CN107313258A - A kind of silk fabric refining is with low bubble alkali-resistant penetrant - Google Patents
A kind of silk fabric refining is with low bubble alkali-resistant penetrant Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/59—Polyamides; Polyimides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The invention discloses a kind of silk fabric refining with low bubble alkali-resistant penetrant, it is related to textile process auxiliary agent technical field, is made up of the raw material of following parts by weight：10 20 parts of poly-aspartic-acid/poly glycol monomethyl ether, modified 15 parts of PLURONICS F87,15 parts of polyglutamic acid, 15 parts of hydroxyethyl cellulose, 0.5 1 parts of hydroxypropyl PASELLI EASYGEL, 0.5 1 parts of rilanit special, 0.1 0.5 parts of sodium gluconate, 0.05 0.2 parts of Tea Polyphenols.Bleeding agent good water solubility of the present invention, alkali resistance and permeability are strong, and low bubble, easily rinsing, rinsing water amount is reduced, coordinates refinery practice effectively to remove the spot being stained with before slurry, the colouring agent added in natural impurity contained on fabric, weaving process, and dyeing and finishing processing.
Description
Technical field：
The present invention relates to textile process auxiliary agent technical field, and in particular to a kind of silk fabric refining steeps alkaline-resisting infiltration with low
Agent.
Background technology：
The purpose of silk fabric refining is to utilize chemical reagent, coordinates physics, machinery effect, is removed contained on fabric
Natural impurity (mainly silk gum, pigment, wax, inorganic matter etc.), the slurry, the colouring agent that add in weaving process, Yi Jiran
The spot (such as greasy dirt, rust stain) being stained with before whole processing, obtains that gloss fertilizer is bright, soft, whiteness is pure, lines is clear, ooze
The white product of the good white silk of permeability, or provide the second best in quality semi-products for dyeing, stamp.
Refining agent is usually to be formed by the surfactant compound of different performance, right with the continuous progress of printing technology
The requirement of refining agent performance is also improved constantly, and it is not required nothing more than should have good wetting infiltration, emulsion dispersion and washing performance,
And its alkali resistance and low bubble also gradually cause the attention of people.
It is well known that the refining of silk fabric is carried out in strongly basic medium, and pushing away with abbreviated system
Extensively, amount of caustic soda is greatly improved, and this just proposes requirements at the higher level to the alkali resistance of refining agent.Furthermore, conventional refinery agent is generally high
Foam type, high foam not only influences to operate but also be difficult rinsing.
The content of the invention：
The technical problems to be solved by the invention are to provide the silk fabric essence that a kind of consumption is few and performance is excellent
Refine with low bubble alkali-resistant penetrant.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of silk fabric refining is made up with low bubble alkali-resistant penetrant of the raw material of following parts by weight：
Poly-aspartic-acid/10-20 parts of poly glycol monomethyl ether, modified 1-5 parts of PLURONICS F87, polyglutamic acid 1-5
Part, 1-5 parts of hydroxyethyl cellulose, 0.5-1 parts of hydroxypropyl PASELLI EASYGEL, 0.5-1 parts of rilanit special, sodium gluconate
0.1-0.5 parts, 0.05-0.2 parts of Tea Polyphenols.
