CN104805719A - Novel discharging agent composition for textile printing and dyeing - Google Patents

Novel discharging agent composition for textile printing and dyeing Download PDF

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Publication number
CN104805719A
CN104805719A CN201510240748.3A CN201510240748A CN104805719A CN 104805719 A CN104805719 A CN 104805719A CN 201510240748 A CN201510240748 A CN 201510240748A CN 104805719 A CN104805719 A CN 104805719A
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CN
China
Prior art keywords
parts
agent composition
discharging agent
novel discharging
textile printing
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Pending
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CN201510240748.3A
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Chinese (zh)
Inventor
厉秀华
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HUZHOU LIHUA YUJIE UNION TEXTILE CO Ltd
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HUZHOU LIHUA YUJIE UNION TEXTILE CO Ltd
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Priority to CN201510240748.3A priority Critical patent/CN104805719A/en
Publication of CN104805719A publication Critical patent/CN104805719A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a novel discharging agent composition for textile printing and dyeing. The novel discharging agent composition is prepared by the following components in parts by weight: 10 to 16 parts of phenyl salicylate, 6 to 15 parts of tetrabutyl titanate, 3 to 5 parts of 2, 4-dihydroxy benaophenonel, 3 to 10 parts of fatty alcohol-polyoxyethylene ether, 3 to 5 parts of sodium lactate, 4 to 5 parts of rongalite, 4 to 5 parts of phenyltriethoxysilane, 5 to 7 parts of sodium citrate, 15 to 20 parts of thiourea dioxide, 2 to 4 parts of epoxidized soybean oil, 5 to 7 parts of fatty acid alkanolamide, 2 to 4 parts of calcium stearate, 6 to 8 parts of oleic acid polyoxyethylene ester, and 100 to 110 parts of water. The novel discharging agent composition has the advantages that a preparation method is simple; the prepared product does not contain formaldehyde and heavy metal ions, and the safety and environment-friendly effects are realized; the stability of the thiourea dioxide is improved, the discharging effect is good, and the novel discharging agent composition is suitable for being popularized and applied.

