CN104845440A - Water-based ink for negative ion decorative paper and preparation method therefor - Google Patents
Water-based ink for negative ion decorative paper and preparation method therefor Download PDFInfo
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- CN104845440A CN104845440A CN201510109056.5A CN201510109056A CN104845440A CN 104845440 A CN104845440 A CN 104845440A CN 201510109056 A CN201510109056 A CN 201510109056A CN 104845440 A CN104845440 A CN 104845440A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/04—Printing inks based on proteins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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Abstract
The invention provides a water-based ink for negative ion decorative paper. Every 100 parts of the ink consist of the following components in parts by weight: 50-60 parts of negative ion color paste, 20-30 parts of a modified casein liquid, 0.5-2 parts of a thickening agent, 0.1-0.5 part of an antifoaming agent A, 1-3 parts of ethanediol A, 1-3 parts of alcohol, 0.1-0.5 part of a mildewproof agent A, and the balance of water A. According to the water-based ink, negative ions can be sustainably released to the air without additionally adding energy resources and the concentration of the negative ions in indoor air reaches the level of that in suburb and fields. The ink is fine and smooth, is not precipitated or layered, and has the characteristics of good storage stability, full coating and the like.
Description
(1) technical field
The present invention relates to water color ink and preparation method thereof, decorative paper printing water color ink being specifically related to a kind of energy anion releasing and preparation method thereof.
(2) background technology
Tourmalinite (tourmaline) is a kind of cyclic silicate salt mineral with additional anionic of boracic, and main chemical compositions is SiO
2, Fe
2o
3, B
2o
3, A1
2o
3, Na
2o, MgO, Li
2o, MnO
2deng.The crystalline structure of tourmalinite is trigonal system, i.e. multiple tripartite's ring of silicon-oxy tetrahedron composition, because crystalline structure is special, cause the atom of two high electric charges in crystal lattice subrack, arrange obviously dislocation, crystal one end is caused to be electric charge positive pole thus, the other end is electric charge negative pole, and electronics flows to positive pole from negative pole with never resting, thus forms electric current and electrostatic field.1989, Japanese scholars Kubo Late Cambrian this unique phenomena of tourmalinite, and expand a series of researchs about tourmalinite micro mist electrical effect.According to the theory of Kubo, there is permanent electrode in tourmalinite, with water molecules effect, water molecules ionization generated OH
-and H
+.H
+oxonium ion (H can be formed
3o
+) or form H
2, OH
-(H is formed with water molecules
3o
2)
-, (H
3o
2)
-be dispersed in air and be negative aeroion.
If other water moleculess such as the sweat of the moisture in air, human body touch tourmalinite, also can there is above-mentioned reaction, produce negative ion and enter human body.Numerous result of study shows, interior wall coating or the wallpaper ink of introducing the anionic additives such as tourmalinite can improve room air negative ion concentration significantly.But function interior wall coating, wallpaper ink etc. that major part in the market contains anionic additive are solvent-based system, unfavorable to environment; And the film that solvent-based system is formed is comparatively fine and close, is unfavorable for the contact of tourmalinite and water in air molecule, therefore can not produces more negative ion.In addition, part interior wall coating, wallpaper ink adopt photoactivation mode to produce negative aeroion, must could produce negative ion, this greatly limits it and apply under illumination condition.As can be seen here, the prerequisite that in tourmalinite ambient air, negative ion produces is that tourmaline crystal fully contacts with air, namely when tourmaline powder being applied in a certain surface, this tourmalinite coating must have certain ventilation property, for the diffusion after negative ion generates provides channel.
On the other hand, the negative ion concentration in current air has been listed in the important indicator that is weighed environment, Air quality.Under negative aeroion refers to the energy that ray, wave waterfall and the various meteorological activity of launching at Millikan's rays, solar ray, rock and soil produce, the out-shell electron deorbit of some atom in air, become unbound electron, the neutral molecules such as the oxygen of these unbound electrons in air or water vapour are combined in electronegativity, become negative aeroion.Medical research shows, the anion concentration in air and HUMAN HEALTH have substantial connection, as shown in the table:
Negative ion concentration and HUMAN HEALTH relation (draw and report from " International Medical magazine ") in table 1. environment
From table 1, the negative ion concentration in the enclosed space such as house, office in air does not reach the basic demand maintaining HUMAN HEALTH far away.Because the most of the time of people is all spent in indoor, the quality of indoor environmental quality directly affects the healthy of people.And decorative paper is as raw material requisite in a lot of building material product, it is widely used in indoor furniture, the low pressing plate of cabinet, hardboard, and floor etc.The area indoor shared by it for the decoration wallpaper on these indoor furniture, floors etc. is larger, if therefore the anionic additives such as tourmalinite can be introduced in decorative paper ink, make it possess the function of release air negative ion, then will be subject to the welcome of consumers in general.
But, wallpaper in the market, decorative paper printing-ink mostly are solvent type ink, it contains a large amount of organic volatiles (content is usually more than 40%), these organic volatile materials in printing and construction process discharged to air, to printing, construction worker and wallpaper, the personnel that live in decorative paper decorative architecture health all cause larger murder by poisoning; On the other hand, the printed layers that solvent type ink is formed is comparatively fine and close, is unfavorable for fully contacting of tourmaline crystal and air, greatly have impact on the negative ion releasing function of decorative paper.
