CN106243886A - A kind of environment-friendly water-based paint of wooden chair - Google Patents
A kind of environment-friendly water-based paint of wooden chair Download PDFInfo
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- CN106243886A CN106243886A CN201610614401.5A CN201610614401A CN106243886A CN 106243886 A CN106243886 A CN 106243886A CN 201610614401 A CN201610614401 A CN 201610614401A CN 106243886 A CN106243886 A CN 106243886A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment-friendly water-based paint of wooden chair, be made up of following material: butyl acrylate, acrylic acid, polyaminoester emulsion, modified alta-mud, allyloxy hydroxypropyl azochlorosulfonate acid sodium, glycerol, propandiol butyl ether, sulfonated oil, hydroxyethyl cellulose, dodecyl sodium sulfate, polyoxyethylene polyoxy propanol amidogen ether, polydimethylsiloxane, silane coupler, water.The water paint that the present invention prepares is strong to the adhesive force of timber, and dispersive property is good, water-fast, corrosion resistant performance is strong, there is good filming performance, the most easy to crack, and it is practically free of volatile solvent, record the content≤0.04g/kg of its formaldehyde, well below the safety criterion of national regulation, safe to use.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of environment-friendly water-based paint of wooden chair.
Background technology
Chair is an important component part in modern house life.The material being widely used in manufacturing chair has wood
Material, metal material, plastics and other various nature materials with some strength and synthetic material etc..Timber is to make
During chair, application is the most universal, is also one of the most traditional material.But because of the characteristic of timber itself, need in manufacturing process
It is carried out paint process and increase its aesthetic measure and decay resistance, but to contain a lot of volatility molten for present paint
Agent, can damage health.Water paint replaces organic solvent, so volatilize film forming when is all owing to using water
Water, also would not bring any injury to human body.The direction that although water paint is people to be pursued and develop, but present aqueous
Paint generally also exists the problem of the poor-performing such as resistance to water, wearability, hinders its further Popularization And Development.
Summary of the invention
In order to solve the problems referred to above, the invention provides a kind of environment-friendly water-based paint of wooden chair, have and be combined with wood materials
Intensity is high, the feature of use safety and environmental protection.
The present invention is achieved through the following technical solutions:
A kind of environment-friendly water-based paint of wooden chair, is made up of the material of following weight portion:
25 ~ 30 parts of butyl acrylate, 12 ~ 16 parts of acrylic acid, 18 ~ 20 parts of polyaminoester emulsions, 5 ~ 9 parts of modified alta-muds, 4 ~ 8 parts of alkene
Propoxyl group hydroxypropyl azochlorosulfonate acid sodium, 1 ~ 2 part of glycerol, 0.5 ~ 0.8 part of propandiol butyl ether, 0.6 ~ 1 part of sulfonated oil, 0.8 ~ 1.5 part of hydroxyl
Ethyl cellulose, 0.5 ~ 1 part of dodecyl sodium sulfate, 0.5 ~ 0.8 part of polyoxyethylene polyoxy propanol amidogen ether, 0.3 ~ 0.5 part poly-two
Methylsiloxane, 0.5 ~ 1 part of silane coupler, 50 ~ 55 parts of water；Described modified alta-mud is made up of the material of following weight portion:
40 ~ 45 parts of bentonite, 5 ~ 7 parts of nano zine oxides, 2 ~ 3 parts of nano-carbon powders, 1 ~ 4 part of sodium hexameta phosphate, 0.4 ~ 0.8 part of dodecyl
Dimethyl benzyl ammonium chloride, 0.2 ~ 0.5 part of agrimophol, 0.3 ~ 0.7 share theine, 3 ~ 6 parts of trioctyl phosphates.
Further, described method for preparing modified bentonite comprises the steps:
(1) bentonite is put in the hydrochloric acid solution that mass fraction is 4 ~ 6% and take out after immersion treatment 1 ~ 2h, then put it into matter
Measure immersion treatment 1 ~ 2h in the salpeter solution that mark is 5 ~ 7%, put it into the sulfuric acid solution that mass fraction is 8 ~ 10% the most again
Middle immersion treatment 1 ~ 2h, rinses well standby with clear water after taking-up；
(2) bentonite after step (1) being processed puts into calcining 4 ~ 5h under conditions of temperature is 800 ~ 850 DEG C, uses nitrogen after taking-up
Gas quickly cooling is to after room temperature, then puts it into calcining 2 ~ 3h under conditions of temperature is 1000 ~ 1200 DEG C, naturally cools to room after taking-up
Temperature is standby；
(3) by total with it to sodium hexameta phosphate, dodecyl dimethyl benzyl ammonium chloride, agrimophol, catechin and trioctyl phosphate
After the distilled water that quality is 3 ~ 5 times mixes jointly, after stirring with the rotating speed of 780 ~ 860 revs/min, uniformly spray in step
(2), on the bentonite after processing, then bentonite is dried to be not more than 12% to water content standby；
(4) after the bentonite of step (3) gained being pulverized 1200 mesh more equal with nano zine oxide, nano-carbon powder mix and blend
Even, obtain modified alta-mud.
