CN104804598A - 一种抗菌型水性环保涂料 - Google Patents
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 24
- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920001661 Chitosan Polymers 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 6
- 230000007613 environmental effect Effects 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 14
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 9
- 229920002050 silicone resin Polymers 0.000 claims description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 8
- 239000003973 paint Substances 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- YMHQVDAATAEZLO-UHFFFAOYSA-N cyclohexane-1,1-diamine Chemical compound NC1(N)CCCCC1 YMHQVDAATAEZLO-UHFFFAOYSA-N 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 4
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 4
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 4
- OABYVIYXWMZFFJ-ZUHYDKSRSA-M sodium glycocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCC([O-])=O)C)[C@@]2(C)[C@@H](O)C1 OABYVIYXWMZFFJ-ZUHYDKSRSA-M 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 21
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
本发明公开一种抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂25~35份、纳米TiO210~20份、二羟甲基丙酸1~5份、钛白粉5~15份、有机硅树脂2~8份、聚氧乙烯醚3~7份、乙二醇2~9份、天然抗菌剂1~10份、表面活性剂4~9份、流平剂1~6份、固化剂1~5份、去离子水20~30份。本发明制备的抗菌型水性环保涂料，采用壳聚糖作为抗菌成分，环保无污染，对人体和环境不会产生毒害，抗菌率达99%以上，抗菌效果持久，附着力强，适用于幼儿园、医院等对环境要求相对较高的场所。
Description
技术领域
本发明涉及涂料领域，尤其涉及一种抗菌型水性环保涂料。
背景技术
涂料在建筑、车辆、装饰行业用量大，与人们的生活息息相关，但普通涂料没有杀菌、抗菌功能。因此，在医院、厨房、卫生间及各种公共场所的涂料表面容易滋生细菌，成为病菌的传染源，影响人体健康。如何做好除菌、抑菌是人们面临的挑战。
抗菌涂料是具有抗菌作用的涂料，其含有较强杀菌作用的杀菌剂，会与涂料中各种成分实现有机结合，因此可长期有效杀菌。
然而，现有的抗菌涂料抗菌效果差，时间短，远远不能满足幼儿园、医院等对环境要求相对较高场所的要求。
发明内容
本发明的目的在于克服上述现有技术存在的不足，提供一种环境友好、抗菌性能优异的的水性环保涂料。
为达到上述目的，本发明是通过以下技术方案实现的：
一种抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂25~35份、纳米TiO210~20份、二羟甲基丙酸1~5份、钛白粉5~15份、有机硅树脂2~8份、聚氧乙烯醚3~7份、乙二醇2~9份、天然抗菌剂1~10份、表面活性剂4~9份、流平剂1~6份、固化剂1~5份、去离子水20~30份。
优选的，所述天然抗菌剂为壳聚糖。
优选的，所述表面活性剂为十二烷基苯磺酸钠、甘胆酸钠、单硬脂酸甘油酯中的任意一种。
优选的，所述流平剂为聚丙烯酸、羧甲基纤维素、丁基纤维素中的任意一种。
优选的，所述固化剂为乙烯基三胺、二氨基环己烷、亚甲基双环己烷胺中的任意一种。
本发明的有益效果：
本发明制备的抗菌型水性环保涂料，采用壳聚糖作为抗菌成分，环保无污染，对人体和环境不会产生毒害，抗菌率达99%以上，抗菌效果持久，附着力强，适用于幼儿园、医院等对环境要求相对较高的场所。
