CN103086795A - Amino-acid chelated organic fertilizer and production method thereof - Google Patents
Amino-acid chelated organic fertilizer and production method thereof Download PDFInfo
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
The invention discloses an amino-acid chelated organic fertilizer and a production method thereof. The amino-acid chelated organic fertilizer is prepared from the following raw materials: 38-56wt% (weight percent) of organic matters, 10-15wt% of composite amino acid, 10-15wt% of chelating agent, 2-4 wt% of trace elements and 20-30wt% of nitrogen, phosphorus and potassium. Each gram of product contains more than 20 millions of live beneficial microbes. The amino-acid chelated organic fertilizer has the functions of improving the physical and chemical performances and the water and nutrient retaining performances of soil and promoting the formation of soil aggregates, is an preferential organic agriculture fertilizer, is suitable for vegetables, fruits, rice, corn, bananas, peppers and other crops, can ensure the high yield, good quality and good taste of agricultural products and can ensure that the nutrients of the agricultural products are increased significantly.
Description
Technical field
The invention belongs to farm crop fertilizer field, be specifically related to a kind of fertilizer and production method thereof of aminoacid chelating microelement.
Background technology
China is a large agricultural country, for thousands of years, the peasant who always makes a living with soil ploughing and weeding on this sheet soil is not stopped, Chinese from one generation to the next have also been brought up, but in decades, due to industrial expansion, increasing sharply of fertilizer production, the peasant relies on chemical fertilizer has become custom, but any kind that use in the farmland and the chemical fertilizer of form all can not all be utilized by plant absorbing, and the life-time service chemical fertilizer has caused serious environmental decay, soil fertility constantly descends, and affects the further raising of crop yield and quality; According to the literature, when chemical fertilizer was used in the field, chemical fertilizer utilization ratio was incomplete, and nitrogen is 30～60%, and phosphorus is 3～25%, and potassium is 30～60%.So fertilizer amount is excessive, though or use normally, due to other natures or artificial origin, chemical fertilizer is run off in a large number.The nitrogen compound that is not in time utilized by plant if exist with the form of the NO-N that can not be adsorbed by soil colloid, will be transferred to when the soil water permeates downwards below the densely distributed level of root system of plant and pollutes.The environmental problem that pollution by chemical fertilizer causes mainly contains: the 1. eutrophication in rivers and creeks, lake, inland sea.Causing the reason of waters eutrophication, is mainly that the content of nitrogen in water, phosphorus increases, and makes the aquatic plants growth such as algae too much.2. soil is polluted, and soil physical properties worsens.Long-term excessive and use merely chemical fertilizer, can make soil acidification.On soil solution sweetening of the soil micelle, the ammonium ion amount of organic and inorganic complex body increases, and replacement Ca
2+, Mg
2+Deng, soil colloid is disperseed, Soil structure destroys, the hardening soil, and directly affect output and the quality of agriculture production cost and crop.3. in food, feed and tap water, toxic ingredient increases.Large 5～10 times than nitrate of the bio-toxicities of nitrite, nitrite are combined the N-nitroso compound that forms with amine be strong carcinogen (seeing N-nitroso compound and cancer).In the well water in the area of use chemical fertilizer or river, the content of nitrogen compound can increase, and even surpasses drinking water standard.The soil of given too much chemicals can make nitrate content increase in the crops such as vegetables and herbage.The food and feed nitrite is too high, once causes children's and livestock intoxication accident.Also contain some other impurity in chemical fertilizer, as containing cadmium 1～100ppm in Rock Phosphate (72Min BPL), leaded 5～10ppm, these impurity also can cause environmental pollution.4. NO_x in Air Environment content increases.Be applied to the nitrogenous fertilizer in farmland, have a great deal ofly directly to evaporate into gas from soil surface, enter atmosphere.Also have quite a few to enter soil with the organic or inorganic nitrogen form, can change into nitrogen and oxynitride from the nitrogen compound of indissoluble attitude, ADSORPTION STATE and water-soluble attitude under the soil microorganisms effect, enter atmosphere.