Further, the size of described nano zine oxide is 60 ~ 75nm, and the size of described nano-carbon powder is 40
~50nm。
The preparation method of a kind of environment-friendly water-based paint of wooden chair, comprises the steps:
(1), after butyl acrylate, acrylic acid, polyaminoester emulsion and water being mixed jointly, stir with the rotating speed of 450 ~ 480 revs/min
After mixing 20 ~ 25min, then modified alta-mud and allyloxy hydroxypropyl azochlorosulfonate acid sodium are added, improve rotating speed to 550 ~ 600 revs/min
Clock, and solution temperature is heated to 45 ~ 47 DEG C, stir 40 ~ 50min；
(2) glycerol, propandiol butyl ether, sulfonated oil and hydroxyethyl cellulose are joined in the solution of step (1) gained, with
The rotating speed of 680 ~ 720 revs/min is standby after stirring 30 ~ 35min；
(3) altogether by dodecyl sodium sulfate, polyoxyethylene polyoxy propanol amidogen ether, polydimethylsiloxane and silane coupler finally
In the same solution joining step (2) gained, after stirring with the rotating speed of 320 ~ 350 revs/min.
There is advantages that the present invention with acrylate and polyurethane for primary raw material composition, wherein
Compounding and with the addition of modified alta-mud and allyloxy hydroxypropyl azochlorosulfonate acid sodium, these two kinds of compositions can good and acrylate, poly-ammonia
Polyisocyanate polyaddition, fills up in the space in polymer molecule, enhances its stability, wearability, resistance to water and Corrosion Protection；Third
The interpolation of glycol butyl ether and sulfonated oil improves dispersibility and the mobility of entirety；Final under the mating reaction of each composition, this
The water paint that invention prepares is strong to the adhesive force of timber, and dispersive property is good, water-fast, corrosion resistant performance strong, has good film property
Can, the most easy to crack, and it is practically free of volatile solvent, record the content≤0.04g/kg of its formaldehyde, well below national regulation
Safety criterion, safe to use.
Detailed description of the invention
Embodiment 1
A kind of environment-friendly water-based paint of wooden chair, is made up of the material of following weight portion:
25 parts of butyl acrylate, 12 parts of acrylic acid, 18 parts of polyaminoester emulsions, 5 parts of modified alta-muds, 4 parts of allyloxy hydroxypropyls
Sodium sulfonate, 1 part of glycerol, 0.5 part of propandiol butyl ether, 0.6 part of sulfonated oil, 0.8 part of hydroxyethyl cellulose, 0.5 part of dodecyl
Sodium sulfonate, 0.5 part of polyoxyethylene polyoxy propanol amidogen ether, 0.3 part of polydimethylsiloxane, 0.6 part of silane coupler, 50 parts of water；
Described modified alta-mud is made up of the material of following weight portion: 40 parts of bentonite, 5 parts of nano zine oxides, 2 parts of nano-carbon powders, 1 part
Sodium hexameta phosphate, 0.4 part of dodecyl dimethyl benzyl ammonium chloride, 0.2 part of agrimophol, 0.3 share theine, 3 parts of tricresyl phosphates are pungent
Ester.
Further, described method for preparing modified bentonite comprises the steps:
(1) bentonite is put in the hydrochloric acid solution that mass fraction is 6% and to take out after immersion treatment 1h, then put it into quality and divide
Number be 7% salpeter solution in immersion treatment 1h, put it into immersion treatment in the sulfuric acid solution that mass fraction is 10% the most again
1h, rinses well standby with clear water after taking-up；
(2) bentonite after step (1) being processed puts into calcining 4h under conditions of temperature is 830 DEG C, uses nitrogen quickly cooling after taking-up
To room temperature, then put it into calcining 2h under conditions of temperature is 1200 DEG C, naturally cool to room temperature after taking-up standby；
(3) by total with it to sodium hexameta phosphate, dodecyl dimethyl benzyl ammonium chloride, agrimophol, catechin and trioctyl phosphate
After the distilled water that quality is 3 times mixes jointly, after stirring with the rotating speed of 840 revs/min, uniformly spray and process in step (2)
After bentonite on, then bentonite is dried to be not more than 12% to water content standby；
(4) after the bentonite of step (3) gained being pulverized 1200 mesh more equal with nano zine oxide, nano-carbon powder mix and blend
Even, obtain modified alta-mud.
