CN104827665B - The Method of printing of three-dimensional printer - Google Patents
The Method of printing of three-dimensional printer Download PDFInfo
- Publication number
- CN104827665B CN104827665B CN201510183820.3A CN201510183820A CN104827665B CN 104827665 B CN104827665 B CN 104827665B CN 201510183820 A CN201510183820 A CN 201510183820A CN 104827665 B CN104827665 B CN 104827665B
- Authority
- CN
- China
- Prior art keywords
- film layer
- layer
- mass parts
- printing
- print job
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
Abstract
The print job platform provided by the invention applied on three-dimensional printer, print job platform include heating layer, glassy layer and film layer successively；Film layer is made of the heterocycle acrylic resin of 12 mass parts and the Weak solvent resin of 24 to 28 mass parts.After printing finishes, after heating layer stops heating, the temperature of film layer is gradually decrease to room temperature, adhesive force at this time between film layer and the contact surface of printing objects is near minimum, user can easily take out printing objects, the integrality of film layer will not be thus damaged, improves the service life of film layer.This film layer applies also for ABS, nylon（PA）And makrolon（PC）It is high Deng 3 D-printing material, versatility.
Description
Technical field
The present invention relates to a kind of coating and film layer applied on the workbench and workbench of three-dimensional printer, tool
Body, which is related to a kind of coating being improved by heterocycle acrylic resin to adhesive force and versatility, film layer, print job, puts down
Platform and preparation method.
Background technology
It is three-dimensional（3D）Printing technique is one kind of rapid shaping technique, its common print procedure is:First pass through computer
Modeling software models, then the threedimensional model built up " subregion " is cut into slices, so as to instruct printer successively to beat into section successively
Print.The material of three-dimensional printer mainly includes powdered-metal or plastics etc. can jointing material.
Rapid shaping technique currently on the market is broadly divided into melt-laminated molding technology（FDM), three dimensional printing technology
（3DP）, stereolithography techniques（SLA）, precinct laser sintering（SLS）, laser forming technology（DLP）.Melted extrusion modeling
Forming technique（FDM）It is common a kind of technical matters in three-dimensional printing technology, principle is existed using thermoplastic, polymeric materials
Under molten condition, melted material is squeezed out at nozzle, melted material solidifies the thin layer for forming contour shape afterwards to the cold, further
One layer of ground superposition of layer ultimately forms product.The most commonly used polymeric material of melted extrusion modeling forming technique is currently on the market
Acrylonitrile-butadiene-styrene terpolymer（ABS）And polylactic acid（PLA）, additionally there are nylon（PA）With poly- carbonic acid
Ester（PC）Deng material.
The melting temperature of printed material PLA is 200 DEG C to 205 DEG C, and ABS melting temperatures are about 220 DEG C, in 3 D-printing
In the machine course of work, ABS or PLA are after nozzle is expressed on workbench, and melted material starts to be converted into solid-state, at this time work
Make that between the contact surface of the film layer structure and melted material on platform an adhesive force can be produced, as melted material is slowly by melting
After state is changed into solid-state, adhesive force can be reduced with the temperature of material and gradually weakened, however, in the inside of printing objects and outside
There are certain temperature difference between portion, under thermal stress effect, the marginal portion of the object after printing easily occurs and platform point
From the situation of, warpage, so as to influence the exquisite degree of printing objects.
Therefore, the adhesive or adhesive force of melted material and workbench contact surface is strengthened, so as to prevent printing objects warpage
Phenomenon be those skilled in the art's problem that there is an urgent need for overcome.One layer would generally be pasted on print job platform in the prior art
Pad pasting, however, printed material such as polylactic acid（PLA）The inside of paster can be directly penetrated into after high-temperature fusion and is occurred with paster viscous
Even, after printing objects are cooled to room temperature, since printing objects and paster are sticked together, it is not easy to remove.Real work
In need to be separated object with paster with scuppit, such operation certainly will be easily destroyed object and paster, and often complete one or
Just need to replace the paster of workbench after pieces printed matter Products, and the technique that paster is replaced in real work is cumbersome, into
Originally significantly improve.
In addition, the Chinese utility model patent of Application No. CN201320392370.5 discloses a kind of 3D of FDM technology
Printer, its technical characteristic are included in one layer of viscous gum of coating, the use of this stickiness jelly on print job deck plate
It is in the warping phenomenon for avoiding printing objects, but this stickiness jelly is similar to above-mentioned paster function, service life
It is shorter, and this material does not provide specific chemical composition, and the material of three-dimensional printer has many kinds, to ability
For the those of ordinary skill of domain, without creative efforts, it is impossible to find a kind of general multiple types printing material
The stickiness jelly of material.