Therefore in order to prevent the pollution of the environment; agricultural experts propose; should recover and increase soil fertility, preserve the ecological environment, the restoring mature econogy balance; and recover and increase soil fertility; best is farm crop application of organic fertilizers as far as possible, so open source literature has been reported a lot of relevant fertilizers, particularly contains the production method of amino acid whose fertilizer; through retrieval, we find following content:
1, Chinese patent, application number: 200410063079.9 titles: process for preparing bio-organic chelated trace fertilizer, open (bulletin) number: CN1721371 applies for (patent right) people: Dalian aquatic product Academy; Ministry of Agriculture's marine fishery aquaculture is learned and biotechnology emphasis open laboratory, the address: No. 52, Shahekou District black stone reef street, Daliang City, Liaoning Province, invention (design) people: Lv Jingcai; Zhao Yuanfeng; Wang Songlin, summary: a kind of process for preparing bio-organic chelated trace fertilizer is first the hydrolysis of albumen waste raw material to be generated aminoacids complex, then add trace element to make itself and composite aminoacid chelating generate amino-acid chelate; Again amino-acid chelate and beneficial microorganism bacterium (root nodule bacterium, vinelandii, phosphorus bacteria, potassium bacterium, milk-acid bacteria, genus bacillus etc.) and efficient organic fertilizer three are scientifically merged and form bio-organic chelated trace fertilizer.This bio-organic chelated trace fertilizer has that utilization rate of fertilizer is high, fertilizer efficiency fastly slowly has both, improvement and activating soil, improve the advantage such as crop quality.This fertilizer has significant fixed nitrogen, phosphorus decomposing, potassium decomposing, promotes the function of plant growth.The method technique is simple, easy to operate, production cost is low, raw material sources are wide, pollution-free, toxicological harmless.This product has advantages of that fertilizer efficiency is high, quality better, cost is low, consumption is few, easy to use, cheap.
2, Chinese patent, application number: 200510031886.7 titles: a kind of preparation of double effect biological organic fertilizer and technique application (patent right) people: Yan Jianhua, address: Changsha, Hunan liberation 10th floor, galaxy of literary talent garden, No. 19, West Road C, invention (design) people: Yan Jianhua, summary: a kind of preparation of double effect biological fertilizer and technique belong to fertilizer.Double effect biological fertilizer can satisfy physiological function, the immunologic function that the plant nutrition needs again can regulating plant.Strengthen the degeneration-resistant of crop, the ability of disease and insect resistance, this fertilizer, select amino acid complex and urea, fused(calcium magnesium)phosphate, MAP, vitriolate of tartar and cereuisiae fermentum, lobster shrimp shell powder, useful symbiosis flora, double effect biological organic fertilizer by zymotechnique, mixing granulation production can effectively increase fertility of land through using, reduce disease and pest, reduce agriculture chemical and use the raising crop quality, increase output.
3, Chinese patent, application number: 201110355244.8 titles: a kind of chelated trace element fertilizer-medicament mixture open (bulletin) number: CN102503698A Chinese patent, application (patent right) people: INST OF AGRICULTURAL RESOURCES, address: No.12 ,zhongguancun south street,Haidian District, Beijing, invention (design) people: Wang Hong; Chu Tianduo; Liu Xinbao; Liu Rongle; Li Chunhua; Yang Qing; Rong Xiangnong: summary: a kind of chelating type trace element fertilizer liquid body mixture, wherein selected the necessary trace element of crop to carry out compatibility, by adding multiple amino acids and sulfonated lignin, promote organism and trace element chelated reaction, selected biological pesticide avermectin to carry out effective the cooperation with fertilizer.The preparation method of fertilizer liquid body mixture product of the present invention is provided, has improved complex reaction level between trace element ion and multiple-effect sequestrant by the method, solved emulsification demixing technology problem.Product sprays in crop leaf, can correct crop trace element and lack, and successful has the disease-resistant, insect-prevention effect concurrently.
4, Chinese patent, application number: 201010500648.7 titles: a kind of production method of amino acid fertilizer, open (bulletin) number: CN102417410A, application (patent right) people: slander million acts, address: sea route Jiangsu New Port gold source chemical fertilizer company limited on the Xinyi City Economic Development Zone, Jiangsu Province, summary: a kind of production method of amino acid fertilizer, this product belong to the agricultural fertilizer field, it is characterized in that relating to a kind of amino acid fertilizer.Fertilizer is mainly derived from animal and plant, with vegeto-animal waste, movement, the processing of residual body, be rich in multiple organic acid, peptide class and nitrogen, phosphorus, potassium at interior abundant nutritive element, can not only provide full nutrition for farm crop, and fertilizer efficiency is long, can increase and upgrade the soil organism, promotes microbial reproduction, improving physico-chemical property and the biological activity of soil, is the Main Nutrients of pollution-free food production.The raw material of producing this amino acid fertilizer use has: the mixture of animal residue, straw, castorseed cake, production monosodium glutamate tankage, vinasse, pollution-free pond sludge, the peat composed of rotten mosses, organic fertilizer fermentation agent, bactericidal deodorant, aminoacid chelating microelement.