Its preparation method comprises the following steps：
(1) rilanit special and Tea Polyphenols are added into hydroxyethyl cellulose, is sufficiently mixed, then heats to 75-80 DEG C
Insulation grinding 10-15min, produces modified hydroxyethylcellulosadsorbing；
(2) modified PLURONICS F87 and the starch phosphorus of hydroxypropyl two are added into poly-aspartic-acid/poly glycol monomethyl ether
Acid esters, is transferred to sealing and standing 1-2h in 0-5 DEG C of environment after being sufficiently mixed, then is warming up to 80-85 DEG C of insulation grinding 10-15min, i.e.,
Obtain powder；
(3) polyglutamic acid, modified hydroxyethylcellulosadsorbing and gluconic acid are added while hot into above-mentioned obtained powder
Sodium, continues, in 80-85 DEG C of insulation grinding 10-15min, finally to naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
The preparation method of the poly-aspartic-acid/poly glycol monomethyl ether is：Add under stirring into poly-aspartic-acid
Water is warming up to 55-60 DEG C of insulated and stirred 10min, adds poly glycol monomethyl ether up to being completely dissolved, and is continuously heating to backflow
State insulated and stirred 2h, then adds N hydroxymethyl acrylamide and double trifluoromethanesulfonimides, flow back insulated and stirred again
30min, and naturally cool in room temperature, gained mixed liquor feeding freeze drier, gained solid is dried through ultramicro grinding mechanism
Into micro mist.
The poly-aspartic-acid, poly glycol monomethyl ether, N hydroxymethyl acrylamide and double trifluoromethanesulfonimides
Mass ratio be 5-10:5-10:0.5-2:0.1-1.
The modified PLURONICS F87 is made by the modified processing of PLURONICS F87, and its preparation method is：Under stirring to
Added water in PLURONICS F87 up to being completely dissolved, obtain the aqueous solution of PLURONICS F87；And add under agitation into stearic acid
Absolute ethyl alcohol obtains stearic ethanol solution up to being completely dissolved；Added into the aqueous solution of PLURONICS F87 stearic
Ethanol solution, is sufficiently mixed after microwave reflow treatment 10min under microwave frequency 2450MHz, power output 700W, stands
Continue microwave reflow treatment 5min after 15min, add allyl glycidyl ether and HPMA, after being well mixed
Microwave reflow treatment 5min again, gained mixture is volatilized in being ground to solvent at 70-75 DEG C, produces modified PLURONICS F87.
The PLURONICS F87, stearic acid, the mass ratio of allyl glycidyl ether and HPMA are 1-5:
0.5-2:0.1-0.5:0.05-0.2。
The beneficial effects of the invention are as follows：The present invention is assisted with many using poly-aspartic-acid/poly glycol monomethyl ether as major ingredient
Kind of auxiliary material is made the low bubble alkali-resistant penetrant of silk fabric refining, the bleeding agent good water solubility, alkali resistance and permeability by force, and
Low bubble, easily rinsing, reduce rinsing water amount；The bleeding agent coordinate refinery practice effectively remove on fabric contained natural impurity,
The spot being stained with before slurry, the colouring agent added in weaving process, and dyeing and finishing processing, obtains good luster, soft, whiteness
Pure, lines is clear, the white product of white silk of good penetrability, or provides the second best in quality semi-products for dyeing, stamp.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) 0.5g rilanit specials and 0.05g Tea Polyphenols are added into 3g hydroxyethyl celluloses, is sufficiently mixed, Ran Housheng
Temperature produces modified hydroxyethylcellulosadsorbing to 75-80 DEG C of insulation grinding 10min；
(2) 3g is added into 15g poly-aspartic-acids/poly glycol monomethyl ether and is modified PLURONICS F87 and 0.5g hydroxypropyls
Base PASELLI EASYGEL, is transferred to sealing and standing 1h in 0-5 DEG C of environment, then be warming up to 80-85 DEG C of insulation grinding after being sufficiently mixed
10min, produces powder；
(3) 3g polyglutamic acids, modified hydroxyethylcellulosadsorbing and 0.1g Portugals are added while hot into above-mentioned obtained powder
Grape sodium saccharate, continues, in 80-85 DEG C of insulation grinding 10min, finally to naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
The preparation of poly-aspartic-acid/poly glycol monomethyl ether：Added water under stirring into 10g poly-aspartic-acids until complete
Fully dissolved, is warming up to 55-60 DEG C of insulated and stirred 10min, adds 5g poly glycol monomethyl ethers, is continuously heating to reflux state guarantor
Temperature stirring 2h, then adds 0.5gN- NMAs and the double trifluoromethanesulfonimides of 0.1g, and the insulation that flows back again is stirred
30min is mixed, and is naturally cooled in room temperature, gained mixed liquor feeding freeze drier, gained solid is dried through micronizer
Micro mist is made.
