CN104761413B - A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action and preparation method thereof - Google Patents
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action and preparation method thereof Download PDFInfo
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000003337 fertilizer Substances 0.000 title claims abstract description 41
- 229920000615 alginic acid Polymers 0.000 title claims abstract description 32
- 235000010443 alginic acid Nutrition 0.000 title claims abstract description 32
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 31
- 239000000783 alginic acid Substances 0.000 title claims abstract description 29
- 229960001126 alginic acid Drugs 0.000 title claims abstract description 29
- 150000004781 alginic acids Chemical class 0.000 title claims abstract description 29
- 230000002401 inhibitory effect Effects 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000002689 soil Substances 0.000 claims abstract description 49
- 241000512259 Ascophyllum nodosum Species 0.000 claims abstract description 46
- 239000002253 acid Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 26
- 239000003516 soil conditioner Substances 0.000 claims abstract description 23
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 23
- 239000011573 trace mineral Substances 0.000 claims abstract description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 22
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims description 84
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 36
- 239000000243 solution Substances 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 24
- 230000002195 synergetic effect Effects 0.000 claims description 23
- 241000726221 Gemma Species 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- 241000195493 Cryptophyta Species 0.000 claims description 20
- 238000000855 fermentation Methods 0.000 claims description 20
- 230000004151 fermentation Effects 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 239000000706 filtrate Substances 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 11
- 239000004327 boric acid Substances 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 11
- 235000001055 magnesium Nutrition 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 10
- 235000016804 zinc Nutrition 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 8
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 8
- IXVMHGVQKLDRKH-YEJCTVDLSA-N (22s,23s)-epibrassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@H](O)[C@@H](O)[C@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-YEJCTVDLSA-N 0.000 claims description 7
- 241001474374 Blennius Species 0.000 claims description 7
- IXVMHGVQKLDRKH-VRESXRICSA-N Brassinolide Natural products O=C1OC[C@@H]2[C@@H]3[C@@](C)([C@H]([C@@H]([C@@H](O)[C@H](O)[C@H](C(C)C)C)C)CC3)CC[C@@H]2[C@]2(C)[C@@H]1C[C@H](O)[C@H](O)C2 IXVMHGVQKLDRKH-VRESXRICSA-N 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- 240000001548 Camellia japonica Species 0.000 claims description 7
- 229920001661 Chitosan Polymers 0.000 claims description 7
- 229930191978 Gibberellin Natural products 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 7
- 235000018597 common camellia Nutrition 0.000 claims description 7
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims description 7
- 239000003448 gibberellin Substances 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- 150000002596 lactones Chemical class 0.000 claims description 7
- 235000013557 nattō Nutrition 0.000 claims description 7
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 241001037822 Bacillus bacterium Species 0.000 claims description 6
- 241000894006 Bacteria Species 0.000 claims description 6
- 241001124569 Lycaenidae Species 0.000 claims description 6
- 241000191998 Pediococcus acidilactici Species 0.000 claims description 6
- 229930006000 Sucrose Natural products 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
- 235000014987 copper Nutrition 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 6
- 235000000396 iron Nutrition 0.000 claims description 6
- 235000015110 jellies Nutrition 0.000 claims description 6
- 239000008274 jelly Substances 0.000 claims description 6
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 6
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 6
- 235000002908 manganese Nutrition 0.000 claims description 6
- 229920001542 oligosaccharide Polymers 0.000 claims description 6
- 239000005720 sucrose Substances 0.000 claims description 6
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 229960001471 sodium selenite Drugs 0.000 claims description 5
- 239000011781 sodium selenite Substances 0.000 claims description 5
- 235000015921 sodium selenite Nutrition 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 241000040710 Chela Species 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims 1
- 235000015097 nutrients Nutrition 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 230000035784 germination Effects 0.000 abstract description 2
- 239000005445 natural material Substances 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 description 11
- 235000010469 Glycine max Nutrition 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 6
- 210000003608 fece Anatomy 0.000 description 6
- 239000010871 livestock manure Substances 0.000 description 6
- 241000193830 Bacillus <bacterium> Species 0.000 description 5
- 150000001413 amino acids Chemical class 0.000 description 5
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 4
- 240000008384 Capsicum annuum var. annuum Species 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229940072056 alginate Drugs 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 229940091258 selenium supplement Drugs 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WJGAPUXHSQQWQF-UHFFFAOYSA-N acetic acid;hydrochloride Chemical compound Cl.CC(O)=O WJGAPUXHSQQWQF-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 229930002875 chlorophyll Natural products 0.000 description 2
- 235000019804 chlorophyll Nutrition 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000618 nitrogen fertilizer Substances 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 239000012747 synergistic agent Substances 0.000 description 2
- 229930192334 Auxin Natural products 0.000 description 1
- 240000008100 Brassica rapa Species 0.000 description 1
- 235000011292 Brassica rapa Nutrition 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Abstract
The invention discloses a kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components form as follows according to parts by weight：60 80 parts of kelp, 25 parts of strain, 5 10 parts of carbon source, 35 parts of nitrogen source, 30 50 parts of water, micro- 1.2 1.5 parts middle, 0.4 0.6 parts of agent of loosening the soil, 24 parts of acid soil conditioner, 0.8 1.2 parts of plant growth regulator.Each component is pure natural substance in alginic acid fertilizer synergist produced by the present invention, the feature of environmental protection is excellent, can very degrade, and can promote absorption of the plant to nutrient in soil, realize ammonia volatilization inhibiting rate and be up to 35 45%, loosen the soil agent energy chesson, and acid soil conditioner can improve improvement soil microenvironment, promotes crop yield, plant growth regulator accelerates speed of germination, the resistance of crops can be improved, trace element improves the utilization rate of nutrient in Chelating state, improves crop quality.