5, Chinese patent, application number: 200710054852.9 titles: amino acid nitrogen biological organic composite fertilizer and production technique thereof, open (bulletin) number: CN101117300, application (patent right) people: Wu Guoliang, address: 2nd floor, No. 23 building of Xinxiang City, Henan Province Hongqi District Henan Science and Technology College invention (design) people: Wu Guoliang, summary: a kind of compound manure, be specifically related to amino acid nitrogen biological organic composite fertilizer and production technique thereof, it contains following composition, and each composition is in weight percent: amino-acid nitrogen 5%-13%; With P
2O
5Meter phosphorus 3%-10%; With K
2O meter potassium 3%-10%; Nitrogen, phosphorus, potassium total amount are 11%-33%; Organic butt 〉=30%; Trace element 〉=2%.This compoiste fertilizer is processed it take fowl plumage, poultry hair as matrix through high temperature, high pressure materialization, then the amino acidifying of Enrichment by Microorganisms makes the high organonitrogen material of amino-acid state under catalyzer; Being equipped with the animal dung of fermenting, alditol slag, vinasse etc. makes with trace mineral supplement again.This biological organic fertilizer contains high organic constituent, homoamino acid attitude (non-urea attitude) organonitrogen and trace element, and abundant that the crop yields such as farm crop, vegetables, fruit tree are increased matter is obvious, can produce the anti-harmful ability of diseases prevention with this fertilizer fertilising strong, Gao You, green, environmentally friendly crop products are the best fertilizer of producing pollution-free vegetable, green food and Organic food.
See from above-mentioned, at present the chelating amino acids compoiste fertilizer of open source literature report be mainly with amino acid, farm manure or factory's tankage and chemical fertilizer by fermentation or configuration obtain, what have also adds chelated microelement, make the existing suitable nitrogen phosphorus potassium of farm crop, required moderate-element is also arranged, also having can absorbable trace element, but some complex manufacturing process, although what have adds chelated microelement, but the nutritive ingredient of fertilizer is comprehensive not, and the fertilizer adaptability that obtains is wideless.
Summary of the invention
The purpose of this invention is to provide a kind of chelating amino acids organic trace element fertilizer and production method thereof, it has considered various proportion of crop planting characteristics and growth regulation of fertilizer requirement, take improve the ecological environment, eliminate side effect, fertilizing soil that fertilizer brings, improve Soil structure, loosing soil does not harden, provides plant nutrition as purpose, by combinations such as inorganic fertilizer, fertilizer, aminoacids complex, moderate-element, trace elements, both satisfy the crop growth demand, improved output and quality.
The raw materials for production of edible mushrooms have cotton seed hulls, wood chip, wheat bran, Semen Maydis powder etc., and bacterial classification provides growth itself fatting up in raw material, and after the bacterial classification maturation, the various nutrients in raw material exhaust substantially, can not as the raw material of cultivating the next batch edible mushrooms, can only abandon.Method by burning with the method for the waste material of pre-treatment edible mushrooms, this method can be processed waste material at short notice in a large number, but can produce a large amount of poison gas, and also contain a large amount of Mierocrystalline celluloses and micro-nutrient in waste material, also have the potentiality that develop.Tapioca (flour) factory produces in the starch process and has produced a large amount of manioc wastes, and the method that former starch factory is processed fecula is also to use burning method, but contains a large amount of Mierocrystalline celluloses and a small amount of starch in fecula, also has the very large potential quality of utilizing.Peanut press pulp, dregs of beans and animal excrement contain abundant organic substance equally, can deep processing and utilization.The present invention adopts the complex microorganism thermophilic fermentation to process the waste that is rich in organic substance, and the organic substance in waste fully is degraded into the nutrient that plant can absorb, and can either process waste without harm, has produced again efficiency of cycling economy.
The slaughterhouse all produces and be difficult in a large number biodegradable waste material every day, and as pig hair, ox hair, wool, chicken feather etc., barber shop all produces a large amount of hairs every day.The main component of hair and feather is Keratin sulfate, because Keratin sulfate contains more Gelucystine, therefore disulfide bond content is many especially, play crosslinked action in protein peptide chain, therefore the Keratin sulfate chemical property is stable especially, and higher physical strength is arranged, thereby their not soluble and digestion.The present invention adopts the strong acid hydrolysis of keratin, makes it be degraded to amino acid or polypeptide, is used for agriculture production, can be not only that plant is replenished nitrogenous source, can also the complexing micro-metals, farm crop are had the double effects of sterilizing disease-preventing and stimulating growth.
