CN1048422A - By containing the cationic surface active fiber conditioning compositions that the long chain hydrocarbon groups compound constitutes - Google Patents

Abstract

A kind of fiber conbidioning compositions with opsonic action of improvement, contain cationic surface active fiber conditioning agent and water dispersible compound, this compound contains the long chain hydrocarbon groups (preferably straight chained alkyl) of 25 above carbon atoms, and the ratio of these two kinds of materials is 1: 20～20: 1.Because the synergism of two components has increased one of them at least and has adhered on fiber in the said composition, produces conditioning effect preferably.This paper composition has hair care hair dyeing element and shampoo, washing rinsing fabric softening decontamination, soft two-in-one washing agent.That can make above-mentioned water dispersible compound has alkane, a carboxylic acid etc., and wherein some can directly adopt some mineral fat, paraffin and beeswax.

Description

By containing the cationic surface active fiber conditioning compositions that the long chain hydrocarbon groups compound constitutes

The present invention relates to fiber conbidioning compositions.More particularly, the present invention relates to such some compositions, promptly by a kind of cationic surface active fiber conditioning agent and the composition formed of water-insoluble compound basically.This water-insoluble compound basically can disperse in water, and contains a very long alkyl that has the chain of 25 carbon atoms at least in the molecule, preferably positive structure base or alkylidene.The combination of a kind of like this compound and cationic surface active fiber conditioning agent, a kind of like this effect improves on the fiber surface by being attached in the aqueous medium to make in the above-mentioned composition at least a material, thereby causes improving the conditioning performance of fiber.The present invention also comprises the compound method of the effective fiber conbidioning compositions of this class, and how to be applied to take care of hair rinse and shampoo, the softening agent that wash the laundry and the rinsing operating process is used and the decontamination-softening detergent (softregent) that has washing and softening clothes effect simultaneously.

Cationic surfactant has been used to handle fibrous material such as the people sends out and the Aquo-composition of daily fabric etc.For the clean composition of sending out, as hair care rinse and shampoo, even if in rare aqua, cationic surfactant also is easier to be attached to the people and sends out, and makes it be easy to combing, and reduces harvesting of static.Be used for fabric washing, cationic surfactant can improve the flexibility of fiber and reduce institute's fabric of washing static of fiber (especially synthetic fiber) surface generation when dry in automatic drier.Hydro carbons such as paraffin, mineral fat, vaseline, mineral oil are used for the agent of preparation hair care already, and this hair care agent can make that the people sends out moist, moulding and glossy.Cationic surfactant and hydro carbons Ceng Jun are used to have an effect with fiber in the water, and in some cases, they also share with some other component.Yet before the present invention, the unmanned proposition made composition of the present invention and used it, and also nobody recognizes because the existence of cation surface activating and water dispersible compound (WDC) is that the opsonic action of above-mentioned composition is improved.

According to the present invention, fiber conbidioning compositions comprises the water dispersible compound (WDC) that contains one at least 25 carbon atom long chain hydrocarbon groups in a kind of cationic surfactant and a kind of molecule.In this composition, the cationic surface active fiber conditioning agent is 1: 20～20: 1 with the ratio that contains the long chain hydrocarbon groups compound.In composition, in the aforementioned proportion scope of two kinds of contained above-mentioned substances, be applied on the fiber surface, can improve in them at least one attached to the lip-deep effect of institute's conditioning fiber by the aqua that will contain above-mentioned composition.The hair care rinse, the softening agent that shampoo, fabric washing and rinsing are used, decontamination one softening detergent etc. all belongs to the category of this based composition.In some applications, contain the water dispersible compound (WDC) of the long chain hydrocarbon groups of at least 25 carbon atoms in this molecule, even in very rare aqua, also can play a part to promote cationic surfactant attached on the fiber.Under some other situation, then observe opposite mechanism, that is: cationic surfactant can impel WDC attached to both impel its adhering on fiber mutually on the fiber He in other occasions.But final result makes the conditioning performance of handled fibrous material be improved, and is same, makes the method for above-mentioned composition and how to be applied to the surface conditioning of knot dimension all to belong to category of the present invention.

The retrieval of prior art has obtained some and can think the patent relevant with the present invention.Wherein closer the having of relation: United States Patent (USP) 3,519,562;

3，630，949；4，184，970；4，360，437；

4，401，578；4，426，299；4，454，049；

4,704,272; With 4,818,523; BP 1,601,360; And Japan Patent 6308,319.

United States Patent (USP) 3,519,562 have introduced textiles makes lubricant compositions, and it contains a kind of cation quaternary ammonium salt emulsifying agent of oxidation Fisher-Tropsch wax and water.The Fisher-Tropsch wax of oxidation is different with the WDC of the best of the present invention, and the two application mode on textiles is all different with purpose.United States Patent (USP) 3,630,949th is eliminated material about a kind of static, and its available aerosol composition mode sprays, and this aerosol composition contains quaternary ammonium chloride and 12-hydroxy stearic acid.The composition of this patent is not moisture, and has and hydroxy stearic acid does not comprise the chain alkyl that WDC had that this is.United States Patent (USP) 4,184,970 have proposed a kind of coccoid agglomerate that is mixed with the quaternary ammonium compound of organic scattered inhibitor and water, and wherein scattered inhibitor can be a paraffin.Though it is introduced that octacosane can be used as scattered inhibitor, this composition is a kind of special type, and is opposite with the form of fluid composition of the present invention.Scattered inhibitor can not work in composition of the present invention, and it can not become bead with quaternary ammonium compound in fluid composition of the present invention certainly.United States Patent (USP) 4,360,437 related compositions are used for rinsing and handle operating process.This composition comprises a kind of cationic fiber softening agent, long chain hydrocarbon and the special single long-chain amine or the derivative of amine.Some is that the present invention is obsolete in several suitable hydrocarbon that this patent proposes.The aliphatic hydrocarbon that is proposed particularly, its alkyl chain is all than the weak point among the present invention.United States Patent (USP) 4,401,578 have introduced the concentration of fibre softening compositio that contains a kind of cationic fiber softening agent and a kind of viscosity-control additive.Viscosity-control additive can be an aliphatic hydrocarbon.But the chain of the aliphatic hydrocarbon of mentioning in this patent is all than weak point required for the present invention.United States Patent (USP) 4,426,299 contents that comprised are identical with United States Patent (USP) 4,401,578.United States Patent (USP) 4,454,049th was operated about rinse fabric and to be selected treatment compositions for use, and it can make fiber softening and control static.This based composition comprises cationic fiber softening agent, water-insoluble nonionic replenishers (can be the hydrocarbon of C10～C40) and organic solvent, and requires the total amount of these materials must not be lower than 50% of product.Although this patent proposes to use straight chain or the branched hydro carbons of C10-40, do not mention during other of this patent set forth in the alkyl chain of this material and have 25 or more a plurality of carbon atom.In fact, this patent has only been discussed the successful use (purpose of this patent) of the n-alkane of much shorter.And the composition of this patent contains the organic solvent of significant proportion, and is different with composition of the present invention.United States Patent (USP) 4,704,272 have described shampoo, and it contains synthetic organic surface active agent, water-insoluble dispersed polyorganosiloxane, quaternary amine and suspending agent, for example xanthomonas glue.Because WDC is not a siloxanes, and do not need siloxanes among the present invention, so the present invention is different from this patent yet.United States Patent (USP) 4,818,523 have proposed the hair washing conditioner, and it can contain hydrocarbon (as mineral fat) (chain length is significantly shorter than C25) and mineral oil (having branched structure), thereby these materials are not suitable for the present invention, and can not produce the effect that the present invention improves the fiber conbidioning performance.BP 1,601,360th, about textile treatment composition, it is made of certain hydro carbons and specific cationic substance, softening textiles and improve flatiron and wrinkle resistance when being used to wash.Mentioned the hydrocarbon of C12～40 in the literary composition, but do not pointed out it is best hydrocarbon, also related to component in this textile treatment composition and contain long-chain WDC among the present invention without any description.Japan Patent 6308,319(was according to chemical abstracts 110: 121001) relate to the people and send out conditioner, contain hydrophobic oil and cationic surfactant.This hydrophobic oil comprises liquid paraffinic hydrocarbon, but can not satisfy the requirement of the present invention to alkyl chain length.