Further, the size of described nano zine oxide is 60 ~ 70nm, and the size of described nano-carbon powder is 45
~50nm。
The preparation method of a kind of environment-friendly water-based paint of wooden chair, comprises the steps:
(1), after butyl acrylate, acrylic acid, polyaminoester emulsion and water being mixed jointly, stir with the rotating speeds of 460 revs/min
After 25min, then modified alta-mud and allyloxy hydroxypropyl azochlorosulfonate acid sodium are added, improve rotating speed to 580 revs/min, and by molten
Liquid temp is heated to 47 DEG C, stirs 44min；
(2) glycerol, propandiol butyl ether, sulfonated oil and hydroxyethyl cellulose are joined in the solution of step (1) gained, with
The rotating speed of 700 revs/min is standby after stirring 32min；
(3) altogether by dodecyl sodium sulfate, polyoxyethylene polyoxy propanol amidogen ether, polydimethylsiloxane and silane coupler finally
In the same solution joining step (2) gained, after stirring with the rotating speed of 330 revs/min.
Comparative example 1
Bentonite compared with Example 1, is not modified processing by this comparative example 1, and method step in addition is the most identical.
Comparative example 2
Compared with Example 1, the allyloxy hydroxypropyl azochlorosulfonate acid sodium of the weight portions such as use replaces bentone to this comparative example 2
Soil, method step in addition is the most identical.
Comparative example 3
Compared with Example 1, the modified alta-mud of the weight portions such as use replaces allyloxy hydroxypropyl sulfonic acid to this comparative example 3
Sodium, method step in addition is the most identical.
Matched group
Existing woodwork water paint.
In order to contrast effect of the present invention, the water paint preparing above-mentioned five kinds of modes carries out performance test, its correction data
As shown in the table:
| Embodiment 1 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Matched group | |
| Hardness of paint film (shoreD) | 68±1 | 65±2 | 60±2 | 62±2 | 60±2 |
| Adhesive force (ISO grade) | 5B | 4B | 3B | 3B | 3B |
| Resistance to water (50d) | Unchanged | Loss of gloss, light discolouration | Light discolouration, loss of gloss, foaming | Variable color, loss of gloss, wrinkling | Variable color, loss of gloss, bubble, come off |
| Thermostability (120 DEG C, 24h) | Unchanged | Light discolouration | Variable color | Variable color | Serious discoloration |
Above-mentioned test is all followed relevant criterion and is carried out.
As can be seen from the above table, the water paint hardness of present invention preparation, adhesive force, water-fast, heat resistance all have well
Promote, and between the allyloxy hydroxypropyl azochlorosulfonate acid sodium of interpolation and modified alta-mud composition, there is the most collaborative facilitation.
Claims (4)
1. the environment-friendly water-based paint of wooden chair, it is characterised in that be made up of the material of following weight portion:
25 ~ 30 parts of butyl acrylate, 12 ~ 16 parts of acrylic acid, 18 ~ 20 parts of polyaminoester emulsions, 5 ~ 9 parts of modified alta-muds, 4 ~ 8 parts of alkene
Propoxyl group hydroxypropyl azochlorosulfonate acid sodium, 1 ~ 2 part of glycerol, 0.5 ~ 0.8 part of propandiol butyl ether, 0.6 ~ 1 part of sulfonated oil, 0.8 ~ 1.5 part of hydroxyl
Ethyl cellulose, 0.5 ~ 1 part of dodecyl sodium sulfate, 0.5 ~ 0.8 part of polyoxyethylene polyoxy propanol amidogen ether, 0.3 ~ 0.5 part poly-two
Methylsiloxane, 0.5 ~ 1 part of silane coupler, 50 ~ 55 parts of water；Described modified alta-mud is made up of the material of following weight portion:
40 ~ 45 parts of bentonite, 5 ~ 7 parts of nano zine oxides, 2 ~ 3 parts of nano-carbon powders, 1 ~ 4 part of sodium hexameta phosphate, 0.4 ~ 0.8 part of dodecyl
Dimethyl benzyl ammonium chloride, 0.2 ~ 0.5 part of agrimophol, 0.3 ~ 0.7 share theine, 3 ~ 6 parts of trioctyl phosphates.