The object of the invention is to overcome the deficiencies in the prior art, a kind of decorative paper printing water color ink of energy anion releasing is provided.This ink introduces tourmaline anion additive, can for good and all release air negative ion, has human body heath care function.Ink adopts modified Casein emulsion system, Environmental Safety.Casein is also known as casein, casein food grade, lactic casein.Being the main component in milk, is a kind of macromolecule resin of natural environmental-protective.When casein without any modification is applied in covering with paint ink as film-forming resin, there is the defect that film forming is more crisp.And the present invention is by hexanolactam modified Casein albumen, the defect of its film forming embrittlement can be solved well.In addition, the film-forming resin (as polyacrylate type resin, cellulosic resin, urethane resin etc.) common compared to other, by the coating of casein film, there is more excellent ventilative and vapor pervious performance, the negative ion that can produce for tourmalinite in coating provides flourishing diffusion admittance, drastically increase the negative ion release concentration of tourmalinite, and this is also innovative point place of the present invention.
(3) summary of the invention
A kind of negative ion decorative paper is the object of the present invention is to provide to print water color ink and preparation method thereof, this ink only need add the negative aeroion that a small amount of tourmaline anion additive just can discharge high density constantly, make room air negative ion concentration reach countryside, field level, strengthen body immunity and antimicrbial power.
The object of the invention is to be achieved through the following technical solutions:
A kind of negative ion decorative paper printing water color ink, every 100 parts of described ink are made up of the component of following weight part: negative ion mill base 50 ~ 60 parts, modified Casein liquid 20 ~ 30 parts, thickening material 0.5 ~ 2 part, defoamer A0.1 ~ 0.5 part, ethylene glycol A1 ~ 3 part, alcohol 1 ~ 3 part, mould inhibitor A0.1 ~ 0.5 part, and surplus is water A;
Wherein, described negative ion mill base is made up of anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, based on described anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, described negative ion mill base is made up of the component of following weight part: anionic additive 3 ~ 5 parts, mineral dye toner 10 ~ 12 parts, wetting dispersing agent 13.5 ~ 16.8 parts, defoamer B0.1 ~ 0.3 part, ethylene glycol B1 ~ 2 part, water B22 ~ 26 part;
Described modified Casein liquid is made up of casein, hexanolactam, alkaline matter, mould inhibitor B, water C, based on described casein, hexanolactam, alkaline matter, mould inhibitor B, water C, described modified Casein liquid is made up of the component of following weight part: casein 40 ~ 50 parts, hexanolactam 12 ~ 15 parts, alkaline matter 3 ~ 6 parts, mould inhibitor B1 ~ 1.5 part, water C220 ~ 240 part.
Negative ion decorative paper printing water color ink of the present invention, described thickening material is the mixture of one or more arbitrary proportions in Natvosol class thickening material, polyether(poly)urethane class thickening material, sodium polyacrylate thickening material, polyethers association type nonionic class thickening material, preferred Natvosol class thickening material;
Concrete, described Natvosol class thickening material, such as Natrosol performax1325 (ASHLAND-AQUALON company), Natrosol performax1425 (ASHLAND-AQUALON company), Natrosol PLUS 330 (ASHLAND-AQUALON company);
Described polyether(poly)urethane class thickening material, such as
212 (De Qian companies),
244 (De Qian companies),
278 (De Qian companies);
Described sodium polyacrylate thickening material, such as SN-Thickener 613 (Diamond Shamrock company), Modicol VD (Diamond Shamrock company);
Described polyethers association type nonionic class thickening material, such as Aquaflow NLS 200 (ASHLAND-AQUALON company), Aquaflow NLS 210 (ASHLAND-AQUALON company), Aquaflow NHS 300 (ASHLAND-AQUALON company), Aquaflow XLS 500 (ASHLAND-AQUALON company), Aquaflow XLS 525 (ASHLAND-AQUALON company);
Above-mentioned concrete thickening material is Natrosol PLUS 330 (ASHLAND-AQUALON company) particularly preferably.
Defoamer A of the present invention or defoamer B is the mixture of one or both arbitrary proportions in silicon oxide polyethers defoamer, polysiloxane defoamer, preferred polysiloxane defoamer;
Concrete, described silicon oxide polyethers defoamer, such as BYK-1650 (BYK company), BYK-1660 (BYK company);
Described polysiloxane defoamer, such as BYK-024 (BYK company), BYK-025 (BYK company), BYK-028 (BYK company), BYK-094 (BYK company);
Above-mentioned concrete defoamer is BYK-094 (BYK company) particularly preferably.
Mould inhibitor A of the present invention or mould inhibitor B is the mixture of one or both arbitrary proportions in isothiazolinone mould inhibitor, imidazole derivative mould inhibitor, preferred isothiazolinone mould inhibitor;
Concrete, described isothiazolinone mould inhibitor, such as KIL100 (the loyal Fine Chemical Co., Ltd in Shanghai), KIL300 (the loyal Fine Chemical Co., Ltd in Shanghai), Preventol D7 (Lanxess Corporation), Preventol D7LT (Lanxess Corporation), Preventol D7F (Lanxess Corporation), Preventol D6 (Lanxess Corporation), Preventol P91 (Lanxess Corporation), Preventol BIT20N (Lanxess Corporation);
Described imidazole derivative mould inhibitor, such as Preventol BCM (Lanxess Corporation);
Above-mentioned concrete mould inhibitor is Preventol BIT20N (Lanxess Corporation) particularly preferably.