Subtilis, the Latin formal name used at school
Bacillus subtilis, the industrial sewage of having stable political situation in the city is processed, the industrial cycle water treatment, and the processing such as septic tank, septic tank, livestock-raising animal waste, stink are processed, excrement and urine treating system, the application during rubbish, manure pit, manure pit etc. are processed is very extensive.Bacillus licheniformis, Latin formal name used at school Baclicus lincheniformis, the ability of its degraded organic matter is very strong, and scientist is utilizing this degradation by bacteria feather, is used for agriculture purpose.Bacillus circulans, Latin formal name used at school Bacillus circulans Jordan can produce very strong polygalacturonase, cellulase, and decomposition of cellulose is had promoter action.The monospore daughter bacteria, Latin formal name used at school micromonospora can utilize the extracellular enzyme of its secretion and have machinery and intert the mycelia of the ability hardly degraded organic substance (as Mierocrystalline cellulose, hemicellulose and xylogen etc.) in compost of jointly degrading.Have a liking for warm nature fungi geotrichum sp, Latin formal name used at school Geotrichum sp. and thermophilic fungi Aspergillus fumigatus, Latin formal name used at school Aspergilbus fumigatus has the ability of stronger decomposing lignocellulose.The present invention adopts the composition of mentioned microorganism to decompose the waste material that is rich in organic substance, (compost fermentation is divided into heat production stage, hot stage and becomes thoroughly decomposed the stage to utilize the advantage that different microorganisms has in different steps,), reach decompose organic waste thoroughly, the kill harmful germ, the purpose that turns waste into wealth.
The elements such as boron, iron, zinc, molybdenum and magnesium are the important component of plant enzyme, these micro-ions of while or the activator of enzymic activity, if lack these elements, the elements such as plant can't absorbed nitrogen, phosphorus, potassium, plant shows as the blade flavescence and turns white, photosynthesis weakens or disappears, and plant-growth is suppressed, and even plant is dead because lacking nutrition.Therefore it is very important giving the plant trace element supplement.Can boric acid and borax be arranged as the material of plant boron make-up element, the present invention adopts common borax.Ammonium molybdate is more common, so the present invention adopts ammonium molybdate as the molybdenum element supplement of plant.And can their vitriol, nitrate or muriate be arranged as the material of the supplement of iron, zinc and magnesium elements, because vitriol can provide element sulphur for plant, so the present invention preferentially adopts the vitriol of iron, zinc and magnesium.These trace elements are had an effect with phosphate fertilizer, can generate water-fast phosphoric acid salt, cause the plant absorbing utilization ratio to descend, therefore need to add sequestrant, by the sequestering action of sequestrant, prevent that iron, magnesium, manganese and zine ion and phosphate anion from forming water-insoluble.Humic acid, English name humic acid is brown, and molecular weight mainly is made of elements such as carbon, hydrogen, oxygen, nitrogen between 400-100000, and carbon, hydrogen ratio are high.Core in its molecular structure has aromatic nucleus, heterocycle and polynuclear compound, and they are connected into loose netted by carbochain or key bridging.There are functional group such as carboxyl, phenolic hydroxyl group, methoxyl group, amido etc. in the edge of humic acid molecule.These functional groups determine that the acidity of humic acid, absorptive capacity reach the ability that forms organic-inorganic composition with inorganics.Fulvic acid, English name fulvic acid, the molecular weight ratio humic acid is little, and institute's carbon containing, nitrogen comparatively small amt in molecule, hydrogen, oxygen are high than humic acid, and be strong with the sequestering power of inorganics.Sodium salts humic acids, English name is Sodium humate, is to adopt the natural low magnesium weathered coal of the low calcium of high-quality that contains humic acids to refine through chemistry to form, and it is multi-functional macromolecular compound, contain hydroxyl, quinonyl, the active group that carboxyl etc. are more has very large internal surface area, stronger absorption is arranged, exchange, complexing, sequestering power.
Technical scheme of the present invention is as follows:
The chelating amino acids organic trace element fertilizer comprises that following raw material forms:
Organic 38-56wt%;
Aminoacids complex 10-15wt%;
Sequestrant 10-15wt%;
Trace element 2-4wt%;
Nitrogen phosphorus potassium 20-30wt%;
described organic matter is the waste material with edible mushrooms, the manioc waste of tapioca (flour) factory, peanut press pulp, animal excrement and dregs of beans are raw material, with weight fraction: the waste material 30-40 of edible mushrooms, manioc waste 30-40, animal excrement 10-15, peanut press pulp 5-10 and dregs of beans 5-10 mix, raw material per ton adds the 0.5-1kg microorganism, it is nitrogenous source and the phosphorus nutrient of microorganism that raw material per ton adds 0.5-1 kg urea and 0.25-0.5kg Secondary ammonium phosphate, add amount of water to mix, regulate moisture content, hold agglomerating, a finger resilience energy gently scatters, do not drip in the middle of webs for easily, the material that mixes is piled the ridge, spontaneous fermentation heats up, when temperature is spent over 70, kept 5-7 days, then turning cooling, organic matter carries out thermophilic and becomes thoroughly decomposed, air-dry, shatter, cross 80 eye mesh screens, obtain organic matter.
Described microorganism is subtilis, Bacillus licheniformis, Bacillus circulans, monospore daughter bacteria, have a liking for warm nature fungi geotrichum sp and thermophilic fungi Aspergillus fumigatus etc. the weight mixture.