From known prior art that above present inventor summarized as can be seen, the present invention is novel in non-obvious, because do not set forth effectively in prior art or WDC and cationic fiber conditioning surfactant that suggestion will contain chain alkyl use in aqueous medium.Do not recognize importance about the discovery of component interphase interaction yet.This interaction makes fiber conbidioning material adhering to than estimate must be many on the processing fiber, even situation also is like this in very rare aqueous medium.

Method of the present invention also is novel in non-obvious, and unexpected, the effective fiber conbidioning that the applicant obtains is done to have is very important.Equally, the use of different types of fiber care composition as described herein also is novel in non-obvious, and can obtain very favourable conditioning effect.

Employed cationic fiber conditioning surfactant can be any suitable cationic surfactant, and it should softening fibre, conditioning human is sent out and/or antistatic.The most useful cationic materials mainly is more such quaternary amines, it should contain the base of a macromolecule at least, 1, the base of 2 or 3 small-molecular weights, all these 4 bases all link to each other with same nitrogen-atoms, form a CATION, individual electric equilibrium anion is wherein arranged, as halogen ion, acetate ion, low alkyl group sulfate ion for example chlorine, bromine or methylsulfuric acid radical ion.The preferably one or more higher molecular weight alkyl that contain 10 or 12～22 or 12～18 or 20 carbon atoms of high molecular substituting group on the nitrogen-atoms, for example dodecyl, COCO-alkyl, myristyl, cetyl, octadecyl, animal tallow alkyl, hydrogenation the animal tallow alkyl or replace senior alkyl.The low molecular weight substituting group preferably contains the low alkyl group of 1-3 or 4 carbon atoms, as methyl, and the low alkyl group of ethyl or replacement.The low son amount of above-mentioned one or more substituting group can comprise aryl moiety, perhaps also can be replaced by aryl (for example phenyl, benzyl) or other suitable substituting group.

Best quaternary amine for textile treatment composition (as washing operation with additive, rinsing operating process with additive and decontamination-softening detergent etc.) usefulness comprises halogenation two senior alkyls two low alkyl group ammoniums, as chlorination two animal tallow alkyl Dimethyl Ammonium and chlorination dihydro animal tallow alkyl Dimethyl Ammonium (two (octadecyl) Dimethyl Ammonium or claim DSDMAC).Send out care composition (comprising hair care rinse, hair conditioner and shampoo) although can the quaternary ammonium salt that these are same be used for the people, but quaternary ammonium salt preferably is halogenation one senior alkyl three low alkyl group ammoniums, as chlorination or cetrimonium bromide, chlorination dodecyl trimethyl ammonium, chlorination octadecyl triethyl ammonium.But, also can partly use halogenation three senior alkyls one low alkyl group ammonium at least, for example chlorination three (dodecyl) ethyl ammonium or chlorination three (cetyl) ammonium methyl.

Except above-mentioned cationic compound, the cationic surfactant that other is suitable, also have imidazoles drone salt, as chlorination 2-heptadecyl 1-methyl isophthalic acid-((2-octadecyl amide groups) ethyl) imidazoles drone; Corresponding methylsulfuric acid salt compound; Chlorination 2-methyl isophthalic acid-(2-ethoxy)-1-benzyl imidazole drone; Chlorination 2-COCO-1-(2-ethoxy)-1-benzyl imidazole drone; Chlorination 2-COCO-1-(2-ethoxy)-1-octadecyl imidazoles drone; Chlorination 2-heptadecyl-1-(2-ethoxy)-1-(4-chloro butyl) imidazoles drone; And sulfuric acid 2-heptadecyl-1-(ethoxy)-1-octadecyl-ethyl imidazol(e) drone.In general, Shi Yi imidazoles drone salt is halide (particularly chloride) and low alkyl group sulfate.

Everyly have that softening fibre, conditioning human are sent out, the quaternary ammonium salt of above mentioning of antistatic these character and imidazoles drone salt all can use in the present invention.United States Patent (USP) 4,000 has been described other this compounds in 077, now incorporates it into the present invention.

Cationic surfactant and anion surfactant and can or can replace cationic fiber conditioner in the above-mentioned composition to small part with the complex of organic acid (as citric acid).This class is joined compound at U.S. Patent application S.N.06/916, is described in 067 and S.N.07/189,560, incorporates the present invention at this.

In order to discern water dispersible compound (WDC) easy and in this composition of refering in particular to is a kind of hydrocarbon, a kind of organic acid, a kind of ester, a kind of acid amides, a kind of amine, a kind of amine salt, a kind of quaternary ammonium compound or alcohol, or their any mixture.But, in order to get a desired effect, be used for each above-claimed cpd of this composition, the hydrocarbyl chain of at least 25 carbon atoms must be arranged in its molecule, this chain is normal chain alkyl (or alkylidene) preferably.The applicant finds: when the long chain of at least 25 carbon atom existed, best carbon atom number range was 25～50 carbon atoms (or average), and 25 or 27～39 carbon atoms are then more better sometimes.When such carbochain exists, even very rare and have under the situation that scale remover exists, by this fiber treatment (conditioning) composition of it and cationic surfactant preparation all will fibrous material (as the people send out, fabric) go up the gratifying conditioning effect of generation.Make hair no matter do or wet situation under, all be easy to the combing moulding, make and knit softness, also antistatic usually.Although washings and washings are rare for cationic surfactant and WDC, the component that enough above-mentioned compositions are arranged when it is used handle knit on adhere to, to produce the conditioning effect of obvious improvement.Such result is very wondrous, and this is because the common synergism of said components has produced better fiber conbidioning effect, rather than as original expectation, the two phase mutual interference.This desirable synergism and component on the attachment fiber, are to accomplish with rare aqueous medium better.Though some WDC and cationic surfactant can still be stayed in the washings, are sizable attached to the ratio on the fiber, the effect that this had both played conditioning is unlikely making the people touch up disagreeable greasy feeling again.In various C25 and C25+ alkyl type compound, in fact can be used for doing among the present invention having of WDC: heneicosane, hexacosane, nonacosane, melene, positive hentriacontane, positive nonatriacontane, hexacosoic acid, melissic acid, the acid of leaf lice, n-hexacosane alcohol, n-octadecane alcohol, n-hexatriacontane alcohol, C25 alkane, C25 mineral fat, C33 mineral fat, melissyl hexadecane acid esters, dotriacontyl hexadecane acid esters, melissyl hexacosane acid esters, melissyl 8-hexadecene acid esters, cerul-2-hydroxyl cetane acid ester, an amine of above-mentioned hydro carbons, diamines and amine salt, the alcohol of above-mentioned hydro carbons and the acid amides of above-mentioned acid.This shows that above-mentioned various WDC contain a normal chain alkyl or alkylidene at least, its carbon number is 25～39, and this is considered to best scope.Compound listed above as representative, is not whole only.Equally, though full combination compound is more welcome, the insatiable hunger material that closes still of great use usually.