具体实施方式
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明，但不以任何形式限制本发明。应当指出的是，对本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进。这些都属于本发明的保护范围。
一种抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂25~35份、纳米TiO210~20份、二羟甲基丙酸1~5份、钛白粉5~15份、有机硅树脂2~8份、聚氧乙烯醚3~7份、乙二醇2~9份、天然抗菌剂1~10份、表面活性剂4~9份、流平剂1~6份、固化剂1~5份、去离子水20~30份。
本发明制备的抗菌型水性环保涂料，具有环境友好、抗菌性能优异等优点。
实施例1
本发明的抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂35份、纳米TiO210份、二羟甲基丙酸1份、钛白粉5份、有机硅树脂8份、聚氧乙烯醚7份、乙二醇9份、壳聚糖1份、十二烷基苯磺酸钠9份、聚丙烯酸1份、乙烯基三胺5份、去离子水30份。
实施例2
本发明的抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂35份、纳米TiO220份、二羟甲基丙酸5份、钛白粉15份、有机硅树脂2份、聚氧乙烯醚3份、乙二醇9份、壳聚糖10份、甘胆酸钠4份、羧甲基纤维素6份、二氨基环己烷1份、去离子水20份。
实施例3
本发明的抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂30份、纳米TiO215份、二羟甲基丙酸3份、钛白粉10份、有机硅树脂5份、聚氧乙烯醚6份、乙二醇6份、壳聚糖5份、单硬脂酸甘油酯7份、丁基纤维素3份、亚甲基双环己烷胺3份、去离子水25份。
实施例4
本发明的抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂27份、纳米TiO212份、二羟甲基丙酸2份、钛白粉6份、有机硅树脂3份、聚氧乙烯醚4份、乙二醇4份、壳聚糖3份、甘胆酸钠5份、羧甲基纤维素2份、二氨基环己烷2份、去离子水23份。
实施例5
本发明的抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂33份、纳米TiO218份、二羟甲基丙酸4份、钛白粉13份、有机硅树脂7份、聚氧乙烯醚6份、乙二醇8份、壳聚糖8份、单硬脂酸甘油酯8份、丁基纤维素5份、亚甲基双环己烷胺4份、去离子水28份。
实施例6
本发明的抗菌型水性环保涂料，按重量份数计包括下列组分：丙烯酸锌树脂25份、纳米TiO220份、二羟甲基丙酸3份、钛白粉9份、有机硅树脂5份、聚氧乙烯醚6份、乙二醇5份、壳聚糖7份、十二烷基苯磺酸钠5份、聚丙烯酸2份、乙烯基三胺3份、去离子水30份。
性能测试
本发明的主要技术性能如表1所示：
表1
从表1可见，本发明制备的抗菌型水性环保涂料抗菌性能优异。
以上对本发明的具体实施例进行了描述。需要理解的是，本发明并不局限于上述特定实施方式，本领域技术人员可以在权利要求的范围内做出各种变形或修改，这并不影响本发明的实质内容。
Claims (5)
1.一种抗菌型水性环保涂料，其特征在于，按重量份数计包括下列组分：丙烯酸锌树脂25~35份、纳米TiO210~20份、二羟甲基丙酸1~5份、钛白粉5~15份、有机硅树脂2~8份、聚氧乙烯醚3~7份、乙二醇2~9份、天然抗菌剂1~10份、表面活性剂4~9份、流平剂1~6份、固化剂1~5份、去离子水20~30份。
2.根据权利要求1所述的水性环保涂料，其特征在于：所述天然抗菌剂为壳聚糖。
3.根据权利要求1所述的水性环保涂料，其特征在于：所述表面活性剂为十二烷基苯磺酸钠、甘胆酸钠、单硬脂酸甘油酯中的任意一种。
4.根据权利要求1所述的水性环保涂料，其特征在于：所述流平剂为聚丙烯酸、羧甲基纤维素、丁基纤维素中的任意一种。
5.根据权利要求1所述的水性环保涂料，其特征在于：所述固化剂为乙烯基三胺、二氨基环己烷、亚甲基双环己烷胺中的任意一种。
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105273544A (zh) * | 2015-11-18 | 2016-01-27 | 广州聚注专利研发有限公司 | 一种水性荧光涂料及其制备方法 |
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| CN105273544A (zh) * | 2015-11-18 | 2016-01-27 | 广州聚注专利研发有限公司 | 一种水性荧光涂料及其制备方法 |
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Application publication date: 20150729 |