The hair that described aminoacids complex is behaved and
/Or animal hair or feather are put into enamel reaction still, be 31-35% salt acid soak with weight concentration, hydrochloric acid add-on behaviour hair and animal skin soaked the surface and got final product, then reacted under 100～120 ℃ 8～12 hours, with sodium hydroxide neutralization, when pH value 5-7 begins filtration, filtrate is compound amino acid primary liquid, being concentrated into degree Beaume is 60 degree, namely obtains aminoacids complex.
Described sequestrant is the composition of humic acid, fulvic acid and Sodium salts humic acids, their weight ratio humic acid: fulvic acid: Sodium salts humic acids is 1～2:1:1～2.
Described trace element is the composition of borax, ammonium molybdate, ferric sulfate, zinc sulfate and sal epsom, contain the element of following mass percent: S 0.050%～2.00% in described trace element in the chelating amino acids organic trace element fertilizer, B 0.030%～0.5%, Zn 0.010%～0.50%, Fe 0.010%～0.50%, Mo 0.030%～0.5%, and Mg 0.050%～0.50%.
Described nitrogen phosphorus potassium is the composition of urea, Secondary ammonium phosphate and Repone K.
The production method of described chelating amino acids organic trace element fertilizer, comprise the steps: that (1) is made into weight concentration with described aminoacids complex is 30% the aqueous solution, add sequestrant, then add borax, zinc sulfate, sal epsom, ammonium molybdate and ferrous sulfate, be stirred to material and all dissolve, continue again to stir 20min, fully stir chelating, then spraying drying, pulverize, cross 80 order mesh screens, obtain chelated microelements;
(2) nitrogen phosphorus potassium is pulverized with pulverizer, crosses 80 order mesh screens, mixes with agitator with organic matter;
(3) mixture that (1) step and (2) step is obtained mixes with agitator and obtains the chelating amino acids organic trace element fertilizer.
Described chelating amino acids organic trace element fertilizer is characterized in that, the beneficial microorganism viable count that every gram chelating amino acids organic trace element fertilizer contains〉0.2 hundred million.
Advantage of the present invention is:
1, use chelating amino acids organic trace element fertilizer of the present invention high in technological content: the fertilizer fermenting raw materials, be equipped with the animal skin hydrolysis and amino acid, use that the modern high technology biotechnology is refining to be formed, nutrient is complete, content is high, fertilizer efficiency is long.
2, can effectively carry content after using, also can be used for fruit trees and vegetables, use rear flower and fruit protecting rate and improve more than 25%.The increasing both production and income high efficiency generally can be increased production more than 25% successful.
3, improve product quality: after use, crop growth is more natural, and product special flavour is good, and sugarcane sugarcane stem is sturdy, and sugar degree is high, and the leaf look light green.
4, cost less investment: use this fertilizer can reduce the usage quantity of chemical fertilizer, reduce costs.
5, diseases and pests of agronomic crop is few: can make the farm crop root system flourishing after use, stem is slightly full of leaves, and is resistant to lodging.This fertilizer contains a large amount of beneficial microorganism viable bacterias, can effectively suppress the growth of harmful bacteria, reduces the generation of disease and pest.
6 human hairs, animal hair and feather are difficult to decompose, if effectively do not utilize, also can cause adverse influence to environment, also affect material cycle and the comprehensive utilization of the ecosystem, are unfavorable for the Sustainable development of agricultural.Can be used for producing green food and Organic food, to protect mankind is healthy.
7, improve environmental nonpollution: this fertilizer can be eliminated the side effect that chemical fertilizer brings, and improves environment, fertilizing soil.
8, widely applicable and excellent: as to be applicable to various farm crop, to improve Soil structure: life-time service, loosing soil does not harden, easily farming.
9, fertilizer efficiency is excellent: allocated rational npk nutrient into according to the crop growth needs in process of production, peasants can be used as base manure or intertillage relieved, easily and topdress.
10, play temperature soon: when temperature was more than 0 ℃, temperature rose to more than 55 ℃ in 48 hours.The organic sulfide that produces stink, organic nitrogen compound etc. can be fully decomposed in fowl poultry kind ight soil, stink can be eliminated in intensification 2-3 days.
11, the compost cycle short, became thoroughly decomposed fully in 10-15 days.
12, compost high temperature (55 ℃-79 ℃) is lasting, can kill germ, worm's ovum, weed seed in fermented product.
13, the loss of compost total nutrient is few, and humus content is high, and the potassium cellulose content increases obviously.