The preparation of modified PLURONICS F87：Add water up to being completely dissolved, moored into 5g PLURONICS F87s under stirring
Luo Shamu 188 aqueous solution；And add absolute ethyl alcohol until being completely dissolved into 2g stearic acid under agitation, obtain stearic second
Alcoholic solution；Stearic ethanol solution is added into the aqueous solution of PLURONICS F87, is sufficiently mixed after microwave frequency
Microwave reflow treatment 10min under 2450MHz, power output 700W, stands and continues microwave reflow treatment 5min after 15min, then add
Enter 0.2g allyl glycidyl ethers and 0.05g HPMAs, microwave reflow treatment 5min, institute again after being well mixed
Mixture is volatilized in being ground to solvent at 70-75 DEG C, produce modified PLURONICS F87.
Embodiment 2
(1) 0.5g rilanit specials and 0.05g Tea Polyphenols are added into 5g hydroxyethyl celluloses, is sufficiently mixed, Ran Housheng
Temperature produces modified hydroxyethylcellulosadsorbing to 75-80 DEG C of insulation grinding 15min；
(2) 5g is added into 20g poly-aspartic-acids/poly glycol monomethyl ether and is modified PLURONICS F87 and 1g hydroxypropyls
PASELLI EASYGEL, is transferred to sealing and standing 2h in 0-5 DEG C of environment, then be warming up to 80-85 DEG C of insulation grinding after being sufficiently mixed
15min, produces powder；
(3) 5g polyglutamic acids, modified hydroxyethylcellulosadsorbing and 0.3g Portugals are added while hot into above-mentioned obtained powder
Grape sodium saccharate, continues, in 80-85 DEG C of insulation grinding 15min, finally to naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
The preparation of poly-aspartic-acid/poly glycol monomethyl ether：Added water under stirring into 10g poly-aspartic-acids until complete
Fully dissolved, is warming up to 55-60 DEG C of insulated and stirred 10min, adds 10g poly glycol monomethyl ethers, be continuously heating to reflux state
Insulated and stirred 2h, then adds 1g N hydroxymethyl acrylamides and the double trifluoromethanesulfonimides of 0.1g, and the insulation that flows back again is stirred
30min is mixed, and is naturally cooled in room temperature, gained mixed liquor feeding freeze drier, gained solid is dried through micronizer
Micro mist is made.
The preparation of modified PLURONICS F87：Add water up to being completely dissolved, moored into 5g PLURONICS F87s under stirring
Luo Shamu 188 aqueous solution；And add absolute ethyl alcohol until being completely dissolved into 1g stearic acid under agitation, obtain stearic second
Alcoholic solution；Stearic ethanol solution is added into the aqueous solution of PLURONICS F87, is sufficiently mixed after microwave frequency
Microwave reflow treatment 10min under 2450MHz, power output 700W, stands and continues microwave reflow treatment 5min after 15min, then add
Enter 0.1g allyl glycidyl ethers and 0.05g HPMAs, microwave reflow treatment 5min, institute again after being well mixed
Mixture is volatilized in being ground to solvent at 70-75 DEG C, produce modified PLURONICS F87.
