CN104738083A - Novel sterilization solution - Google Patents

Novel sterilization solution Download PDF

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Publication number
CN104738083A
CN104738083A CN201310735651.0A CN201310735651A CN104738083A CN 104738083 A CN104738083 A CN 104738083A CN 201310735651 A CN201310735651 A CN 201310735651A CN 104738083 A CN104738083 A CN 104738083A
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CN
China
Prior art keywords
solution
citric acid
percent concentration
sodium chlorite
bactericidal liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310735651.0A
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Chinese (zh)
Inventor
姚德勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Continent Pharmaceutical Co Ltd
Original Assignee
Qingdao Continent Pharmaceutical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Continent Pharmaceutical Co Ltd filed Critical Qingdao Continent Pharmaceutical Co Ltd
Priority to CN201310735651.0A priority Critical patent/CN104738083A/en
Publication of CN104738083A publication Critical patent/CN104738083A/en
Pending legal-status Critical Current

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a novel sterilization solution. The novel sterilization solution is formed by mixing a solution A with a solution B, the solution A is formed by mixing a sodium chlorite solution with the concentration of 10-15% with a stabilizer solution, and the solution B is a citric acid and oxalic acid mixed aqueous solution. The stabilizer solution is a solution with the mass percentage concentration of 10-15% prepared by uniformly mixing hydrazine sulfate, triethanolamine, ammonium persulfate and aluminum trichloride according to a mass ratio of 1:0.5-1.5:0.5-1:1.5-2.5. The volume of the stabilizer solution is 7-12% of the total volume of the solution A. A mass ratio of citric acid to oxalic acid is 1:2-4, and the mass percentage concentration of the solution B is 40-50%. The used volume ratio of the solution A to the solution B is 1-4:1. The sterilization solution has the advantages of stable medicine performances, no damages to environment or human body in the use or production process, and no corrosion to apparatuses in the production.