Specific embodiment
Embodiment 1
organic production: waste material 30 weight parts of edible mushrooms, manioc waste 40 weight parts, animal excrement 15 weight parts, peanut press pulp 10 weight parts and dregs of beans 5 weight parts, add the 0.5kg subtilis according to raw material per ton, Bacillus licheniformis, Bacillus circulans, the monospore daughter bacteria, have a liking for warm nature fungi geotrichum sp and thermophilic fungi Aspergillus fumigatus etc. weight mixture and raw material per ton add 0.5kg urea and 0.25kg Secondary ammonium phosphate, add amount of water to mix, regulate moisture content, hold agglomerating, a finger resilience energy gently scatters, do not drip in the middle of webs for easily, the material that mixes is piled the ridge, spontaneous fermentation heats up, when temperature is spent over 70, kept 5-7 days, then turning cooling, organic matter carries out thermophilic and becomes thoroughly decomposed, air-dry, shatter, cross 80 eye mesh screens, obtain organic matter.
Embodiment 2
organic production: waste material 35 weight parts of edible mushrooms, manioc waste 35 weight parts, animal excrement 10 weight parts, peanut press pulp 5 weight parts and dregs of beans 10 weight parts, add the 0.75kg subtilis according to raw material per ton, Bacillus licheniformis, Bacillus circulans, the monospore daughter bacteria, have a liking for warm nature fungi geotrichum sp and thermophilic fungi Aspergillus fumigatus etc. weight mixture and raw material per ton add 0.75kg urea and 0.4kg Secondary ammonium phosphate, add amount of water to mix, regulate moisture content, hold agglomerating, a finger resilience energy gently scatters, do not drip in the middle of webs for easily, the material that mixes is piled the ridge, spontaneous fermentation heats up, when temperature is spent over 70, kept 5-7 days, then turning cooling, organic matter carries out thermophilic and becomes thoroughly decomposed, air-dry, shatter, cross 80 eye mesh screens, obtain organic matter.
Embodiment 3
organic production: waste material 40 weight parts of edible mushrooms, manioc waste 30 weight parts, animal excrement 13 weight parts, peanut press pulp 8 weight parts and dregs of beans 8 weight parts, add the 1kg subtilis according to raw material per ton, Bacillus licheniformis, Bacillus circulans, the monospore daughter bacteria, have a liking for warm nature fungi geotrichum sp and thermophilic fungi Aspergillus fumigatus etc. weight mixture and raw material per ton add 1kg urea and 0. 5kg Secondary ammonium phosphate, add amount of water to mix, regulate moisture content, hold agglomerating, a finger resilience energy gently scatters, do not drip in the middle of webs for easily, the material that mixes is piled the ridge, spontaneous fermentation heats up, when temperature is spent over 70, kept 5-7 days, then turning cooling, organic matter carries out thermophilic and becomes thoroughly decomposed, air-dry, shatter, cross 80 eye mesh screens, obtain organic matter.
Embodiment 4
The production of aminoacids complex:
After people's hair and pig hair are suitably pulverized, put into enamel reaction still, be 31-35% salt acid soak with weight concentration, hydrochloric acid add-on behaviour hair and animal skin soaked the surface and got final product, and then reacted under 100～120 ℃ 8～12 hours, neutralized with sodium hydroxide, when pH value 5-7 begins to filter, filtrate is compound amino acid primary liquid, and being concentrated into degree Beaume is 60 degree, namely obtains aminoacids complex.
Embodiment 5
The production of chelating amino acids organic trace element fertilizer:
(1) aminoacids complex 10kg adds 40kg water, adds humic acid 3.75kg under stirring, fulvic acid 2.5kg, Sodium salts humic acids 3.75kg; Add borax 0.8kg, ferrous sulfate 0.2kg, zinc sulfate 0.5kg, sal epsom 2.1kg and ammonium molybdate 0.4kg are stirred to material and all dissolve again, continue again to stir 20min, fully stir chelating, last spraying drying, pulverizing, cross 80 order mesh screens, obtain chelated microelements;
(2) take organic 56kg, added the urea 10kg of 80 order mesh screens, Secondary ammonium phosphate 4kg and Repone K 6kg mix with agitator
(3) mixture that (1) step and (2) step is obtained mixes, and packing is the chelating amino acids organic trace element fertilizer.
Embodiment 6
The production of chelating amino acids organic trace element fertilizer:
(1) aminoacids complex 14kg adds 40kg water, adds humic acid 3kg under stirring, fulvic acid 3kg, Sodium salts humic acids 6kg; Add borax 1.0kg, ferrous sulfate 0.05kg, zinc sulfate 1.0kg, sal epsom 0.35kg and ammonium molybdate 0.6kg are stirred to material and all dissolve again, continue again to stir 20min, fully stir chelating, last spraying drying, pulverizing, cross 80 order mesh screens, obtain chelated microelements;
(2) take organic 49kg, added the urea 10kg of 80 order mesh screens, Secondary ammonium phosphate 6kg and Repone K 6kg mix with agitator;
(3) mixture that (1) step and (2) step is obtained mixes, and packing is the chelating amino acids organic trace element fertilizer.
