CN104789169A - Rubber bonding film, preparation method of rubber bonding film as well as method for using rubber bonding film for bonding soles - Google Patents
Rubber bonding film, preparation method of rubber bonding film as well as method for using rubber bonding film for bonding soles Download PDFInfo
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- CN104789169A CN104789169A CN201510164623.7A CN201510164623A CN104789169A CN 104789169 A CN104789169 A CN 104789169A CN 201510164623 A CN201510164623 A CN 201510164623A CN 104789169 A CN104789169 A CN 104789169A
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- rubber
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- sole
- bound film
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 99
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 41
- 229920005989 resin Polymers 0.000 claims abstract description 41
- 229920006000 epoxidized styrene-butadiene-styrene block copolymer Polymers 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 6
- DYAHQFWOVKZOOW-UHFFFAOYSA-N Sarin Chemical compound CC(C)OP(C)(F)=O DYAHQFWOVKZOOW-UHFFFAOYSA-N 0.000 claims description 14
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 14
- 229920001195 polyisoprene Polymers 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 238000005987 sulfurization reaction Methods 0.000 claims description 7
- 229920002799 BoPET Polymers 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007766 curtain coating Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims description 3
- DLTNJZHTPYXGGE-UHFFFAOYSA-L [Zn+2].CC=CC(=O)[O-].C=C.CC=CC(=O)[O-] Chemical compound [Zn+2].CC=CC(=O)[O-].C=C.CC=CC(=O)[O-] DLTNJZHTPYXGGE-UHFFFAOYSA-L 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000004026 adhesive bonding Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 229920003182 Surlyn® Polymers 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 229920003049 isoprene rubber Polymers 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 238000007788 roughening Methods 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000003292 glue Substances 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000002313 adhesive film Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- 238000001994 activation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Abstract
The invention relates to the technical field of bonding materials, and provides a rubber bonding film, a preparation method of the rubber bonding film as well as a method for using the rubber bonding film for bonding soles. The rubber bonding film comprises raw materials in parts by weight as follows: 30 parts of epoxidized SBS rubber, 20-30 parts of vinisol, 15-25 parts of Surlyn, 12-18 parts of liquid isoprene rubber, 8-12 parts of terpene resin, 3-5 parts of zinc stearate and 0.5-1.5 parts of an antioxidant; the rubber bonding film is free of any chemical solvent, energy-saving, environment-friendly, pollution-free, good in bonding force, good in heat resistance and good in water resistance, traditional bonding manners are changed when the rubber bonding film is used for bonding middle soles and large rubber soles of the soles, treatment such as roughening, back gluing and the like are not required to be performed on the soles, machining procedures are simplified, the sole production efficiency can be improved, and the economic benefit is increased.
Description
Technical field
The present invention relates to matrix material technical field, particularly relating to a kind of adhesive film for the daughter attaching shoes material large end and the middle end and preparation method thereof and the using method for boning during sole thereof.
Background technology
Along with the progress of standard of living, the sole of one-component is as met the demand of client at the bottom of rubber soles, EVA shoe etc., and rubber soles has the distinguishing features such as wear resisting property is good, non-skid property is good, but than great, dress is inconvenient; At the bottom of EVA shoe, there is good springiness, proportion is little, but wear-resisting, non-skid property is poor, and in the prior art, the sole that over-all properties is superior comprises the large end and the middle end, and the large end is generally rubber soles, TPR sole etc., and the middle end is generally at the bottom of EVA shoe, PU sole etc.In the production process of sole, first the large end and the middle end, produced respectively, and then relied in the large end and the middle end PU glue to be bonded as an entirety.There is a lot of shortcoming in such technique: 1, pollutes large.The large end and the middle end, all need to carry out surface treatment, and it is thick that the large end needs surface to beat, and contamination by dust is serious, and need to use treatment agent before the large end and the gluing of the middle end, treatment agent is all organic solvent, contaminate environment, injures greatly to relevant operating personnel; 2, solvent-borne type PU glue, allotment is needed before each use, need to be finished in 5 hours of regulation, validity period is short, and wherein uses the isocyanic ester of large toxicity, life-threatening is healthy, also have the water-based PU glue that a lot of pollution is little in the market, but adhesive power is bad, cannot replace solvent-borne type PU glue; 3, gluing is all manual operation, is difficult to smear evenly, causes fraction defective high, if glue from overflowing, directly can pollute sole, make it unsightly untidy, even affect sole anti-yellowing property.