Various WDC can use with the form of pure compound or with the form of mixture.They can synthesize, or from natural material, extract.Some compound is synthesized out, can be used in this composition as WDC, and they can also mix with other this class synthetic compound and contain use.In addition, this compounds also can extract from the product of natural material and chemical refining factory (as oil plant).Such material and product can be processed, and with the more desirable WDC of production high concentration, or directly use it.Mineral fat is arranged in the raw material of the component WDC in the present composition, paraffin, beeswax, and come from candelilla genus, bayberry, various waxes and other native paraffins such as mineral wax, C25 that they are enough and C25+ normal chain alkyl or positive structure alkylidene hydrocarbon compound content all can meet the demands.Experiment shows that Brazil wax can not get a desired effect.But have been found that the microwax that contains Zhong Zhilian and uncle's alicyclic ring chain except the N-alkanes hydrocarbon chain is available.This obviously shows, cyclisation in the alkane chain and branch and not serious interference contain the fiber conbidioning effect of C25 or longer alkyl alkylidene compound.Therefore, be similar to the side chain of microwax also within the description category of the present invention about the WDC n-alkane.Certainly, as long as have the existence of positive structure C25 chain one branch and other base, can't make these compounds exceed the description scope of the present invention about WDC.

Except the cationic surfactant and WDC component of this composition, for taking care of hair the washing of rinse and laundry, rinsing operating process for composition, other component of unique needs is exactly a water-bearing media.In water-bearing media, cationic surfactant and WDC are emulsified or disperseed.When helping aqueous solvent, emulsifying agent and/or other surfactant that is suitable for to form emulsion, it will prepare water-bearing media by some method described below can be water, or moisture pure medium, also can contain various conventional auxiliary agents, those auxiliary agents that are used for composition of describing as mentioned.Used water is deionized water preferably, but running water also is suitable for.Used alcohol (if any) is generally modification alcohol, as SD-40, and when it is present in the fiber conbidioning compositions, accounts for 3～15% of final composition usually.For example about 5%.

Used synthetic organic de-sludging component is a kind of synthetic organic anion detergent in shampoo and the de-sludging-softening detergent compositions, or synthetic organic nonionic detergent, or their mixture.Certainly also can use the mixture of various anionic detergents, or the mixture of nonionic detergent.

Outside the decationize fiber conbidioning surfactant, both sexes, ampholytes, zwitterionic detergent, even cationic detergent and surfactant also can be used for composition of the present invention.

The various suitable detergent of listing in " detergent and emulsifying agent " book (1984, the North America version) that Mccutcheon showed is also incorporated the present invention at this.In these compounds, the preferred anionic surfactants detergent is sulphation type and/or sulfonated type, can be called " sulphation (sulfonated) thing ".Such detergent is the water soluble salt of lipotropic sulfuric acid or sulfonic acid.The lipophilic fat part of this class acid generally has 8～30 carbon atoms, and preferably comprises an alkyl, and this base should contain 8～22 or 10～18 or 20 carbon atoms, more is preferably 10～14 or 16 carbon atoms, for example 12 carbon.The example of these ion detergents has higher alkyl sulfates, straight chain senior alkyl benzene sulfonate, chain alkyl sulfonate salt, alkenyl sulphonate, monoglyceryl ester sulfate and higher aliphatic lower alkoxy sulfuric ester.Above-mentioned higher aliphatic or senior alkyl or lower alkoxy sulfate preferably it higher aliphatic or moieties in contain 10～14 or 16 carbon atoms, and every molar content is up to 20 moles lower alkoxy, as 1～20 mole of lower alkoxy, be preferably 2～4 or 2～6 moles of lower alkoxies, for example (lower alkoxy is generally ethyoxyl to 2,3 moles of lower alkoxies, and also comprise about 30% propoxyl group sometimes), so just can obtain best shampoo detergent.A kind of noticeable especially higher aliphatic sulfate is dodecyl sulphate, and a kind of noticeable especially many lower alkoxies of higher aliphatic sulfuric ester is the dodecyl alcohol that wherein high fat alcohol is the triethoxy change.For decontamination one softening detergent, better suited anionic detergent is a straight chain senior alkyl benzene sulfonate, as the straight chain DBSA.For shampoo, anionic detergent generally is ammonium salt and/or triethanolamine salt.Or its one or more and the mixture of sodium salt.Concerning decontamination one softening detergent, used salt is generally sodium salt, is referred to as the sodium salt of detergent in as mentioned.

Though various detergent compositions of the present invention are best with anionic all, they also can be nonionics or be mainly nonionic.In this case, main nonionic detergent component generally is alkoxyl alcohol or phenol (phenol can be that alkyl replaces, and the chain of 8～10 carbon atoms is arranged usually).Lower alkoxy generally is an ethyoxyl, but can partly be propoxyl group at least (nearly 30% alkoxyl).The condensation product of the rudimentary alkylene oxide of a kind of higher aliphatic with 8～15 carbon atoms and 5～12 molecules is suitable for as the nonionic detergent.And, have the better effects if of condensation product of the rudimentary alkylene oxide of the higher aliphatic of 8～12 carbon atoms and 6～10 molecules.Equally, when oxirane and alkyl phenol condensation, the molal quantity of the used oxirane of every moles of phenol is identical with what have with every mol of alcohol, concerning the alkyl phenol of the fatty alcohol of ethoxylation and ethoxylation, close limit ethoxylation type (NRE ' S) relatively good, and the wide region type (BRE ' S) also be available.

Though shampoo and decontamination-softening detergent compositions washing agent can be made into only to use the ion detergent as detergent surfactant, but because the nonionic detergent is generally low alveolitoid, and wishing all that usually detergent compositions can produce foam (especially true to shampoo), institute preferably adds some anionic detergents usually in above-mentioned composition.When with this understanding, during with a kind of complementary element as the nonionic detergent in the above-mentioned anionic detergent, find, when having a kind of nonionic detergent to exist, preferably use the detergent of sulfate or sulfonate type, as have the aliphatic alkyl sulfate of 8～18 or 10～16 carbon atoms, for example ammonium lauryl sulfate or a triethanol ammonium (TEALS).

Various auxiliary agents can use together with the necessary component of the present composition, to improve the performance of composition.In all fluid composition of the present invention, can contain ethanol and/or other polar latent solvent, also can select pearling agent, thickener, opacifier, foam improver and colouring agent and spices to add composition together.To Wo 2008069000,, also can contain higher aliphatic (if any the hexadecanol of thickening power), thickener (as hydroxyethylcellulose), neutralizer and buffer (as Boratex) as the hair care rinse.Concerning fabric valency fiber softening washing operation is used additive and rinsing additive, find the rheological characteristic of using multivalent ion chelating agent (as natrium citricum) in a small amount and low-grade alkylidene glycol (as propylene glycol) can assist to improve fluid product as diluent.For shampoo, auxiliary agent can comprise thickener and opacifier (as cetyl alcohol stearate and ethanol distearate), other thickener (as: xanthomonas glue, hydroxyethylcellulose-Natrosol, methylcellulose-Methocel, and sodium chloride), preservative agent, antioxidant, sequestering agent, low-grade alkylidene glycol solubilizer and diluent (propylene glycol).For the decontamination softening washing, available auxiliary agent has fluorescent bleaches (as two stilbene brightening agents), preservative agent (as Fu Er Malin) and neutralizer (comprising triethanolamine).Except above-mentioned auxiliary agent, also has technical known other auxiliary agent that can use with liquid-type composition of the present invention.When above-mentioned composition is made the granular solids composition, also to make proper assistant, this comprises that flow improver additive, anti-precipitating agent again, fiber softening powder (as bentonite), builder are (as poly-hexadecane carboxylic acid ester, zeolite, sodium phosphate trimer and sodium carbonate), bleaching powder (as sodium perborate), bleach-activating and/or stabilizing agent and solid isolate promoter (as the copolymer of polyethylene terephthalate-polyoxyethylene terephthalate, i.e. PET-POET copolymer).

