CN104744165B - A kind of alginic acid envelope composite fertilizer with urease inhibiting effect and preparation method thereof - Google Patents
A kind of alginic acid envelope composite fertilizer with urease inhibiting effect and preparation method thereof Download PDFInfo
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- CN104744165B CN104744165B CN201510133389.1A CN201510133389A CN104744165B CN 104744165 B CN104744165 B CN 104744165B CN 201510133389 A CN201510133389 A CN 201510133389A CN 104744165 B CN104744165 B CN 104744165B
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 99
- 238000002360 preparation method Methods 0.000 title claims abstract description 36
- 108010046334 Urease Proteins 0.000 title claims abstract description 23
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 230000002401 inhibitory effect Effects 0.000 title claims abstract description 23
- 235000010443 alginic acid Nutrition 0.000 title claims abstract description 22
- 229920000615 alginic acid Polymers 0.000 title claims abstract description 22
- 239000000783 alginic acid Substances 0.000 title claims abstract description 19
- 229960001126 alginic acid Drugs 0.000 title claims abstract description 19
- 150000004781 alginic acids Chemical class 0.000 title claims abstract description 19
- 241000195493 Cryptophyta Species 0.000 claims abstract description 37
- 239000012747 synergistic agent Substances 0.000 claims abstract description 35
- 238000000576 coating method Methods 0.000 claims abstract description 30
- 102000004190 Enzymes Human genes 0.000 claims abstract description 29
- 108090000790 Enzymes Proteins 0.000 claims abstract description 29
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 238000002156 mixing Methods 0.000 claims abstract description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 28
- 150000001413 amino acids Chemical class 0.000 claims abstract description 28
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000005696 Diammonium phosphate Substances 0.000 claims abstract description 22
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims abstract description 22
- 235000019838 diammonium phosphate Nutrition 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 14
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 11
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004021 humic acid Substances 0.000 claims abstract description 11
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 11
- 235000011151 potassium sulphates Nutrition 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 48
- 229940088598 enzyme Drugs 0.000 claims description 27
- 235000001014 amino acid Nutrition 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 20
- 230000002195 synergetic effect Effects 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 16
- 241000894006 Bacteria Species 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000008187 granular material Substances 0.000 claims description 15
- 238000005469 granulation Methods 0.000 claims description 15
- 230000003179 granulation Effects 0.000 claims description 15
- 238000007792 addition Methods 0.000 claims description 13
- 239000004365 Protease Substances 0.000 claims description 12
- 150000007524 organic acids Chemical class 0.000 claims description 12
- 238000000855 fermentation Methods 0.000 claims description 11
- 230000004151 fermentation Effects 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 10
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 9
- 230000008020 evaporation Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 229920001661 Chitosan Polymers 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 108091005804 Peptidases Proteins 0.000 claims description 7
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 7
- 239000005416 organic matter Substances 0.000 claims description 7
- 235000019419 proteases Nutrition 0.000 claims description 7
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 235000013922 glutamic acid Nutrition 0.000 claims description 6
- 239000004220 glutamic acid Substances 0.000 claims description 6
- 229920001542 oligosaccharide Polymers 0.000 claims description 6
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 5
- 241000512259 Ascophyllum nodosum Species 0.000 claims description 5
- 241000228245 Aspergillus niger Species 0.000 claims description 5
- 241001037822 Bacillus bacterium Species 0.000 claims description 5
- 244000063299 Bacillus subtilis Species 0.000 claims description 5
- 241001474374 Blennius Species 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- IXVMHGVQKLDRKH-VRESXRICSA-N Brassinolide Natural products O=C1OC[C@@H]2[C@@H]3[C@@](C)([C@H]([C@@H]([C@@H](O)[C@H](O)[C@H](C(C)C)C)C)CC3)CC[C@@H]2[C@]2(C)[C@@H]1C[C@H](O)[C@H](O)C2 IXVMHGVQKLDRKH-VRESXRICSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 235000019750 Crude protein Nutrition 0.000 claims description 5
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 5
- 108090000526 Papain Proteins 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 5
- 102000005158 Subtilisins Human genes 0.000 claims description 5
- 108010056079 Subtilisins Proteins 0.000 claims description 5
- 239000008351 acetate buffer Substances 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- RQFQJYYMBWVMQG-IXDPLRRUSA-N chitotriose Chemical compound O[C@@H]1[C@@H](N)[C@H](O)O[C@H](CO)[C@H]1O[C@H]1[C@H](N)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)N)[C@@H](CO)O1 RQFQJYYMBWVMQG-IXDPLRRUSA-N 0.000 claims description 5
- 210000003298 dental enamel Anatomy 0.000 claims description 5
- 230000005496 eutectics Effects 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 239000002509 fulvic acid Substances 0.000 claims description 5
- 229940095100 fulvic acid Drugs 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 235000015110 jellies Nutrition 0.000 claims description 5
- 239000008274 jelly Substances 0.000 claims description 5
- 235000001055 magnesium Nutrition 0.000 claims description 5
- 235000012054 meals Nutrition 0.000 claims description 5
- 229920000609 methyl cellulose Polymers 0.000 claims description 5
- 239000001923 methylcellulose Substances 0.000 claims description 5
- 235000010755 mineral Nutrition 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 238000006396 nitration reaction Methods 0.000 claims description 5
- 229940055729 papain Drugs 0.000 claims description 5
- 235000019834 papain Nutrition 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- 239000002893 slag Substances 0.000 claims description 5
- 239000001632 sodium acetate Substances 0.000 claims description 5
- 235000017281 sodium acetate Nutrition 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 230000001954 sterilising effect Effects 0.000 claims description 5
- 238000004659 sterilization and disinfection Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 235000016804 zinc Nutrition 0.000 claims description 5
- IXVMHGVQKLDRKH-YEJCTVDLSA-N (22s,23s)-epibrassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@H](O)[C@@H](O)[C@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-YEJCTVDLSA-N 0.000 claims description 4
- 239000013522 chelant Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 241000726221 Gemma Species 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 229930191978 Gibberellin Natural products 0.000 claims 1
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims 1
- 239000003448 gibberellin Substances 0.000 claims 1
- 150000002475 indoles Chemical class 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 15
