CN104861841A - 用于衣服的阻燃薄膜 - Google Patents
用于衣服的阻燃薄膜 Download PDFInfo
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 74
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 13
- 239000010409 thin film Substances 0.000 title abstract 7
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 239000004417 polycarbonate Substances 0.000 claims abstract description 14
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 14
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 14
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 13
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 11
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 11
- 229920001194 natural rubber Polymers 0.000 claims abstract description 11
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
- 239000000347 magnesium hydroxide Substances 0.000 claims description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000012757 flame retardant agent Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 description 9
- 239000011347 resin Substances 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- -1 bromos benzo alkane Chemical class 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 229910000951 Aluminide Inorganic materials 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000003721 gunpowder Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/78—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon; with halides or oxyhalides of silicon; with fluorosilicates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
- D06M15/513—Polycarbonates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开一种用于衣服的阻燃薄膜,所述的用于衣服的阻燃薄膜包括最上层的热塑性涂料、中间层的阻燃剂和最下层的天然橡胶组合而成,所述热塑性涂料为聚碳酸脂,所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的67%-71%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的22%-25%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的3%-12%。本发明提供一种用于衣服的阻燃薄膜,具有耐热,抗冲击,阻燃和耐磨的优点。
Description
技术领域
本发明涉及一种用于衣服的阻燃薄膜。
背景技术
市场上的薄膜品种很多,但最常用的印刷膜有BOPP,NY,PET,PE。就印刷而言,最重要的当然是薄膜的表面处理效果,NY膜是否受潮。印刷时应该制定对膜的表面张力一个膜卷一测的工艺要求。电晕效果具有时效性,放置过长时间,电晕效果可能下降幅度太多达不到印刷的要求;也可以避免由于不小心弄反膜面印刷的故障隐患。
阻燃材料绿色化的关键是阻燃剂的选择。为克服卤系阻燃剂的不足和提高环保效果,无卤、高效、低烟、低毒新型阻燃剂的合成及其阻燃技术的研究,是当今高分子阻燃材料的发展方向从阻燃剂发展的前景来看,无卤的膨胀型阻燃剂、有机硅阻燃剂、纳米级阻燃剂显示了强大的生命力,为阻燃材料的绿色化提供了可能。 在我国的阻燃技术基本上与国外先进国家处在同一水平线上,各种阻燃制品的难燃要求也是参照发达国家的同类标准制订出来的。但由于我国目前还没有一部较为完整的阻燃法律规范,使得我国阻燃制品的生产总量及其使用仍远远落后于发达国家。如美国在上世纪九十年代末期,阻燃塑料制品占其塑料总使用量的40%左右,而与此同时我国连1%的阻燃制品都达不到。 我国在高聚物(各种塑料包括工程塑料)的阻燃中,主要是以用量少、阻燃效率高且适应性广的添加型溴系阻燃剂为主。溴系中多溴二苯醚(PBD PO)在燃烧时会产生有毒致癌的多溴代苯并烷(PBDD)和多溴代苯并呋喃(PBDF)。而且卤素阻燃剂在燃烧时生成大量的烟和有毒且具腐蚀性的气体,可导致单纯由火所不能引起的电路系统开关和其它金属物件的腐蚀及对人体呼吸道和其它器官造成危害的严重缺点。所以我国虽然阻燃材料研究方面比较不错,但将阻燃材料应用到实际中还在很落后。