For the performance of the improvement that obtains above-mentioned composition, the ratio in the above-mentioned composition between required component is very important.For all compositions of the present invention, the cationic surface active fiber conditioning agent is to the ratio of WDC, one of two kinds of above-mentioned substances being contained in the present composition are applied on the fiber surface by the water-bearing media that will contain the present invention's combination, and the effect that is attached on the fibre substrate improves.Find that above-mentioned two kinds of components in proportions generally are in 1: 20～20: 1 scope, suitable is in 1: 3～20: 1 scope, normally better at 1: 2～20: 1.In other words, these scopes were respectively 0.5: 1～20: 1,0.33: 1～20: 1 and 0.5: 1～20: 1.Precentagewise is calculated, and when doing the cationic surface active fiber conditioning agent with quaternary ammonium salt, moisture emulsification composition generally contains 0.1～20% above-mentioned quaternary ammonium salt and 0.1～10% WDC, and the latter is better with n-alkane usually.

For the hair conditioner that generally is used in behind the shampoo, the percentage range of quaternary ammonium salt, WDC and water-bearing media is respectively 0.2～10%, 0.1～5% and 75～99%, suitable is 0.2～5%, 0.1～2% and 85～98%, and 0.3～2%, 0.1～1% and 90～97% ratio is more better, 0.4～1.2%, 0.1～0.5% and 95～97%, and best.If desired, its surplus can be auxiliary agent, and auxiliary agent also can be its surplus of other composition of the present invention, and the back is described contrast.In above-mentioned composition, suitable water-bearing media is a water, and suitable quaternary ammonium halide is the senior fatty alkyl three low alkyl group ammoniums of halogenation.The senior alkyl here has 12～18 carbon atoms, and low alkyl group has 1～3 carbon atom.WDC is selected from the alkane, carboxylic acid, carboxylic acid ester of the alkyl chain with at least 25 carbon atoms, pure and mild their mixture.In the best composition of effect, quaternary ammonium halides can be used cetyltrimethylammonium chloride, chlorination two (cetyl) dimethylammonium, (octadecyl) Dimethyl Ammonium, WDC can use beeswax, positive structure C27～33 mineral fat, paraffin or microwax, or the approximate equal amount of mixture of mineral fat and beeswax, wherein should on average contain 27～33 carbon atoms in the former n-alkane.

About recuperating shampoo of the present invention, the proportion of wherein synthetic organic machine detergent, quaternary ammonium salt, WDC and water-bearing media generally is respectively: 5～25%, 0.2～10%, 0.1～5% and 65～94%, suitable scope is 8～20%, 0.2～5%, 0.1～3% and 70～90%, more better scope is 10～18%, 0.3～2%, 0.1～1.5 and 75～85%, best scope is 12～18%, about 0.4～2.0%, 0.1～2.0 and 80%.This effect synthetic organic anion detergent of recuperating shampoo preferably is a kind of mixture, and it contains the synthetic organic detergent of at least two kinds of different sulphation anion, and wherein at least a is ammonium salt, sodium salt or triethanolamine salt.Quaternary ammonium halides then is senior fatty alkyl one low alkyl group ammonium of tri-chlorination or chlorination two senior fatty alkyl two low alkyl group ammoniums, and wherein senior alkyl has 12～22 carbon atoms, low alkyl groups that 1～3 carbon atom is arranged.WDC is selected from the alkane, carboxylic acid, carboxylic acid ester of the chain base chain with at least 25 carbon, pure and mild their mixture.The best composition of effect contain 5～15% dodecyl sulphate acid ammonium and or the dodecyl diethoxy ammonium sulfate and/or the sodium of sodium and 1～10%, WDC adopts has the paraffin of 25～30 carbon and/or the mineral fat and/or the beeswax of the average carbon containing 27～33 of its n-alkane.

With regard to the softening agent that the fabric washing operating process is used and the rinsing operating process is used, the percentage range of quaternary ammonium salt or materials similar, WDC and aqueous medium (or water) is respectively: 1～20%, 0.1～5% and 70～97.9%, and suitable scope is 1.5～10%, 0.1～2% and 80～97.9%.More better scope is that (wherein senior alkyl has 12～22 carbon for 1.5～7% halogenation two senior fatty alkyl two rudimentary carbon alkylammoniums, low alkyl group has 1～3 carbon), 0.1～2% WDC(is selected from alkane with at least 25 carbon atoms, carboxylic acid, carboxylic acid ester, pure and mild their mixture) and 85～95% water, best above-mentioned composition will contain 2～8% chlorination two (octadecyl) Dimethyl Ammonium, 0.1～1%WDC(can use beeswax, mineral fat and/or paraffin) and 90～95% water, if the words that need also can add auxiliary agent.

Decontamination-softening detergent composed as follows: the detergent of synthetic organic detergent of decontamination effective dose (it generally is anionic detergent, nonionic detergent or their mixture) 0～75% with builder (one or more), 2～20 softening fibre with quaternary ammonium salt or similar substance, 0.1～2% WDC, 0～75% water is (to graininess decontamination-softening detergent, the ratio of water will be hanged down) if needed, one or more auxiliary agents of its surplus *.Decontamination-softening detergent compositions preferably contains the water of synthetic organic detergent of 10～35%, 2～15% quaternary ammonium salt or quaternary ammonium salt complex or their mixture, 0.1～2% WDC and 50～92% and one or more auxiliary agents of surplus thereof.Be more preferably and contain 10～25% nonionic detergent (1 mole has the higher aliphatic of 10～16 carbon atoms and the condensation product of 3～11 moles of ethylene oxide), 2～10% anionic detergent (suitable chain senior alkyl benzene sulfonate, its senior alkyl contains 10～16 carbon), (its middle-and-high-ranking fatty alkyl has 12～22 carbon to 7～13% halogenation two senior fatty alkyl two low alkyl group ammoniums, low alkyl group has 1～3 carbon), or cooperation of their citric acid or their mixture, 0.1～1% WDC(choosing place has the alkane of the alkyl of at least 25 carbon atoms, carboxylic acid, carboxylic acid ester, pure and mild their mixture) and 60～75% the water and the water-bearing media (preferably water) of surplus thereof.The most effective decontamination softening detergent compositions comprises 12～20% nonionic detergent (a mole contains the higher aliphatic of 12～15 carbon and the condensation product of 5～9 moles of ethylene oxide), 3～7% anionic detergent (sodium n-alkylbenzenesulfonate, wherein alkyl is 10～14 carbon), 1～5% oxidation two (octadecane) Dimethyl Ammonium, the citric acid compound of 7～11% octacosyl methyl amine, 0.1～0.5% WDC(can adopt its n-alkane on average to contain the mineral fat of 27～33 carbon) and 65～70% water and one or more auxiliary agents of surplus thereof.