- 235000015097 nutrients Nutrition 0.000 abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract description 5
- 239000004202 carbamide Substances 0.000 abstract description 5
- 229910052700 potassium Inorganic materials 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 201000010099 disease Diseases 0.000 abstract description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 235000013619 trace mineral Nutrition 0.000 abstract description 3
- 239000011573 trace mineral Substances 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 241000196324 Embryophyta Species 0.000 description 9
- 240000008042 Zea mays Species 0.000 description 9
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 9
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 9
- 235000005822 corn Nutrition 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 6
- 235000013877 carbamide Nutrition 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000618 nitrogen fertilizer Substances 0.000 description 3
- 230000014075 nitrogen utilization Effects 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- -1 phosphorus compound Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- 229930192334 Auxin Natural products 0.000 description 1
- 241000040710 Chela Species 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229940090496 Urease inhibitor Drugs 0.000 description 1
- 101710097943 Viral-enhancing factor Proteins 0.000 description 1
- JJEJDZONIFQNHG-UHFFFAOYSA-N [C+4].N Chemical compound [C+4].N JJEJDZONIFQNHG-UHFFFAOYSA-N 0.000 description 1
- WJEIYVAPNMUNIU-UHFFFAOYSA-N [Na].OC(O)=O Chemical compound [Na].OC(O)=O WJEIYVAPNMUNIU-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- 239000002363 auxin Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 125000003861 brassinosteroid group Chemical group 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- KMQAPZBMEMMKSS-UHFFFAOYSA-K calcium;magnesium;phosphate Chemical compound [Mg+2].[Ca+2].[O-]P([O-])([O-])=O KMQAPZBMEMMKSS-UHFFFAOYSA-K 0.000 description 1
- 230000032823 cell division Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 244000000037 crop pathogen Species 0.000 description 1
- 239000004062 cytokinin Substances 0.000 description 1
- UQHKFADEQIVWID-UHFFFAOYSA-N cytokinin Natural products C1=NC=2C(NCC=C(CO)C)=NC=NC=2N1C1CC(O)C(CO)O1 UQHKFADEQIVWID-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- ZDXPYRJPNDTMRX-UHFFFAOYSA-M glutaminate Chemical compound [O-]C(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 239000002367 phosphate rock Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Chemical class 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010563 solid-state fermentation Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002601 urease inhibitor Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a kind of alginic acid envelope composite fertilizer with urease inhibiting effect and preparation method thereof, it is characterised in that feed components form as follows according to parts by weight：24 parts 40 50 parts of ammonium nitrate, 26 28 parts of Diammonium phosphate (DAP), 22 24 parts of potassium sulfate, 15 18 parts of enzyme preparation filter residue, 57 parts of amino acid synergistic agent, 32 35 parts of sulfuric acid, 16 18 parts of liquefied ammonia, 35 parts of humic acid, 68 parts of Algae synergistic agent, coating of additive.N P and K organic element is rich in fertilizer produced by the present invention, the addition of enzyme preparation filter residue can effectively prevent the generation of soil-borne disease, so as to promote fertilizer efficiency to play, the addition of amino acid synergistic agent can reduce harm of the ammonia to crop, improve plant recovery of nutrient, the trace element of soil can be supplemented with the synergy of chelated microelements, being sprayed on the film formed on urea after Algae synergistic agent and coating additive mixing has urease inhibiting effect and slow releasing function, volume increase can be promoted, and energy natural degradation, the feature of environmental protection are excellent.
Description
Technical field
The invention belongs to composite heat transfer technical field, and in particular to a kind of alginic acid envelope with urease inhibiting effect
Composite fertilizer and preparation method thereof.
Background technology
The development experience of China's chemical fertilizer by sulphur ammonium, carbon ammonium to high concentration urea, the developing stage of forth generation nitrogenous fertilizer,
Phosphate fertilizer is by ground phosphate rock to calcium superphosphate (or calcium magnesium phosphate) developing deeply to phosphorus compound fertilizer, and the administration of potash fertilizer is by experiment and demonstration to big face
Product popularization and application experienced nearly 20 years, initially plant ash, low concentration potassium chloride, phosphorus compound fertilizer again from low concentration, single variety to
The development of high concentration diversification, nutrient form are also constantly changing, and new-type fertilizer is constantly filled with.Fertilizer synergist, concise contains
Justice is exactly to improve a kind of product of chemical fertilizer utilization ratio.Refer to improve fertilizer efficiency, reduce fixation, volatilization, leaching loss, runoff, improve fertilizer efficiency
Effect and nutrient contribution rate, beneficial to sorption enhanced, extend fertilizer efficiency period, improvement or rehabilitating soil, adjust fertilizer provision from soil fertilizer-preserving ability,
Improve a kind of fertilizer auxiliary product of crop quality.
As is well known, the volume increase of grain relies primarily on the use of chemical fertilizer for many years, but China's chemical fertilizer application is deposited all the time
Dose is big, nutrient loss is too fast, crop absorption rate is not high the features such as, and the environmental pollution that brings of excessive fertilization and
The problems such as wasting of resources, therefore study, using fertilizer synergistic agent, chemical fertilizer utilization ratio is improved, to China's grain security, environmental protection
Etc. significant.At present, the fertilizer synergist product of most domestic uses inorganic raw material or artificial synthesized macromolecule
Material produces, exist cost is high, effect is poor, it is toxic, influence the deficiencies of fertilizer nutrient content.
In order to effectively improve fertilizer nitrogen use efficiency and reduce the environmental pollution of nitrogen, people rest subpackage using certain material and risen
Come, then the method for being discharged nutrient by certain characteristic of this packing material.This fertilizer includes coated fertilizer again
With coating type fertilizer.Coating type fertilizer relies on penetrable coating layer, by friction, is released after chemistry or this coating of biological agent opening
Put dissolved fertilizer.The fertilizer that also many organic matter coatings form, such as alkyd based resin coated fertilizer, polyamine resin bag
Film fertilizer, thermohardening resin coated fertilizer etc..The factor of this kind of fertilizer release or more is influenceed, in different soil environments
Under, significant change may occur for the release mode of fertilizer, it is difficult to reach satisfied controlled-release effect, be this problem of most critical
A little coated fertilizers are difficult to be decomposed and stay in and pollution is formed in soil.