In addition, the Chinese invention patent application of Application No. CN201410459324.1 disclose a kind of 3D printer and its
The preparation method of workbench film layer.In actual application, it is found that the film layer that the program provides has good attachment for PLA
Power, and the generation of warping phenomenon is avoided well.However, when using ABS material or other 3 D-printing materials,
The object printed still can there are a degree of warping phenomenon in film layer.In addition, the manufacture method of this film layer is opposite
It is cumbersome, it is necessary to further improve chemical constituent, while a variety of printed material versatilities are improved, optimize preparation method, with more
It is adapted to industrial production well.
The content of the invention
For problem above existing in the prior art, the first object of the present invention is to provide one kind and applies in 3 D-printing
Print job platform on machine, the second object of the present invention are to provide a kind of painting of the print job platform coated in three-dimensional printer
Material, the third object of the present invention is to provide a kind of preparation method of the coating coated in 3 D-printing machine worktable, of the invention
4th purpose is to provide a kind of method of film layer on print job platform for preparing three-dimensional printer, and the fifth object of the present invention is to carry
For a kind of three-dimensional printer.
The print job platform provided by the invention applied on three-dimensional printer, print job platform include heating successively
Layer, glassy layer and film layer；Film layer is by the heterocycle acrylic resin of 12 mass parts and the Weak solvent resin group of 24 to 28 mass parts
Into.
Such scheme is taken, in practice, when being printed using PLA material, the temperature control of extrusion head is at 200 DEG C
To 205 DEG C, under the action of heating layer, the temperature of glassy layer is heated to 70 DEG C or so.Due to scribbling film layer on glassy layer, and film
Layer is molten state at high operating temperatures, when the filamentary material of melting comes out from extrusion head, can be maintained at 200 DEG C or so
The condition of high temperature, when melted material PLA is contacted with film layer, the PLA under the condition of high temperature can promote film layer by Solid State Transformation for melting
State, film layer in molten state and can produce an adhesive force between the contact surface of printing objects, can by this adhesive force
Printing objects are effectively adsorbed in film layer, therefore, warpage would not be produced between printing objects and the contact surface of film layer
Phenomenon.After the temperature of printing objects gradually reduces, the adhesive force between film layer and printing objects can gradually weaken, film layer
It can be recovered therewith by molten condition to solid-state.After printing finishes, after heating layer stops heating, the temperature of film layer is gradually decrease to
Room temperature, the adhesive force between film layer and the contact surface of printing objects is near minimum at this time, and user can easily take off
Printing objects, will not thus damage the integrality of film layer, improve the service life of film layer.When user needs replacing printing material
During material, such as when PLA is switched to ABS material, the temperature control of extrusion head is at 220 DEG C or so, but on print platform
Film layer without needing to change, and this film layer can play good warpage preventing effect for ABS.This film layer applies also for Buddhist nun
Dragon（PA）And makrolon（PC）It is high Deng 3 D-printing material, versatility.In addition, the print job platform of the present invention includes glass
The main reason for glass layer, selection glassy layer, includes at following 2 points：On the one hand, strong adhesive force of the film layer to glassy layer；And work as film
After layer is damaged, user only needs to remove glassy layer to be replaced, and of low cost due to glass, cost is low
It is and easy to operate.
One preferable scheme is that the thickness of film layer is 0.1 millimeter to 1 millimeter.
Take such scheme, it is contemplated that the thermal conductivity factor and bonding adhesion effect of film layer, practice, it is found that the thickness of film layer
Control is advisable in the range of 0.1 millimeter to 1 millimeter.
One preferable scheme is that Weak solvent resin is acrylic resin.
One preferable scheme is that heterocycle acrylic resin passes through tertiary carbonic acid glycidyl ester, methyl methacrylate, third
Olefin(e) acid butyl ester, methacrylic acid monomer, hydroxy propyl methacrylate monomer polymerization form.
The coating of print job platform provided by the invention coated in three-dimensional printer, print job platform include glassy layer,
Coating is used to be coated in glassy layer, and coating is prepared by following components：Heterocycle acrylic resin is 12 mass parts；Weak solvent
Resin is 24 to 28 mass parts；Diluent is 10 to 14 mass parts.
