alloy pipe - Google Patents

Lubricant composition for cold spinning lead alloy pipe Download PDF

Info

Publication number
CN104862046A
CN104862046A CN201510303907.XA CN201510303907A CN104862046A CN 104862046 A CN104862046 A CN 104862046A CN 201510303907 A CN201510303907 A CN 201510303907A CN 104862046 A CN104862046 A CN 104862046A
Authority
CN
China
Prior art keywords
lead alloy
alloy pipe
cold spinning
lubricant composition
property
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510303907.XA
Other languages
Chinese (zh)
Inventor
黄福川
李康春
卢朝霞
黄旖瑶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201510303907.XA priority Critical patent/CN104862046A/en
Publication of CN104862046A publication Critical patent/CN104862046A/en
Pending legal-status Critical Current

Links

Landscapes

  • Lubricants (AREA)

Abstract

The invention discloses a lubricant composition for a cold spinning lead alloy pipe. The lubricant composition adopts 325SN base oil as base oil, and is cooperated with various additives, wherein the additives comprise an oiliness agent, an extreme-pressure agent, an antioxidant, an antiwear agent and a friction improver. The lubricant composition disclosed by the invention is relatively high in anti-milling property, adsorbing property, bearing property, soaking property and diffusing property, a uniform oil film with a certain thickness and certain oil film strength can be formed; the spinning friction coefficient is reduced, the adhesion and coking possibilities are lowered, and the lubrication performance, cooling performance, cleaning performance, and heat oxidation invariability performance are relatively high.