The content of the invention
For problems of the prior art, it is an object of the invention to provide a kind of sea with urease inhibiting effect
Alginic acid coated compound fertilizer and preparation method thereof, the amino acid synergistic agent of extraction and N P and K mixed slurry are mixed to prepare compound
Fertilizer, it is granulated by comminutor, the Algae synergistic agent of extraction and coating additive is mixed and be sprayed on fertilizer surface, obtained coating
Chemical Mixed Fertilizer has urease inhibiting effect and slow releasing function, and energy natural degradation, does not form harm to soil, crop, environment.
The technical scheme that the present invention takes is：
A kind of alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that feed components are according to weight
Part composition is as follows：
Ammonium nitrate 40-50 parts, Diammonium phosphate (DAP) 26-28 parts, potassium sulfate 22-24 parts, enzyme preparation filter residue 15-18 parts, amino acid
Synergist 5-7 parts, sulfuric acid 32-35 parts, liquefied ammonia 16-18 parts, humic acid 3-5 parts, Algae synergistic agent 6-8 parts, coating additive 2-4
Part.
Further, each component is as follows according to parts by weight composition in the coating additive：It is brassinosteroid 4-6 parts, red
Mycin 3-5 parts, heteroauxin 2-4 parts, melissyl alcohol 3-5 parts, chitosan oligosaccharide 8-12 parts, methylcellulose 2-3 parts.
Further, the enzyme preparation filter residue be residue after separating enzyme through 110 DEG C of high-temperature sterilizations, and crude protein contains
Amount >=30%, the content of organic matter >=50%, content of mineral substances >=10%, fineness are the granulated slag of 60-70 mesh.
Further, 5-6% organic acid promoter is added in the enzyme preparation filter residue, prepared by the organic acid promoter
Process is：According to weight than 2:3:2 take amino-oligosaccharide, chitosan, then add the acetate buffer solution containing 40% sodium acetate,
It is dissolved in the fulvic acid of 2 times of volumes, control pressure 1.8MPa, keeps 8-12min, be warming up to 65 DEG C, acidolysis 3h is obtained
Mixed liquor.
A kind of preparation method of the alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that specifically include
Following steps：
(1) amino acid polymeric solution processed：In enamel reaction still, according to weight than 10：(5-6) fetches water and glutamic acid mixes
Close, stir, 2-3% bio protease is added into mixture, rise temperature is to 68-78 DEG C, polymerisation 10-12h；
(2) amino acid synergistic agent processed：The 2-4% micro member of Chelating state is added into amino acid polymeric solution obtained above
Element, it is mixed evenly, is put into concentration tank, under 65-70 DEG C of environment, is concentrated into the 25-35% of liquid volume；
(3) fermentation of seaweed liquid processed：It is 20-30% to select wild kelp clothes to water content, and 60- is crushed to by pulverizer
80 mesh, 0.5-0.7% mixed bacteria, seawood meal and water are added according to weight ratio 2：1 mixing, stirs, controls the temperature to be
68-72 DEG C, ferment 5-7 days；
(4) Algae synergistic agent processed：Into the material after fermentation ends, the water of 2.5-3 times of volume is added, is stirred, used
Alkaline carbonic acid sodium adjusts pH between 7.5-8.5, and solution is that 9-11h is extracted in 55-62 DEG C of stirring by automatic steam control temperature, is passed through
Filter press carries out press filtration, and it is 6.5-7.5 that obtained filtrate adjusts pH with dilute sulfuric acid, is concentrated by evaporation to the 20% of liquor capacity；
(5) nitration mixture reacts slurry processed：Ammonium nitrate, Diammonium phosphate (DAP), potassium sulfate and enzyme preparation filter residue is taken to mix according to weight proportion
Conjunction obtains batch mixing, and it is 130-150 mesh to be put into pulverizer and be crushed to grain fineness, takes sulfuric acid and liquefied ammonia to be placed according to weight proportion
In tubular reactor, reaction pressure 0.35-0.45MPa, hybrid reaction 5-10s, and batch mixing is controlled to be well mixed；
(6) it is granulated：Obtained slurry in step (5) is added in 100 DEG C of granulation tower, amino is added according to weight proportion
Sour synergist, humic acid and Algae synergistic liquid, obtained eutectic is sprayed by the rotary nozzle on granulation tower top, in granulation tower
Bottom sieve gets size 1.5mm-3.75mm fertiliser granulates；
(7) coating is handled：Algae synergistic agent and coating additive mixing are taken according to weight proportion, adds 3-5% brown alga
The polyethylene glycol of glue and 4-6%, it is uniformly dissolved at 45-55 DEG C, fertiliser granulates table is sprayed on according to fertilizer 5-6% quantity for spray
Face, it is 180-200 DEG C of wink-dry to control hot blast temperature；
(8) anti-caking is handled：According to the addition of 1.5kg-2.5kg/ tons, anti-caking is added into the fertilizer on fluid bed
Agent, stir, screening obtains size 2.5mm-4.75mm fertiliser granulates.
Further, the bio protease in the step (1) is papain and subtilopeptidase A according to weight
Measure ratio 2：The mixture of 3 compositions.
Further, the chelated microelements in the step (2) are EDTA chelated zincs, EDTA chelated magnesiums, EDTA chelas
Close boron, EDTA chelates calcium according to weight than 2：3：2：The mixture of 5 compositions.
Further, the mixed bacteria in the step (3) be bacillus subtilis bacterium powder, jelly bacillus bacterium powder,
Aspergillus niger bacterium powder is according to weight than 2：1：1 composition is no less than 2.0 × 10 containing effective gemma number11Cfu bacterium powder.
Further, the concentration Algae synergistic agent is that obtained Algae synergistic liquid in step (4) is concentrated by evaporation to molten
The 30-40% of liquid product.