Description
Technical field
The invention belongs to fertilizer synergist technical field, and in particular to a kind of alginate fertilizer with ammonia volatilization inhibitory action
Expect synergist and preparation method thereof.
Background technology
Traditional chemical fertilizer fertilizer efficiency is single, seriously polluted, and chronic administration chemical fertilizer has made the reason of farmland ecological environment, soil
Change character and soil profitable strain receives different degrees of destruction, it is very big to the qualitative effects of crops.It is especially excessive
Using chemical fertilizer of simple substance such as nitrogen manure, aggravate soil hardening, soil fertility declines, and makes the quality of crop products and nutrition difficult
To meet the needs of people, the requirement of pollution-free food is not reached more, and cause serious environmental pollution.
Acid salinized soil is easy to cause soil hardening, fertility declines, and is unfavorable for crop and absorbs nutrient, hinders crops life
It is long.It is higher and higher to the demand of soda acid soil conditioner since the soil salinization is increasingly severe, how to reduce salinity in soil,
Acidity, adjusts soil salt level, is that the current industry compels problem to be solved.How a kind of compound acid soil is researched and developed
The synergist of conditioner, changes the physicochemical environment of soil, improves the biochemical activity of soil, improve synergist utilization rate and
Using effect, has important practical significance.
The utilization rate of nitrogen manure is greatly improved by various synergist in the prior art, improves grain yield and reduction pair
The pollution of environment.However, the existing preparation for improving utilization rate of nitrogen fertilizer and technical measures also Shortcomings, nitrogen manure are dissolved in soil
After being absorbed in earth by root system of plant, the absorption rate and absorption efficiency of crop root need to be improved, the nitrogen manure in soil
The phenomenon being lost in by factors such as leaching loss, nitrification and hydrolysis does not obtain essence containment also, and existing preparation improves utilization rate of nitrogen fertilizer
Effect need to be improved.Regulating and controlling the conversion process of ammonia in soil using the alginic acid fertilizer synergist of ammonia volatilization inhibitory action is
The measure of relative efficiency.The compound with suppression ammonia loss by volatilization having now been found that is more, but possesses efficient, less toxic, matter
The honest and clean person of favorable rates is very few.
Crops often occur in planting process at present, and seed vitality reduces, speed of emergence slows down, Phase ofsprouting is poor,
And easily there is rotten kind of phenomenon, therefore, seed vitality is improved, promote seed quick-speed germination and seedling fast-growth, solve crop
Emerge slow, rotten kind the problem of, the key of synergist production-increasing function in production is given full play to, for popularization synergistic agent tool
There is important meaning.
China's seashore line length, possesses abundant ocean resources superiority, particularly kelp resource very abundant, is fully beneficial to sea
Foreign resource has great importance for developing pollution-less agriculture production.Alginic acid synergist is harmless to people, animal, to environment without dirt
Dye, is natural, efficient, new organic synergistic agent.Alginate fertilizer has been used widely as a kind of agricultural fertilizer, example
Such as, 201110221042.4 micro-ecological alginic acid organic fertilizer synergist of the patent No., the extraction of relevant alginic acid
Also there is patent document, such as extracted involved in a kind of method for extracting alginic acid of Patent No. 201310621689.5 to seaweed,
But kelp is used as raw material, therefore how the method that Algae synergistic liquid is made by solid fermentation method, is researched and developed still without disclosure
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action and preparation method thereof, fully improves and using soil capabilities,
Reaching makes crop yield increase income optimum efficiency, has important practical significance.
The content of the invention
For problems of the prior art, it is an object of the invention to provide a kind of with ammonia volatilization inhibitory action
Alginic acid fertilizer synergist and preparation method thereof.
The technical solution that the present invention takes is：
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components are according to weight
It is as follows to measure part composition：
60-80 parts of kelp, 2-5 parts of strain, 5-10 parts of carbon source, 3-5 parts of nitrogen source, 30-50 parts of water, middle trace element 1.2-
1.5 parts, 0.4-0.6 parts of agent of loosening the soil, 2-4 parts of acid soil conditioner, 0.8-1.2 parts of plant growth regulator.
Further, the strain is to be no less than 2.0 × 10 containing effective gemma number11The Pediococcus acidilactici bacterium powder of cfu and contain
Effective gemma number is no less than 1.0 × 1011The mix bacterium agent of the jelly bacillus bacterium powder composition of cfu.
Further, the carbon source is glucose, the sucrose of 20-40% and the starch group of 60-80% that content is 10-20%
Into mixture.
Further, the nitrogen source is the urea that content is 20-40% and the mixture that 60-80% ammonium sulfate forms.
Further, it is described it is middle trace element for be 0.1-0.3% by percentage composition EDTA chelated coppers, 0.4-0.6%
EDTA chelated irons, the EDTA Chelated Manganeses of 0.1-0.3%, the EDTA chelated zincs of 0.3-0.5%, 0.1-0.3% EDTA chelated magnesiums,
The Chelating state element of the EDTA chelating calcium compositions of 0.5-0.7%.
Further, the agent of loosening the soil is carboxymethyl chitosan, precipitated calcium carbonate and diatomite according to weight ratio 1：3：3 groups
Into mixture.