Description

A kind of novel discharging agent composition for textile printing and dyeing
Technical field
The present invention relates to a kind of fabric finishing agent, especially a kind of novel discharging agent composition for textile printing and dyeing.
Technical background
At present, when printing and dyeing enterprise carries out DISCHARGE PRINTING to fabric, it need add a certain amount of discharging agent in printing paste, the discharging agent used mostly is reductant, discharging agent is the key chemical agent that discharge printing process is implemented, ground colour dyestuff generation chemical reaction (normally reduction reaction) of evaporating in (process certain wet heat condition under) process with printing position of its effect normally after stamp, makes the color development system of ground colour dyestuff destroy colour killing.The defect that the most existence and stability of existing discharging agent commodity is poor, storage period is short, this is mainly because discharging agent absorbs and the oxygen (oxygen may be dissolved in water) contacted in moisture content (pulpous state formulation and aqueous formulation are directly with water as medium) and ingress of air in storage process, thus cause discharging agent to decompose, active ingredient is incurred loss.In addition, solid fraction discharging agent is when modulating printing paste, and needing of having dissolves by hot water or other method, also easily causes the loss of active ingredient.
Discharging agent is the key chemical agent that discharge printing process is implemented, and its effect is the dyestuff generation reduction reaction of evaporating with printing position in process after stamp.Discharging agent conventional in current printing and dyeing is rongalite C, De Gulin and the white agent H of carving etc., they all easily discharge free formaldehyde, make printed articles not reach the requirement of ecological spinning, especially in coating discharge printing technique, after using adhesive, be difficult to especially remove the residual aldehyde of discharging agent.Thiourea dioxide also claims formamidine sulfinic acid, stablizes at normal temperatures, both non-oxidative, also without reducibility, isolates the sulphoxylic acid of strong reducing property under heating or alkali condition.But the solubility of thiourea dioxide in water is lower, and during DISCHARGE PRINTING, discharge slurry preparation hourly water consumption is little, and this makes thiourea dioxide can not be dissolved in discharge slurry fully, greatly affects its saturating net and the validity to the reduction of printing position.Therefore how overcoming the deficiencies in the prior art is problems that current technical field of textile auxiliary agent needs solution badly.
Summary of the invention
To achieve these goals, the invention provides a kind of novel discharging agent composition for textile printing and dyeing.
The object of the invention is to be achieved through the following technical solutions:
A kind of novel discharging agent composition for textile printing and dyeing, it is made up of the component mix and blend of following parts by weight: phenyl salicytate 10-16 part, butyl titanate 6-15 part, 2,4-DihydroxyBenzophenone 3-5 part, fatty alcohol-polyoxyethylene ether 3-10 part, sodium lactate 3-5 part, rongalite 4-5 part, phenyl triethoxysilane 4-5 part, natrium citricum 5-7 part, thiourea dioxide 15-20 part, epoxidized soybean oil 2-4 part, fatty acid alkanol amides 5-7 part, calcium stearate 2-4 part, polyoxyethylene oleic acid ester 6-8 part, water 100-110 part.
One of preferred version: it is obtained by the component of following parts by weight: phenyl salicytate 10 parts, butyl titanate 6 parts, 2,4-DihydroxyBenzophenone 3 parts, fatty alcohol-polyoxyethylene ether 3 parts, sodium lactate 3 parts, rongalite 4 parts, phenyl triethoxysilane 4 parts, natrium citricum 5 parts, thiourea dioxide 15 parts, epoxidized soybean oil 2 parts, fatty acid alkanol amides 5 parts, calcium stearate 2 parts, polyoxyethylene oleic acid ester 6 parts, 100 parts, water.
Preferred version two: it is obtained by the component of following parts by weight: phenyl salicytate 16 parts, butyl titanate 15 parts, 2,4-DihydroxyBenzophenone 5 parts, fatty alcohol-polyoxyethylene ether 10 parts, sodium lactate 5 parts, rongalite 5 parts, phenyl triethoxysilane 5 parts, natrium citricum 7 parts, thiourea dioxide 20 parts, epoxidized soybean oil 4 parts, fatty acid alkanol amides 7 parts, calcium stearate 4 parts, polyoxyethylene oleic acid ester 8 parts, 110 parts, water.
Preferred version three: it is obtained by the component of following parts by weight: phenyl salicytate 12 parts, butyl titanate 8 parts, 2,4-DihydroxyBenzophenone 4 parts, fatty alcohol-polyoxyethylene ether 4 parts, sodium lactate 4 parts, rongalite 4 parts, phenyl triethoxysilane 4 parts, natrium citricum 6 parts, thiourea dioxide 16 parts, epoxidized soybean oil 3 parts, fatty acid alkanol amides 6 parts, calcium stearate 3 parts, polyoxyethylene oleic acid ester 7 parts, 105 parts, water.
Preferred version four: it is obtained by the component of following parts by weight: phenyl salicytate 15 parts, butyl titanate 13 parts, 2,4-DihydroxyBenzophenone 4 parts, fatty alcohol-polyoxyethylene ether 8 parts, sodium lactate 4 parts, rongalite 5 parts, phenyl triethoxysilane 5 parts, natrium citricum 6 parts, thiourea dioxide 18 parts, epoxidized soybean oil 3 parts, fatty acid alkanol amides 6 parts, calcium stearate 3 parts, polyoxyethylene oleic acid ester 7 parts, 105 parts, water.
Its preparation method is: by weight ratio, each component is mixed, after stirring finished product.
The present invention has following beneficial effect:
Preparation method of the present invention is simple, and obtained product does not contain formaldehyde and heavy metal ion, safety and environmental protection; Improve thiourea dioxide stability to improve, discharge is good, is easy to apply.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Embodiment 1
A kind of novel discharging agent composition for textile printing and dyeing, it is made up of the component mix and blend of following parts by weight: phenyl salicytate 10 parts, butyl titanate 6 parts, 2,4-DihydroxyBenzophenone 3 parts, fatty alcohol-polyoxyethylene ether 3 parts, sodium lactate 3 parts, rongalite 4 parts, phenyl triethoxysilane 4 parts, natrium citricum 5 parts, thiourea dioxide 15 parts, epoxidized soybean oil 2 parts, fatty acid alkanol amides 5 parts, calcium stearate 2 parts, polyoxyethylene oleic acid ester 6 parts, 100 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Embodiment 2
A kind of novel discharging agent composition for textile printing and dyeing, it is made up of the component mix and blend of following parts by weight: phenyl salicytate 16 parts, butyl titanate 15 parts, 2,4-DihydroxyBenzophenone 5 parts, fatty alcohol-polyoxyethylene ether 10 parts, sodium lactate 5 parts, rongalite 5 parts, phenyl triethoxysilane 5 parts, natrium citricum 7 parts, thiourea dioxide 20 parts, epoxidized soybean oil 4 parts, fatty acid alkanol amides 7 parts, calcium stearate 4 parts, polyoxyethylene oleic acid ester 8 parts, 110 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Embodiment 3
A kind of novel discharging agent composition for textile printing and dyeing, it is made up of the component mix and blend of following parts by weight: phenyl salicytate 12 parts, butyl titanate 8 parts, 2,4-DihydroxyBenzophenone 4 parts, fatty alcohol-polyoxyethylene ether 4 parts, sodium lactate 4 parts, rongalite 4 parts, phenyl triethoxysilane 4 parts, natrium citricum 6 parts, thiourea dioxide 16 parts, epoxidized soybean oil 3 parts, fatty acid alkanol amides 6 parts, calcium stearate 3 parts, polyoxyethylene oleic acid ester 7 parts, 105 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Embodiment 4
A kind of novel discharging agent composition for textile printing and dyeing, it is made up of the component mix and blend of following parts by weight: phenyl salicytate 15 parts, butyl titanate 13 parts, 2,4-DihydroxyBenzophenone 4 parts, fatty alcohol-polyoxyethylene ether 8 parts, sodium lactate 4 parts, rongalite 5 parts, phenyl triethoxysilane 5 parts, natrium citricum 6 parts, thiourea dioxide 18 parts, epoxidized soybean oil 3 parts, fatty acid alkanol amides 6 parts, calcium stearate 3 parts, polyoxyethylene oleic acid ester 7 parts, 105 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.