Beneficial effects of the present invention are：
N P and K organic element is rich in fertilizer produced by the present invention, enzyme preparation filter residue is rich in microbial mycelial, plant
Albumen, amino acid, vitamin, trace element, the bacteriostatic activity of mycelia residuum have good inhibiting effect to crop pathogenses, had
The generation of effect prevention soil-borne disease, so as to promote fertilizer efficiency to play, significant effect.
The present invention is to take the technologies such as solid state fermentation, high molecular polymerization, normal temperature chelating by primary raw material of natural glutamate,
The effectively extraction synergistic activity factor obtains amino acid synergistic agent, and vital work is played in the growth and development process of plant
Can form amide glutaminate in plant with, glutamic acid, storage nitrogen and can eliminate because ammonia density it is too high caused by poison
Effect, harm of the ammonia to crop is reduced, improves plant recovery of nutrient, and the synergy of chelated microelements can supplement soil
Trace element, improve crops quality.
The Algae synergistic liquid that the present invention extracts from marine alga has degradability for organic principle, and spy is used in extraction process
Different bacteria fermentation, weak base regulation and temperature are kept, and improve synergistic factor level, plant source is rich in obtained Algae synergistic liquid
Natural regulation synergistic component, including the 0.003-0.006% basic element of cell division, 0.002-0.007% auxin, 0.001-
0.005% cytokinin, 0.003-0.008% mannitol, 0.02-0.06% algal polysaccharides, 0.001-0.005%
Amino acid, 0.002-0.007% natural urease inhibitor, can promote crop absorb nutrient, to be effectively increased fertilizer
Utilization rate, improve the yield and quality of crop.
The Algae synergistic liquid of the present invention is divided into two parts, and a part is applied in fertilizer making, and another part and coating add
Add agent to be sprayed on the film formed on urea after mixing, there is urease inhibiting effect and slow releasing function, inhibition rate of urease up to 25% with
On, the utilization rate of urea is effectively improved, 3-4 times slower than common fertilizer of the dissolution velocity in water, coating additive is to plant life
With stimulation, volume increase, the natural degradation after crop nutritional utilization end cycle, not to soil, crop, environment shape can be promoted
Into harm.
Organic acid promoter is added in the enzyme preparation filter residue of the present invention, the preparation method of organic acid promoter is advantageous to improve
The activity of chitosan, the stability of chitosan liquid is added, plant cell is absorbed the combination permeability of the compositions such as amino acid and increase
By force, the composition such as its amino-oligosaccharide being rich in, chitosan, plant can be improved to self early harmful resist ability of disease, promote crop
Well developed root system, pesticide dosage is greatly lowered, Environmental Safety.
Brief description of the drawings
Fig. 1 arranges schematic diagram for field test in the present invention.
Fig. 2 is earth pillar schematic diagram in the present invention.
Embodiment
Embodiment 1
A kind of alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that feed components are according to weight
Part composition is as follows：
40 parts of ammonium nitrate, 26 parts of Diammonium phosphate (DAP), 22 parts of potassium sulfate, 15 parts of enzyme preparation filter residue, 5 parts of amino acid synergistic agent, sulphur
2 parts 32 parts of acid, 16 parts of liquefied ammonia, 3 parts of humic acid, 6 parts of Algae synergistic agent, coating of additive.
Further, each component is as follows according to parts by weight composition in the coating additive：It is 4 parts of brassinosteroid, red mould
3 parts of element, 2 parts of heteroauxin, 3 parts of melissyl alcohol, 8 parts of chitosan oligosaccharide, 2 parts of methylcellulose.
Further, the enzyme preparation filter residue be residue after separating enzyme through 110 DEG C of high-temperature sterilizations, and crude protein contains
Amount >=30%, the content of organic matter >=50%, content of mineral substances >=10%, fineness are the granulated slag of 60 mesh.
Further, 5-6% organic acid promoter is added in the enzyme preparation filter residue, prepared by the organic acid promoter
Process is：According to weight than 2:3:2 take amino-oligosaccharide, chitosan, then add the acetate buffer solution containing 40% sodium acetate,
It is dissolved in the fulvic acid of 2 times of volumes, control pressure 1.8MPa, keeps 8-12min, be warming up to 65 DEG C, acidolysis 3h is obtained
Mixed liquor.
A kind of preparation method of the alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that specifically include
Following steps：
(1) amino acid polymeric solution processed：In enamel reaction still, according to weight than 10：5 water intakings and glutamic acid mixing, are stirred
Mix uniformly, into mixture add 2% by papain and subtilopeptidase A according to weight ratio 2：The biology of 3 compositions
Protease, rise temperature is to 68 DEG C, polymerisation 12h；
(2) amino acid synergistic agent processed：Into amino acid polymeric solution obtained above addition 2% by EDTA chelated zincs,
EDTA chelated magnesiums, EDTA chelatings boron, EDTA chelate calcium according to weight than 2：3：2：The chelated microelements of 5 compositions, mixing are stirred
Mix uniformly, be put into concentration tank, under 65 DEG C of environment, be concentrated into the 25-35% of liquid volume；
(3) fermentation of seaweed liquid processed：It is 20-30% to select wild kelp clothes to water content, and 60 are crushed to by pulverizer
Mesh, addition 0.5% is by bacillus subtilis bacterium powder, jelly bacillus bacterium powder, aspergillus niger bacterium powder according to weight than 2：1：1 composition
Mixed bacteria, seawood meal and water are according to weight ratio 2：1 mixing, stirs, and it is 68 DEG C to control temperature, is fermented 7 days；
(4) Algae synergistic agent processed：Into the material after fermentation ends, the water of 2.5 times of volumes is added, stirs, uses alkali
Property sodium carbonate adjust pH for 7.5-8.5 between, solution by automatic steam control temperature be 55 DEG C stirring extraction 11h, pass through filter press
Press filtration is carried out, it is 6.5-7.5 that obtained filtrate adjusts pH with dilute sulfuric acid, is concentrated by evaporation to the 20% of liquor capacity；
(5) nitration mixture reacts slurry processed：Ammonium nitrate, Diammonium phosphate (DAP), potassium sulfate and enzyme preparation filter residue is taken to mix according to weight proportion
Conjunction obtains batch mixing, and it is 130 mesh to be put into pulverizer and be crushed to grain fineness, takes sulfuric acid and liquefied ammonia to be placed in tubular type according to weight proportion
In reactor, reaction pressure 0.35MPa, hybrid reaction 10s, and batch mixing is controlled to be well mixed；
(6) it is granulated：Obtained slurry in step (5) is added in 100 DEG C of granulation tower, amino is added according to weight proportion
Sour synergist, humic acid and Algae synergistic liquid, obtained eutectic is sprayed by the rotary nozzle on granulation tower top, in granulation tower
Bottom sieve gets size 1.5mm-3.75mm fertiliser granulates；
(7) coating is handled：Obtained Algae synergistic liquid in step (4) is concentrated by evaporation to the 30-40% of liquor capacity and obtained
To concentration Algae synergistic agent, according to weight proportion take Algae synergistic agent and coating additive mixing, add 3% algin and
4% polyethylene glycol, it is uniformly dissolved at 45 DEG C, is sprayed on fertiliser granulates surface according to the quantity for spray of fertilizer 5%, controls hot blast
Temperature is 180 DEG C of wink-dries；
(8) anti-caking is handled：According to the addition of 1.5kg/ tons, anticaking agent is added into the fertilizer on fluid bed, is stirred
Mix uniformly, screening obtains size 2.5mm-4.75mm fertiliser granulates.