Further, the preparation method of the acid soil conditioner is according to weight ratio 2：5 take camellia leaf and Camellia Leaves to mix
Close, add the water of 3 times of volumes, controlled at 20-24 DEG C, addition is no less than 1.0 × 10 containing effective gemma number11The natto of cfu
Bacillus, ferments 8-10 days, in the filtrate for filtering gained, adds the neopelex and 0. 2- of 0.05-0.07%
0.4% citric acid, is mixed evenly.
Further, the plant growth regulator is by 2-4 parts of brassinosteroid, 4-6 parts of brassin lactones, gibberellin
3-5 parts, 3-5 parts of 6-benzyl aminopurine, 4-6 parts of heteroauxin, the mixtures of 10-12 parts of amino-oligosaccharide composition.
A kind of preparation method of the alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that specific bag
Include following steps：
（1）Kelp is cleaned：Kelp is taken according to weight proportion, is cleaned 1-2 times with clear water；
（2）Kelp clothes：By the kelp clothes that have cleaned 10-15 days, it is less than 10% to moisture；
（3）Crush：The kelp dried is put into pulverizer and is crushed to 50-60 mesh；
（4）Fermentation：Kelp, strain, carbon source, nitrogen source, water and middle trace element mixing are taken according to formulation ratio, is stirred evenly
Stack fermentation 7-15 days；
（5）Weak base extracts：Into material after fermentation, the water of 2.6-3.6 times of volume is added, stirs evenly, uses carbon
Sour sodium and sodium hydroxide are according to weight ratio 2：（3-5）The alkaline extractant of composition adjusts pH between 8-9.5, and solution passes through steam
Controlled at 60 DEG C of -80 DEG C of stirring extraction 8-11h；
（6）Algae synergistic liquid processed：Solution carries out press filtration by filter press, and 2-5 parts of boric acid is added into obtained filtrate,
The pH that solution is adjusted with the hydrochloric acid solution containing 3-5% acetic acid is 7.5-8.5, and evaporation and concentration obtains solid content >=8%, and alginic acid contains
Amount >=2.5, the Algae synergistic liquid of ammonia volatilization inhibiting rate 25-45%；
（7）Fertilizer synergist processed：Agent of loosening the soil, acid soil conditioner, plant growth regulator are taken according to weight proportion successively
Add step（6）In obtained Algae synergistic liquid, stir evenly, encapsulate.
Further, the step（6）In boric acid in added with 0.6-0.8% concentration be 100mg/kg seven water sulfuric acid
Magnesium aqueous solution and the sodium selenite aqueous solution that 2-3% concentration is 120mg/kg, boric acid can be replaced Chelating state copper, chelated ferrous iron, chela
Close the one or more in trace element in the Chelating states such as state manganese, Chelating state zinc, Chelating state calcium, Chelating state magnesium.
Beneficial effects of the present invention are：
The present invention uses kelp to coordinate the components such as nitrogen source, carbon source, strain for the main material that ferments, sent out by solid fermentation method
Algae synergistic liquid solid content >=8% made from ferment method, seaweed acid content >=2.5, glucose, sugarcane sugar and starch in carbon source etc.
The components such as urea and ammonium sulfate in component and nitrogen source are containing the basic element of cell division, auxin, cell excitement by microbe conversion
The vegetable source naturals such as element, mannitol, algal polysaccharides, amino acid adjust synergistic component, are applied in synergist, each component is pure
Natural materials, the feature of environmental protection is excellent, can very degrade, and can promote absorption of the plant to nutrient in soil, realizes ammonia volatilization suppression
Rate processed is up to 35-45%, increases chlorophyll content in leaf blades, improves light and the effect of crop, greatly improves the utilization rate of synergist.
Mixture of the agent for carboxymethyl chitosan, precipitated calcium carbonate and diatomite composition that loosen the soil of the present invention, the height included
Active material is under the action of water, and the material of micropore, gradually gets through soil micropore, loose soil between breakdown obstruction soil granular
Earth, reverts to porous crumb structure, so as to promote aerobic beneficial microorganism growth and activity, the increase soil organism contains
Amount.
The acid soil conditioner of the present invention, uses camellia leaf and Camellia Leaves as fermentation raw material, adds bafillus natto hair
Rich in acid modifying ingredients in filtrate obtained by ferment, effective component extracting it is efficient, be a kind of environmental and ecological conditioner, rich in plant
Thing albumen, amino acid, trace element, while soil acidity or alkalinity is adjusted, can improve improvement soil microenvironment, be a kind of
The environmental and ecological compound acid soil conditioner of auxotype, can promote crop yield.
Gibberellin, 6-benzyl aminopurine and heteroauxin in the plant growth regulator of the present invention can improve seed work
Power, promotes cell elongation and division to accelerate speed of emergence, hestening rooting；Brassinosteroid, brassin lactones and amino-oligosacchride
The synergistic effect of element, has special bioactivity, has the function of diseases prevention, disease-resistant, regulating plant growth, development, to a variety of
Nematode has good preventive effect, improves the resistance of crops.
Trace element during the present invention adds in composition of raw materials, and add boric acid isochela in the filtrate after weak base extraction
Trace element in state is closed, using secondary chelating technology, amino acid and alginic acid are chelated, reduce high-purity amino acid
Cost, avoids middle and trace element and produces precipitation with alginate reaction, improve the utilization rate of nutrient；At the same time can also be with soil
The heavy metal of earth is chelated, and reduces harm of the heavy metal to the mankind, improves crop quality.