Anionic additive of the present invention is tourmaline powder, such as tourmaline powder (Lingshou County Yan Tai mineral products processing factory).
Mineral dye toner of the present invention is any one in inorganic red pigment, Inorganic yellow pigment, titanium dioxide, charcoal blacks, inorganic blue pigments;
Concrete, described inorganic red pigment, such as Paliogen Maroon L3920P.R.179 (BASF AG), the red L3130S P.R.104 (BASF AG) of Paliogen Red L4120P.R.179 (BASF AG), Sicomin;
Described Inorganic yellow pigment, yellow L0962HD P.Y.138 (BASF AG) of such as Paliotol, the yellow L1820P.Y.139 (BASF AG) of Paliotol, yellow L2140HD P.Y.139 (BASF AG) of Paliotol;
Described titanium dioxide, such as R-105 (E.I.Du Pont Company), R-706 (E.I.Du Pont Company);
Described charcoal blacks, such as NEROX 500 (Orion company), NEROX 505 (Orion company), NEROX 600 (Orion company), NEROX 605 (Orion company);
Described inorganic blue pigments, such as
blue 6875 (BASF AG),
blue 7080 (BASF AG);
Particularly preferably described inorganic red pigment is the red L3130S P.R.104 (BASF AG) of Sicomin, described Inorganic yellow pigment is the yellow L1820P.Y.139 (BASF AG) of Paliotol, described titanium dioxide is R-706 (E.I.Du Pont Company), described charcoal blacks is NEROX 605 (Orion company), and described inorganic blue pigments is
blue 7080 (BASF AG).
Wetting dispersing agent of the present invention is the mixture of one or both arbitrary proportions in high-molecular block copolymer class wetting dispersing agent, polyacrylate wetting dispersing agent, preferred high-molecular block copolymer class wetting dispersing agent;
Concrete, described high-molecular block copolymer class wetting dispersing agent, such as DISPERBYK-180 (BYK company), DISPERBYK-182 (BYK company), DISPERBYK-182 (BYK company);
Described polyacrylate wetting dispersing agent, such as Disponer W-511 (ElEMENTIS company), Disponer W-518 (ElEMENTIS company), Disponer W-519 (ElEMENTIS company);
Above-mentioned concrete wetting dispersing agent is DISPERBYK-182 (BYK company) particularly preferably.
Alkaline matter of the present invention is the mixture of one or more arbitrary proportions in monoethanolamine, diethanolamine, trolamine, ammoniacal liquor, sodium carbonate, sodium bicarbonate, sodium-acetate, water glass, sodium phosphate, sodium hydrogen phosphate, SODIUM PHOSPHATE, MONOBASIC, hydroxyethylethylene diamine; The mixture of one or more arbitrary proportions in preferred monoethanolamine, diethanolamine, trolamine, particularly preferably trolamine.
Concrete recommendering folder invention negative ion decorative paper printing water color ink, every 100 parts of described ink are made up of the component of following weight part: negative ion mill base 50 ~ 60 parts, modified Casein liquid 20 ~ 30 parts, thickening material 0.5 ~ 2 part, defoamer A0.1 ~ 0.5 part, ethylene glycol A1 ~ 3 part, alcohol 1 ~ 3 part, mould inhibitor A0.1 ~ 0.5 part, and surplus is water A;
Wherein, described negative ion mill base is made up of anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, based on described anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, described negative ion mill base is made up of the component of following weight part: anionic additive 3 ~ 5 parts, mineral dye toner 10 ~ 12 parts, wetting dispersing agent 13.5 ~ 16.8 parts, defoamer B0.1 ~ 0.3 part, ethylene glycol B1 ~ 2 part, water B22 ~ 26 part;
Described modified Casein liquid is made up of casein, hexanolactam, alkaline matter, mould inhibitor B, water C, based on described casein, hexanolactam, alkaline matter, mould inhibitor B, water C, described modified Casein liquid is made up of the component of following weight part: casein 40 ~ 50 parts, hexanolactam 12 ~ 15 parts, alkaline matter 3 ~ 6 parts, mould inhibitor B1 ~ 1.5 part, water C220 ~ 240 part;
Further, described thickening material is the mixture of one or more arbitrary proportions in Natvosol class thickening material, polyether(poly)urethane class thickening material, sodium polyacrylate thickening material, polyethers association type nonionic class thickening material; Wherein, described Natvosol class thickening material is selected from Natrosol performax 1325, Natrosol performax 1425 or the Natrosol PLUS 330 of the production of ASHLAND-AQUALON company; Described polyether(poly)urethane class thickening material is selected from the production of De Qian company
212,
244 or
278; Described sodium polyacrylate thickening material is selected from SN-Thickener 613 or the Modicol VD of the production of Diamond Shamrock company; Described polyethers association type nonionic class thickening material is selected from Aquaflow NLS 200, Aquaflow NLS 210 that ASHLAND-AQUALON company produces, Aquaflow NHS 300, Aquaflow XLS 500 or Aquaflow XLS 525;
Described defoamer A or defoamer B is the mixture of one or both arbitrary proportions in silicon oxide polyethers defoamer, polysiloxane defoamer; Wherein, described silicon oxide polyethers defoamer is selected from BYK-1650 or BYK-1660 that BYK company produces; Described polysiloxane defoamer is selected from BYK-024, BYK-025, BYK-028 or BYK-094 that BYK company produces;