Embodiment 2
A kind of alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that feed components are according to weight
Part composition is as follows：
45 parts of ammonium nitrate, 27 parts of Diammonium phosphate (DAP), 23 parts of potassium sulfate, 16 parts of enzyme preparation filter residue, 6 parts of amino acid synergistic agent, sulphur
3 parts 34 parts of acid, 17 parts of liquefied ammonia, 4 parts of humic acid, 7 parts of Algae synergistic agent, coating of additive.
Further, each component is as follows according to parts by weight composition in the coating additive：It is 5 parts of brassinosteroid, red mould
4 parts of element, 3 parts of heteroauxin, 4 parts of melissyl alcohol, 10 parts of chitosan oligosaccharide, 2.5 parts of methylcellulose.
Further, the enzyme preparation filter residue be residue after separating enzyme through 110 DEG C of high-temperature sterilizations, and crude protein contains
Amount >=30%, the content of organic matter >=50%, content of mineral substances >=10%, fineness are the granulated slag of 60-70 mesh.
Further, 5-6% organic acid promoter is added in the enzyme preparation filter residue, prepared by the organic acid promoter
Process is：According to weight than 2:3:2 take amino-oligosaccharide, chitosan, then add the acetate buffer solution containing 40% sodium acetate,
It is dissolved in the fulvic acid of 2 times of volumes, control pressure 1.8MPa, keeps 8-12min, be warming up to 65 DEG C, acidolysis 3h is obtained
Mixed liquor.
A kind of preparation method of the alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that specifically include
Following steps：
(1) amino acid polymeric solution processed：In enamel reaction still, according to weight than 10：6 water intakings and glutamic acid mixing, are stirred
Mix uniformly, into mixture add 2% by papain and subtilopeptidase A according to weight ratio 2：The biology of 3 compositions
Protease, rise temperature is to 70 DEG C, polymerisation 11h；
(2) amino acid synergistic agent processed：Into amino acid polymeric solution obtained above addition 3% by EDTA chelated zincs,
EDTA chelated magnesiums, EDTA chelatings boron, EDTA chelate calcium according to weight than 2：3：2：The chelated microelements of 5 compositions, mixing are stirred
Mix uniformly, be put into concentration tank, under 68 DEG C of environment, be concentrated into the 25-35% of liquid volume；
(3) fermentation of seaweed liquid processed：It is 20-30% to select wild kelp clothes to water content, and 70 are crushed to by pulverizer
Mesh, addition 0.6% is by bacillus subtilis bacterium powder, jelly bacillus bacterium powder, aspergillus niger bacterium powder according to weight than 2：1：1 composition
Mixed bacteria, seawood meal and water are according to weight ratio 2：1 mixing, stirs, and it is 70 DEG C to control temperature, is fermented 6 days；
(4) Algae synergistic agent processed：Into the material after fermentation ends, the water of 2.8 times of volumes is added, stirs, uses alkali
Property sodium carbonate adjust pH for 7.5-8.5 between, solution by automatic steam control temperature be 60 DEG C stirring extraction 10h, pass through filter press
Press filtration is carried out, it is 6.5-7.5 that obtained filtrate adjusts pH with dilute sulfuric acid, is concentrated by evaporation to the 20% of liquor capacity；
(5) nitration mixture reacts slurry processed：Ammonium nitrate, Diammonium phosphate (DAP), potassium sulfate and enzyme preparation filter residue is taken to mix according to weight proportion
Conjunction obtains batch mixing, and it is 140 mesh to be put into pulverizer and be crushed to grain fineness, takes sulfuric acid and liquefied ammonia to be placed in tubular type according to weight proportion
In reactor, reaction pressure 0.4MPa, hybrid reaction 8s, and batch mixing is controlled to be well mixed；
(6) it is granulated：Obtained slurry in step (5) is added in 100 DEG C of granulation tower, amino is added according to weight proportion
Sour synergist, humic acid and Algae synergistic liquid, obtained eutectic is sprayed by the rotary nozzle on granulation tower top, in granulation tower
Bottom sieve gets size 1.5mm-3.75mm fertiliser granulates；
(7) coating is handled：Obtained Algae synergistic liquid in step (4) is concentrated by evaporation to the 30-40% of liquor capacity and obtained
To concentration Algae synergistic agent, according to weight proportion take Algae synergistic agent and coating additive mixing, add 4% algin and
5% polyethylene glycol, it is uniformly dissolved at 50 DEG C, is sprayed on fertiliser granulates surface according to the quantity for spray of fertilizer 6%, controls hot blast
Temperature is 200 DEG C of wink-dries；
(8) anti-caking is handled：According to the addition of 2kg/ tons, anticaking agent is added into the fertilizer on fluid bed, is stirred
Uniformly, screening obtains size 2.5mm-4.75mm fertiliser granulates.