In the preparation method of the present invention, added with seven that 0.6-0.8% concentration is 100mg/kg in the boric acid of final step
Water magnesium sulfate aqueous solution and the sodium selenite aqueous solution that 2-3% concentration is 120mg/kg, obtained final products can supplement plant institute
The micro magnesium elements and selenium element needed, may advantageously facilitate increasing crop yield, supplement the nutrient of needed by human body indirectly.
Embodiment
With reference to embodiment, the invention will be further elaborated.
Embodiment 1
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components are according to weight
It is as follows to measure part composition：
60 parts of kelp, 2 parts of strain, 5 parts of carbon source, 3 parts of nitrogen source, 30 parts of water, micro- 1.2 parts middle, 0.4 part of agent of loosening the soil,
2 parts of acid soil conditioner, 0.8 part of plant growth regulator.
Further, the strain is to be no less than 2.0 × 10 containing effective gemma number11The Pediococcus acidilactici bacterium powder of cfu and contain
Effective gemma number is no less than 1.0 × 1011The mix bacterium agent of the jelly bacillus bacterium powder composition of cfu.
Further, the carbon source is the mixing of glucose, 20% sucrose and 70% starch composition that content is 10%
Thing.
Further, the nitrogen source is the urea that content is 20% and the mixture that 80% ammonium sulfate forms.
Further, it is described it is middle trace element for be 0.1-0.3% by percentage composition EDTA chelated coppers, 0.4-0.6%
EDTA chelated irons, the EDTA Chelated Manganeses of 0.1-0.3%, the EDTA chelated zincs of 0.3-0.5%, 0.1-0.3% EDTA chelated magnesiums,
The Chelating state element of the EDTA chelating calcium compositions of 0.5-0.7%.
Further, the agent of loosening the soil is carboxymethyl chitosan, precipitated calcium carbonate and diatomite according to weight ratio 1：3：3 groups
Into mixture.
Further, the preparation method of the acid soil conditioner is according to weight ratio 2：5 take camellia leaf and Camellia Leaves to mix
Close, add the water of 3 times of volumes, controlled at 20 DEG C, addition is no less than 1.0 × 10 containing effective gemma number11The natto gemma of cfu
Bacillus, ferments 10 days, in the filtrate for filtering gained, adds 0.05% neopelex and 0. 2% citric acid, mixes
Conjunction stirs evenly.
Further, the plant growth regulator be by 2 parts of brassinosteroid, 4 parts of brassin lactones, 3 parts of gibberellin,
3 parts of 6-benzyl aminopurine, 4 parts of heteroauxin, the mixture of 10 parts of compositions of amino-oligosaccharide.
A kind of preparation method of the alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that specific bag
Include following steps：
（1）Kelp is cleaned：Kelp is taken according to weight proportion, is cleaned 2 times with clear water；
（2）Kelp clothes：By the kelp clothes that have cleaned 10-15 days, it is less than 10% to moisture；
（3）Crush：The kelp dried is put into pulverizer and is crushed to 50-60 mesh；
（4）Fermentation：Kelp, strain, carbon source, nitrogen source, water and middle trace element mixing are taken according to formulation ratio, is stirred evenly
Stack fermentation 15 days；
（5）Weak base extracts：Into material after fermentation, the water of 2.6 times of volumes is added, stirs evenly, uses sodium carbonate
With sodium hydroxide according to weight ratio 2：The alkaline extractant of 3 compositions adjusts pH between 8-9.5, and solution passes through automatic steam control temperature
For 60 DEG C of stirring extraction 11h；
（6）Algae synergistic liquid processed：Solution carries out press filtration by filter press, and 2 parts of boric acid, boron are added into obtained filtrate
The sub- selenium that the epsom salt aqueous solution and 2-3% concentration for being 100mg/kg added with 0.6-0.8% concentration in acid are 120mg/kg
Acid sodium aqueous solution, with containing 3% acetic acid hydrochloric acid solution adjust solution pH be 7.5-8.5, evaporation and concentration obtain solid content >=
8%, seaweed acid content >=2.5, the Algae synergistic liquid of ammonia volatilization inhibiting rate 25-45%；
（7）Fertilizer synergist processed：Agent of loosening the soil, acid soil conditioner, plant growth regulator are taken according to weight proportion successively
Add step（6）In obtained Algae synergistic liquid, stir evenly, encapsulate.
Further, the step（6）In boric acid can be replaced Chelating state copper, chelated ferrous iron, Chelating state manganese, Chelating state
One or more in the Chelating states such as zinc, Chelating state calcium, Chelating state magnesium in trace element.
Embodiment 2
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components are according to weight
It is as follows to measure part composition：
70 parts of kelp, 3 parts of strain, 8 parts of carbon source, 4 parts of nitrogen source, 40 parts of water, micro- 1.3 parts middle, 0.5 part of agent of loosening the soil,
3 parts of acid soil conditioner, 1 part of plant growth regulator.
Further, the strain is to be no less than 2.0 × 10 containing effective gemma number11The Pediococcus acidilactici bacterium powder of cfu and contain
Effective gemma number is no less than 1.0 × 1011The mix bacterium agent of the jelly bacillus bacterium powder composition of cfu.
Further, the carbon source is the mixing of glucose, 25% sucrose and 60% starch composition that content is 15%
Thing.
Further, the nitrogen source is the urea that content is 25% and the mixture that 75% ammonium sulfate forms.
Further, it is described it is middle trace element for be 0.1-0.3% by percentage composition EDTA chelated coppers, 0.4-0.6%
EDTA chelated irons, the EDTA Chelated Manganeses of 0.1-0.3%, the EDTA chelated zincs of 0.3-0.5%, 0.1-0.3% EDTA chelated magnesiums,
The Chelating state element of the EDTA chelating calcium compositions of 0.5-0.7%.