Embodiment 7
The production of chelating amino acids organic trace element fertilizer:
(1) aminoacids complex 15kg adds 40kg water, adds humic acid 7.5kg under stirring, fulvic acid 3.75kg, Sodium salts humic acids 3.75kg; Add borax 0.28kg, ferrous sulfate 1.32kg, zinc sulfate 0.05kg, sal epsom 0.25kg and ammonium molybdate 0.1kg are stirred to material and all dissolve again, continue again to stir 20min, fully stir chelating, last spraying drying, pulverizing, cross 80 order mesh screens, obtain chelated microelements;
(2) take organic 38kg, urea 16kg, Secondary ammonium phosphate 6kg and Repone K 8kg mix with agitator
(3) mixture that (1) step and (2) step is obtained mixes, and packing is the chelating amino acids organic trace element fertilizer.
Chelating amino acids organic trace element fertilizer using method of the present invention:
Banana: execute 50-75 kilograms of chelating amino acids organic trace element fertilizers+20 kilogram urea+50 kilograms of phosphate fertilizer for every mu and make base manure, during large ridging every mu execute chelating amino acids organic trace element fertilizer 150 kilograms+20 kilograms urea+50 kilogram potash fertilizer mix execute for stem fertile, blinding after general trench digging imposes in ditch.
Paddy rice: execute 50 kilograms for every mu and make base manure, plow harrow is spread on the field face before the field, by the plow harrow field sneaking in topsoil uniformly.
Peanut: execute 25-50 kilograms to make base manure disposable employed for every mu, under generally executing when whole ground.Note sowing after fertilizer is executed lower bonnet last layer thin soil, do not allow seed directly contact with fertilizer.
Corn: execute 50-75 kilograms to make base manure disposable employed for every mu, generally execute in the sowing thing.
Cotton: execute 50-100 kilograms of urea of chelating amino acids organic trace element fertilizer+20 kilograms of phosphate fertilizer for every mu and make base manure, when buddingging, every mu of large ridging is executed 50 kilograms+20 kilograms urea of chelating amino acids organic trace element fertilizer and is mixed and do, blinding after general trench digging imposes in ditch.
Huai Shan: execute 75-100 kilograms to make base manure disposable employed for every mu, generally be sprinkling upon in the sowing cave, fertilizer and soil are mixed even, the lid kind.
Watermelon: execute 100-150 kilograms to make base manure disposable employed for every mu, under generally executing when whole ground.
Leaf vegetables: execute 75-100 kilograms (leaf mustard can be executed 100-150 kilograms) to make base manure disposable employed for every mu, under generally executing when whole ground.
Eggplant: execute 100-150 kilograms to make base manure disposable employed for every mu, under generally executing when whole ground.
Grape: execute 100-150 kilograms for every mu and make base manure, execute at root system 15-20cm trench digging the beginning of spring.
Citrus: generally can every strain use 2-3 kilograms (adjusting flexibly depending on fruit tree size, output height) when expanding the cave in conjunction with clear garden autumn and winter, can be mixed together with the weeds in clear garden and execute in the ditch that expands the cave, execute one deck fertilizer weeds lid layer soil.
Attention: should suitably adjust amount of application according to soil fertility level, crop varieties, yield level etc. during use.
Chelating amino acids organic trace element fertilizer of the present invention and conventional composite fertilizer are compared as follows the volume increase of farm crop:
Application Example 1
Table 1The chelating amino acids organic trace element fertilizer is used for the contrast table of banana
Illustrate: the banana variety of three is all William B6;
Conventional fertilizer application is composite fertilizer (15-15-15)
As seen from Table 1, use chelating amino acids organic trace element fertilizer of the present invention, than using conventional composite fertilizer, banana can increase production 3%～9%, and fertilizer cost can descend approximately 50%.
Application Example 2
Open 2 groups, slope and open six and account for the contrast table that the chelating amino acids organic trace element fertilizer is used for corn in Gu Yi town, Xiangyang City, table 2 Hubei
Indicate: conventional fertilizer application is composite fertilizer (15-8-12) corn variety: Zheng Dan 958; Cotton variety: " cotton No. 9 of brilliant China; Peanut varieties: in spend No. 8
As seen from Table 2, use chelating amino acids organic trace element fertilizer of the present invention, than using conventional composite fertilizer, corn can increase production approximately 10%; Yield Increase In Cotton approximately 30%, and every mu of fertilizer cost can descend approximately 50%.
Application Example 3
Table 3
Grape (temperature can (Wink)) the fertilising effect contrast table of pool village model industry hero is strangled in the literary composition town in Guanyang, guangxi county in 2011:
Indicate: conventional fertilizer (100 kilograms of composite fertilizer+50 kilogram farm manures), grape is life in 4 years.