Embodiment 3
A kind of alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that feed components are according to weight
Part composition is as follows：
50 parts of ammonium nitrate, 28 parts of Diammonium phosphate (DAP), 24 parts of potassium sulfate, 18 parts of enzyme preparation filter residue, 7 parts of amino acid synergistic agent, sulphur
4 parts 35 parts of acid, 18 parts of liquefied ammonia, 5 parts of humic acid, 8 parts of Algae synergistic agent, coating of additive.
Further, each component is as follows according to parts by weight composition in the coating additive：It is 6 parts of brassinosteroid, red mould
5 parts of element, 4 parts of heteroauxin, 5 parts of melissyl alcohol, 12 parts of chitosan oligosaccharide, 3 parts of methylcellulose.
Further, the enzyme preparation filter residue be residue after separating enzyme through 110 DEG C of high-temperature sterilizations, and crude protein contains
Amount >=30%, the content of organic matter >=50%, content of mineral substances >=10%, fineness are the granulated slag of 70 mesh.
Further, 5-6% organic acid promoter is added in the enzyme preparation filter residue, prepared by the organic acid promoter
Process is：According to weight than 2:3:2 take amino-oligosaccharide, chitosan, then add the acetate buffer solution containing 40% sodium acetate,
It is dissolved in the fulvic acid of 2 times of volumes, control pressure 1.8MPa, keeps 8-12min, be warming up to 65 DEG C, acidolysis 3h is obtained
Mixed liquor.
A kind of preparation method of the alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that specifically include
Following steps：
(1) amino acid polymeric solution processed：In enamel reaction still, according to weight than 10：6 water intakings and glutamic acid mixing, are stirred
Mix uniformly, into mixture add 3% by papain and subtilopeptidase A according to weight ratio 2：The biology of 3 compositions
Protease, rise temperature is to 78 DEG C, polymerisation 10h；
(2) amino acid synergistic agent processed：Into amino acid polymeric solution obtained above addition 4% by EDTA chelated zincs,
EDTA chelated magnesiums, EDTA chelatings boron, EDTA chelate calcium according to weight than 2：3：2：The chelated microelements of 5 compositions, mixing are stirred
Mix uniformly, be put into concentration tank, under 70 DEG C of environment, be concentrated into the 25-35% of liquid volume；
(3) fermentation of seaweed liquid processed：It is 20-30% to select wild kelp clothes to water content, and 80 are crushed to by pulverizer
Mesh, addition 0.7% is by bacillus subtilis bacterium powder, jelly bacillus bacterium powder, aspergillus niger bacterium powder according to weight than 2：1：1 composition
Mixed bacteria, seawood meal and water are according to weight ratio 2：1 mixing, stirs, and it is 72 DEG C to control temperature, is fermented 5 days；
(4) Algae synergistic agent processed：Into the material after fermentation ends, the water of 3 times of volumes is added, is stirred, with alkalescence
Sodium carbonate adjusts pH between 7.5-8.5, and solution is that 9h is extracted in 62 DEG C of stirrings by automatic steam control temperature, is carried out by filter press
Press filtration, it is 6.5-7.5 that obtained filtrate adjusts pH with dilute sulfuric acid, is concentrated by evaporation to the 20% of liquor capacity；
(5) nitration mixture reacts slurry processed：Ammonium nitrate, Diammonium phosphate (DAP), potassium sulfate and enzyme preparation filter residue is taken to mix according to weight proportion
Conjunction obtains batch mixing, and it is 150 mesh to be put into pulverizer and be crushed to grain fineness, takes sulfuric acid and liquefied ammonia to be placed in tubular type according to weight proportion
In reactor, reaction pressure 0.45MPa, hybrid reaction 5s, and batch mixing is controlled to be well mixed；
(6) it is granulated：Obtained slurry in step (5) is added in 100 DEG C of granulation tower, amino is added according to weight proportion
Sour synergist, humic acid and Algae synergistic liquid, obtained eutectic is sprayed by the rotary nozzle on granulation tower top, in granulation tower
Bottom sieve gets size 1.5mm-3.75mm fertiliser granulates；
(7) coating is handled：Obtained Algae synergistic liquid in step (4) is concentrated by evaporation to the 30-40% of liquor capacity and obtained
To concentration Algae synergistic agent, according to weight proportion take Algae synergistic agent and coating additive mixing, add 5% algin and
6% polyethylene glycol, it is uniformly dissolved at 55 DEG C, is sprayed on fertiliser granulates surface according to the quantity for spray of fertilizer 6%, controls hot blast
Temperature is 200 DEG C of wink-dries；
(8) anti-caking is handled：According to the addition of 2.5kg/ tons, anticaking agent is added into the fertilizer on fluid bed, is stirred
Mix uniformly, screening obtains size 2.5mm-4.75mm fertiliser granulates.
Fertilizer produced by the present invention is in corn planting using as follows：
1 experimental condition and experimental design
1.1 experimental field basic conditions
Test site is tested and carried out in the solarium of base in Qingdao of Shandong province proving ground.One's respective area belongs to warm temperate zone
Semi-moist monsoon climate, parent soil material are the Yellow River alluvial deposits, and soil types is moisture soil, the light earth of topsoil quality, foundation soil fertility
Index is organic matter 10.50g/kg, available nitrogen 53.5mg/kg, rapid available phosphorus (P2O5) 14.6mg/kg, available potassium (K2O)70mg/
Kg, belong to medium higher fertile soil, summer corn growing area tool is broadly representative in China.
1.2 experimental designs are with implementing
Fertilizer used in experiment carries out soil by the marine alga coated slow release fertilizer produced in embodiments of the invention 1, embodiment 2
Post experiment in cultivation, set 1. CK1 (full blank control), 2. CK2 (common fertilizer control), 3. U (coated compound fertilizer of embodiment 1),
4. 4 processing of HU (coated compound fertilizer of embodiment 2), 6 repetitions, nitrogen application level are 0.15gN/kg soil, corn variety is
Zheng Dan 958, sowed on May 30th, 2010, September harvests on the 12nd, after sample air-dries, determines corn yield and constituent element, nitrogen
The indexs such as plain utilization ratio.