Further, the agent of loosening the soil is carboxymethyl chitosan, precipitated calcium carbonate and diatomite according to weight ratio 1：3：3 groups
Into mixture.
Further, the preparation method of the acid soil conditioner is according to weight ratio 2：5 take camellia leaf and Camellia Leaves to mix
Close, add the water of 3 times of volumes, controlled at 22 DEG C, addition is no less than 1.0 × 10 containing effective gemma number11The natto gemma of cfu
Bacillus, ferments 9 days, in the filtrate for filtering gained, adds 0.06% neopelex and 0. 3% citric acid, mixing
Stir evenly.
Further, the plant growth regulator be by 3 parts of brassinosteroid, 5 parts of brassin lactones, 4 parts of gibberellin,
4 parts of 6-benzyl aminopurine, 5 parts of heteroauxin, the mixture of 11 parts of compositions of amino-oligosaccharide.
A kind of preparation method of the alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that specific bag
Include following steps：
（1）Kelp is cleaned：Kelp is taken according to weight proportion, is cleaned 2 times with clear water；
（2）Kelp clothes：By the kelp clothes that have cleaned 10-15 days, it is less than 10% to moisture；
（3）Crush：The kelp dried is put into pulverizer and is crushed to 50-60 mesh；
（4）Fermentation：Kelp, strain, carbon source, nitrogen source, water and middle trace element mixing are taken according to formulation ratio, is stirred evenly
Stack fermentation 14 days；
（5）Weak base extracts：Into material after fermentation, add the water of 3 times of volumes, stir evenly, with sodium carbonate and
Sodium hydroxide is according to weight ratio 2：The alkaline extractant of 4 compositions adjusts pH between 8-9.5, and solution is by automatic steam control temperature
70 DEG C of stirring extraction 10h；
（6）Algae synergistic liquid processed：Solution carries out press filtration by filter press, and 3 parts of boric acid, boron are added into obtained filtrate
The sub- selenium that the epsom salt aqueous solution and 2-3% concentration for being 100mg/kg added with 0.6-0.8% concentration in acid are 120mg/kg
Acid sodium aqueous solution, with containing 4% acetic acid hydrochloric acid solution adjust solution pH be 7.5-8.5, evaporation and concentration obtain solid content >=
8%, seaweed acid content >=2.5, the Algae synergistic liquid of ammonia volatilization inhibiting rate 25-45%；
（7）Fertilizer synergist processed：Agent of loosening the soil, acid soil conditioner, plant growth regulator are taken according to weight proportion successively
Add step（6）In obtained Algae synergistic liquid, stir evenly, encapsulate.
Embodiment 3
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components are according to weight
It is as follows to measure part composition：
75 parts of kelp, 4 parts of strain, 9 parts of carbon source, 4 parts of nitrogen source, 45 parts of water, micro- 1.4 parts middle, 0.5 part of agent of loosening the soil,
3.5 parts of acid soil conditioner, 1.1 parts of plant growth regulator.
Further, the strain is to be no less than 2.0 × 10 containing effective gemma number11The Pediococcus acidilactici bacterium powder of cfu and contain
Effective gemma number is no less than 1.0 × 1011The mix bacterium agent of the jelly bacillus bacterium powder composition of cfu.
Further, the carbon source is the mixing of glucose, 24% sucrose and 60% starch composition that content is 16%
Thing.
Further, the nitrogen source is the urea that content is 30% and the mixture that 70% ammonium sulfate forms.
Further, it is described it is middle trace element for be 0.1-0.3% by percentage composition EDTA chelated coppers, 0.4-0.6%
EDTA chelated irons, the EDTA Chelated Manganeses of 0.1-0.3%, the EDTA chelated zincs of 0.3-0.5%, 0.1-0.3% EDTA chelated magnesiums,
The Chelating state element of the EDTA chelating calcium compositions of 0.5-0.7%.
Further, the agent of loosening the soil is carboxymethyl chitosan, precipitated calcium carbonate and diatomite according to weight ratio 1：3：3 groups
Into mixture.
Further, the preparation method of the acid soil conditioner is according to weight ratio 2：5 take camellia leaf and Camellia Leaves to mix
Close, add the water of 3 times of volumes, controlled at 24 DEG C, addition is no less than 1.0 × 10 containing effective gemma number11The natto gemma of cfu
Bacillus, ferments 8 days, in the filtrate for filtering gained, adds 0.07% neopelex and 0.4% citric acid, mixes
Stir evenly.
Further, the plant growth regulator be by 4 parts of brassinosteroid, 6 parts of brassin lactones, 5 parts of gibberellin,
5 parts of 6-benzyl aminopurine, 6 parts of heteroauxin, the mixture of 12 parts of compositions of amino-oligosaccharide.