The whole bag of tricks of preparation emulsion oil-in-water is technically for people know, and this also can be used to prepare fiber conbidioning combination agent of the present invention (when liquid state).Yet the stability that has had emulsion to have to improve for what guarantee to prepare, maximum fiber conbidioning is active and can find preferably to use a kind of special preparation method in the reappearance under this maximum activity.The method also is a part of the present invention.This method comprises: at high temperature prepare the surface active agent composition of fiber conbidioning and the melt of WDC; Heating makes its temperature close with the former as the aqueous medium (the hydrophilic composition that can contain heat endurance) of emulsion continuous phase; Oleophylic, water seeking liquid with gained under approximately identical high temperature mix.Frequently rose Song of the Southern Song Dynasty thus

The emulsion of reason composition has high its stability and result of use.The heating-up temperature scope of surfactant and WDC is generally 70～95 or 100 ℃, and 70～90 ℃ better, and (for example 80 ℃) are then better about 80 ℃.Aqueous medium preferably contains the stable hydrophilic composition in the composition, is heated to identical temperature, and the oleophylic fused mass is mixed in the water-bearing media gradually, to form emulsion, becomes microemulsion sometimes.With emulsion cool to room temperature gradually, this needs 5 minutes to 1 hour usually.Destroy for fear of emulsion, need the limit to stir, also will stir when adding the temperature-sensitive auxiliary agent.Product under this room temperature is a kind of stable emulsion.Layering is shaken container and can be made it can make its emulsification again if place for a long time under elevated temperature.When this based composition of fiber conbidioning emulsion or other form is dissolved in water or is scattered in the water, for example in washings or washings, cationic surfactant and WDC still can be attached on the fibers, thereby, improved the fiber conbidioning effect unexpectedly, significantly.

During application, composition of the present invention is dissolved in water or is scattered in the water, its concentration range is 0.01～50%.Under some situation, the working concentration of hair conditioner and shampoo can reach 100%, but all is to be used for water usually, and its concentration is that 10～50%(20～30% item is better).On the other hand, laundry is all very low with the used concentration of ingredients, as if 0.05～2%, and for example 0.1～0.5% and 1%.Normal serviceability temperature scope is 10～60 ℃, the type that this depends on the type of the fiber of handling and uses composition.Concerning most of purposes, water temperature is all in 10～40 ℃ of scopes, but 25～40 ℃ better, and is especially true during hair on washing head.The fibrous material of being nursed one's health, no matter be that the people sends out, cotton or synthetic fiber (for example: polyester fiber and cotton-polyester mixture fiber, all to keep in touch 1/2 or 1～30 minute for example about 10 minutes with the fiber conbidioning compositions aqueous solution or aqueous dispersions.At this therebetween, cationic surfactant and WDC can play opsonic action attached on the fiber surface.WDC usually promotes adhering to of cationic surfactant, but just in time opposite sometimes.Above-mentioned active component is used for the people with the form of hair conditioner and shampoo to be sent out, detected the major improvement of conditioning performance with instrument, that is: no matter be at wet comb or when doing comb, use after hair conditioner of the present invention or the shampoo that hair all becomes significantly and is easy to combing.Though fiber conbidioning compositions solution or aqueous dispersions are very rare, and the fiber conbidioning material on fiber also can be swept away by washings subsequently, but because these components are taken away by fibrous material from dilute aqueous solution and are always had some to be retained on the knot dimension material, therefore, the absorption or the adhesion mechanism that contain the composition of cationic fiber conditioning surfactant and WDC are not also explained clear, but clearly, it is more more complex than only being that component is adhered to.After rinsing, the amount of staying the active conditioner on the fiber still is enough to produce effective conditioning effect.Because concerning the shampoo of the synergist of the organic synthesis detergent that do not contain builder, not because not existing of builder, can make active conditioner adsorb better, therefore, the content of its cation opsonizing agent and WDC can be lower than the requirement in the decontamination softening detergent of the present invention.Yet, a significant advantage of the present invention, handling fabric in the laundry in additive with detergent, shampoo, hair conditioner and laundry washing and rinsing operating process just still is that the people sends out and used cationic fiber conditioning surfactant and WDC, cause the remarkable improvement of opsonic action, thereby the consumption that reduces conditioner has reduced expense.The product of making has so also improved its stability, and this point is extremely important.Because the consumer also dislikes also must shaking it to disperse its composition before using fluid product.Equally, from the viewpoint of selling, stable emulsion also than layering and again the product of emulsification have more attraction.

Above set forth the various advantages of the compositions and methods of the invention, but had a special advantage also need underline again.That is: the remarkable improvement of the opsonic action that combination brought of cationic surface active fiber conditioning agent and WDC.When composition of the present invention is used for hair conditioner, just to have observed with using the resulting effect of homogeneous groups compound that does not contain WDC and compared, its conditioning effect improves significantly, as easier combing.In addition, the content of the content shampoo of hair conditioning shampoo specific activity conditioner of the present invention is low, and more effective.More wondrous and be considered to this class technology breakthrough a bit be that shampoo of the present invention can be the same effective with commodity hair care hair dyeing element.And before this, always think and can not obtain the plain conditioning effect of having hair dyed of taking care of hair with shampoo.With washing of the present invention and rinsing operating process conditioner and decontamination-softening detergent, also can see the improvement of similar conditioning effect.

The suitable form of the present composition is a liquid, preferably stable emulsion.Yet, composition of the present invention such as decontamination-softening detergent can be transformed into the form of solid or mealy solid particle, this need replace part with solid-state carrier or auxiliary agent (as bentonite sodium sulphate, zeolite, three sodium polyphosphates, sodium carbonate and other builder), or whole aqueous medium.For example, the water in liquid cleaning-softening detergent can be replaced by builder or carrier, and it can be up to 75% or more in composition.Therefore, the physical aspect of product also changes thereupon.

The anti-illustration that rises of following example does not limit the present invention, unless through particularly pointing out, all deals in example explanation and the accompanying Claim book all by weight.All temperature are ℃.

The hair care hair dyeing for preparing above-mentioned various prescriptions is plain, and method is: each lipophilic ingredient (chlorination cetyl trimethylammonium, mineral fat, beeswax and hexadecanol) is fused together under 80 ℃; Under 80 ℃, mix the aqueous medium of its surplus then, and make it emulsification, make then and make each emulsion by each prescription and all be cooled to room temperature approximately through 20 minutes.Plain to each hair care hair dyeing, all use a gram product that the people of one standard unit is sent out (per unit 3 grams) and carry out one minute processing, with afterflush and wet comb, record the complexity that wets and comb with a kind of instrument, its reading is 1～5, corresponding to from the difficult to the easy.Each sample is all carried out ten secondary detection, calculating mean value.Then, in another test, with the sample after the rinsing, dry up and combing, with same instrument and method mensuration combing complexity, calculating mean value.Following table has gathered these mean value.

Table 1

Combing type mean value (combing easness)

A B C D E F G

Wet comb 2.52 4.50 4.25 5.15 4.25 4.20 4.10

Do comb 2.98 4.75 4.21 4.25 4.52 4.22 4.17

From these real alkali results as can be seen, owing in the present composition WDC is arranged, (1A) compares with the reference composition that does not contain WDC, and the carding property that the people who handled with the present composition sends out sample improves greatly.This is considered to total conditioning performance confidential relation is arranged.In the experiment of having reported, experiment 1B has obtained optimal its WDC as a result and has been made by beeswax.The effect of 1D is gratifying and compares more economical with 1B.The overhead people that grows sent out also confirmed such result in the test.In the experiment, the people send out with the hair conditioner emulsion of diluting (thinner ratio is 1: 1,1: 2,1: 3, composition: water) contact.