Fig. 1 is shown in field test arrangement, and Fig. 2 is shown in earth pillar signal.
2 result of the tests
Influence of the 2.1 marine alga coated slow-release ureas to corn yield
The corn yield of table 1 and constituent element
As can be seen from Table 1, the grain number per spike of coated slow-release composite fertilizer processing is higher by 11 compared with common fertilizer, tassel row number and hundred
Weight also increased, so as to add corn yield.Compared with common fertilizer, coated slow-release composite fertilizer has obvious increasing to corn
Production acts on, and U is than CK2 volume increase 43.72%.HU is than CK2 volume increase 44.91%.
Influence of the 2.2 marine alga coated slow-release ureas to nitrogen utilization efficiency
The nitrogen utilization efficiency of table 2
As can be seen from Table 2, the nitrogen harvest index of HU processing and the agronomy efficiency of nitrogenous fertilizer are above U processing, and this may
It is because marine alga coated slow-release urea promotes photosynthate and nitrogen to be transported into seed, to improving corn kernel protein content
Also there is certain effect.Coated slow-release composite fertilizer can significantly improve nitrogen utilization efficiency, and 39.16% is brought up to by 36.32%, more general
Logical fertilizer increase by 6.9%.
3. brief summary
Soil-column test result shows that coated slow-release composite fertilizer produced by the invention has the good effect that increases production and improves productivity, its
Amount of increase in production is higher by 10.35 percentage points compared with common fertilizer, and utilization rate of nitrogen fertilizer improves 6.8%.
It is limitation of the present invention that described above, which is not, and the present invention is also not limited to the example above, the art
The variations, modifications, additions or substitutions that technical staff is made in the essential scope of the present invention, it should also belong to the protection of the present invention
Scope.
Claims (5)
1. a kind of alginic acid envelope composite fertilizer with urease inhibiting effect, it is characterised in that feed components are according to parts by weight
Composition is as follows：
Ammonium nitrate 40-50 parts, Diammonium phosphate (DAP) 26-28 parts, potassium sulfate 22-24 parts, enzyme preparation filter residue 15-18 parts, amino acid synergistic
Agent 5-7 parts, sulfuric acid 32-35 parts, liquefied ammonia 16-18 parts, humic acid 3-5 parts, Algae synergistic liquid 6-8 parts, concentration Algae synergistic agent 2-4
Part, coating additive 2-4 parts；
Each component forms as follows according to parts by weight in the coating additive：Brassinosteroid 4-6 parts, gibberellin 3-5 parts, indoles
Acetic acid 2-4 parts, melissyl alcohol 3-5 parts, chitosan oligosaccharide 8-12 parts, methylcellulose 2-3 parts；
5-6% organic acid promoter is added in the enzyme preparation filter residue, the organic acid promoter preparation process is：According to weight
Measure ratio 2:3:2 take amino-oligosaccharide, chitosan, then add the acetate buffer solution containing 40% sodium acetate, are dissolved in 2 times of volumes
Fulvic acid in, control pressure 1.8MPa, keep 8-12min, be warming up to 65 DEG C, the mixed liquor that acidolysis 3h is obtained；
The preparation method of the above-mentioned alginic acid envelope composite fertilizer with urease inhibiting effect, specifically comprises the following steps：
(1) amino acid polymeric solution processed：In enamel reaction still, according to weight than 10：(5-6) fetches water and glutamic acid mixing, stirs
The bio protease that 2-3% is uniformly added into mixture is mixed, rise temperature is to 68-78 DEG C, polymerisation 10-12h；
(2) amino acid synergistic agent processed：2-4% chelated microelements are added into amino acid polymeric solution obtained above,
It is mixed evenly, is put into concentration tank, under 65-70 DEG C of environment, is concentrated into the 25-35% of liquid volume；
(3) fermentation of seaweed liquid processed：It is 20-30% to select wild kelp clothes to water content, and 60-80 is crushed to by pulverizer
Mesh, adds 0.5-0.7% mixed bacteria, and mixed bacteria is bacillus subtilis bacterium powder, jelly bacillus bacterium powder, aspergillus niger
Bacterium powder is according to weight than 2：1：1 composition is no less than 2.0 × 10 containing effective gemma number11Cfu bacterium powder, seawood meal and water are according to weight
Measure ratio 2：1 mixing, stirs, and it is 68-72 DEG C to control temperature, is fermented 5-7 days；
(4) Algae synergistic liquid processed：Into the material after fermentation ends, the water of 2.5-3 times of volume is added, is stirred, with alkalescence
Sodium carbonate adjusts pH between 7.5-8.5, and solution is that 9-11h is extracted in 55-62 DEG C of stirring by automatic steam control temperature, passes through press filtration
Machine carries out press filtration, and it is 6.5-7.5 that obtained filtrate adjusts pH with dilute sulfuric acid；
(5) nitration mixture reacts slurry processed：Ammonium nitrate, Diammonium phosphate (DAP), potassium sulfate and enzyme preparation filter residue is taken to mix according to weight proportion
To batch mixing, it is 130-150 mesh to be put into pulverizer and be crushed to grain fineness, takes sulfuric acid and liquefied ammonia to be placed in tubular type according to weight proportion
In reactor, reaction pressure 0.35-0.45MPa, hybrid reaction 5-10s, and batch mixing is controlled to be well mixed；
(6) it is granulated：Obtained slurry in step (5) is added in 100 DEG C of granulation tower, increased according to weight proportion addition amino acid
Agent, humic acid and Algae synergistic liquid are imitated, obtained eutectic is sprayed by the rotary nozzle on granulation tower top, in granulation tower bottom sieve
Get size 1.5mm-3.75mm fertiliser granulates；
(7) coating is handled：Concentration Algae synergistic agent and coating additive mixing are taken according to weight proportion, adds 3-5% brown alga
The polyethylene glycol of glue and 4-6%, it is uniformly dissolved at 45-55 DEG C, fertiliser granulates table is sprayed on according to fertilizer 5-6% quantity for spray
Face, it is 180-200 DEG C of wink-dry to control hot blast temperature；
(8) anti-caking is handled：According to the addition of 1.5kg-2.5kg/ tons, anticaking agent is added into the fertilizer on fluid bed,
Stir, screening obtains size 2.5mm-4.75mm fertiliser granulates.