A kind of preparation method of the alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that specific bag
Include following steps：
（1）Kelp is cleaned：Kelp is taken according to weight proportion, is cleaned 2 times with clear water；
（2）Kelp clothes：By the kelp clothes that have cleaned 10-15 days, it is less than 10% to moisture；
（3）Crush：The kelp dried is put into pulverizer and is crushed to 50-60 mesh；
（4）Fermentation：Kelp, strain, carbon source, nitrogen source, water and middle trace element mixing are taken according to formulation ratio, is stirred evenly
Stack fermentation 15 days；
（5）Weak base extracts：Into material after fermentation, the water of 3.6 times of volumes is added, stirs evenly, uses sodium carbonate
With sodium hydroxide according to weight ratio 2：The alkaline extractant of 5 compositions adjusts pH between 8-9.5, and solution passes through automatic steam control temperature
For 80 DEG C of stirring extraction 8h；
（6）Algae synergistic liquid processed：Solution carries out press filtration by filter press, and 5 parts are added into obtained filtrate by Chelating state
Iron, Chelating state manganese, Chelating state zinc are according to weight ratio 3：2：The mixture of 2 compositions, mixture are added with 0.6-0.8% concentration
The epsom salt aqueous solution and 2-3% concentration of 100mg/kg is the sodium selenite aqueous solution of 120mg/kg, with containing 5% acetic acid
The pH that hydrochloric acid solution adjusts solution is 7.5-8.5, and evaporation and concentration obtains solid content >=8%, seaweed acid content >=2.5, ammonia volatilization suppression
The Algae synergistic liquid of rate 25-45% processed；
（7）Fertilizer synergist processed：Agent of loosening the soil, acid soil conditioner, plant growth regulator are taken according to weight proportion successively
Add step（6）In obtained Algae synergistic liquid, stir evenly, encapsulate.
Embodiment 4
A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components are according to weight
It is as follows to measure part composition：
80 parts of kelp, 5 parts of strain, 10 parts of carbon source, 5 parts of nitrogen source, 50 parts of water, micro- 1.5 parts middle, 0.6 part of agent of loosening the soil,
4 parts of acid soil conditioner, 1.2 parts of plant growth regulator.
Further, the strain is to be no less than 2.0 × 10 containing effective gemma number11The Pediococcus acidilactici bacterium powder of cfu and contain
Effective gemma number is no less than 1.0 × 1011The mix bacterium agent of the jelly bacillus bacterium powder composition of cfu.
Further, the carbon source is the mixing of glucose, 20% sucrose and 60% starch composition that content is 20%
Thing.
Further, the nitrogen source is the urea that content is 40% and the mixture that 60% ammonium sulfate forms.
Further, it is described it is middle trace element for be 0.1-0.3% by percentage composition EDTA chelated coppers, 0.4-0.6%
EDTA chelated irons, the EDTA Chelated Manganeses of 0.1-0.3%, the EDTA chelated zincs of 0.3-0.5%, 0.1-0.3% EDTA chelated magnesiums,
The Chelating state element of the EDTA chelating calcium compositions of 0.5-0.7%.
Further, the agent of loosening the soil is carboxymethyl chitosan, precipitated calcium carbonate and diatomite according to weight ratio 1：3：3 groups
Into mixture.
Further, the preparation method of the acid soil conditioner is according to weight ratio 2：5 take camellia leaf and Camellia Leaves to mix
Close, add the water of 3 times of volumes, controlled at 24 DEG C, addition is no less than 1.0 × 10 containing effective gemma number11The natto gemma of cfu
Bacillus, ferments 9 days, in the filtrate for filtering gained, adds 0.07% neopelex and 0.4% citric acid, mixes
Stir evenly.
Further, the plant growth regulator be by 4 parts of brassinosteroid, 6 parts of brassin lactones, 5 parts of gibberellin,
5 parts of 6-benzyl aminopurine, 6 parts of heteroauxin, the mixture of 12 parts of compositions of amino-oligosaccharide.
A kind of preparation method of the alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that specific bag
Include following steps：
（1）Kelp is cleaned：Kelp is taken according to weight proportion, is cleaned 2 times with clear water；
（2）Kelp clothes：By the kelp clothes that have cleaned 10-15 days, it is less than 10% to moisture；
（3）Crush：The kelp dried is put into pulverizer and is crushed to 50-60 mesh；
（4）Fermentation：Kelp, strain, carbon source, nitrogen source, water and middle trace element mixing are taken according to formulation ratio, is stirred evenly
Stack fermentation 15 days；
（5）Weak base extracts：Into material after fermentation, add the water of 3 times of volumes, stir evenly, with sodium carbonate and
Sodium hydroxide is according to weight ratio 2：The alkaline extractant of 4 compositions adjusts pH between 8-9.5, and solution is by automatic steam control temperature
60 DEG C of stirring extraction 11h；
（6）Algae synergistic liquid processed：Solution by filter press carry out press filtration, into obtained filtrate add 4 parts by chelating
State copper, chelated ferrous iron, Chelating state calcium are according to weight ratio 2：3：It is micro- in the Chelating state of 1 composition, trace element in Chelating state
The sodium selenite that the epsom salt aqueous solution and 2-3% concentration for being 100mg/kg added with 0.6-0.8% concentration are 120mg/kg
Aqueous solution, the pH that solution is adjusted with the hydrochloric acid solution containing 5% acetic acid is 7.5-8.5, and evaporation and concentration obtains solid content >=8%, sea
Alginic acid content >=2.5, the Algae synergistic liquid of ammonia volatilization inhibiting rate 25-45%；
（7）Fertilizer synergist processed：Agent of loosening the soil, acid soil conditioner, plant growth regulator are taken according to weight proportion successively
Add step（6）In obtained Algae synergistic liquid, stir evenly, encapsulate.