Summary of the invention
In order to overcome the defect of existing patented technology, the present invention adopts rubber components epoxidized SBS rubber and the polyisoprene rubber of energy covulcanization, large polar resin vinyl chloride-vinyl acetate resin and sarin resin, provide a kind of rubber bound film and preparation method thereof and the using method for boning during sole thereof, described rubber bound film does not use any chemical solvents, energy-conserving and environment-protective are pollution-free, adhesive power is good, good heat resistance, water-tolerant, and described rubber bound film for the middle end of the sole that bonds and rubber sole time, change traditional bonding mode, sole does not need to beat slightly, the process such as upper primer, simplify manufacturing procedure, sole can be improved and prepare production efficiency, increase economic efficiency.
For achieving the above object, the solution that the present invention takes is: a kind of rubber bound film, is made up of obtained: epoxidized SBS rubber, vinyl chloride-vinyl acetate resin, sarin resin, liquid polyisoprene rubber, terpine resin, Zinic stearas, oxidation inhibitor following raw material.
Further, the weight part of each raw material of described rubber bound film is as follows:
Epoxidized SBS rubber 30 parts
Vinyl chloride-vinyl acetate resin 20-30 parts
Sarin resin 15-25 parts
Liquid polyisoprene rubber 12-18 parts
Terpine resin 8-12 parts
Zinic stearas 2-3 parts
0.5-1.5 part, oxidation inhibitor.
Preferred further, each component presses row parts by weight:
Epoxidized SBS rubber 30 parts
Vinyl chloride-vinyl acetate resin 30 parts
Sarin resin 17 parts
Liquid polyisoprene rubber 12 parts
Terpine resin 11 parts
Zinic stearas 2.5 parts
1.2 parts, oxidation inhibitor.
Further: the epoxy group(ing) massfraction of epoxidized SBS rubber is 5%-13%; Vinyl chloride-vinyl acetate resin chlorinity is greater than 20%; Sarin resin is ethene-(methyl) vinylformic acid zinc salt or sodium salt.
A kind of preparation method preparing described rubber bound film, by starting material epoxidized SBS rubber, vinyl chloride-vinyl acetate resin, sarin resin, liquid polyisoprene rubber, terpine resin, Zinic stearas, oxidation inhibitor, after 110 degree of banburyings, granulation, pellet joins curtain coating in casting machine, obtaining take PET film as the energy-conserving and environment-protective rubber bound film of counterdie, adhesive film thickness 0.5-2mm.
Described rubber bound film, for the using method bondd during sole, comprises the steps:
Step 1, the rubber sole mixing, treat sulfuration is put into vulcanization of rubber mould together with described rubber bound film, wherein said rubber bound film is attached to the one side that rubber sole needs the end in stickup, then to tear PET film, rubber sole is taken out, naturally cooling more than 2 hours after 180 degree of sulfidization moldings;
Step 2, the rubber sole after sulfuration is put into secondary oil compression mould, and described rubber sole is provided with one of rubber bound film faces up, again the end in EVA, is attached on rubber sole, close tight mould, 180 degree of mold pressings 300 seconds, cooling is taken out, and namely obtains at the bottom of the product shoes using described rubber bound film to fit.
By taking preceding solution, the present invention has following beneficial effect:
1, rubber bound film of the present invention does not use any chemical solvents, and energy-conserving and environment-protective are pollution-free, has no side effect to relevant operating worker, meets international energy-saving environmental protection safety standard, has both protected the healthy of workman, additionally reduce the pollution to environment.
2, preparation and the operation of rubber bound film of the present invention are simple to operation, during for boning, mix as long as adhesive film is attached to, treat at vulcanized rubber the large end, make its sulfuration together with rubber sole, follow-up directly shaping with the direct oil pressure in the end in EVA, change traditional bonding process, do not increase operation sequence, decrease sole beats slightly simultaneously, brush process water, dry, brush coating, the treatment process such as heat-activated, decrease the energy consumption of heating, drying and activation, substantially increase production efficiency simultaneously, significantly reduce production cost, and glue from overflowing pollution sole can be avoided to cause sole untidy attractive in appearance, the problem affecting sole anti-yellowing property occurs, improve sole quality.