Description

Cold spinning lead alloy pipe lubricant compositions
Technical field
The invention belongs to extrusion process field of lubricant in intermetallic composite coating, particularly cold spinning lead alloy pipe lubricant compositions.
Background technology
Lead is bluish silvery white heavy metal, and it is toxic, is a kind of malleable main group metal.Fusing point 327.502 DEG C, boiling point 1740 DEG C, density 11.3437g/cm 3, hardness 1.5, quality is soft, and tensile strength is little.Lead is easy to get rusty---oxidation.Lead is often grizzly, be exactly due to it in atmosphere, very easily become the plumbous oxide of grey black by the dioxygen oxidation in air, make its argenteous gloss gradually become intensely dark.The important use of metallic lead manufactures store battery.The resistance to deformation of lead alloy is little, and the techniques such as extruding can be adopted to make sheet material, band, tubing, bar and wire rod.Because the shearing of lead alloy, creep strength are low, under certain load and rolling shear effect, lead alloy is easily deformable and thinningly become foil-like; And the self-lubricity of lead alloy, running-in ability and damping property are good, noise is little, because of but good bearing metal.Graphite metal and tinhase bearing metals are referred to as Babbitt metal, can make the Locomotive Bearing of high-load.Do not have the plumbous bright in color of zone of oxidation, density is high, and hardness is very low, and extensibility is very strong.Its conductivity is quite low, and corrosion resistance is very high, and therefore it is often used as the container of the strong material (such as sulfuric acid) of dress corrosion strength.Add the corrosion resistance that a small amount of antimony or other metal can improve it more.The tensile strength of lead alloy is 3 ~ 7kgf/mm 2, more much lower than other metal alloys of great majority.Antimony is for one of important element strengthening matrix, and only part is solid-solution in lead, both can be used for solution strengthening, and can be used for ageing strengthening again; If but too high levels, the toughness of lead alloy and solidity to corrosion can be made to degenerate.Consider from over-all properties, when lead alloy is for making the corrosion-resistant element such as chemical industry equipment, pipeline, to be advisable containing antimony about 6%; During for making transom, to contain antimony 8% ~ 10% as well.Lead antimony alloy adds a small amount of copper, arsenic, silver, calcium, tellurium etc., can gain in strength, be called antimonial lead.Lead alloy has not easily by the characteristic that X and gamma-rays penetrate, and can make the protective material of radiation work.
Cold spinning lead alloy pipe requires that lubricant compositions has higher wear-resistant, absorption, carrying, diffusibility, ensures that forming certain thickness even oil film also has certain oil film strength; Reduce the frictional coefficient of spinning, reduce adhesion and coking, and there is better lubrication, cooling, cleaning and thermal oxidation stability energy.
Summary of the invention
The technical problem to be solved in the present invention is to provide one and has higher wear-resistant, absorption, carrying, infiltrate, diffusibility, ensures that forming certain thickness even oil film also has certain oil film strength; Reduce the frictional coefficient of spinning, reduce adhesion and coking, and have better lubrication, cooling, cleaning and thermal oxidation stability can cold spinning lead alloy pipe lubricant compositions.
The present invention adopts following technical scheme to solve the problems of the technologies described above:
Cold spinning lead alloy pipe lubricant compositions, adopt oil based on 325SN base oil, coordinate multiple additives, its each component and mass percent thereof are:
Component Mass percent content
Base oil Surplus
Oiliness improver 8.0%~12.0%
Extreme pressure agent 3.0%~5.0%
Oxidation inhibitor 0.5%~1.2%
Anti-wear agent 3.0%~4.0%
Friction improver 1.0%~2.0%
Oiliness improver is industrial lard;
Extreme pressure agent is lead naphthenate;
Oxidation inhibitor is the dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50%;
Anti-wear agent is that dibutyl dithiocaarbamate is plumbous;
Friction improver is molybdenum phosphate T451.
Remarkable advantage of the present invention has: have higher wear-resistant, absorption, carrying, infiltrate, diffusibility, ensures that forming certain thickness even oil film also has certain oil film strength; Reduce the frictional coefficient of spinning, reduce adhesion and coking, and there is better lubrication, cooling, cleaning and thermal oxidation stability energy.
Embodiment
Embodiment 1:
Each component of following masses percentage ratio is in harmonious proportion and forms:
Component Mass percent content
325SN base oil 80.3%
Industrial lard 10.0%
Lead naphthenate 4.0%
The dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50% 0.7%
Dibutyl dithiocaarbamate is plumbous 3.0%
Molybdenum phosphate T451 2.0%
Embodiment 2:
Each component of following masses percentage ratio is in harmonious proportion and forms:
Component Mass percent content
325SN base oil 80.2%
Industrial lard 11.0%
Lead naphthenate 3.0%
The dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50% 0.8%
Dibutyl dithiocaarbamate is plumbous 3.5%
Molybdenum phosphate T451 1.5%
Embodiment 3: each component of following masses percentage ratio is in harmonious proportion and forms:
Component Mass percent content
325SN base oil 80.0%
Industrial lard 9.0%
Lead naphthenate 5.0%
The dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50% 1.0%
Dibutyl dithiocaarbamate is plumbous 3.5%
Molybdenum phosphate T451 1.5%
The main physical and chemical index of embodiment 3 product:
Project Quality index
40 DEG C of kinematic viscosity/(mm 2﹒s -1) 63.5
Viscosity index 98
Pour point/DEG C -11
Flash-point (opening)/DEG C 225
Corrosion test (copper sheet, 100 DEG C, 3h) Qualified
Acid number/mg KOH ﹒ g -1 0.033
Moisture, % Vestige
Last non seizure load P B/N 920
Mechanical impurity, % Nothing

Claims (6)