Described mould inhibitor A or mould inhibitor B is the mixture of one or both arbitrary proportions in isothiazolinone mould inhibitor, imidazole derivative mould inhibitor; Wherein, described isothiazolinone mould inhibitor is selected from KIL100 or KIL300 that the loyal Fine Chemical Co., Ltd in Shanghai produces, or Lanxess Corporation produce Preventol D7, Preventol D7LT, Preventol D7F, Preventol D6, Preventol P91 or Preventol BIT20N; Described imidazole derivative mould inhibitor is selected from the Preventol BCM that Lanxess Corporation produces;
Described anionic additive is tourmaline powder;
Described mineral dye toner be BASF AG produce yellow L1820P.Y.139, the Paliotol of Paliogen Maroon L3920 P.R.179, Paliogen Red L4120 P.R.179, Sicomin red L3130S P.R.104, Paliotol yellow L0962 HD P.Y.138, Paliotol yellow L2140 HD P.Y.139,
blue 6875 or
blue 7080, or R-105 or R-706 that E.I.Du Pont Company produces, or Orion company produce NEROX 500, NEROX 505, any one in NEROX 600 or NEROX 605;
Described wetting dispersing agent is the mixture of one or both arbitrary proportions in high-molecular block copolymer class wetting dispersing agent, polyacrylate wetting dispersing agent; Wherein, described high-molecular block copolymer class wetting dispersing agent is selected from DISPERBYK-180, DISPERBYK-182 or DISPERBYK-182 that BYK company produces; Described polyacrylate wetting dispersing agent is selected from Disponer W-511, Disponer W-518 or the Disponer W-519 of the production of ElEMENTIS company;
Described alkaline matter is the mixture of one or more arbitrary proportions in monoethanolamine, diethanolamine, trolamine, ammoniacal liquor, sodium carbonate, sodium bicarbonate, sodium-acetate, water glass, sodium phosphate, sodium hydrogen phosphate, SODIUM PHOSPHATE, MONOBASIC, hydroxyethylethylene diamine.
Present invention also offers a kind of preparation method of described negative ion decorative paper printing water color ink, described preparation method comprises the steps:
(1) grinding of negative ion mill base
According to formula ratio, the granulated glass sphere being 2mm by the defoamer B of water B, anionic additive, mineral dye toner, wetting dispersing agent, ethylene glycol B, half formula ratio and diameter adds in rapid dispersion machine, grinding distribution is after 2 ~ 3 hours, add the defoamer B of residue half formula ratio again, obtain negative ion mill base;
(2) preparation of modified Casein liquid
According to formula ratio, water C is added in flask, under the stirring velocity of 100 ~ 150rpm, add casein, system is warming up to 50 ~ 70 DEG C, then adds the aqueous solution of alkaline matter, be warming up to 75 ~ 80 DEG C, improve stirring velocity to 300 ~ 400rpm, keep 1 ~ 2 hour, then add the aqueous solution of hexanolactam, insulated and stirred was cooled to room temperature after 2 ~ 3 hours, add mould inhibitor B, obtain modified Casein liquid; Wherein, in the aqueous solution of alkaline matter and the aqueous solution of hexanolactam, the water as solvent counts in the formula ratio of water C;
(3) preparation of negative ion decorative paper printing water color ink
According to formula ratio, water A, step (1) gained negative ion mill base, step (2) gained modified Casein liquid are added in dispersion sand mill, stir with the speed of 200 ~ 500rmp, then thickening material, ethylene glycol A and alcohol is added, finally add mould inhibitor A and defoamer A, keep stirring 20 ~ 40 minutes, namely obtain described negative ion decorative paper printing water color ink.
In the present invention, " water A ", " water B ", " water C " do not have special implication, all refer to water, are labeled as " A ", " B ", " C " just for distinguishing water used in various process;
" defoamer A ", " defoamer B ", " ethylene glycol A ", " ethylene glycol B ", " mould inhibitor A ", " mould inhibitor B " are with it in like manner.
Compared with prior art, the present invention has following advantage:
1, adopt tourmaline powder to be anionic additive, evenly, be stably dispersed in decorative paper printing water color ink, without the need to external energy just release air negative ion sustainably;
2, modified Casein is adopted to be low-melting ink vehicle resin, modified Casein coating is pliable and tough, and there is excellent ventilative and vapor pervious performance, the negative ion that can produce for tourmalinite in coating provides flourishing diffusion admittance, drastically increase the negative ion release concentration of tourmalinite, only need add a small amount of tourmalinite (3 ~ 5wt%), room air negative ion concentration just can be made to reach countryside, field level (5800 ~ 7800/cm
3);
3, by the choose reasonable of each analog assistant, ensure that described ink is fine and smooth, do not precipitate, not stratified that there is the features such as excellent storage stability, coating be plentiful.