Specific experiment process：
1st, the fertilizer of synergist and common fertilizer made from above-described embodiment will be added and is separately to the big of soybean growth
In the experiment of field, statistical result such as table 1：
Influence of 1 synergist of table to soybean emergence situation and soybean yields
Table 1 the result shows that, on sandy loam, 1 synergist of the present invention+embodiment plantation soybean seedling-growing time respectively than list
The time of pure synergist processing shortens 3.3d, and emergence rate improves 3 percentage points, and the dry matter weight of soybean seedling phase increases by 23 %,
Maturity period Pod Yield improves 6.6%；On loam, the soya seeds seedling-growing time point of 2 synergist of the present invention+embodiment processing
5.0d is not shortened than the processing of simple synergist, emergence rate improves 2 percentage points, and the dry matter weight of soybean seedling phase increases respectively
27.9%, maturity period Pod Yield improves 17.8%；On clay loam, the soya seeds of 3 synergist of the present invention+embodiment processing go out
The seedling time shortens 2.4d than the processing of simple synergist respectively, and emergence rate improves 2 percentage points, the dry matter weight point of soybean seedling phase
Not than control increase by 23.2%, maturity period Pod Yield improves 8.48%；The soya seeds of 4 synergist of the present invention+embodiment processing
Seedling-growing time shortens 4.8d than the processing of simple synergist respectively, and emergence rate improves 3 percentage points, the dry matter weight of soybean seedling phase
Respectively than control increase by 23.2%, maturity period Pod Yield improves 9.4 %.
2nd, by enhancer composition made from embodiment 1-4（7%, SP）Mixed with urea（Mu 30g-50g）Combination is mixed
500 times of dilution, filled every 7 days and applies once, and fertilising 3 altogether is inferior to 465kg/ mus of green pepper field, is individually spread fertilizer over the fields using urea dilution
In 465kg/ mus of green pepper field, as blank control group, plantation measures blank control group and embodiment 1-4 group green peppers in 35 days respectively
Quality, physical signs and yield.The statistical result such as table 2 below after overtesting.
Influence of 2 seaweed amino acid composite liquid manure of table to Brassica rapa L quality
Found after overtesting, enhancer composition of the invention can effectively extend the fertilizer efficiency period of all kinds of nitrogen manures, fertilizer
The effect phase reaches more than 30 days, there is significant disease-resistant, degeneration-resistant effect to crops such as green peppers, has the nutrient for improving soil storage and changes
The effect of good soil, as shown in Table 2, compared with the control, using the processing of embodiment 1-4 group synergist in chlorophyll content, life
7-7.8%, 25-26%, 34.8-35.9% is respectively increased in terms of object amount, economic flow rate.The bud under the action of plant growth adjustment
Number is formed to be averagely calculated as more than 12/plant（Embodiment 1-4 group compound synergic agent）, 9.6/plant（Blank control test）, because
This, by the effect of the plant growth regulator in synergist of the present invention, dramatically increases the formation number of bud.
More than embodiment be only the preferred embodiment of the present invention is described, not to the scope of the present invention into
Row limits, on the premise of design spirit of the present invention is not departed from, technical side of this area ordinary skill technical staff to the present invention
The various modifications and improvement that case is made, should all fall into the protection domain that claims of the present invention determines.
Claims (4)
1. a kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action, it is characterised in that feed components are according to weight
Part composition is as follows：
60-80 parts of kelp, 2-5 parts of strain, 5-10 parts of carbon source, 3-5 parts of nitrogen source, 30-50 parts of water, middle 1.2-1.5 parts of trace element,
Loosen the soil 0.4-0.6 parts of agent, 2-4 parts of acid soil conditioner, 0.8-1.2 parts of plant growth regulator；
The nitrogen source is the mixture of the urea that content is 20-40% and 60-80% ammonium sulfate composition；
The agent of loosening the soil is carboxymethyl chitosan, precipitated calcium carbonate and diatomite according to weight ratio 1：3：The mixture of 3 compositions；
The preparation method of the acid soil conditioner is according to weight ratio 2：5 take camellia leaf and Camellia Leaves to mix, and add 3 times of volumes
Water, controlled at 20-24 DEG C, addition containing effective gemma number be no less than 1.0 × 1011The bafillus natto of cfu, ferment 8-
10 days, filter gained filtrate in, add the neopelex of 0.05-0.07% and the citric acid of 0.2-0.4%, mix
Conjunction stirs evenly；
The strain is to be no less than 2.0 × 10 containing effective gemma number11The Pediococcus acidilactici bacterium powder of cfu and many containing effective gemma number
In 1.0 × 1011The mix bacterium agent of the jelly bacillus bacterium powder composition of cfu；
The carbon source is the mixture that glucose, the sucrose of 20-40% and the starch of 60-80% that content is 10-20% form；
The preparation method of the alginic acid fertilizer synergist, specifically includes following steps：
(1) kelp is cleaned：Kelp is taken according to weight proportion, is cleaned 1-2 times with clear water；
(2) kelp clothes：By the kelp clothes that have cleaned 10-15 days, it is less than 10% to moisture；
(3) crush：The kelp dried is put into pulverizer and is crushed to 50-60 mesh；
(4) ferment：Kelp, strain, carbon source, nitrogen source, water and middle trace element mixing are taken according to formulation ratio, stirs evenly stacking
Fermentation 7-15 days；
(5) weak base extracts：Into material after fermentation, the water of 2.6-3.6 times of volume is added, stirs evenly, uses sodium carbonate
With sodium hydroxide according to weight ratio 2：The alkaline extractant of (3-5) composition adjusts pH between 8-9.5, and solution passes through automatic steam control
Temperature is 60 DEG C of -80 DEG C of stirring extraction 8-11h；
(6) Algae synergistic liquid processed：Solution carries out press filtration by filter press, and 2-5 parts of boric acid is added into obtained filtrate, with containing
The pH that the hydrochloric acid solution for having 3-5% acetic acid adjusts solution is 7.5-8.5, and evaporation and concentration obtains solid content >=8%, seaweed acid content
>=2.5, the Algae synergistic liquid of ammonia volatilization inhibiting rate 25-45%；
(7) fertilizer synergist processed：Agent of loosening the soil, acid soil conditioner, plant growth regulator is taken to sequentially add according to weight proportion
In Algae synergistic liquid made from step (6), stir evenly, encapsulate.