One preferable scheme is that Weak solvent resin is 26 mass parts, and diluent is 12 mass parts.
Such scheme is taken, searches out the optimization scheme of component proportions.
One preferable scheme is that diluent is ethyl acetate and/or amyl acetate and/or butyl acetate.
A kind of preparation method of coating coated in 3 D-printing machine worktable provided by the invention, print job platform include
Glassy layer, coating are used to be coated in glassy layer；By the heterocycle acrylic resin of 12 mass parts, 24 mass parts to 28 mass parts
Weak solvent resin, 10 mass parts obtain coating after mixing to the diluent of 14 mass parts.
Such scheme is taken, manufacturing process is very simple, and without harsh chemical operation, is very suitable for being applied to work
Industry produces.
The method of film layer on a kind of print job platform for preparing three-dimensional printer provided by the invention, it is characterised in that：Beat
Print workbench includes glassy layer, and film layer is attached on glassy layer；The method for preparing film layer comprises the following steps：By 12 mass parts
The Weak solvent resin of heterocycle acrylic resin, 24 to 28 mass parts；The diluent of 10 to 14 mass parts, is applied after mixing
Material；Coating is sprayed at glassy layer, is toasted 60 to 90 minutes at a temperature of 150 DEG C to 180 DEG C and obtains film layer.
A kind of three-dimensional printer provided by the invention, including print job platform, print job platform include heating successively
Layer, glassy layer and film layer；Film layer is by the heterocycle acrylic resin of 12 mass parts and the Weak solvent resin group of 24 to 28 mass parts
Into.The method for preparing film layer comprises the following steps：By the heterocycle acrylic resin of 12 mass parts, the Weak solvent of 24 to 28 mass parts
Resin；The diluent of 10 to 14 mass parts, obtains coating after mixing；Coating is sprayed at glassy layer, at 150 DEG C to 180
Toasted 60 to 90 minutes at a temperature of DEG C and obtain film layer.
Brief description of the drawings
Fig. 1 is the structure chart of the three-dimensional printer embodiment of the present invention.
Fig. 2 is the structure chart of the print job platform embodiment of the three-dimensional printer of the present invention.
Fig. 3 is the cutaway view Amplified image of the print job platform embodiment of the three-dimensional printer of the present invention.
Embodiment
First embodiment：
As shown in Figure 1, Figure 2 and Figure 3, three-dimensional printer 10 provided by the invention, including print job platform 11, print job
Platform 11 includes heating layer 12, glassy layer 13 and film layer 14 successively from up to down.Coating provided in this embodiment is used to be coated in glass
On glass layer 11.By the heterocycle acrylic resin of 12 mass parts, the Weak solvent resin of 24 mass parts to 28 mass parts, 10 mass parts extremely
The diluent of 14 mass parts, obtains coating after mixing.
Preferably, Weak solvent resin is acrylic resin, and acrylic resin is 26 mass parts, and Weak solvent resin is by Zhuhai day
Ran Baojie numeral science and technology company provides, product type NZZ009X.
Preferably, diluent includes at least following one kind：Ethyl acetate, amyl acetate, butyl acetate, diluent are 12 matter
Measure part.
The preparation method of hydridization acrylic resin is as follows：Equipped with blender, condenser, thermometer and constant pressure funnel
Four-hole boiling flask in add solvent and reactive intermediate tertiary carbonic acid glycidyl ester, by acrylic monomer mixing for standby use, propylene
Acrylic monomer can choose methyl methacrylate（MMA）, butyl acrylate（BA）, methacrylic acid（MAA）, methacrylic acid
Hydroxypropyl acrylate（HPMA）In one or more, the initiator of monomer polymerization is dissolved in the acrylic monomer of mixing.By flask
Acrylic compounds mix monomer is added dropwise after being warming up to 90 DEG C in middle solvent, and about 2.5 are added dropwise when small.Constant temperature is kept, is continued anti-
Answer 3 it is small when or so, be made slightly lurid transparent viscous liquid.Then, 60 DEG C or so are cooled to, quantitative amine is added and neutralizes
10 to 20 parts of agent, continue stirring 0.5 it is small when, added water in a manner of dropwise addition in system, heterocycle acrylic resin be made.Into one
The scheme of step optimization is can to add isocyanate curing agent in the reaction system（GH）, to lift the performance of acrylic monomers.