Description

A kind of new bactericidal liquid
Technical field
The invention belongs to pharmaceutical sanitary field, disclose a kind of bactericidal liquid.
Background technology
At livestock breeding industry, livestock and poultry communicate illness be prevented, need to use bactericidal liquid.Compound sodium chlorite solution is efficient, the wide spectrum of the latest generation of generally acknowledging in the world at present, the sterilization of safety, antistaling agent, is the optimal substitute of chlorinated product, is widely used in World Developed Countries.Compound sodium chlorite solution have safety high, possess double sterilization effect,
Sterilizing ability is extremely strong, without drug-fast advantage.
Existing compound sodium chlorite solution is made up of solution A and B solution, two kinds of solution independent packagings, and wherein solution A is made up of the aqueous solution of sodium chlorite, and B solution is activator salt aqueous acid.Two kinds of liquid mix in 4: 1 ratios, after activator activation, produce chlorine dioxide, to reach the effect of sterilization, sterilization.
Existing sodium chlorite aqueous solution can be alkalescent after mixing, even if also can degrade under conventional sense, causes the instability of product; Activator hydrochloric acid is monoacid, and belong to one of three large strong acid (sulfuric acid, hydrochloric acid, nitric acid), have extremely strong volatility, in actual production, hydrochloric acid solution has superpower corrosivity to instrument and equipment, also can to environment when raw material accumulating
Protection causes pollution in various degree; and high volatility; after the container filling concentrated hydrochloric acid is opened; can can see acid mist up; that is combined the little water droplet producing hydrochloric acid after volatile hydrogen chloride to have pungent smell with the steam of air; producers in operation must be very careful, brings great inconvenience to production work.
Summary of the invention
The object of the embodiment of the present invention is the defect for above-mentioned prior art, provide a kind of pharmaceutical properties stable, to use and production process can not damage environment and the person, the bactericidal liquid of instrument and equipment can not be corroded in production.
The technical scheme that the present invention takes to achieve these goals is: a kind of bactericidal liquid, the solution mixed by solution A and B solution, described solution A is mixed by sodium chlorite solution and stabiliser solution, and described B solution is the mixed aqueous solution of citric acid and oxalic acid.
Described stabiliser solution is that the mixing of hydrazine sulfate, triethanolamine, Ammonium Persulfate 98.5 and alchlor is mixed with quality
Percent concentration is the solution of 10%-15%, and the mass ratio of described hydrazine sulfate, triethanolamine, Ammonium Persulfate 98.5 and alchlor is 1: 0.5-1.5: 0.5-1: 1.5-2.5, and the mass percent concentration of described sodium chlorite solution is 15%-20%.
The volume of described stabiliser solution is the 7%-10% of solution A cumulative volume.
The mass ratio of described citric acid and oxalic acid is 1: 2-4, described B: solution quality percent concentration is 40%-50%.
Consumption volume ratio 1-4: 1 of described solution A and B solution.
The beneficial effect of the embodiment of the present invention is: in sodium chlorite solution, add stabilizing agent, effectively can prevent the degradation reaction under sodium chlorite solution's natural conditions, and ensure that content can not reduce, under mild alkaline conditions, pharmaceutical properties is more stable.Novel activated dose that activator raw material adopts citric acid, oxalic acid combines; novel activated dose of oxalic acid, citric acid; for the simplest binary acid; oxalic acid and citric acid are extensively present in occurring in nature; particularly in plant and natural fruits in such as herbaceous plant, Rheum plant, creeping oxalis, spinach etc.; therefore use and production process can not cause any harm to environment and the person; also instrument and equipment can not be corroded in production; also there is the generation of decreasing pollution thing; realize cleaner production, the advantage of protection of the environment.
Check that solution acidity has had obvious change in mensuration at PH, use after original hydrochloric acid solution activation two kinds of liquid blendings completely after belong to faintly acid, reach after using novel activated dose to activate and substantially belong to neutral solution, and make the more environmental protection of this product.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but not as a limitation of the invention.
Embodiment 1
A kind of bactericidal liquid, comprise A liquid and the B liquid of packaging separately, concrete preparation method is as follows:
Solution A is prepared: first prepare stabiliser solution, get hydrazine sulfate 2kg, triethanolamine 2kg, Ammonium Persulfate 98.5 2kg and alchlor 4kg and mix, add water 90kg, and the mass percent concentration making mixed solution is 10%, obtains stabiliser solution; Then get the stabiliser solution for preparing and mass percent concentration be 20% sodium chlorite solution according to volume ratio be 3: 97 mix after obtain solution A;
B solution is prepared: get in the water-soluble 6kg water of citric acid 1kg and oxalic acid 3kg and mix, obtain the B solution that mass percent concentration is 40%.
[solution A and B molten 4: 1 are mixed rear use during use by using method: solution A and B solution are independently packs.
[embodiment 2
A kind of bactericidal liquid, comprise solution A and the B solution of packaging separately, concrete preparation method is as follows:
Solution A is prepared: first prepare stabiliser solution, get hydrazine sulfate 1kg, triethanolamine 1.5kg, Ammonium Persulfate 98.5 1kg and alchlor 2.5kg and mix, add water 94kg, and the mass percent concentration making mixed solution is 6%, obtains stabiliser solution; Then get the stabiliser solution for preparing and mass percent concentration be 18% sodium chlorite solution according to volume ratio be 5: 95 mix after obtain solution A;
B solution is prepared: get in the water-soluble 5.5kg water of citric acid 1kg and oxalic acid 3.5kg and mix, obtain the B solution that mass percent concentration is 45%.
[using method: solution A and B solution are independently packs, mixes rear use by solution A and B solution according to volume ratio 2: 1 during use.
[embodiment 3
A kind of bactericidal liquid, comprise solution A and the B solution of packaging separately, concrete preparation method is as follows:
Solution A is prepared: first prepare stabiliser solution, get hydrazine sulfate 2kg, triethanolamine 1kg, Ammonium Persulfate 98.5 1kg and alchlor 4kg and mix, add water 92kg, and the mass percent concentration making mixed solution is 8%, obtains stabiliser solution; Then get the stabiliser solution for preparing and mass percent concentration be 15% sodium chlorite solution according to volume ratio be 2: 98 mix after obtain solution A;
B solution is prepared: get in the water-soluble 5kg water of citric acid 1kg and oxalic acid 4kg and mix, obtain the B solution that mass percent concentration is 50%.
[using method: solution A and B solution are independently packs, mixes rear use by solution A and B solution according to volume ratio 1: 1 during use.
 

Claims (5)

1. a bactericidal liquid, is the solution mixed by A solution and B solution, it is characterized in that: described A solution is mixed by sodium chlorite solution and stabiliser solution, and described B solution is the mixed aqueous solution of citric acid and oxalic acid.
2. according to the bactericidal liquid described in claim 1, it is characterized in that: described stabiliser solution is that the mixing of hydrazine sulfate, triethanolamine, Ammonium Persulfate 98.5 and alchlor is mixed with the solution that mass percent concentration is 10%-15%, the mass ratio of described hydrazine sulfate, triethanolamine, Ammonium Persulfate 98.5 and alchlor is 1:0.5-1.5:0.5-1:1.5-2.5, and the mass percent concentration of described sodium chlorite solution is 15%-20%.
3. according to the bactericidal liquid described in claim 2, it is characterized in that: the volume of described stabiliser solution is the 7%-10% of A overall solution volume.
4. according to the bactericidal liquid described in claim 3, it is characterized in that: the mass ratio of described citric acid and oxalic acid is 1:2-4, described B solution quality percent concentration is 40%-50%.
5. the bactericidal liquid according to any one of claim 1-4, is characterized in that: the consumption volume ratio of described A solution and B solution: 1-4:1.
CN201310735651.0A 2013-12-28 2013-12-28 Novel sterilization solution Pending CN104738083A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310735651.0A CN104738083A (en) 2013-12-28 2013-12-28 Novel sterilization solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310735651.0A CN104738083A (en) 2013-12-28 2013-12-28 Novel sterilization solution

Publications (1)

Publication Number Publication Date
CN104738083A true CN104738083A (en) 2015-07-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310735651.0A Pending CN104738083A (en) 2013-12-28 2013-12-28 Novel sterilization solution

Country Status (1)

Country Link
CN (1) CN104738083A (en)

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Application publication date: 20150701