(4) embodiment
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in this:
The package stability of ink refers to that ink leaves standstill 9 days under 60 DEG C of conditions, not precipitate, not stratifiedly represents ink storage stability >6 month;
The generating capacity of negative aeroion is checked in the detection of the negative ion concentration that wallpaper ink discharges according to Q/JC JJT030 ~ 2002, by Chinese architecture material tests Spot detection.
Embodiment 1
(1) grinding of negative ion redness slurry
The red slurry formula table of table 1 negative ion
According to the formula ratio in table 1, the granulated glass sphere being 2mm by the BYK-094 defoamer of water, tourmaline powder anionic additive, Sicomin red L3130S P.R.104 red pigment, DISPERBYK-182 wetting dispersing agent, ethylene glycol, half formula ratio and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, grinding distribution is after 3 hours, add the BYK-094 defoamer of residue half formula ratio again, obtain negative ion redness slurry;
(2) preparation of modified Casein liquid
Table 2 modified Casein liquid formula table
According to the formula ratio in table 2,182kg water is added in flask, keep the stirring velocity of 100rpm, add 40kg casein, system is warming up to 65 DEG C, add the aqueous solution (4kg trolamine is dissolved in 10kg water) of alkaline matter again, raised temperature to 75 DEG C, improve stirring velocity to 350rpm, keep 1 hour, then add the aqueous solution (12kg hexanolactam is dissolved in 28kg water) of hexanolactam, insulated and stirred was cooled to room temperature after 3 hours, finally add 1kg Preventol BIT20N mould inhibitor, discharging obtains modified Casein liquid;
(3) preparation of the red ink of negative ion decorative paper
The table red ink formulas table of 3100kg negative ion decorative paper (5wt% anionic additive content)
According to the formula ratio in table 3, negative ion redness slurry, modified Casein liquid are added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir with the speed of 300rmp, slowly add Natrosol PLUS 330 thickening material, ethylene glycol and alcohol successively, finally add Preventol BIT20N mould inhibitor and BYK-094 defoamer again, keep stirring within 30 minutes, namely to obtain the red ink of negative ion decorative paper.
Embodiment 2
(1) grinding of negative ion yellow pulp
Table 4 negative ion yellow pulp formula table
According to the formula ratio in table 4, the granulated glass sphere being 2mm by the BYK-094 defoamer of water, tourmaline powder anionic additive, the yellow L1820P.Y.139 yellow ultramarine of Paliotol, DISPERBYK-182 wetting dispersing agent, ethylene glycol, half formula ratio and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, grinding distribution is after 2 hours, add the BYK-094 defoamer of residue half formula ratio again, obtain negative ion yellow pulp;
(2) preparation of modified Casein liquid
Table 5 modified Casein liquid formula table
According to the formula ratio in table 5,190kg water is added in flask, keep the stirring velocity of 140rpm, add 48kg casein, system is warming up to 70 DEG C, add the aqueous solution (3kg trolamine is dissolved in 8kg water) of alkaline matter again, raised temperature to 78 DEG C, improve stirring velocity to 300rpm, keep 1.5 hours, then add the aqueous solution (14kg hexanolactam is dissolved in 32kg water) of hexanolactam, insulated and stirred was cooled to room temperature after 3 hours, finally add 1kg Preventol BIT20N mould inhibitor, discharging obtains modified Casein liquid;
(3) preparation of negative ion decoration paper yellow ink
Table 6 100kg negative ion decoration paper yellow ink formulas table (3wt% anionic additive content)
According to the formula ratio in table 6, negative ion yellow pulp, modified Casein liquid are added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir with the speed of 250rmp, slowly add Natrosol PLUS 330 thickening material, ethylene glycol and alcohol successively, finally add Preventol BIT20N mould inhibitor and BYK-094 defoamer again, keep stirring within 40 minutes, namely to obtain negative ion decoration paper yellow ink.
Embodiment 3
(1) grinding of negative ion stock white
Table 7 negative ion stock white formula table
According to the formula ratio in table 7, the granulated glass sphere being 2mm by the BYK-094 defoamer of water, tourmaline powder anionic additive, R-706 titanium dioxide, DISPERBYK-182 wetting dispersing agent, ethylene glycol, half formula ratio and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, grinding distribution is after 2 hours, add the BYK-094 defoamer of residue half formula ratio again, obtain negative ion stock white;
(2) preparation of modified Casein liquid
Table 8 modified Casein liquid formula table
According to the formula ratio in table 8,192kg water is added in flask, keep the stirring velocity of 100rpm, add 40kg casein, system is warming up to 50 DEG C, add the aqueous solution (6kg trolamine is dissolved in 12kg water) of alkaline matter again, raised temperature to 75 DEG C, improve stirring velocity to 360rpm, keep 2 hours, then add the aqueous solution (15kg hexanolactam is dissolved in 36kg water) of hexanolactam, insulated and stirred was cooled to room temperature after 2 hours, finally add 1.2kg Preventol BIT20N mould inhibitor, discharging obtains modified Casein liquid;
(3) preparation of negative ion decorative paper chalk
Table 9 100kg negative ion decorative paper chalk formula table (4wt% anionic additive content)
According to the formula ratio in table 9, negative ion stock white, modified Casein liquid are added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir with the speed of 200rmp, slowly add Natrosol PLUS 330 thickening material, ethylene glycol and alcohol successively, finally add Preventol BIT20N mould inhibitor and BYK-094 defoamer again, keep stirring within 20 minutes, namely to obtain negative ion decoration paper yellow ink.