The scheme further optimized is that the optimal addn of isocyanate curing agent is the 0.8% of overall reaction system quality, by this ratio
Example adds isocyanates, and the cementability and resistance to elevated temperatures of heterocycle acrylic acid are excellent.
Second embodiment：
The method of film layer, print job platform include glass on the print job platform provided in this embodiment for preparing three-dimensional printer
Glass layer, film layer are attached on glassy layer；The method for preparing film layer comprises the following steps：By the heterocycle acrylic acid tree of 12 mass parts
Fat, the Weak solvent resin of 24 to 28 mass parts, the diluent of 10 to 14 mass parts, obtain coating after mixing；Coating is equal
It is sprayed at evenly on glassy layer, is toasted 60 to 90 minutes at a temperature of 150 DEG C to 180 DEG C and obtain film layer.Preferably, the thickness of film layer
Spend for 0.3 millimeter.
Hydridization acrylic resin is provided by dongguan new world technology co., ltd, and product type is the product of WZ510.
3rd embodiment：
The print job platform provided by the invention applied on three-dimensional printer, print job platform include heating successively
Layer, glassy layer and film layer；Film layer is by the heterocycle acrylic resin of 12 mass parts and the Weak solvent resin group of 24 to 28 mass parts
Into.The method for preparing glass platform comprises the following steps：By the heterocycle acrylic resin of 12 mass parts, 24 to 28 mass parts it is weak
The diluent of Solvent Resin, 10 to 14 mass parts, obtains coating after mixing；Coating is equably sprayed on glassy layer,
Toasted 60 to 90 minutes at a temperature of 150 DEG C to 180 DEG C and obtain glass platform.After glass platform is fixed on heating layer just
Form print job platform.After the film layer of glass platform sends damage, the glass platform that operating personnel directly more renew is i.e.
Can.
Fourth embodiment：
A kind of three-dimensional printer provided by the invention, including print job platform, print job platform include heating successively
Layer, glassy layer and film layer；Film layer is by the heterocycle acrylic resin of 12 mass parts and the Weak solvent resin group of 24 to 28 mass parts
Into.The method for preparing glass platform comprises the following steps：By the heterocycle acrylic resin of 12 mass parts, 24 to 28 mass parts it is weak
The diluent of Solvent Resin, 10 to 14 mass parts, obtains coating after mixing；Coating is equably sprayed on glassy layer,
Toasted 60 to 90 minutes at a temperature of 150 DEG C to 180 DEG C and obtain glass platform.After glass platform is fixed on heating layer just
Form print job platform.
Claims (1)
1. a kind of Method of printing of three-dimensional printer, including print job platform, it is characterised in that：
The print job platform includes heating layer, glassy layer and film layer successively；
The film layer is made of the heterocycle acrylic resin of 12 mass parts and the Weak solvent resin of 24 to 28 mass parts, described weak
Solvent Resin is acrylic resin；
The method for preparing the film layer comprises the following steps：
By the heterocycle acrylic resin of 12 mass parts, the Weak solvent resin of 24 to 28 mass parts；The diluent of 10 to 14 mass parts,
Coating is obtained after mixing；
The coating is sprayed at the glassy layer, is toasted 60 to 90 minutes at a temperature of 150 DEG C to 180 DEG C and obtains the film
Layer；
The Method of printing includes following step：
When melted material is contacted with film layer, it by Solid State Transformation is molten state that the melted material under the condition of high temperature, which can promote film layer,
Film layer in molten state and an adhesive force can be produced between the contact surface of printing objects, can be by this adhesive force
Printing objects are effectively adsorbed in film layer, and therefore, between printing objects and the contact surface of film layer would not produce warpage shows
As；After the temperature of printing objects gradually reduces, the adhesive force between film layer and printing objects can gradually weaken, and film layer also can
Recovered therewith by molten condition to solid-state；After printing finishes, after heating layer stops heating, the temperature of film layer is gradually decrease to room
