CN104804358A - 一种轻量耐老化热塑性鞋底及其制备方法 - Google Patents
一种轻量耐老化热塑性鞋底及其制备方法 Download PDFInfo
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- CN104804358A CN104804358A CN201510200285.8A CN201510200285A CN104804358A CN 104804358 A CN104804358 A CN 104804358A CN 201510200285 A CN201510200285 A CN 201510200285A CN 104804358 A CN104804358 A CN 104804358A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 230000003712 anti-aging effect Effects 0.000 title abstract 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 229920001400 block copolymer Polymers 0.000 claims abstract description 18
- 229920000098 polyolefin Polymers 0.000 claims abstract description 18
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 15
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000002480 mineral oil Substances 0.000 claims abstract description 12
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 12
- 238000001746 injection moulding Methods 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 230000032683 aging Effects 0.000 claims description 45
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- 238000007254 oxidation reaction Methods 0.000 claims description 12
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- 230000003179 granulation Effects 0.000 claims description 3
- 238000002844 melting Methods 0.000 abstract description 3
- 230000008018 melting Effects 0.000 abstract description 3
- 239000002861 polymer material Substances 0.000 abstract description 2
- 229920001169 thermoplastic Polymers 0.000 abstract description 2
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 13
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- 229910052724 xenon Inorganic materials 0.000 description 8
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- 230000008602 contraction Effects 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000003094 microcapsule Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920005601 base polymer Polymers 0.000 description 2
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- JMTMSDXUXJISAY-UHFFFAOYSA-N 2H-benzotriazol-4-ol Chemical compound OC1=CC=CC2=C1N=NN2 JMTMSDXUXJISAY-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
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- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
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- 238000004383 yellowing Methods 0.000 description 1
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- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Description
实施例 | 1 | 2 | 3 | 4 |
密度 (g/cm3) | 0.72 | 0.70 | 0.73 | 0.73 |
硬度 | 56 | 50 | 55 | 58 |
DIN耐磨 (mm3) | 152 | 139 | 116 | 207 |
抗撕强度 (N/mm) | 25 | 27 | 20 | 19 |
拉伸强度(MPa) | 4.1 | 4.3 | 3.2 | 2.8 |
尺寸收缩率(%) | 0.3 | 0.8 | 0.4 | 1.2 |
耐折测试(6万次) | 无裂纹 | 无裂纹 | 无裂纹 | 无裂纹 |
氙灯老化试验 | 无吐霜 | 无吐霜 | 无吐霜 | 无吐霜 |
臭氧老化试验 | 无龟裂 | 无龟裂 | 无龟裂 | 无龟裂 |
动态止滑系数(平滑干式) | 0.78 | 0.75 | 0.63 | 0.68 |