Reference examples 1
(1) 5g is added into 20g poly-aspartic-acids/poly glycol monomethyl ether and is modified PLURONICS F87 and 1g hydroxypropyls
PASELLI EASYGEL, is transferred to sealing and standing 2h in 0-5 DEG C of environment, then be warming up to 80-85 DEG C of insulation grinding after being sufficiently mixed
15min, produces powder；
(2) 5g polyglutamic acids, 5g hydroxyethyl celluloses and 0.3g grapes are added while hot into above-mentioned obtained powder
Sodium saccharate, continues, in 80-85 DEG C of insulation grinding 15min, finally to naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
The preparation of poly-aspartic-acid/poly glycol monomethyl ether：Added water under stirring into 10g poly-aspartic-acids until complete
Fully dissolved, is warming up to 55-60 DEG C of insulated and stirred 10min, adds 10g poly glycol monomethyl ethers, be continuously heating to reflux state
Insulated and stirred 2h, then adds 1g N hydroxymethyl acrylamides and the double trifluoromethanesulfonimides of 0.1g, and the insulation that flows back again is stirred
30min is mixed, and is naturally cooled in room temperature, gained mixed liquor feeding freeze drier, gained solid is dried through micronizer
Micro mist is made.
The preparation of modified PLURONICS F87：Add water up to being completely dissolved, moored into 5g PLURONICS F87s under stirring
Luo Shamu 188 aqueous solution；And add absolute ethyl alcohol until being completely dissolved into 1g stearic acid under agitation, obtain stearic second
Alcoholic solution；Stearic ethanol solution is added into the aqueous solution of PLURONICS F87, is sufficiently mixed after microwave frequency
Microwave reflow treatment 10min under 2450MHz, power output 700W, stands and continues microwave reflow treatment 5min after 15min, then add
Enter 0.1g allyl glycidyl ethers and 0.05g HPMAs, microwave reflow treatment 5min, institute again after being well mixed
Mixture is volatilized in being ground to solvent at 70-75 DEG C, produce modified PLURONICS F87.
Reference examples 2
(1) 0.5g rilanit specials and 0.05g Tea Polyphenols are added into 5g hydroxyethyl celluloses, is sufficiently mixed, Ran Housheng
Temperature produces modified hydroxyethylcellulosadsorbing to 75-80 DEG C of insulation grinding 15min；
(2) 5g PLURONICS F87s are added into 20g poly-aspartic-acids/poly glycol monomethyl ether and 1g hydroxypropyls two forms sediment
Powder phosphate, is transferred to sealing and standing 2h in 0-5 DEG C of environment after being sufficiently mixed, then is warming up to 80-85 DEG C of insulation grinding 15min, i.e.,
Obtain powder；
(3) 5g polyglutamic acids, modified hydroxyethylcellulosadsorbing and 0.3g Portugals are added while hot into above-mentioned obtained powder
Grape sodium saccharate, continues, in 80-85 DEG C of insulation grinding 15min, finally to naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
The preparation of poly-aspartic-acid/poly glycol monomethyl ether：Added water under stirring into 10g poly-aspartic-acids until complete
Fully dissolved, is warming up to 55-60 DEG C of insulated and stirred 10min, adds 10g poly glycol monomethyl ethers, be continuously heating to reflux state
Insulated and stirred 2h, then adds 1g N hydroxymethyl acrylamides and the double trifluoromethanesulfonimides of 0.1g, and the insulation that flows back again is stirred
30min is mixed, and is naturally cooled in room temperature, gained mixed liquor feeding freeze drier, gained solid is dried through micronizer
Micro mist is made.
Reference examples 3
(1) 0.5g rilanit specials and 0.05g Tea Polyphenols are added into 5g hydroxyethyl celluloses, is sufficiently mixed, Ran Housheng
Temperature produces modified hydroxyethylcellulosadsorbing to 75-80 DEG C of insulation grinding 15min；
(2) 5g is added into 20g poly-aspartic-acids/poly glycol monomethyl ether and is modified PLURONICS F87 and 1g hydroxypropyls
PASELLI EASYGEL, is transferred to sealing and standing 2h in 0-5 DEG C of environment, then be warming up to 80-85 DEG C of insulation grinding after being sufficiently mixed
15min, produces powder；
(3) 5g polyglutamic acids, modified hydroxyethylcellulosadsorbing and 0.3g Portugals are added while hot into above-mentioned obtained powder
Grape sodium saccharate, continues, in 80-85 DEG C of insulation grinding 15min, finally to naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
The preparation of poly-aspartic-acid/poly glycol monomethyl ether：Added water under stirring into 10g poly-aspartic-acids until complete
Fully dissolved, is warming up to 55-60 DEG C of insulated and stirred 10min, adds 10g poly glycol monomethyl ethers, be continuously heating to reflux state
Insulated and stirred 2h, and naturally cool in room temperature, gained mixed liquor feeding freeze drier, gained solid is dried through ultramicro grinding
Micro mist is made in machine.