3, use the sole of energy-conserving and environment-protective rubber bound film of the present invention, adhesive power is good, good heat resistance, water-tolerant, and good dimension stability, there are good market outlook.
Embodiment
Now the present invention is further described in conjunction with specific embodiments.
Embodiment 1:
In the present embodiment, a kind of rubber bound film is made up of by weight following component: epoxidized SBS rubber 30 parts, vinyl chloride-vinyl acetate resin 30 parts, sarin resin 17 parts, liquid polyisoprene rubber 12 parts, terpine resin 11 parts, Zinic stearas 2.5 parts, 1.2 parts, oxidation inhibitor.By aforementioned starting material after 110 degree of banburyings, granulation, pellet joins curtain coating in casting machine, and obtaining take PET film as the rubber bound film of counterdie, and thickness is 3mm.
The above-mentioned rubber bound film preparing gained is put into vulcanization of rubber mould together with mixing, treat the rubber sole of sulfuration, rubber bound film is attached to the one side that rubber sole needs the end in stickup, and PET film of then tearing, after 180 degree of sulfidization moldings, take out rubber sole, naturally cooling more than 2 hours; Rubber sole after sulfuration is put into secondary oil compression mould, rubber sole is provided with one of rubber bound film and faces up, again one-step mould is foamed gained EVA in the end be attached on rubber sole, close tight mould, 180 degree of mold pressings 300 seconds, cooling, takes out sole, namely obtains at the bottom of the product shoes using described rubber bound film to fit.
At the bottom of the above-mentioned product shoes prepared, initial adhesion strength is 51 degree of N/cm; After heat aging, without variable color, without coming unglued, bond strength is 52 degree of N/cm; After adding deterioration with moisture, without variable color, without coming unglued, bond strength is 42 degree of N/cm.
Embodiment 2:
In the present embodiment, preparation method and the using method of described rubber bound film are in the same manner as in Example 1, and difference is:
Vinyl chloride-vinyl acetate resin 25 parts, sarin resin 25 parts, liquid polyisoprene rubber 15 parts, terpine resin 12 parts.
At the bottom of the above-mentioned product shoes prepared, initial adhesion strength is 46 degree of N/cm; After heat aging, without variable color, without coming unglued, bond strength is 48 degree of N/cm; After adding deterioration with moisture, without variable color, without coming unglued, bond strength is 39 degree of N/cm.
Embodiment 3:
In the present embodiment, preparation method and the using method of described rubber bound film are in the same manner as in Example 1, and difference is:
Vinyl chloride-vinyl acetate resin 20 parts, sarin resin 15 parts, liquid polyisoprene rubber 18 parts, terpine resin 8 parts, Zinic stearas 2 parts, 0.5 part, oxidation inhibitor.
At the bottom of the above-mentioned product shoes prepared, initial adhesion strength is 41 degree of N/cm; After heat aging, without variable color, without coming unglued, bond strength is 38 degree of N/cm; After adding deterioration with moisture, without variable color, without coming unglued, bond strength is 32 degree of N/cm.
After the data preparation of above-described embodiment 1 ~ 3, obtain as following table 1(note: bond strength tests the bond strength at the large end and the middle end according to GB ∕ T 532-2008, heat aging with add deterioration with moisture and test according to GB ∕ T 3903.7-2005):
Table 1: the performance perameter synopsis of the rubber bound film of a kind of energy-conserving and environment-protective prepared by embodiment 1 ~ 3
In sum, when rubber bound film of the present invention is for the middle end of the sole that bonds and the large end, change traditional bonding mode, sole does not need to play the process such as thick, upper primer, and simplify manufacturing procedure, environmental protection is energy-conservation again, and use the sole of energy-conserving and environment-protective adhesive film of the present invention, adhesive power is good, water-tolerant, and good dimension stability, there are good market outlook.
Above, be only the embodiment utilizing this origination techniques content, the modification that any those skilled in the art use this creation to do, change, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (6)
1. a rubber bound film, is characterized in that, is made up of obtained: epoxidized SBS rubber, vinyl chloride-vinyl acetate resin, sarin resin, liquid polyisoprene rubber, terpine resin, Zinic stearas, oxidation inhibitor following raw material.