Temperature, the adhesive force between film layer and the contact surface of printing objects is near minimum at this time.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810232957.7A CN108466422B (en) | 2015-04-17 | 2015-04-17 | Working method of three-dimensional printer |
| CN201510183820.3A CN104827665B (en) | 2015-04-17 | 2015-04-17 | The Method of printing of three-dimensional printer |
| PCT/CN2016/079165 WO2016165619A1 (en) | 2015-04-17 | 2016-04-13 | Three-dimensional printer, printing working platform applied to three-dimensional printer, paint, film layer and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510183820.3A CN104827665B (en) | 2015-04-17 | 2015-04-17 | The Method of printing of three-dimensional printer |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810232957.7A Division CN108466422B (en) | 2015-04-17 | 2015-04-17 | Working method of three-dimensional printer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104827665A CN104827665A (en) | 2015-08-12 |
| CN104827665B true CN104827665B (en) | 2018-04-27 |
Family
ID=53806030
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810232957.7A Active CN108466422B (en) | 2015-04-17 | 2015-04-17 | Working method of three-dimensional printer |
| CN201510183820.3A Active CN104827665B (en) | 2015-04-17 | 2015-04-17 | The Method of printing of three-dimensional printer |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810232957.7A Active CN108466422B (en) | 2015-04-17 | 2015-04-17 | Working method of three-dimensional printer |
Country Status (2)
| Country | Link |
|---|---|
| CN (2) | CN108466422B (en) |
| WO (1) | WO2016165619A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108466422B (en) * | 2015-04-17 | 2020-06-19 | 珠海天威飞马打印耗材有限公司 | Working method of three-dimensional printer |
| CN105563827B (en) * | 2015-11-06 | 2018-05-11 | 佛山市翔德工业设计有限公司 | 3D printer Anti-curling Method of printing |
| CN105459407B (en) * | 2016-01-31 | 2018-11-16 | 浙江智源办公设备制造有限公司 | A kind of 3d printing bottom plate |
| CN105904733B (en) * | 2016-06-08 | 2018-08-14 | 杭州百桥医疗技术有限公司 | A kind of bone biologic material 3D biometric print device and methods |
| CN107650381B (en) * | 2016-07-26 | 2021-02-19 | 精工爱普生株式会社 | Three-dimensional object molding table, manufacturing device, and manufacturing method |
| CN106515021A (en) * | 2016-09-30 | 2017-03-22 | 宁夏共享模具有限公司 | Working table for FDM printing equipment |
| JP6989272B2 (en) * | 2017-03-17 | 2022-01-05 | 日東電工株式会社 | Molding mat |
| GB2579089B (en) * | 2018-11-20 | 2022-07-13 | Henkel IP & Holding GmbH | Removal of a 3D printed part from a build substrate |
| CN109605734B (en) * | 2019-01-29 | 2020-09-11 | 张子厚 | 3D printer |
| CN110700013A (en) * | 2019-07-29 | 2020-01-17 | 曲阜远东职业技术学院 | 3D printing adhesive paper and method |
| CN113459510A (en) * | 2020-03-30 | 2021-10-01 | 上海翼青科技有限公司 | 3D printer |
| CN112642683A (en) * | 2020-12-24 | 2021-04-13 | 蒋明成 | Method for spraying glass 3D printer panel based on PEI powder |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1611542A (en) * | 2003-09-10 | 2005-05-04 | 住友化学工业株式会社 | Acrylic resin composition |
| CN104263150A (en) * | 2014-09-10 | 2015-01-07 | 珠海天威飞马打印耗材有限公司 | 3D printer and preparation method of worktable film thereof, and paint coated on 3D printer worktable and preparation method thereof |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0812381A (en) * | 1994-06-27 | 1996-01-16 | Kiyoojin Kk | Composite panel and its production |
| US6806308B2 (en) * | 2000-03-06 | 2004-10-19 | Chemico Systems, Inc. | Method for protecting paint on an article, a composition useful therefor, and a method for making the composition |
| CN101050259A (en) * | 2007-04-29 | 2007-10-10 | 江苏三木集团有限公司 | Water-soluble acrylic resin as lacquer in use for glass and preparation |
| CN202986389U (en) * | 2012-11-22 | 2013-06-12 | 上海纳尔数码喷印材料股份有限公司 | Three-layer three-dimensional one-way perspective printing material |
| CN103897537B (en) * | 2012-12-27 | 2016-12-28 | 青岛佳艺影像新材料技术有限公司 | Delustring Weak solvent phase paper coating composition |
| CN203449608U (en) * | 2013-07-03 | 2014-02-26 | 桂林半岛电子科技有限公司 | 3D (three dimensional) printer based on FDM (frequency-division multiplexing) technique |
| CN103386760A (en) * | 2013-07-03 | 2013-11-13 | 桂林半岛电子科技有限公司 | 3D printer based on FDM technology |