Embodiment 4
(1) grinding of negative ion black slurry
Table 10 negative ion black slurry formula table
According to the formula ratio in table 10, the granulated glass sphere being 2mm by the BYK-094 defoamer of water, tourmaline powder anionic additive, NEROX 605 charcoal blacks, DISPERBYK-182 wetting dispersing agent, ethylene glycol, half formula ratio and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, grinding distribution is after 2.5 hours, add the BYK-094 defoamer of residue half formula ratio again, obtain negative ion black slurry;
(2) preparation of modified Casein liquid
Table 11 modified Casein liquid formula table
According to the formula ratio in table 11,182kg water is added in flask, keep the stirring velocity of 150rpm, add 40kg casein, system is warming up to 70 DEG C, add the aqueous solution (3.6kg trolamine is dissolved in 10kg water) of alkaline matter again, raised temperature to 80 DEG C, improve stirring velocity to 400rpm, keep 2 hours, then add the aqueous solution (12kg hexanolactam is dissolved in 28kg water) of hexanolactam, insulated and stirred was cooled to room temperature after 2 hours, finally add 1kg Preventol BIT20N mould inhibitor, discharging obtains modified Casein liquid;
(3) preparation of negative ion decorative paper tusche
Table 12 100kg negative ion decorative paper tusche formula table (4wt% anionic additive content)
According to the formula ratio in table 12, negative ion black slurry, modified Casein liquid are added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir with the speed of 500rmp, slowly add Natrosol PLUS 330 thickening material, ethylene glycol and alcohol successively, finally add Preventol BIT20N mould inhibitor and BYK-094 defoamer again, keep stirring within 35 minutes, namely to obtain negative ion decorative paper tusche.
Embodiment 5
(1) grinding of negative ion blueness slurry
The blue slurry formula table of table 13 negative ion
According to the formula ratio in table 13, by water, tourmaline powder anionic additive,
the BYK-094 defoamer of blue 7080 blue pigmentss, DISPERBYK-182 wetting dispersing agent, ethylene glycol, half formula ratio and diameter are that the granulated glass sphere of 2mm adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, grinding distribution is after 3 hours, add the BYK-094 defoamer of residue half formula ratio again, obtain negative ion blueness slurry;
(2) preparation of modified Casein liquid
Table 14 modified Casein liquid formula table
According to the formula ratio in table 14,181kg water is added in flask, keep the stirring velocity of 150rpm, add 40kg casein, system is warming up to 65 DEG C, add the aqueous solution (5.1kg trolamine is dissolved in 11kg water) of alkaline matter again, raised temperature to 80 DEG C, improve stirring velocity to 400rpm, keep 2 hours, then add the aqueous solution (12kg hexanolactam is dissolved in 28kg water) of hexanolactam, insulated and stirred was cooled to room temperature after 2 hours, finally add 1kg Preventol BIT20N mould inhibitor, discharging obtains modified Casein liquid;
(3) preparation of the blue ink of negative ion decorative paper
The blue ink formulas table (3wt% anionic additive content) of table 15 100kg negative ion decorative paper
According to the formula ratio in table 15, negative ion blueness slurry, modified Casein liquid are added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir with the speed of 400rmp, slowly add Natrosol PLUS 330 thickening material, ethylene glycol and alcohol successively, finally add Preventol BIT20N mould inhibitor and BYK-094 defoamer again, keep stirring within 40 minutes, namely to obtain the blue ink of negative ion decorative paper.
Table 16 negative ion decorative paper ink performance table (3 ~ 5wt% anionic additive content)
As shown in Table 16, by the choose reasonable of each analog assistant, the negative ion decorative paper ink of patent of the present invention can be made into 5 kinds of look ink such as red, yellow, white, black, blue, and suitability is wide; And its stability in storage has all exceeded 6 months, normal requirement of producing storage can be met.The negative ion release concentration of ink depends primarily on the content of anionic additive, and anionic additive content is higher, and the release concentration of negative ion is larger.The anionic additive content of 3wt% can reach 5800/cm
3negative ion release concentration, reach the negative ion concentration (5000 ~ 50000/cm of countryside, field level
3), body immunity and antimicrbial power can be strengthened, improve the healthy state of human body.
Above-described embodiment is used for explaining and the present invention is described, instead of limits the invention, and in the protection domain of spirit of the present invention and claim, any amendment make the present invention and change, all fall into protection scope of the present invention.