2. rubber bound film according to claim 1, is characterized in that, the weight part of each raw material is as follows:
Epoxidized SBS rubber 30 parts
Vinyl chloride-vinyl acetate resin 20-30 parts
Sarin resin 15-25 parts
Liquid polyisoprene rubber 12-18 parts
Terpine resin 8-12 parts
Zinic stearas 2-3 parts
0.5-1.5 part, oxidation inhibitor.
3. rubber bound film according to claim 1 and 2, is characterized in that, is prepared from by following raw materials in part by weight by following component:
Epoxidized SBS rubber 30 parts
Vinyl chloride-vinyl acetate resin 30 parts
Sarin resin 17 parts
Liquid polyisoprene rubber 12 parts
Terpine resin 11 parts
Zinic stearas 2.5 parts
1.2 parts, oxidation inhibitor.
4. rubber bound film according to claim 1 and 2, is characterized in that: the epoxy group(ing) massfraction of epoxidized SBS rubber is 5%-13%; Vinyl chloride-vinyl acetate resin chlorinity is greater than 20%; Sarin resin is ethene-(methyl) vinylformic acid zinc salt or sodium salt.
5. prepare the preparation method of the arbitrary described rubber bound film of claim 1-4 for one kind, it is characterized in that: by starting material epoxidized SBS rubber, vinyl chloride-vinyl acetate resin, sarin resin, liquid polyisoprene rubber, terpine resin, Zinic stearas, oxidation inhibitor, after 110 degree of banburyings, granulation, pellet joins curtain coating in casting machine, and obtaining take PET film as the described rubber bound film of counterdie.
6. the arbitrary described rubber bound film of claim 1-4 is for the using method bondd during sole, it is characterized in that, comprises the steps:
Step 1, the rubber sole mixing, treat sulfuration is put into vulcanization of rubber mould together with described rubber bound film, wherein said rubber bound film is attached to the one side that rubber sole needs the end in stickup, then to tear PET film, rubber sole is taken out, naturally cooling more than 2 hours after 180 degree of sulfidization moldings;
Step 2, the rubber sole after sulfuration is put into secondary oil compression mould, and described rubber sole is provided with one of rubber bound film faces up, again the end in EVA, is attached on rubber sole, close tight mould, 180 degree of mold pressings 300 seconds, cooling is taken out, and namely obtains at the bottom of the product shoes using described rubber bound film to fit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510164623.7A CN104789169B (en) | 2015-04-09 | 2015-04-09 | A kind of rubber bound film and preparation method thereof and for bond sole time using method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510164623.7A CN104789169B (en) | 2015-04-09 | 2015-04-09 | A kind of rubber bound film and preparation method thereof and for bond sole time using method |
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| Publication Number | Publication Date |
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| CN104789169A true CN104789169A (en) | 2015-07-22 |
| CN104789169B CN104789169B (en) | 2017-01-04 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018191904A1 (en) * | 2017-04-20 | 2018-10-25 | 欧利速精密工业股份有限公司 | Shoe component pretreatment solution and pretreatment method using solution |
| CN110733194A (en) * | 2019-10-24 | 2020-01-31 | 东莞市五世昌新材料有限公司 | kinds of net films used for adhering rubber outsole and EVA midsole in compression molding mode |
| CN111004584A (en) * | 2019-10-28 | 2020-04-14 | 茂泰(福建)鞋材有限公司 | Adhesive film, preparation method of adhesive film and shoe sole comprising adhesive film |
| CN111019571A (en) * | 2019-10-28 | 2020-04-17 | 茂泰(福建)鞋材有限公司 | Adhesive film, preparation method of adhesive film and shoe sole comprising adhesive film |
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| CN102020948A (en) * | 2009-09-15 | 2011-04-20 | 上海永冠胶粘制品有限公司 | High-temperature resistance hot melt glue |
| CN103788897A (en) * | 2014-01-16 | 2014-05-14 | 张志东 | Metal strip nail adhesive and preparation method thereof |
| CN104292597A (en) * | 2014-08-28 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | EVA luminous shoe material and preparation method thereof |
| CN104356581A (en) * | 2014-11-13 | 2015-02-18 | 茂泰(福建)鞋材有限公司 | Anti-slip thermoplastic shoe sole and preparation method thereof |