| JP2016531027A (en) * | 2013-07-30 | 2016-10-06 | イデアル ジェイコブス コーポレイション | Cover of 3D printer forming surface |
| CN104193908A (en) * | 2014-08-26 | 2014-12-10 | 太仓碧奇新材料研发有限公司 | Polyphenyl thioether composite material for 3D printing and preparation method thereof |
| CN108466422B (en) * | 2015-04-17 | 2020-06-19 | 珠海天威飞马打印耗材有限公司 | Working method of three-dimensional printer |
-
2015
- 2015-04-17 CN CN201810232957.7A patent/CN108466422B/en active Active
- 2015-04-17 CN CN201510183820.3A patent/CN104827665B/en active Active
-
2016
- 2016-04-13 WO PCT/CN2016/079165 patent/WO2016165619A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1611542A (en) * | 2003-09-10 | 2005-05-04 | 住友化学工业株式会社 | Acrylic resin composition |
| CN104263150A (en) * | 2014-09-10 | 2015-01-07 | 珠海天威飞马打印耗材有限公司 | 3D printer and preparation method of worktable film thereof, and paint coated on 3D printer worktable and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| FDM快速成型机原型精度分析及对策;于海波;《装备制造技术》;20140531(第5期);第139页第1.1节材料性能的影响、第140页第2.1节材料性能的影响 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104827665A (en) | 2015-08-12 |
| CN108466422A (en) | 2018-08-31 |
| WO2016165619A1 (en) | 2016-10-20 |
| CN108466422B (en) | 2020-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104827665B (en) | The Method of printing of three-dimensional printer | |
| US9707717B2 (en) | Thixotropic, thermosetting resins for use in a material extrusion process in additive manufacturing | |
| CN100560340C (en) | The adhering method of a kind of metal and plastic composite panel shell and device | |
| CN105196660B (en) | A kind of hot pressing shaping diaphragm and preparation method thereof | |
| CN104263150B (en) | The preparation method of a kind of 3D printer and its workbench film layer, coating coated in 3D printer workbench and preparation method thereof | |
| CN104802339B (en) | A kind of fast precise mould preparation method | |
| CN103660302B (en) | A kind of 3D printer of easy Model for ablation | |
| CN104015406B (en) | Embedded co-curing grid damp composite material structure and manufacture craft thereof | |
| CN105109044A (en) | Three-dimensional printing platform, three-dimensional forming base, three-dimensional printer and three-dimensional printing method | |
| CN203472158U (en) | 3D (Three-Dimensional) printing realizing device based on fused deposition modeling | |
| CN103418533A (en) | Synthetic plate and decorating method for the surface of synthetic plate | |
| CN106032064B (en) | A kind of 3D printing aftertreatment technology based on FDM technology | |
| CN103895274A (en) | Ceramic and plastic complex and preparation method thereof | |
| CN108249895A (en) | A kind of ceramic material and its 3D printing method of rapid curing forming | |
| CN204955462U (en) | Three -dimensional print platform , three -dimensional shaping seat and three -dimensional inkjet printer | |
| CN102277026A (en) | Lacquer putty for block board and preparation method thereof | |
| CN108943705A (en) | A kind of sand mold 3D rapid forming equipment using flat-panel printer | |
| CN105400443A (en) | Thermal-expansion strippable pressure-sensitive adhesive sheet and coater | |
| JP2008013732A (en) | Slurry composition for formed article, method for forming formed article, various materials using the slurry composition for the formed article, and method for using the same | |
| CN107877833A (en) | Terminal screen diaphragm preparation method and terminal screen diaphragm | |
| CN107553893A (en) | A kind of 3D printer bed process | |
| CN102873816B (en) | Screening method of integrated injection moulding glue | |
| CN203021838U (en) | Artificial leather manufacturing machine adopting novel coating method | |
| CN209723481U (en) | Lifeless thing moulds three-decker decorative material material | |
| JP6533457B2 (en) | Manufacturing method of emboss pattern transfer surface in injection mold |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220913 Address after: Room 103-036, 1st Floor, Building 1, No. 18, Futian Road, Xiangzhou District, Zhuhai City, Guangdong Province, 519000 (centralized office area) Patentee after: Zhuhai Tianwei Additives Co.,Ltd. Address before: 519060 Guangdong province Zhuhai Nanping Science and Technology Industrial Park, ping North Road No. 32 Patentee before: PRINT RITE UNICORN IMAGE PRODUCTS Co.,Ltd. OF ZHUHAI |
|
| TR01 | Transfer of patent right |