Claims (10)
1. a negative ion decorative paper printing water color ink, it is characterized in that, every 100 parts of described ink are made up of the component of following weight part: negative ion mill base 50 ~ 60 parts, modified Casein liquid 20 ~ 30 parts, thickening material 0.5 ~ 2 part, defoamer A0.1 ~ 0.5 part, ethylene glycol A1 ~ 3 part, alcohol 1 ~ 3 part, mould inhibitor A0.1 ~ 0.5 part, and surplus is water A;
Wherein, described negative ion mill base is made up of anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, based on described anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, described negative ion mill base is made up of the component of following weight part: anionic additive 3 ~ 5 parts, mineral dye toner 10 ~ 12 parts, wetting dispersing agent 13.5 ~ 16.8 parts, defoamer B0.1 ~ 0.3 part, ethylene glycol B1 ~ 2 part, water B22 ~ 26 part;
Described modified Casein liquid is made up of casein, hexanolactam, alkaline matter, mould inhibitor B, water C, based on described casein, hexanolactam, alkaline matter, mould inhibitor B, water C, described modified Casein liquid is made up of the component of following weight part: casein 40 ~ 50 parts, hexanolactam 12 ~ 15 parts, alkaline matter 3 ~ 6 parts, mould inhibitor B1 ~ 1.5 part, water C220 ~ 240 part.
2. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described thickening material is the mixture of one or more arbitrary proportions in Natvosol class thickening material, polyether(poly)urethane class thickening material, sodium polyacrylate thickening material, polyethers association type nonionic class thickening material.
3. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described defoamer A or defoamer B is the mixture of one or both arbitrary proportions in silicon oxide polyethers defoamer, polysiloxane defoamer.
4. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described mould inhibitor A or mould inhibitor B is the mixture of one or both arbitrary proportions in isothiazolinone mould inhibitor, imidazole derivative mould inhibitor.
5. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described anionic additive is tourmaline powder.
6. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described mineral dye toner is selected from one of following: yellow L1820 P.Y.139, the Paliotol of Paliogen Maroon L3920 P.R.179, Paliogen Red L4120 P.R.179, Sicomin that BASF AG produces red L3130S P.R.104, Paliotol yellow L0962 HD P.Y.138, Paliotol yellow L2140 HD P.Y.139,
blue 6875 or
blue 7080, or R-105 or R-706 that E.I.Du Pont Company produces, or Orion company produce NEROX 500, NEROX 505, NEROX 600 or NEROX 605.
7. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described wetting dispersing agent is the mixture of one or both arbitrary proportions in high-molecular block copolymer class wetting dispersing agent, polyacrylate wetting dispersing agent.
8. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, described alkaline matter is the mixture of one or more arbitrary proportions in monoethanolamine, diethanolamine, trolamine, ammoniacal liquor, sodium carbonate, sodium bicarbonate, sodium-acetate, water glass, sodium phosphate, sodium hydrogen phosphate, SODIUM PHOSPHATE, MONOBASIC, hydroxyethylethylene diamine.
9. negative ion decorative paper printing water color ink as claimed in claim 1, it is characterized in that, every 100 parts of described ink are made up of the component of following weight part: negative ion mill base 50 ~ 60 parts, modified Casein liquid 20 ~ 30 parts, thickening material 0.5 ~ 2 part, defoamer A0.1 ~ 0.5 part, ethylene glycol A1 ~ 3 part, alcohol 1 ~ 3 part, mould inhibitor A0.1 ~ 0.5 part, and surplus is water A;
Wherein, described negative ion mill base is made up of anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, based on described anionic additive, mineral dye toner, wetting dispersing agent, defoamer B, ethylene glycol B, water B, described negative ion mill base is made up of the component of following weight part: anionic additive 3 ~ 5 parts, mineral dye toner 10 ~ 12 parts, wetting dispersing agent 13.5 ~ 16.8 parts, defoamer B0.1 ~ 0.3 part, ethylene glycol B1 ~ 2 part, water B22 ~ 26 part;
Described modified Casein liquid is made up of casein, hexanolactam, alkaline matter, mould inhibitor B, water C, based on described casein, hexanolactam, alkaline matter, mould inhibitor B, water C, described modified Casein liquid is made up of the component of following weight part: casein 40 ~ 50 parts, hexanolactam 12 ~ 15 parts, alkaline matter 3 ~ 6 parts, mould inhibitor B1 ~ 1.5 part, water C220 ~ 240 part;
Further, described thickening material is the mixture of one or more arbitrary proportions in Natvosol class thickening material, polyether(poly)urethane class thickening material, sodium polyacrylate thickening material, polyethers association type nonionic class thickening material; Wherein, described Natvosol class thickening material is selected from Natrosol performax1325, Natrosol performax1425 or the Natrosol PLUS 330 of the production of ASHLAND-AQUALON company; Described polyether(poly)urethane class thickening material is selected from the production of De Qian company
212,
244 or
278; Described sodium polyacrylate thickening material is selected from SN-Thickener 613 or the Modicol VD of the production of Diamond Shamrock company; Described polyethers association type nonionic class thickening material is selected from Aquaflow NLS 200, Aquaflow NLS 210 that ASHLAND-AQUALON company produces, Aquaflow NHS 300, Aquaflow XLS 500 or Aquaflow XLS 525;