Claims (5)

1. the novel discharging agent composition for textile printing and dyeing, it is characterized in that it is obtained by the component of following parts by weight: phenyl salicytate 10-16 part, butyl titanate 6-15 part, 2,4-DihydroxyBenzophenone 3-5 part, fatty alcohol-polyoxyethylene ether 3-10 part, sodium lactate 3-5 part, rongalite 4-5 part, phenyl triethoxysilane 4-5 part, natrium citricum 5-7 part, thiourea dioxide 15-20 part, epoxidized soybean oil 2-4 part, fatty acid alkanol amides 5-7 part, calcium stearate 2-4 part, polyoxyethylene oleic acid ester 6-8 part, water 100-110 part.
2. a kind of novel discharging agent composition for textile printing and dyeing according to claim 1, it is characterized in that it is obtained by the component of following parts by weight: phenyl salicytate 10 parts, butyl titanate 6 parts, 2,4-DihydroxyBenzophenone 3 parts, fatty alcohol-polyoxyethylene ether 3 parts, sodium lactate 3 parts, rongalite 4 parts, phenyl triethoxysilane 4 parts, natrium citricum 5 parts, thiourea dioxide 15 parts, epoxidized soybean oil 2 parts, fatty acid alkanol amides 5 parts, calcium stearate 2 parts, polyoxyethylene oleic acid ester 6 parts, 100 parts, water.
3. a kind of novel discharging agent composition for textile printing and dyeing according to claim 1, it is characterized in that it is obtained by the component of following parts by weight: phenyl salicytate 16 parts, butyl titanate 15 parts, 2,4-DihydroxyBenzophenone 5 parts, fatty alcohol-polyoxyethylene ether 10 parts, sodium lactate 5 parts, rongalite 5 parts, phenyl triethoxysilane 5 parts, natrium citricum 7 parts, thiourea dioxide 20 parts, epoxidized soybean oil 4 parts, fatty acid alkanol amides 7 parts, calcium stearate 4 parts, polyoxyethylene oleic acid ester 8 parts, 110 parts, water.
4. a kind of novel discharging agent composition for textile printing and dyeing according to claim 1, it is characterized in that it is obtained by the component of following parts by weight: phenyl salicytate 12 parts, butyl titanate 8 parts, 2,4-DihydroxyBenzophenone 4 parts, fatty alcohol-polyoxyethylene ether 4 parts, sodium lactate 4 parts, rongalite 4 parts, phenyl triethoxysilane 4 parts, natrium citricum 6 parts, thiourea dioxide 16 parts, epoxidized soybean oil 3 parts, fatty acid alkanol amides 6 parts, calcium stearate 3 parts, polyoxyethylene oleic acid ester 7 parts, 105 parts, water.
5. a kind of novel discharging agent composition for textile printing and dyeing according to claim 1, it is characterized in that it is obtained by the component of following parts by weight: phenyl salicytate 15 parts, butyl titanate 13 parts, 2,4-DihydroxyBenzophenone 4 parts, fatty alcohol-polyoxyethylene ether 8 parts, sodium lactate 4 parts, rongalite 5 parts, phenyl triethoxysilane 5 parts, natrium citricum 6 parts, thiourea dioxide 18 parts, epoxidized soybean oil 3 parts, fatty acid alkanol amides 6 parts, calcium stearate 3 parts, polyoxyethylene oleic acid ester 7 parts, 105 parts, water.
CN201510240748.3A 2015-05-12 2015-05-12 Novel discharging agent composition for textile printing and dyeing Pending CN104805719A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105672008A (en) * 2016-04-01 2016-06-15 成都纺织高等专科学校 Laser heat thermal induction reduction reaction type discharge printing agent as well as preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101275366A (en) * 2007-03-28 2008-10-01 浙江丝绸科技有限公司 Pulpy discharging agent for textile printing and preparation thereof
CN103711013A (en) * 2013-11-27 2014-04-09 江苏中新资源集团有限公司 Discharging agent for textile printing and preparation thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101275366A (en) * 2007-03-28 2008-10-01 浙江丝绸科技有限公司 Pulpy discharging agent for textile printing and preparation thereof
CN103711013A (en) * 2013-11-27 2014-04-09 江苏中新资源集团有限公司 Discharging agent for textile printing and preparation thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105672008A (en) * 2016-04-01 2016-06-15 成都纺织高等专科学校 Laser heat thermal induction reduction reaction type discharge printing agent as well as preparation method and application thereof

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Application publication date: 20150729

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