The preparation of modified PLURONICS F87：Add water up to being completely dissolved, moored into 5g PLURONICS F87s under stirring
Luo Shamu 188 aqueous solution；And add absolute ethyl alcohol until being completely dissolved into 1g stearic acid under agitation, obtain stearic second
Alcoholic solution；Stearic ethanol solution is added into the aqueous solution of PLURONICS F87, is sufficiently mixed after microwave frequency
Microwave reflow treatment 10min under 2450MHz, power output 700W, stands and continues microwave reflow treatment 5min after 15min, then add
Enter 0.1g allyl glycidyl ethers and 0.05g HPMAs, microwave reflow treatment 5min, institute again after being well mixed
Mixture is volatilized in being ground to solvent at 70-75 DEG C, produce modified PLURONICS F87.
Embodiment 3
Permeability is determined：10g embodiments 1, embodiment 2, reference examples 1, the made bleeding agent of reference examples 2 are dissolved in 1L water respectively
In, take 10 pieces of diameter 1cm × 1cm silk fabric to keep flat in solution, and manual time-keeping is opened, when silk fabric is complete by solution
Stopwatch is pressed when soaking entirely, read access time is averaged.
Alkali resistance is determined：10g embodiments 1, embodiment 2, reference examples 1, the made bleeding agent of reference examples 2 are dissolved in 1L water respectively
In, sodium hydroxide is slowly added under stirring, stops being hydrogenated with sodium oxide molybdena if there is turbid phenomenon in water, and record added hydroxide
The quality of sodium.
Foaming characteristic is determined：10g embodiments 1, embodiment 2, reference examples 1, the made bleeding agent of reference examples 2 are dissolved in 1L water respectively
In, take 50mL solution to add in 100mL beakers, 5min is stirred under 600rpm rotating speeds, determine foam height.
The performance of the made bleeding agent of table 3
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (6)
1. a kind of silk fabric refining is with low bubble alkali-resistant penetrant, it is characterised in that be made up of the raw material of following parts by weight：
Poly-aspartic-acid/10-20 parts of poly glycol monomethyl ether, modified 1-5 parts of PLURONICS F87,1-5 parts of polyglutamic acid,
1-5 parts of hydroxyethyl cellulose, 0.5-1 parts of hydroxypropyl PASELLI EASYGEL, 0.5-1 parts of rilanit special, sodium gluconate 0.1-
0.5 part, 0.05-0.2 parts of Tea Polyphenols.
2. silk fabric refining according to claim 1 is with low bubble alkali-resistant penetrant, it is characterised in that：Its preparation method bag
Include following steps：
(1) rilanit special and Tea Polyphenols are added into hydroxyethyl cellulose, is sufficiently mixed, then heats to 75-80 DEG C of insulation
10-15min is ground, modified hydroxyethylcellulosadsorbing is produced；
(2) modified PLURONICS F87 and the starch phosphate of hydroxypropyl two are added into poly-aspartic-acid/poly glycol monomethyl ether
Ester, is transferred to sealing and standing 1-2h in 0-5 DEG C of environment after being sufficiently mixed, then is warming up to 80-85 DEG C of insulation grinding 10-15min, produces
Powder；
(3) polyglutamic acid, modified hydroxyethylcellulosadsorbing and sodium gluconate are added while hot into above-mentioned obtained powder, after
Continue in 80-85 DEG C of insulation grinding 10-15min, finally naturally cool to room temperature, produce low bubble alkali-resistant penetrant.