2. a kind of alginic acid envelope composite fertilizer with urease inhibiting effect according to claim 1, it is characterised in that described
Enzyme preparation filter residue be residue after separating enzyme through 110 DEG C of high-temperature sterilizations, and crude protein content >=30%, the content of organic matter >=
50%, content of mineral substances >=10%, fineness is the granulated slag of 60-70 mesh.
3. a kind of alginic acid envelope composite fertilizer with urease inhibiting effect according to claim 1, it is characterised in that described
Bio protease in step (1) is papain and subtilopeptidase A according to weight ratio 2：The mixture of 3 compositions.
4. a kind of alginic acid envelope composite fertilizer with urease inhibiting effect according to claim 1, it is characterised in that described
Chelated microelements in step (2) are EDTA chelated zincs, EDTA chelated magnesiums, EDTA chelate boron, EDTA chelates calcium according to weight
Measure ratio 2：3：2：The mixture of 5 compositions.
5. a kind of alginic acid envelope composite fertilizer with urease inhibiting effect according to claim 1, it is characterised in that described
The agent of concentration Algae synergistic is that obtained Algae synergistic liquid in step (4) is concentrated by evaporation to the 30-40% of liquor capacity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510133389.1A CN104744165B (en) | 2015-03-25 | 2015-03-25 | A kind of alginic acid envelope composite fertilizer with urease inhibiting effect and preparation method thereof |
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| CN105693379B (en) * | 2016-01-20 | 2019-11-08 | 领先生物农业股份有限公司 | A kind of seaweed polyglutamic acid urea and its production method |
| CN105906458A (en) * | 2016-04-13 | 2016-08-31 | 青岛鲸灵海洋科技有限公司 | Soil improvement slow-release compound fertilizer and preparation method thereof |
| CN105941111A (en) * | 2016-05-06 | 2016-09-21 | 安徽山珍藏生态农业有限公司 | Dendrobium huoshanense C.Z.Tang et S.J.Cheng breeding method |
| CN107445780A (en) * | 2017-08-04 | 2017-12-08 | 史丹利化肥扶余有限公司 | It is a kind of containing alginic acid and middle micro- compound fertilizer and preparation method thereof |
| CN108424310A (en) * | 2018-06-26 | 2018-08-21 | 拉多美（宁陵）化肥有限公司 | Humic acid potassium synergy fertilizer production technology |
| CN110156517A (en) * | 2019-06-03 | 2019-08-23 | 史丹利农业集团股份有限公司 | One cultivates peanut Special slow release fertilizer and preparation method thereof |
| CN111393220A (en) * | 2020-04-09 | 2020-07-10 | 山东恩宝生物科技有限公司 | Alginic acid double-control coated controlled-release urea and preparation method thereof |
| CN111499452A (en) * | 2020-04-09 | 2020-08-07 | 山东恩宝生物科技有限公司 | Environment-friendly alginic acid double-control slow-release urea and preparation method thereof |
| CN112159283B (en) * | 2020-10-18 | 2022-05-13 | 史丹利化肥（平原）有限公司 | Preparation and use methods of chitosan oligosaccharide coated slow-release fertilizer |
| CN112175143B (en) * | 2020-10-18 | 2022-03-29 | 山东喜美农业科技有限公司 | Preparation method of chitosan oligosaccharide coated sustained release agent |
| CN113480346A (en) * | 2021-08-18 | 2021-10-08 | 安徽坤健生物科技有限公司 | Biological treatment process for preparing organic biofertilizer from chicken manure |
| CN114105705A (en) * | 2021-12-23 | 2022-03-01 | 北京局气网络技术有限公司 | Composite oligosaccharide trace element fertilizer for tobacco planting and preparation method thereof |
| CN114920605A (en) * | 2022-02-24 | 2022-08-19 | 天脊煤化工集团股份有限公司 | Phosphorus potassium nitrate type alginic acid compound fertilizer and preparation method thereof |
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| JP5753019B2 (en) * | 2011-08-01 | 2015-07-22 | 学校法人慶應義塾 | Slow-acting fertilizer and method for producing the same |
| CN102503710B (en) * | 2011-12-02 | 2013-04-17 | 青岛丰泰海洋生物科技有限公司 | Synergistic compound fertilizer and preparation method thereof |
| CN102515945B (en) * | 2011-12-06 | 2014-02-05 | 中国农业科学院农业资源与农业区划研究所 | Algae-enhanced urea, production method thereof, and purpose thereof |
| CN102515952B (en) * | 2011-12-14 | 2013-03-13 | 山东宝源生物有限公司 | Chitosan coated alga bioorganic fertilizer and preparation method thereof |
| CN102701866B (en) * | 2012-06-27 | 2015-10-07 | 中国农业科学院农业资源与农业区划研究所 | A kind of fermentation liquid seaweed extract material synergistic agent and production method thereof and purposes |
| CN102775222B (en) * | 2012-09-04 | 2014-01-15 | 盘锦施壮肥业有限公司 | Production method of drying-free compound fertilizer |
| CN103102216B (en) * | 2013-01-21 | 2014-12-10 | 华南农业大学 | Coated fertilizer for inducing root growth and preparation method and application thereof |
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Denomination of invention: Alginic acid coated compound fertilizer with urease inhibiting effect and preparation method of alginic acid coated compound fertilizer Effective date of registration: 20200427 Granted publication date: 20180202 Pledgee: Qingdao Changyang financing Company limited by guarantee Pledgor: SHANDONG ENBAO BIOTECHNOLOGY Co.,Ltd. Registration number: Y2020370010011 |
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Denomination of invention: Alginate coated compound fertilizer with urease inhibition and its preparation method Effective date of registration: 20210325 Granted publication date: 20180202 Pledgee: Qingdao Changyang financing Company limited by guarantee Pledgor: SHANDONG ENBAO BIOTECHNOLOGY Co.,Ltd. Registration number: Y2021370010009 |
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