A kind of 2. alginic acid fertilizer synergist with ammonia volatilization inhibitory action according to claim 1, it is characterised in that institute
State middle trace element to be the EDTA chelated coppers for being 0.1-0.3% by percentage composition, EDTA chelated irons, the 0.1- of 0.4-0.6%
0.3% EDTA Chelated Manganeses, the EDTA chelated zincs of 0.3-0.5%, the EDTA chelated magnesiums of 0.1-0.3%, the EDTA of 0.5-0.7%
Chelate the Chelating state element of calcium composition.
A kind of 3. alginic acid fertilizer synergist with ammonia volatilization inhibitory action according to claim 1, it is characterised in that institute
It is by 2-4 parts of brassinosteroid, 4-6 parts of brassin lactones, 3-5 parts of gibberellin, 6-benzyl aminopurine to state plant growth regulator
3-5 parts, 4-6 parts of heteroauxin, the mixtures of 10-12 parts of amino-oligosaccharide composition.
A kind of 4. alginic acid fertilizer synergist with ammonia volatilization inhibitory action according to claim 1, it is characterised in that institute
State in the boric acid in step (6) added with the epsom salt aqueous solution and 2-3% concentration that 0.6-0.8% concentration is 100mg/kg
For the sodium selenite aqueous solution of 120mg/kg, boric acid can be replaced Chelating state copper, chelated ferrous iron, Chelating state manganese, Chelating state zinc, chela
Close the one or more in trace element in state calcium, Chelating state magnesium Chelating state.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510132551.8A CN104761413B (en) | 2015-03-25 | 2015-03-25 | A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510132551.8A CN104761413B (en) | 2015-03-25 | 2015-03-25 | A kind of alginic acid fertilizer synergist with ammonia volatilization inhibitory action and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104761413A CN104761413A (en) | 2015-07-08 |
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| CN108794140B (en) * | 2017-05-04 | 2022-05-03 | 江苏龙灯化学有限公司 | Alginic acid and trace element compounded solid preparation and preparation method and application thereof |
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| CN109438139A (en) * | 2018-11-09 | 2019-03-08 | 中国农业科学院农业资源与农业区划研究所 | A kind of preparation method with the alginic acid synergistic carrier for slowing down urea conversion |
| CN109180393A (en) * | 2018-11-09 | 2019-01-11 | 中国农业科学院农业资源与农业区划研究所 | A kind of granular urea preparation method containing alginic acid synergistic carrier suitable for corn top dressing |
| CN109665915A (en) * | 2019-02-14 | 2019-04-23 | 王永刚 | A kind of high activity fertilizer synergist and preparation method |
| CN111348977A (en) * | 2020-04-23 | 2020-06-30 | 青岛海力源生物科技有限公司 | Bacterial enzyme linked alginic acid fertilizer synergist and preparation method thereof |
| CN111499456A (en) * | 2020-04-23 | 2020-08-07 | 青岛海力源生物科技有限公司 | Fertilizer synergist containing chitosan oligosaccharide and preparation method thereof |
| CN111454105A (en) * | 2020-04-23 | 2020-07-28 | 青岛海力源生物科技有限公司 | Fertilizer synergist containing fish protein oligopeptide and preparation method thereof |
| CN112209765B (en) * | 2020-08-17 | 2022-06-07 | 中化化肥有限公司 | Synergist, synergistic potassium fertilizer and preparation method thereof |
| CN113046087B (en) * | 2021-03-18 | 2023-02-28 | 中国科学院海洋研究所 | Medicament and method for promoting microorganisms to restore soil secondary salinization |
| CN114133290A (en) * | 2021-12-21 | 2022-03-04 | 山东润银生物化工股份有限公司 | Biological organic fertilizer prepared from bacillus subtilis and used for increasing yield and improving quality of crops and preparation method |
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Denomination of invention: Alginic acid fertilizer synergist with ammonia volatilization inhibiting effect and preparation method of alginic acid fertilizer synergist Effective date of registration: 20200427 Granted publication date: 20180424 Pledgee: Qingdao Changyang financing Company limited by guarantee Pledgor: QINGDAO HAILIYUAN BIOTECHNOLOGY Co.,Ltd. Registration number: Y2020370010010 |
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Denomination of invention: Alginate fertilizer synergist with ammonia volatilization inhibition and its preparation method Effective date of registration: 20210325 Granted publication date: 20180424 Pledgee: Qingdao Changyang financing Company limited by guarantee Pledgor: QINGDAO HAILIYUAN BIOTECHNOLOGY Co.,Ltd. Registration number: Y2021370010011 |
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Denomination of invention: The invention relates to a alginate fertilizer synergist with ammonia volatilization inhibition and a preparation method thereof Effective date of registration: 20220402 Granted publication date: 20180424 Pledgee: Qingdao Changyang financing Company limited by guarantee Pledgor: QINGDAO HAILIYUAN BIOTECHNOLOGY CO.,LTD. Registration number: Y2022370010045 |
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