CN104718275A - 生物质的选择性催化脱氧和其催化剂 - Google Patents

生物质的选择性催化脱氧和其催化剂 Download PDF

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Publication number
CN104718275A
CN104718275A CN201380041666.5A CN201380041666A CN104718275A CN 104718275 A CN104718275 A CN 104718275A CN 201380041666 A CN201380041666 A CN 201380041666A CN 104718275 A CN104718275 A CN 104718275A
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metal
hydrotalcite
pyrolysis
mixture
catalyst
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Chinese (zh)
Inventor
M.瓦西奇
M.科赫
M.H.普伦克
L.C.A.范登厄特拉尔
R.范杜伦
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Albemarle Europe SPRL
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Albemarle Europe SPRL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8474—Niobium
    • C—CHEMISTRY; METALLURGY
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    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
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    • B01J37/0213—Preparation of the impregnating solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • C—CHEMISTRY; METALLURGY
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    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
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    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201380041666.5A 2012-08-08 2013-08-07 生物质的选择性催化脱氧和其催化剂 Pending CN104718275A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261681064P 2012-08-08 2012-08-08
US61/681064 2012-08-08
PCT/EP2013/066532 WO2014023758A2 (en) 2012-08-08 2013-08-07 Selective catalytic deoxygenation of biomass and catalysts therefor

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CN104718275A true CN104718275A (zh) 2015-06-17

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US (1) US20150190788A1 (https=)
EP (1) EP2882827A2 (https=)
JP (1) JP2015529556A (https=)
CN (1) CN104718275A (https=)
BR (1) BR112015002752A2 (https=)
CA (1) CA2878793A1 (https=)
IN (1) IN2015DN00325A (https=)
WO (1) WO2014023758A2 (https=)

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CN108772070A (zh) * 2016-07-18 2018-11-09 山东省科学院能源研究所 用于生物油在线提质的铁基复合催化剂的制备方法

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US10040735B2 (en) * 2014-05-08 2018-08-07 Exxonmobil Research And Engineering Company Method of producing an alcohol-containing pyrolisis product
CN106795443B (zh) 2014-07-17 2022-05-13 沙特基础全球技术有限公司 在加氢热解过程中使用氢供体料流改质贫氢料流
US10786806B2 (en) * 2015-10-05 2020-09-29 University Of Pretoria Oxygenate reduction catalyst and process
ES2932125A1 (es) * 2021-06-29 2023-01-13 Univ Cordoba Nuevas hidrotalcitas y su uso como catalizadores para la transesterificacion de aceite
CN114797878B (zh) * 2022-03-24 2023-02-24 华北电力大学 一种生物质灰制备焦油催化裂解重整制氢并吸附二氧化碳双功能催化剂的方法
CN117101661B (zh) * 2023-09-21 2025-11-25 北华大学 一种金属改性c-rbp复合催化剂材料的制备方法及其应用

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US6028023A (en) * 1997-10-20 2000-02-22 Bulldog Technologies U.S.A., Inc. Process for making, and use of, anionic clay materials
CN1665587A (zh) * 2002-06-28 2005-09-07 阿尔伯麦尔荷兰有限公司 用于降低汽油和柴油中硫含量的fcc催化剂
EP2105486A1 (en) * 2008-03-25 2009-09-30 KiOR Inc. Low total acid number bio-crude
WO2011123508A2 (en) * 2010-03-31 2011-10-06 Exxonmobil Research And Engineering Company Methods for producing pyrolysis products

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US5340466A (en) * 1993-04-19 1994-08-23 Texaco Inc. Hydrodesulfurization of cracked naphtha with hydrotalcite-containing catalyst
CN1956782A (zh) * 2004-04-26 2007-05-02 阿尔伯麦尔荷兰有限公司 含添加剂的阴离子粘土的制备方法
CA2821241C (en) * 2010-12-13 2017-08-22 Exxonmobil Research And Engineering Company Phosphorus recovery from hydrothermal treatment of biomass
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US6028023A (en) * 1997-10-20 2000-02-22 Bulldog Technologies U.S.A., Inc. Process for making, and use of, anionic clay materials
CN1665587A (zh) * 2002-06-28 2005-09-07 阿尔伯麦尔荷兰有限公司 用于降低汽油和柴油中硫含量的fcc催化剂
EP2105486A1 (en) * 2008-03-25 2009-09-30 KiOR Inc. Low total acid number bio-crude
WO2011123508A2 (en) * 2010-03-31 2011-10-06 Exxonmobil Research And Engineering Company Methods for producing pyrolysis products

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Publication number Priority date Publication date Assignee Title
CN108772070A (zh) * 2016-07-18 2018-11-09 山东省科学院能源研究所 用于生物油在线提质的铁基复合催化剂的制备方法
CN108772070B (zh) * 2016-07-18 2020-10-20 山东省科学院能源研究所 用于生物油在线提质的铁基复合催化剂的制备方法

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JP2015529556A (ja) 2015-10-08
CA2878793A1 (en) 2014-02-13
IN2015DN00325A (https=) 2015-06-12
WO2014023758A3 (en) 2014-04-17
US20150190788A1 (en) 2015-07-09
BR112015002752A2 (pt) 2017-07-04
EP2882827A2 (en) 2015-06-17

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