In similarly testing, replace WDC with mineral oil, the result shows that its conditioning effect is very different, can see greasy phenomenon sometimes, this is normally tedious.Sending out with the people after the compositions-treated that makes of prescription 1A-1G does not have greasy phenomenon.When replacing WDC with Brazil wax, it is poorer than composition of the present invention that the people sends out conditioning effect, and this is because it contains aromatic.But can use microwax.

Although the selling at exorbitant prices of this cationoid surfactant at present, with the chlorination heptacosane base trimethyl ammonium of 1% or 0.5% concentration or the cetyltrimethylammonium chloride in the chlorination hentriacontyl trimethylammonium replacement prescription, under situation without any the WDC of appointment, these cationic surfactants also can play the effect of WDC, and improve the conditioning effect that the people sends out, as described experimental formula.

In the prescription of this example, cetyltrimethylammonium chloride is replaced by cetrimonium bromide, is perhaps replaced by the chlorination dodecyl trimethyl ammonium.Cetyl alcohol is replaced by myristyl alcohol, and mineral fat is that a kind of C25 alkane replaces, and its result is similar.And, cetyl alcohol to the ratio of cetyltrimethylammonium chloride can become 3: 1 by 2: 1 among the embodiment～1: 1, the moisturizing effect of the cetyl alcohol that still can obtain expecting.

*-contain the peak value of its distribution curve of n-alkane of 60% average carbon number 27～33 just in this scope.

Contrast emulsion (A) and emulsion of the present invention (B-G) are all executed routine described method preparation according to food, and test in the same way, in addition, detector has been measured general impression of conditioning performance (bag is opened up the adjustable rational faculty, the look and feel) and wet comb that they send out the people and the evaluation of doing comb.Testing result sees Table 2.

By the data of following table 2 as seen, can improve the conditioning effect that the people sends out significantly having to send out by a small amount of WDC of the present invention and cation surface activating people under the situation that shampoo ingredients that conditioning compound (quaternary ammonium halides) makes exists.Because control formula A does not contain WDC,, this improvement causes so obviously being existence by WDC.This cation conditioner, do not contain the prescription A of WDC, compare with prescription B-G of the present invention, conditioning effect differs greatly.Practical application test (promptly washing hair with the shampoo of above-mentioned preparation of compositions) has also proved same result.

Want to change the prescription of being tested, can other detergent system above-mentioned detergent system be replaced.Active de-sludging component in other the detergent system can be any or their mixture in the following material.That is: triethanol ammonium lauryl sulfate, olefin sulfonic acid ammonium, C12～18 alkyl group ichthyodins or their mixture.Non-ionic and detergents both sexes also can be used for above-mentioned composition.The cation surface activating conditioner also changes.As in example 1, WDC can be obtained by other material, and this comprises ceresine, candelila wax, synthetic bees wax and Japan tallow, and microwax also can join in the composition.Equally, WDC can be a pure compound, for example: hydro carbons, alcohols, carboxylic acids and carboxylic acid esters; Or one class as the fraction in WDC source, as beeswax; Also can be alcohol, amine, amine salt and the quaternary ammonium salt of this class hydrocarbon; It can also be this carboxylic acid amides.Such shampoo group

The people that compound also has improvement sends out opsonic activity.To further improve the prescription of shampoo, except that adding anionic detergent (help send out with scalp to remove deoil and adhered to superincumbent conditioner in the past from the people), also to add the many ethoxy compounds of a spot of nonionic detergent such as higher aliphatic, resemble Nedol25-3,23-6.5 or 25-7 and close.Usually can add this class nonionic detergent of 1～10%, preferably 2～5%, for example about 3%.

Embodiment 3

Component	Percentage (weight)
				A	B	C
	Chlorination two, the complex beeswax of (octadecyl) Dimethyl Ammonium * * lemon acid amide, (yellow) * mineral fat natrium citricum propylene glycol deionized water	6.0 － － － 0.05 0.1 93.85 ------ 100.0	6.0 － 0.5 0.1 0.05 0.1 93.25 ------- 100.0				3.0 3.0 0.5 0.1 － 0.1 93.3 ------- 100.0

* contain the n-alkane of 60% carbon number average out to 27-33, the peak value of its distribution curve is in a scope.

The give system complex of * by two (octadecyl) methyl amine and citric acid are made by 1: 1 mixed in molar ratio.

Washing and rinsing operating process fiber conbidioning compositions in this example are used for the laundry and handle fabric, generally are to be used in the automatic washing machine.This composition is to prepare according to the program described in the example 1.Be about to the fusion together of each lipophilic ingredient, then in water-bearing media with hydrophilic component fusion, cool to room temperature then.

The reference composition (3A) and the present composition (3B and 3C) have all carried out washing operation and rinsing operating process test respectively, and the used concentration of commodity detergent in washings is the concentration of manufacturer's recommended.In the washing operation test, hardness of washing water is equivalent to the CaCO of 125PPm ₃, its temperature is 32 ℃.The fabric charge weight is big, and wash time is 14 minutes, and adopts cold rinse.The commodity detergent that is added in the washing operation additive is Tide washing powder (phosphorous hydrochlorate builder), FRESH START, liquid Tide and liquid Wisk.According to used composition of detergent, can change the washing operation additive concentration in the washings, make to contain 4～9% conditioning component in the water (or 68 liters of washings contain 75～150 gram conditioning compositions, promptly be approximately 0.1～0.2% concentration).5 pounds of common fabric samples that mix comprise: COTTON FABRIC, the single fabric of nylon tricot, Dacron, the two fabrics of Dacron, the cotton blending of 65/35Dacron/, Banlon cloth specimen (being used to estimate static focus) and flannelette towel (evaluation flexibility).Use big capacity, the automatic washing dryer of many performances with washing fabric drying 60 minutes, whole washing, dry run repeat secondary, (synthetic fiber) and the flexibility (flannelette towel) of the static of evaluation test fabric adhesion subsequently.After drying is finished shutdown for the third time, estimate the static adhesion at once.To static and soft test, the relative humidity in the test room is in 44～56% scope.After the drying machine taking-up, on clothes hanger, hung about 12 hours in the flannelette hand, estimate flexibility then.

In the washings that contain 3B and 3C washing operation additive, under the various concentration that are verified active conditioning component, all can see, compare with the 3A composition time, its static adheres to wants much slight, even careless which observer, all can find out the difference that apparent static adheres to.For the fiber softening evaluation, no matter be to carry out by veteran expert or by unskilled personnel, the result of the present composition is satisfactory equally.

An important observed result is: under the identical situation of active component content, make washing operation with the present composition and compare with commodity rinsing operating process softening agent Downg with softening agent

Make washing operation with capable better softness and the antistatic effect of having arrived of additive.

Except only using washing and the drying, in the rinsing operating process, use same handling procedure, obtained identical result.

Develop a kind of theory and explained detergent of the present invention when washing operation is used, composition is better than contrasting the reason of care composition and commercial fibre fabric softener, Here it is the applicant's WDC has played the effect of the reaction of the anion chemical combination of avoiding in cationic surfactant and the washings, thereby makes it give full play to its fiber conbidioning ability.This viewpoint has also obtained the support of some test results, as the experiment composition with to the electrical conductivity of composition and the mensuration of Zeta potential.

People such as desire change the example of enumerating in the literary composition, except that sun from the surface-activity conditioner WDC, other various components all can be omitted, the result of report is basic identical.Equally, different CATION composition among aforementioned or other embodiment of this specification and the source of WDC can replace the congener in the example 3, fabric soft and antistatic aspect, still can see similarly obvious differently, this has embodied the superiority of the present composition.For example, the ammonium and the halogenation trialkyl one low alkyl group ammonium of halogenation one senior alkyl three low alkyl groups all can be used, and it also can be above-mentioned WDC compound.