3. silk fabric refining according to claim 1 or 2 is with low bubble alkali-resistant penetrant, it is characterised in that：The poly- day
The preparation method of L-aminobutanedioic acid/poly glycol monomethyl ether is：Added water under stirring into poly-aspartic-acid until being completely dissolved, liter
Temperature adds poly glycol monomethyl ether, is continuously heating to reflux state insulated and stirred 2h, so to 55-60 DEG C of insulated and stirred 10min
N hydroxymethyl acrylamide and double trifluoromethanesulfonimides are added afterwards, and flow back insulated and stirred 30min again, and naturally cools to
In room temperature, gained mixed liquor feeding freeze drier, dry gained solid and micro mist is made through micronizer.
4. silk fabric refining according to claim 3 is with low bubble alkali-resistant penetrant, it is characterised in that：The poly- lucid asparagus
Propylhomoserin, poly glycol monomethyl ether, the mass ratio of N hydroxymethyl acrylamide and double trifluoromethanesulfonimides are 5-10:5-10:
0.5-2:0.1-1。
5. silk fabric refining according to claim 1 or 2 is with low bubble alkali-resistant penetrant, it is characterised in that：The modification
PLURONICS F87 is made by the modified processing of PLURONICS F87, and its preparation method is：Added water under stirring into PLURONICS F87
Until being completely dissolved, the aqueous solution of PLURONICS F87 is obtained；And add absolute ethyl alcohol until completely molten into stearic acid under agitation
Solution, obtains stearic ethanol solution；Stearic ethanol solution is added into the aqueous solution of PLURONICS F87, is sufficiently mixed
After microwave reflow treatment 10min under microwave frequency 2450MHz, power output 700W, stand and continue after 15min at microwave backflow
5min is managed, allyl glycidyl ether and HPMA is added, microwave reflow treatment 5min again after being well mixed,
Gained mixture is volatilized in being ground to solvent at 70-75 DEG C, produces modified PLURONICS F87.
6. silk fabric refining according to claim 5 is with low bubble alkali-resistant penetrant, it is characterised in that：The poloxamer
188th, the mass ratio of stearic acid, allyl glycidyl ether and HPMA is 1-5:0.5-2:0.1-0.5:0.05-
0.2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710486455.2A CN107313258A (en) | 2017-06-23 | 2017-06-23 | A kind of silk fabric refining is with low bubble alkali-resistant penetrant |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710486455.2A CN107313258A (en) | 2017-06-23 | 2017-06-23 | A kind of silk fabric refining is with low bubble alkali-resistant penetrant |
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| CN107313258A true CN107313258A (en) | 2017-11-03 |
Family
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|---|---|---|---|
| CN201710486455.2A Pending CN107313258A (en) | 2017-06-23 | 2017-06-23 | A kind of silk fabric refining is with low bubble alkali-resistant penetrant |
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| Country | Link |
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| CN (1) | CN107313258A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110006918A (en) * | 2019-04-17 | 2019-07-12 | 湖北三环锻造有限公司 | A kind of penetrant flaw detection agent for penetrant inspection technique |
| CN108642217B (en) * | 2018-04-03 | 2021-02-12 | 嘉兴宏麟皮化有限公司 | Special efficient degreasing agent for natural leather |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108642217B (en) * | 2018-04-03 | 2021-02-12 | 嘉兴宏麟皮化有限公司 | Special efficient degreasing agent for natural leather |
| CN110006918A (en) * | 2019-04-17 | 2019-07-12 | 湖北三环锻造有限公司 | A kind of penetrant flaw detection agent for penetrant inspection technique |
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