Described defoamer A or defoamer B is the mixture of one or both arbitrary proportions in silicon oxide polyethers defoamer, polysiloxane defoamer; Wherein, described silicon oxide polyethers defoamer is selected from BYK-1650 or BYK-1660 that BYK company produces; Described polysiloxane defoamer is selected from BYK-024, BYK-025, BYK-028 or BYK-094 that BYK company produces;
Described mould inhibitor A or mould inhibitor B is the mixture of one or both arbitrary proportions in isothiazolinone mould inhibitor, imidazole derivative mould inhibitor; Wherein, described isothiazolinone mould inhibitor is selected from KIL100 or KIL300 that the loyal Fine Chemical Co., Ltd in Shanghai produces, or Lanxess Corporation produce Preventol D7, Preventol D7LT, Preventol D7F, Preventol D6, Preventol P91 or Preventol BIT20N; Described imidazole derivative mould inhibitor is selected from the Preventol BCM that Lanxess Corporation produces;
Described anionic additive is tourmaline powder;
Described mineral dye toner be BASF AG produce yellow L1820 P.Y.139, the Paliotol of Paliogen Maroon L3920 P.R.179, Paliogen Red L4120 P.R.179, Sicomin red L3130S P.R.104, Paliotol yellow L0962 HD P.Y.138, Paliotol yellow L2140 HD P.Y.139,
blue 6875 or
blue 7080, or R-105 or R-706 that E.I.Du Pont Company produces, or Orion company produce NEROX 500, NEROX 505, any one in NEROX 600 or NEROX 605;
Described wetting dispersing agent is the mixture of one or both arbitrary proportions in high-molecular block copolymer class wetting dispersing agent, polyacrylate wetting dispersing agent; Wherein, described high-molecular block copolymer class wetting dispersing agent is selected from DISPERBYK-180, DISPERBYK-182 or DISPERBYK-182 that BYK company produces; Described polyacrylate wetting dispersing agent is selected from Disponer W-511, Disponer W-518 or the Disponer W-519 of the production of ElEMENTIS company;
Described alkaline matter is the mixture of one or more arbitrary proportions in monoethanolamine, diethanolamine, trolamine, ammoniacal liquor, sodium carbonate, sodium bicarbonate, sodium-acetate, water glass, sodium phosphate, sodium hydrogen phosphate, SODIUM PHOSPHATE, MONOBASIC, hydroxyethylethylene diamine.
10. a preparation method for negative ion decorative paper printing water color ink as claimed in claim 1, described preparation method comprises the steps:
(1) grinding of negative ion mill base
According to formula ratio, the granulated glass sphere being 2mm by the defoamer B of water B, anionic additive, mineral dye toner, wetting dispersing agent, ethylene glycol B, half formula ratio and diameter adds in rapid dispersion machine, grinding distribution is after 2 ~ 3 hours, add the defoamer B of residue half formula ratio again, obtain negative ion mill base;
(2) preparation of modified Casein liquid
According to formula ratio, water C is added in flask, under the stirring velocity of 100 ~ 150rpm, add casein, system is warming up to 50 ~ 70 DEG C, then adds the aqueous solution of alkaline matter, be warming up to 75 ~ 80 DEG C, improve stirring velocity to 300 ~ 400rpm, keep 1 ~ 2 hour, then add the aqueous solution of hexanolactam, insulated and stirred was cooled to room temperature after 2 ~ 3 hours, add mould inhibitor B, obtain modified Casein liquid; Wherein, in the aqueous solution of alkaline matter and the aqueous solution of hexanolactam, the water as solvent counts in the formula ratio of water C;
(3) preparation of negative ion decorative paper printing water color ink
According to formula ratio, water A, step (1) gained negative ion mill base, step (2) gained modified Casein liquid are added in dispersion sand mill, stir with the speed of 200 ~ 500rmp, then thickening material, ethylene glycol A and alcohol is added, finally add mould inhibitor A and defoamer A, keep stirring 20 ~ 40 minutes, namely obtain described negative ion decorative paper printing water color ink.
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Cited By (4)
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| CN105368135A (en) * | 2015-12-08 | 2016-03-02 | 浙江帝龙新材料股份有限公司 | Anti-penetrating water-based ink used for decorative paper, and preparation method thereof |
| CN106380928A (en) * | 2016-09-28 | 2017-02-08 | 武汉长江日报创印科技有限公司 | Printing ink with negative ion generation actions and manufacturing technique thereof |
| CN107384006A (en) * | 2017-05-05 | 2017-11-24 | 江苏唐彩油墨科技股份有限公司 | A kind of cork paper water-base gravure ink and preparation method thereof |
| CN109971244A (en) * | 2019-04-10 | 2019-07-05 | 柳行均 | A kind of formula printed for intaglio plate facing paper printing technology and negative oxygen ion |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368135A (en) * | 2015-12-08 | 2016-03-02 | 浙江帝龙新材料股份有限公司 | Anti-penetrating water-based ink used for decorative paper, and preparation method thereof |
| CN105368135B (en) * | 2015-12-08 | 2018-12-11 | 浙江帝龙新材料有限公司 | Permeation-proof bottom water-based ink and its manufacturing process for facing paper |
| CN106380928A (en) * | 2016-09-28 | 2017-02-08 | 武汉长江日报创印科技有限公司 | Printing ink with negative ion generation actions and manufacturing technique thereof |
| CN107384006A (en) * | 2017-05-05 | 2017-11-24 | 江苏唐彩油墨科技股份有限公司 | A kind of cork paper water-base gravure ink and preparation method thereof |
| CN109971244A (en) * | 2019-04-10 | 2019-07-05 | 柳行均 | A kind of formula printed for intaglio plate facing paper printing technology and negative oxygen ion |
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Application publication date: 20150819 |