The environment-friendly water-based paint of the wooden chair of one the most according to claim 1, it is characterised in that the preparation of described modified alta-mud
Method comprises the steps:
(1) bentonite is put in the hydrochloric acid solution that mass fraction is 4 ~ 6% and take out after immersion treatment 1 ~ 2h, then put it into matter
Measure immersion treatment 1 ~ 2h in the salpeter solution that mark is 5 ~ 7%, put it into the sulfuric acid solution that mass fraction is 8 ~ 10% the most again
Middle immersion treatment 1 ~ 2h, rinses well standby with clear water after taking-up；
(2) bentonite after step (1) being processed puts into calcining 4 ~ 5h under conditions of temperature is 800 ~ 850 DEG C, uses nitrogen after taking-up
Gas quickly cooling is to after room temperature, then puts it into calcining 2 ~ 3h under conditions of temperature is 1000 ~ 1200 DEG C, naturally cools to room after taking-up
Temperature is standby；
(3) by total with it to sodium hexameta phosphate, dodecyl dimethyl benzyl ammonium chloride, agrimophol, catechin and trioctyl phosphate
After the distilled water that quality is 3 ~ 5 times mixes jointly, after stirring with the rotating speed of 780 ~ 860 revs/min, uniformly spray in step
(2), on the bentonite after processing, then bentonite is dried to be not more than 12% to water content standby；
(4) after the bentonite of step (3) gained being pulverized 1200 mesh more equal with nano zine oxide, nano-carbon powder mix and blend
Even, obtain modified alta-mud.
The environment-friendly water-based paint of the wooden chair of one the most according to claim 1 and 2, it is characterised in that described nano zine oxide
Size is 60 ~ 75nm, and the size of described nano-carbon powder is 40 ~ 50nm.
The environment-friendly water-based paint of the wooden chair of one the most according to claim 1, it is characterised in that its preparation method includes walking as follows
Rapid:
(1), after butyl acrylate, acrylic acid, polyaminoester emulsion and water being mixed jointly, stir with the rotating speed of 450 ~ 480 revs/min
After mixing 20 ~ 25min, then modified alta-mud and allyloxy hydroxypropyl azochlorosulfonate acid sodium are added, improve rotating speed to 550 ~ 600 revs/min
Clock, and solution temperature is heated to 45 ~ 47 DEG C, stir 40 ~ 50min；
(2) glycerol, propandiol butyl ether, sulfonated oil and hydroxyethyl cellulose are joined in the solution of step (1) gained, with
The rotating speed of 680 ~ 720 revs/min is standby after stirring 30 ~ 35min；
(3) altogether by dodecyl sodium sulfate, polyoxyethylene polyoxy propanol amidogen ether, polydimethylsiloxane and silane coupler finally
In the same solution joining step (2) gained, after stirring with the rotating speed of 320 ~ 350 revs/min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610614401.5A CN106243886A (en) | 2016-07-29 | 2016-07-29 | A kind of environment-friendly water-based paint of wooden chair |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614401.5A CN106243886A (en) | 2016-07-29 | 2016-07-29 | A kind of environment-friendly water-based paint of wooden chair |
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| CN106243886A true CN106243886A (en) | 2016-12-21 |
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| CN201610614401.5A Pending CN106243886A (en) | 2016-07-29 | 2016-07-29 | A kind of environment-friendly water-based paint of wooden chair |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107699192A (en) * | 2017-08-30 | 2018-02-16 | 含山县茂盛胶合板厂 | A kind of glued board High-performance adhesive |
| CN107804989A (en) * | 2017-11-02 | 2018-03-16 | 马鞍山市宝奕金属制品工贸有限公司 | A kind of bentonite filler for construction material manufacture |
| CN108299935A (en) * | 2018-01-31 | 2018-07-20 | 枞阳县三金颜料有限责任公司 | A kind of preparation method of the filler of reinforced resin coating intensity |
| CN109111839A (en) * | 2018-07-17 | 2019-01-01 | 安徽江淮车轮有限公司 | A kind of anti-ultraviolet paint and preparation method thereof |
| CN112622344A (en) * | 2019-10-09 | 2021-04-09 | 大理州祥云大宇包装有限公司 | Energy-saving and environment-friendly corrugated carton production process |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107699192A (en) * | 2017-08-30 | 2018-02-16 | 含山县茂盛胶合板厂 | A kind of glued board High-performance adhesive |
| CN107804989A (en) * | 2017-11-02 | 2018-03-16 | 马鞍山市宝奕金属制品工贸有限公司 | A kind of bentonite filler for construction material manufacture |
| CN107804989B (en) * | 2017-11-02 | 2021-02-05 | 马鞍山市宝奕金属制品工贸有限公司 | Bentonite filler for building material manufacture |
| CN108299935A (en) * | 2018-01-31 | 2018-07-20 | 枞阳县三金颜料有限责任公司 | A kind of preparation method of the filler of reinforced resin coating intensity |
| CN109111839A (en) * | 2018-07-17 | 2019-01-01 | 安徽江淮车轮有限公司 | A kind of anti-ultraviolet paint and preparation method thereof |
| CN112622344A (en) * | 2019-10-09 | 2021-04-09 | 大理州祥云大宇包装有限公司 | Energy-saving and environment-friendly corrugated carton production process |
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| C06 | Publication | ||
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Application publication date: 20161221 |
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| RJ01 | Rejection of invention patent application after publication |