Embodiment 4

Component	Percentage (weight)
			A	B
	Linear alkyl benzene sulphonate sodium sulphate (cooperation anionic detergent) * * * Neodol 25-7 chlorination two (octadecyl) Dimethyl Ammonium * mineral fat citric acids (50% aqueous solution) triethanolamine Fu Er Malin optical brightener (TinopalR5BM, Extra Conc.) colouring agent (0.5% the aqueous solution) spices deionized water	5.0 1.7 15.0 6.0 - 9.0 0.3 0.2 0.2 1.0 0.4 61.2 -------- 100.0			5.0 1.7 15.0 6.0 0.5 9.0 0.3 0.2 0.2 1.0 0.4 60.7 ------- 100.0

* containing 60% average carbon number is the n-alkane of 27-33, and the peak value of distribution curve is in a scope.

* * nonionic detergent, it is 1 mole and contains the fatty alcohol of 12-15 carbon and the condensation product of 7 moles of ethylene oxide.

A kind of contrast decontamination, softening detergent compositions (4A) and the present composition (4B) be used for COTTON FABRIC and the synthetic fabrics tested, carry out according to the program described in the example 3, promptly only carry out single washing and drying, the method for describing by example 3 is estimated the static adhesiveness and the flexibility of fiber then.Since the effect of decontamination-softening detergent compositions of the present invention with will wash conditioner and join the effect that is produced in the washings of decontamination softening detergent compositions, be the same to a great extent, therefore, just as expected, the result that the washing operation in the result who obtains and the example 3 is reported with the fabric care composition is similar.Shown as example 3, repeatedly washed with drying by institute's test thread fabric and to help to improve conditioning effect, this is favourable to the present composition.

In order to improve the prescription of this composition, can all adopt anionic detergent or all adopt non-ionic surfactant, and anion and nonionic detergent can be replaced by other detergent in the example of front or described in the explanation, can replace by other quaternary ammonium salt (those) as chlorination two (octadecyl) Dimethyl Ammonium as mentioning in the preamble, or by other amine and quaternary ammonium complex (such as above-mentioned) replacement.In addition, WDC can replace with other type WDC that was introduced in the past.Result this or that this class develops remains: with the contrast that does not contain WDC but compound compare, it has the fabric conditioning performance of improvement, comprises softening performance and/or antistatic property.Another advantage of the present invention is under the concentration that this paper mentioned, various WDC can use safely (wherein many be accepted or approve be used for oral), and do not need the permission of toxicity test and government.

Embodiment 5

In front described prescription of embodiment and combination in, the variation of each component can realize by replacing.That is: with substitute wherein one or more of other material of mentioning in the explanation as congener or replacement.The ratio of component also can change, be generally ± 10%, ± 20% or ± 50%, only otherwise exceeding the scope of stipulating in the explanation gets final product.By replacing water with particulate vector (as builder or filler), preferably the mixture of the cationic surface active fiber conditioning agent of fusion and WDC is added respectively in washings or the washings in some cases, the mixture preferably liquid, or fusion or in suitable organic solvent (as isopropyl alcohol), or mix with the powder carrier.Also cationic surface active fiber conditioning agent and WDC can be added separately in washing or the washings.But just as previously noted, only depending on the mixing of such big degree when melting said components together at first is to obtain desirable fiber conbidioning effect.Moreover when they were used for washings or washings, optimum form was an emulsion.In addition, the present invention's expansion that awaits comprises quaternary ammonium salt with various WDC() be used to promote material the adhering to and absorption on processed fiber (sending out and daily fabric) that dissolubility is on duty mutually as the people.This class material has: fluorescent bleaches, colouring agent, spices, promotion soil release polymer, mildewcide, pest repellant, anti-fouling agent, crease-resistant chemical agent etc.They all can be used for hair-washing hair-care element, additive and detergent compositions.

Claims (26)

1, a kind of fiber conbidioning compositions, it comprises a kind of cationic surface active fiber conditioning agent and a kind of water dispersible compound WDC, contain long chain hydrocarbon group in the molecule of this compound with at least 25 carbon atoms, in above-mentioned composition, the cationic surface active fiber conditioning agent is in 1: 20～20: 1 scope with the ratio that contains the long chain hydrocarbon groups compound, these two kinds of materials are present in the composition with such ratio, are applied to just can improve on the fiber surface at least one adhering on institute's conditioning fiber matrix in them by the water-bearing media that will contain this composition.

2, according to the composition of claim 1, cationic surface active fiber conditioning agent wherein is a kind of quaternary ammonium salt; WDC is a kind of hydrocarbon, a kind of acid, a kind of ester, a kind of acid amides, a kind of amine, a kind of amine salt, a kind of quaternary ammonium salt or a kind of alcohol, or their mixtures arbitrarily, said composition contains water, above-mentioned quaternary ammonium salt is to be 0.5: 1～20: 1 scope to the ratio of WDC, and has a kind of above-claimed cpd at least attached on institute's conditioning fiber matrix (being that the people sends out or daily fabric).

3, according to the composition of claim 2, quaternary ammonium salt wherein and WDC are in aqueous emulsion, and wherein the ratio of quaternary ammonium salt is in 0.1～20% scope, and the ratio of WDC is in 0.1～10% scope.

4, according to the composition of claim 3; It can be after hair washing, and it is composed as follows as nursing one's health purificant: 0.2～10% quaternary ammonium salt, 0.1～5% WDC, 75～99% water-bearing media and one or more auxiliary agents (if desired) that all the other are.

5, according to the composition of claim 4; It consists of 0.2～5% quaternary ammonium halides, 0.1～2% WDC, one or more auxiliary agents of 85～98% water and surplus thereof (if needs).

6, according to the composition of claim 5; It consists of 0.3～2% the senior fatty alkyl three low alkyl group ammoniums of halogenation, halogenation two senior fatty alkyl two low alkyl group ammoniums or halogenation three senior fatty alkyl one low alkyl group ammoniums, and (wherein senior alkyl has 12～22 carbon atoms, low alkyl group has 1～3 carbon former), 0.1～1% WDC(is selected from the alkane that contains at least 25 carbon atoms, carboxylic acid, carboxylic acid ester, pure and mild their mixture), 90～97% water and one or more auxiliary agents (if needs) of surplus thereof.

7, according to the composition of claim 6, it consists of 0.4～2.0% cetyltrimethylammonium chloride, chlorination two (cetyl) Dimethyl Ammonium or chlorination two (octadecyl) Dimethyl Ammonium, 0.1 it is the n-alkane that about equal amount of mixture of mineral fat and beeswax and mineral fat and beeswax should contain average carbon number 27～33 for～0.5% WDC(), one or more auxiliary agents of 95～97% water and surplus thereof (if needs).

8, according to the composition of claim 3, its available conditioner shampoo, it consists of synthetic organic detergent of 5～25%, 0.2～10% quaternary ammonium salt, 0.1～5% WDC, one or more auxiliary agents of 65～94% aqueous medium and surplus thereof (if needs).

9, composition according to Claim 8; Its composition is 8～20% the synthetic organic detergent of anion, 0.2～5% quaternary ammonium halides, 0.1～2% WDC, one or more auxiliary agents of 70～90% water and surplus thereof (if needs).