动态止滑系数(平滑湿式) | 0.49 | 0.40 | 0.35 | 0.35 |
Claims (6)
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CN104804358A true CN104804358A (zh) | 2015-07-29 |
CN104804358B CN104804358B (zh) | 2018-03-30 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105566735A (zh) * | 2015-12-30 | 2016-05-11 | 厦门联合信诺新材料有限公司 | 柔软高弹耐磨eva发泡鞋材及其制造方法 |
CN105670198A (zh) * | 2016-01-21 | 2016-06-15 | 苏州市景荣科技有限公司 | 一种耐水型sbs发泡鞋底材料及其制备方法 |
CN106221113A (zh) * | 2016-08-18 | 2016-12-14 | 泉州福达纳米科技发展有限公司 | 橡胶模内发泡材料的加工方法及该方法制得的鞋底材料 |
CN107629387A (zh) * | 2017-04-14 | 2018-01-26 | 莆田市三迪鞋服有限公司 | 一种改进的tpr超轻鞋底材料 |
CN108587033A (zh) * | 2018-05-16 | 2018-09-28 | 黄欣 | 一种耐老化性能好的发泡材料 |
WO2023138055A1 (zh) * | 2022-01-21 | 2023-07-27 | 茂泰(福建)鞋材有限公司 | 一种轻质防龟裂橡胶鞋底及其制备方法 |
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CN1813025A (zh) * | 2003-06-27 | 2006-08-02 | 三井化学株式会社 | 发泡体用树脂组合物及其用途 |
CN101578307A (zh) * | 2005-03-17 | 2009-11-11 | 陶氏环球技术公司 | 乙烯/α-烯烃嵌段共聚体 |
CN101583664A (zh) * | 2006-09-20 | 2009-11-18 | 陶氏环球技术公司 | 用于弹性膜和层合体的乙烯/α-烯烃多嵌段互聚物组合物 |
CN101805475A (zh) * | 2010-04-26 | 2010-08-18 | 泰亚鞋业股份有限公司 | 射出仿pu发泡运动鞋鞋底配方及制造方法 |
CN102239213A (zh) * | 2008-10-03 | 2011-11-09 | 陶氏环球技术有限责任公司 | 具有乙烯/α-烯烃互聚物的聚合物共混物 |
CN103194017A (zh) * | 2013-04-28 | 2013-07-10 | 泰亚鞋业股份有限公司 | 抗皱eva发泡鞋材及其制造方法 |
CN103709581A (zh) * | 2012-09-29 | 2014-04-09 | 安踏(中国)有限公司 | 一种耐磨止滑鞋底用发泡组合物及其制备方法 |
CN104245807A (zh) * | 2012-03-16 | 2014-12-24 | 陶氏环球技术有限责任公司 | 可发泡组合物、泡沫体及其制品 |
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2015
- 2015-04-24 CN CN201510200285.8A patent/CN104804358B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1813025A (zh) * | 2003-06-27 | 2006-08-02 | 三井化学株式会社 | 发泡体用树脂组合物及其用途 |
CN101578307A (zh) * | 2005-03-17 | 2009-11-11 | 陶氏环球技术公司 | 乙烯/α-烯烃嵌段共聚体 |
CN101583664A (zh) * | 2006-09-20 | 2009-11-18 | 陶氏环球技术公司 | 用于弹性膜和层合体的乙烯/α-烯烃多嵌段互聚物组合物 |
CN102239213A (zh) * | 2008-10-03 | 2011-11-09 | 陶氏环球技术有限责任公司 | 具有乙烯/α-烯烃互聚物的聚合物共混物 |
CN101805475A (zh) * | 2010-04-26 | 2010-08-18 | 泰亚鞋业股份有限公司 | 射出仿pu发泡运动鞋鞋底配方及制造方法 |
CN104245807A (zh) * | 2012-03-16 | 2014-12-24 | 陶氏环球技术有限责任公司 | 可发泡组合物、泡沫体及其制品 |
CN103709581A (zh) * | 2012-09-29 | 2014-04-09 | 安踏(中国)有限公司 | 一种耐磨止滑鞋底用发泡组合物及其制备方法 |
CN103194017A (zh) * | 2013-04-28 | 2013-07-10 | 泰亚鞋业股份有限公司 | 抗皱eva发泡鞋材及其制造方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105566735A (zh) * | 2015-12-30 | 2016-05-11 | 厦门联合信诺新材料有限公司 | 柔软高弹耐磨eva发泡鞋材及其制造方法 |
CN105670198A (zh) * | 2016-01-21 | 2016-06-15 | 苏州市景荣科技有限公司 | 一种耐水型sbs发泡鞋底材料及其制备方法 |
CN105670198B (zh) * | 2016-01-21 | 2019-01-11 | 苏州市景荣科技有限公司 | 一种耐水型sbs发泡鞋底材料及其制备方法 |
CN106221113A (zh) * | 2016-08-18 | 2016-12-14 | 泉州福达纳米科技发展有限公司 | 橡胶模内发泡材料的加工方法及该方法制得的鞋底材料 |
CN107629387A (zh) * | 2017-04-14 | 2018-01-26 | 莆田市三迪鞋服有限公司 | 一种改进的tpr超轻鞋底材料 |
CN108587033A (zh) * | 2018-05-16 | 2018-09-28 | 黄欣 | 一种耐老化性能好的发泡材料 |
WO2023138055A1 (zh) * | 2022-01-21 | 2023-07-27 | 茂泰(福建)鞋材有限公司 | 一种轻质防龟裂橡胶鞋底及其制备方法 |
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