As seen from Table 3, use chelating amino acids organic trace element fertilizer of the present invention, than using conventional composite fertilizer, grape can increase production approximately 4%; And use grape outward appearance that the chelating amino acids organic trace element fertilizer obtains than using the large of conventional composite fertilizer, soluble sugar content is high, and taste is relatively good.
Application Example 4
Table 4
The potato fertilization effect contrast table of Guangxi agricultural college of Guangxi University in 2011:
Indicate: Potato Cultivars is purple-colored potato; Composite fertilizer (16-10-12)
As seen from Table 4, use chelating amino acids organic trace element fertilizer of the present invention, than using conventional composite fertilizer, potato can increase production approximately 17%, and protein content improves approximately 80%; And the potato of using the chelating amino acids organic trace element fertilizer has pest-resistant evil.
Claims (8)
1. a chelating amino acids organic trace element fertilizer, is characterized in that, comprises that following raw material forms:
Organic 38-56wt%;
Aminoacids complex 10-15wt%;
Intercalating agent 10-15wt%;
Trace element 2-4wt%;
Nitrogen phosphorus potassium 20-30wt%.
2. chelating amino acids organic trace element fertilizer according to claim 1, it is characterized in that, described organic matter is the waste material with edible mushrooms, the manioc waste of tapioca (flour) factory, peanut press pulp, animal excrement and dregs of beans are raw material, in weight fraction: the waste material 30-40 of edible mushrooms, manioc waste 30-40, animal excrement 10-15, after peanut press pulp 5-10 and dregs of beans 5-10 mix, raw material per ton adds the 0.5-1kg microorganism, it is nitrogenous source and the phosphorus nutrient of microorganism that raw material per ton adds 0.5-1 kg urea and 0.25-0.5kg Secondary ammonium phosphate, add appropriate moisture content to mix, regulate moisture content, hold agglomerating, a finger resilience energy gently scatters, do not drip in the middle of webs for easily, the material that mixes is piled the ridge, spontaneous fermentation heats up, when temperature surpasses 70 ℃, kept 5-7 days, then turning cooling, organic matter carries out thermophilic and becomes thoroughly decomposed, air-dry, shatter, cross 80 eye mesh screens, obtain organic matter,
Described microorganism is subtilis, Bacillus licheniformis, Bacillus circulans, monospore daughter bacteria, have a liking for warm nature fungi geotrichum sp and thermophilic fungi Aspergillus fumigatus etc. the complex microorganism that mixes of weight.
3. chelating amino acids organic trace element fertilizer according to claim 1, is characterized in that, the hair that described aminoacids complex is behaved and
/Or animal hair or feather are put into enamel reaction still, be 31-35% salt acid soak with weight concentration, hydrochloric acid add-on behaviour hair and animal skin soaked the surface and got final product, then reacted under 100～120 ℃ 8～12 hours, with sodium hydroxide neutralization, when pH value 5-7 begins filtration, filtrate is compound amino acid primary liquid, being concentrated into degree Beaume is 60 degree, namely obtains aminoacids complex.
4. chelating amino acids organic trace element fertilizer according to claim 1, is characterized in that, described intercalating agent is the composition of humic acid, fulvic acid and Sodium salts humic acids, their weight ratio humic acid: fulvic acid: Sodium salts humic acids is 1～2:1:1～2.
5. chelating amino acids organic trace element fertilizer according to claim 1, is characterized in that, described trace element is borax, ammonium molybdate, ferrous sulfate, zinc sulfate and sal epsom; Described trace element contains following mass percent: S 0.050%～2.00% in the chelating amino acids organic trace element fertilizer, B 0.030%～0.5%, Zn 0.010%～0.50%, and Fe 0.010%～0.50%, and Mo 0.030%～0.5%, and Mg 0.050%～0.50%.
6. chelating amino acids organic trace element fertilizer according to claim 1, is characterized in that, described nitrogen phosphorus potassium is the composition of urea, Secondary ammonium phosphate and Repone K.
7. the production method of chelating amino acids organic trace element fertilizer according to claim 1, is characterized in that, comprises the steps:
(1) described aminoacids complex being made into weight concentration is 20～30% the aqueous solution, add sequestrant, add again borax, zinc sulfate, sal epsom, ammonium molybdate and ferrous sulfate, be stirred to material and all dissolve, then continue to stir 20min, fully stir chelating, then spraying drying, pulverize, cross 80 order mesh screens, obtain chelated microelements;
(2) nitrogen phosphorus potassium is pulverized with pulverizer, crosses 80 order mesh screens, mixes with agitator with organic matter;
(3) mixture that (1) step and (2) step is obtained mixes with agitator and obtains the chelating amino acids organic trace element fertilizer.
8. chelating amino acids organic trace element fertilizer according to claim 1, is characterized in that, the beneficial microorganism viable count that every gram chelating amino acids organic trace element fertilizer contains〉0.2 hundred million.
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