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2015
- 2015-04-09 CN CN201510164623.7A patent/CN104789169B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102020948A (en) * | 2009-09-15 | 2011-04-20 | 上海永冠胶粘制品有限公司 | High-temperature resistance hot melt glue |
| CN103788897A (en) * | 2014-01-16 | 2014-05-14 | 张志东 | Metal strip nail adhesive and preparation method thereof |
| CN104292597A (en) * | 2014-08-28 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | EVA luminous shoe material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018191904A1 (en) * | 2017-04-20 | 2018-10-25 | 欧利速精密工业股份有限公司 | Shoe component pretreatment solution and pretreatment method using solution |
| CN110733194A (en) * | 2019-10-24 | 2020-01-31 | 东莞市五世昌新材料有限公司 | kinds of net films used for adhering rubber outsole and EVA midsole in compression molding mode |
| CN111004584A (en) * | 2019-10-28 | 2020-04-14 | 茂泰(福建)鞋材有限公司 | Adhesive film, preparation method of adhesive film and shoe sole comprising adhesive film |
| CN111019571A (en) * | 2019-10-28 | 2020-04-17 | 茂泰(福建)鞋材有限公司 | Adhesive film, preparation method of adhesive film and shoe sole comprising adhesive film |
| CN111019571B (en) * | 2019-10-28 | 2021-08-03 | 茂泰(福建)鞋材有限公司 | Adhesive film, preparation method of adhesive film and shoe sole comprising adhesive film |
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| CN104789169B (en) | 2017-01-04 |
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Inventor after: Ding Sibo Inventor after: Zheng Rongda Inventor after: Lu Xin Inventor after: Luo Xianfa Inventor after: Liao Yibin Inventor after: Guo Cailian Inventor after: Wang Yuling Inventor after: Zhou Xiaolan Inventor after: Lin Jiang Inventor after: Jin Xiaohong Inventor before: Lu Xin Inventor before: Zheng Rongda Inventor before: Ding Sibo Inventor before: Luo Xianfa Inventor before: Liao Yibin Inventor before: Guo Cailian Inventor before: Zhou Xiaolan Inventor before: Lin Hexiang Inventor before: Lin Jiang Inventor before: Jin Xiaohong |
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Effective date of registration: 20160713 Address after: 362200 Jinjiang City, Quanzhou Province, the first industrial zone of the village of the village of Fujian Applicant after: FUJIAN DENGTAI SCIENCE AND TECHNOLOGY Co.,Ltd. Address before: Chen Dai Zhen Jiang tou Cun 362000 Fujian city of Quanzhou province Jinjiang City Applicant before: Maotai(Fujian) Soles Co.,Ltd. |
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Inventor after: Lu Xin Inventor after: Luo Xianfa Inventor after: Ding Sibo Inventor after: Liao Yibin Inventor after: Guo Cailian Inventor after: Lin Hexiang Inventor after: Lin Chouzhi Inventor after: Jin Xiaohong Inventor after: Zheng Rongda Inventor before: Ding Sibo Inventor before: Zheng Rongda Inventor before: Lu Xin Inventor before: Luo Xianfa Inventor before: Liao Yibin Inventor before: Guo Cailian Inventor before: Wang Yuling Inventor before: Zhou Xiaolan Inventor before: Lin Jiang Inventor before: Jin Xiaohong |
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Effective date of registration: 20161012 Address after: 362200 Jinjiang Province, Quanzhou City, the first village of the town of Applicant after: Maotai(Fujian) Soles Co.,Ltd. Address before: 362200 Jinjiang City, Quanzhou Province, the first industrial zone of the village of the village of Fujian Applicant before: FUJIAN DENGTAI SCIENCE AND TECHNOLOGY Co.,Ltd. |
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Application publication date: 20150722 Assignee: Shengtai (Fujian) shoe material Co.,Ltd. Assignor: Maotai(Fujian) Soles Co.,Ltd. Contract record no.: X2021980009629 Denomination of invention: The invention relates to a rubber adhesive film, a preparation method thereof and a method for bonding a sole Granted publication date: 20170104 License type: Common License Record date: 20210922 |
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Address after: No. 588, Jinxin Road, Jiangtou Village, Chendai Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Maotai (Fujian) New Material Technology Co.,Ltd. Address before: 362200 Chen Dai Jiang tou Cun, Jinjiang City, Quanzhou City, Fujian Province Patentee before: Maotai(Fujian) Soles Co.,Ltd. |