发明内容
本发明提供一种具有耐热,抗冲击,阻燃和耐磨优点的用于衣服的阻燃薄膜。
本发明的技术方案是:一种用于衣服的阻燃薄膜,所述的用于衣服的阻燃薄膜包括最上层的热塑性涂料、中间层的阻燃剂和最下层的天然橡胶组合而成,所述热塑性涂料为聚碳酸脂,所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的67%-71%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的22%-25%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的3%-12%。
在本发明一个较佳实施例中,所述阻燃剂包括三氧化二锑、氢氧化镁、氢氧化铝和硅。
在本发明一个较佳实施例中,所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的68%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的23%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的9%。
本发明的一种用于衣服的阻燃薄膜,具有耐热,抗冲击,阻燃和耐磨的优点。
具体实施方式
下面对本发明的较佳实施例进行详细阐述,以使本发明的优点和特征能更易于被本领域技术人员理解,从而对本发明的保护范围做出更为清楚明确的界定。
其中,所述的用于衣服的阻燃薄膜包括最上层的热塑性涂料、中间层的阻燃剂和最下层的天然橡胶组合而成,所述热塑性涂料为聚碳酸脂,所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的67%-71%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的22%-25%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的3%-12%,所述阻燃剂包括三氧化二锑、氢氧化镁、氢氧化铝和硅。
进一步说明,所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的68%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的23%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的9%。
在进一步说明,聚碳酸酯是几乎无色的玻璃态的无定形聚合物,有很好的光学性。聚碳酸酯高分子量树脂有很高的韧性,悬臂梁缺口冲击强度为600~900J/m,未填充牌号的热变形温度大约为130°C ,玻璃纤维增强后可使这个数值增加10°C。聚碳酸酯的弯曲模量可达2400MPa以上,树脂可加工制成大的刚性制品。低于100°C 时,在负载下的蠕变率很低。聚碳酸酯耐水解性差,不能用于重复经受高压蒸汽的制品。聚碳酸酯主要性能缺陷是耐水解稳定性不够高,对缺口敏感,耐有机化学品性,耐刮痕性较差,长期暴露于紫外线中会发黄。和其他树脂一样,聚碳酸酯容易受某些有机溶剂的浸浊。聚碳酸酯材料具有阻燃性,耐磨。抗氧化性。物理密度:1.18-1.22 g/cm^3 线膨胀率:3.8×10^-5 cm/°C 热变形温度:135°C 低温-45°C。聚碳酸酯无色透明,耐热,抗冲击,阻燃BI级,在普通使用温度内都有良好的机械性能。同性能接近聚甲基丙烯酸甲酯相比,聚碳酸酯的耐冲击性能好,折射率高,加工性能好,不需要添加剂就具有UL94 V-0级阻燃性能。但是聚甲基丙烯酸甲酯相对聚碳酸酯价格较低,并可通过本体聚合的方法生产大型的器件。
在进一步说明,阻燃剂常用品种有以下几种:①三氧化二锑。必须与有机阻燃材料协同使用。②氢氧化镁、氢氧化铝。可分别单独使用,但加入量大,往往与树脂用量相当。③无机磷类。常用红磷及硫酸盐,纯红磷在使用前最后经过微化处理,可单用和并用,磷酸盐有磷酸铵、硝酸铵等。④硼类阻燃材料。常用水合硼酸锌,一般与其他阻燃材料协同使用。其他金属氧化物,如金属铝化物、金属铁化物等,主要用于硝烟。⑤金属卤化物。如各类卤化锑类。本发明提供一种用于衣服的阻燃薄膜,具有耐热,抗冲击,阻燃和耐磨的优点。
本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本领域的技术人员在本发明所揭露的技术范围内,可不经过创造性劳动想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求书所限定的保护范围为准。
Claims (3)
1.一种用于衣服的阻燃薄膜,其特征在于:所述的用于衣服的阻燃薄膜包括最上层的热塑性涂料、中间层的阻燃剂和最下层的天然橡胶组合而成,所述热塑性涂料为聚碳酸脂,所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的67%-71%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的22%-25%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的3%-12%。
2.根据权利要求1所述的用于衣服的阻燃薄膜,其特征在于:所述阻燃剂包括三氧化二锑、氢氧化镁、氢氧化铝和硅。
3.根据权利要求1所述的用于衣服的阻燃薄膜,其特征在于:所述的热塑性涂料占用于衣服的阻燃薄膜总体分量的68%,所述的阻燃剂占用于衣服的阻燃薄膜总体分量的23%,所述的天然橡胶占用于衣服的阻燃薄膜总体分量的9%。
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