1. cold spinning lead alloy pipe lubricant compositions, is characterized in that: adopt oil based on 325SN base oil, coordinate multiple additives, its each component and mass percent thereof are:
Base oil surplus,
Oiliness improver 8.0% ~ 12.0%,
Extreme pressure agent 3.0% ~ 5.0%,
Oxidation inhibitor 0.5% ~ 1.2%,
Anti-wear agent 3.0% ~ 4.0%,
Friction improver 1.0% ~ 2.0%.
2. cold spinning lead alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, oiliness improver is industrial lard.
3. cold spinning lead alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, extreme pressure agent is lead naphthenate.
4. cold spinning lead alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, oxidation inhibitor is the dialkyl diphenylamine of mass ratio 50% and the phenolic ester type oxidation inhibitor T508 compound of 50%.
5. cold spinning lead alloy pipe lubricant compositions as claimed in claim 1, is characterized in that, anti-wear agent is that dibutyl dithiocaarbamate is plumbous.
6. cold spinning lead alloy pipe lubricant compositions as claimed in claim 1, it is characterized in that, friction improver is molybdenum phosphate T451.
CN201510303907.XA 2015-06-05 2015-06-05 Lubricant composition for cold spinning lead alloy pipe Pending CN104862046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510303907.XA CN104862046A (en) 2015-06-05 2015-06-05 Lubricant composition for cold spinning lead alloy pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510303907.XA CN104862046A (en) 2015-06-05 2015-06-05 Lubricant composition for cold spinning lead alloy pipe

Publications (1)

Publication Number Publication Date
CN104862046A true CN104862046A (en) 2015-08-26

Family

ID=53908232

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510303907.XA Pending CN104862046A (en) 2015-06-05 2015-06-05 Lubricant composition for cold spinning lead alloy pipe

Country Status (1)

Country Link
CN (1) CN104862046A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004263087A (en) * 2003-03-03 2004-09-24 Kao Corp Lubricating oil for use in hot rolling oil for aluminum plate
CN103666701A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for aluminum and aluminum alloy plate die forging
CN103695091A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold forging of aluminum and aluminum alloy materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004263087A (en) * 2003-03-03 2004-09-24 Kao Corp Lubricating oil for use in hot rolling oil for aluminum plate
CN103666701A (en) * 2013-12-14 2014-03-26 广西大学 Lubricant for aluminum and aluminum alloy plate die forging
CN103695091A (en) * 2013-12-18 2014-04-02 广西大学 Lubricant for cold forging of aluminum and aluminum alloy materials

Similar Documents

Publication Publication Date Title
CN103468362B (en) Cold-rolling lubricant for lead and lead alloy foils
CN104862035A (en) Lubricant composition for cold spinning titanium alloy pipe
CN103725381A (en) Lubricant for cold forging of carbon steel and low alloy steel materials
CN103710103B (en) Lubricant for cold extrusion of zinc and zinc alloy materials
CN103468359B (en) Cold rolling lubricating agent for lead and lead alloy sheet strip
CN103710106B (en) The lubricant of drawing beryllium and beryllium alloy line, rod, tubing
CN104974842A (en) Castor-base rotary cold-forging beryllium alloy lubricant composition
CN103710088B (en) Hot rolling lubricant for plate strips of lead and lead alloy
CN103666671B (en) Cold rolling lubricant for zinc and zinc alloy foil
CN104862046A (en) Lubricant composition for cold spinning lead alloy pipe
CN103666703A (en) Lubricant for stamping lead and lead alloy material
CN104893801A (en) Cold-stretch-reducing seamless steel tube lubricant composition
CN103450991B (en) Cold rolling lubricating agent for zinc and zinc alloy plates and strips
CN103666704A (en) Lubricant for extruding lead and lead alloy materials
CN103421589B (en) Zirconium and zirconium alloy board strip cold rolling lubricant
CN103421586B (en) Zirconium and zirconium alloy foil cold rolling lubricant
CN104862045A (en) Lubricant combination for cold spinning copper alloy tube
CN103450989B (en) Tungsten and alloy plate strip cold-rolling lubricant thereof
CN104962344A (en) Lubricant composition for cold spinning of zirconium alloy pipe
CN103725380B (en) Lubricant for cold forging of beryllium and beryllium alloy materials
CN103468368A (en) Lubricating agent for hot rolling of tungsten and tungsten alloy plates and strips
CN103695116B (en) The lubricant of drawing height sintering load steel plate
CN103666674B (en) Cold rolling lubricant for antimony and antimony alloy plate strip
CN103409202B (en) Titanium or titanium alloy foil cold-rolling lubricant
CN103695113B (en) Lubricant for drawing lead and alloy thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
EXSB Decision made by sipo to initiate substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20150826