10, according to claim 9 composition, its composition is, (wherein at least one is an ammonium to the mixture of the synthetic organic detergent of at least two kinds of different sulphation anion of 10～18%, sodium or triethanolamine salt), 0.3 (senior alkyl wherein has 12～22 carbon atoms to～2% chlorination three senior fatty alkyl one low alkyl group ammoniums, low alkyl group has 1～3 carbon atom), 0.1～1.5% WDC(is selected from the alkane of at least 25 carbon atoms, carboxylic acid, carboxylic esters, alcohol, acid amides, amine salt, quaternary ammonium salt and their mixture), one or more auxiliary agents of 75～85% water and surplus thereof (if needs).

11, according to the composition of claim 10, its composition is, 5～15% dodecyl sulphate amine and/or sodium, 1～10% dodecyl diethoxy ammonium sulfate and/or sodium, 0.4～2.0% chlorination three (cetyl) ammonium methyl, 0.1～2.0% WDC(takes from the mineral fat of the n-alkane that contains average carbon number 27～33, on average contains the paraffin and/or the beeswax of carbon number 25～30), one or more auxiliary agents of about 80% water and surplus thereof (if needs).

12, according to the combination of claim 3, it can be used as the fiber softening agents in fabric washing or the rinsing operating process, it consists of: the complex of 1～20% fiber softening quaternary ammonium salt, amine CATION, quaternary ammonium salt and anion surfactant or cationic complex of amine or their mixture, 0.1～5% WDC, one or more auxiliary agents of 70～97.9% aqueous medium and surplus thereof (if needs).

13, according to the composition of claim 12; Its composition is: 1.5～10% fiber softening quaternary ammonium salt, 0.1～2% WDC, 70～97.9% the water and the auxiliary agent of surplus thereof (if needs).

14, according to the composition of claim 13, it consists of 1.5～7% halogenation two senior fatty alkyl two low alkyl group ammoniums, and (senior alkyl has 12～22 carbon atoms, low alkyl group has 1～3 carbon atom), 0.1～2% WDC(is selected from the alkane that contains at least 25 carbon atoms, carboxylic acid, carboxylic acid ester, amine, amine salt, acid amides, quaternary ammonium salt, pure and mild their mixture), 85～95% the water and the auxiliary agent of surplus thereof (if needs).

15, according to the composition of claim 14, it consists of 2～8% chlorination two (octadecyl) Dimethyl Ammonium, 0.1～1% WDC(can adopt beeswax, mineral fat and/or paraffin), one or more auxiliary agents of 90～95% water and surplus thereof (if needs).

16, according to a composition of claim 3, can be used as decontamination, decontamination-softening detergent, be used for washing and softening fabrics, its composition is: synthetic organic detergent of decontamination effective dose, one or more decontamination builders of 0～75%, 2～20% fiber softening quaternary ammonium salt, the complex of amine CATION, quaternary ammonium salt and anion surfactant, the cationic complex of amine and their mixture, 0.1～2% WDC, one or more auxiliary agents of 0～75% water and surplus thereof (needing altogether).

17, according to a composition of claim 16, its composition is: synthetic organic detergent of 10～35% (being selected from anionic detergent, nonionic detergent one-tenth or their mixture), 2～15% quaternary ammonium salt or quaternary ammonium salt complex or their mixture, 0.1～2% WDC, one or more auxiliary agents of 50～92% water and surplus thereof (if needs).

18, according to the composition of claim 17, its composition is: 10～25% nonionic detergent (a mole contains the higher aliphatic of 10～16 carbon atoms and the condensation product of 3～11 moles of ethylene oxide), 2～10% anionic detergent (straight chain senior alkyl benzene sulfonate, wherein senior alkyl has 10～16 carbon atoms), (senior alkyl has 12～18 carbon former to 7～13% halogenation two senior fatty alkyl two lower alkyl ammoniums, low alkyl group has 1～3 carbon atom), or its citric acid compound.Or their mixture, 0.1～1% WDC(is selected from alkane, carboxylic acid, carboxylic acid ester and alcohol, or its mixture, and alkyl chain wherein has 25 carbon at least), one or more auxiliary agents of 60～75% water and surplus thereof (if needs).

19, composition according to claim 18, its composition is: 12～20% nonionic detergent (1 mole contains the higher aliphatic of 12～15 carbon atoms and the condensation product of 5～9 moles of ethylene oxide), 3～7% the moon are from detergent (sodium n-alkylbenzenesulfonate, wherein alkyl contains 10～14 carbon atoms), 1～5% chlorination two (octadecyl) Dimethyl Ammonium, the citric acid compound of 7～11% 2 (octadecyl) ammonium methyl, 0.1～0.5% WDC(can adopt the mineral fat of the n-alkane that contains average carbon number 27～33), one or more auxiliary agents of 65～70% water and surplus thereof (if needs).

20, a kind of method of fiber conbidioning compositions of the claim 1 of making the stable emulsion attitude, this method comprises: under 70～90 ℃ the high temperature range, and the melt of other thermally-stabilised lipophilic constituent (if the words that exist) in preparation cationic surfactant, WDC and the fiber conbidioning compositions; The aqueous medium that may contain other the thermally-stabilised hydrophilic component in the fiber conbidioning compositions is heated to 70～90 ℃ temperature range; Under roughly the same temperature, they are mixed then, make the fiber conbidioning compositions of stable emulsion attitude.

21, according to the method for claim 20, oleophylic and water seeking liquid component mix under about 80 ℃ temperature, and make it be cooled to room temperature while stirring, mix any temperature-sensitive component subsequently.

22, a kind ofly be used to handle fibrous material to nurse one's health its method, it comprises: make with 0.01～50% concentration to be scattered in fiber conbidioning compositions in the claim 1 in the water, in 10～40 ℃ temperature range, be used for above-mentioned 1～30 minute; Wash fiber conbidioning compositions solution or dispersion liquid on the fiber then, still, in the cationic fiber conditioner and WDC composition in the above-mentioned composition, at least a or two kinds all have some still to stay on the fiber.

23, according to the method for claim 22, fiber conbidioning compositions wherein is a kind of hair care hair dyeing promotor composition, it contains 0.2～10% quaternary ammonium salt, 0.1～5% WDC, one or more auxiliary agents (as needs) of 75～99% aqueous medium and surplus thereof, this hair care hair dyeing promotor composition is dispersed in the water by 10～50% concentration.

24, according to a method of claim 22, wherein, fiber conbidioning compositions is a kind of shampoo of hair washing and conditioning, it contains synthetic organic detergent of 5～25%, 0.2～10% quaternary ammonium salt, 0.1～5% WDC, one or more auxiliary agents (as needs) of 65～94% aqueous medium and surplus thereof, this shampoo is dissolved by 10～50% concentration or is dispersed in the water.

25, according to the method for claim 22, wherein, fiber conbidioning compositions is fabric washing and rinsing operating process fabric softening, it contains the cationic complex of complex, amine or their any mixture of 2～20% fiber softening quaternary ammonium salt, cationic amine, quaternary ammonium salt and anionic surfactant, 0.1～5% WDC, one or more auxiliary agents of 70～97.9% aqueous medium and surplus thereof (if needs), washing or rinsing operating process are dissolved by 0.05～2% concentration with fabric softening or are dispersed in the water.

26, according to the method for claim 22, wherein fiber conbidioning compositions is decontamination-softening detergent, it contains synthetic organic detergent of decontamination effective dose, 0～75% decontamination builder, 2～20% fiber softening quaternary ammonium salt, cationic amine, quaternary ammonium salt and cloudy from complex or the complex of cationic amine or their any mixture of surfactant, 0.1～0.5% WDC, one or more auxiliary agents of 0～75% water and surplus thereof (if needs), this decontamination-softening detergent dissolves by 0.1～2% concentration or is dispersed in the water.