CN104707159A - Odor scavenger and preparation method thereof - Google Patents
Odor scavenger and preparation method thereof Download PDFInfo
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- CN104707159A CN104707159A CN201510101643.XA CN201510101643A CN104707159A CN 104707159 A CN104707159 A CN 104707159A CN 201510101643 A CN201510101643 A CN 201510101643A CN 104707159 A CN104707159 A CN 104707159A
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Abstract
The invention discloses an odor scavenger. The odor scavenger is composed of poly-ethoxy alkyl ether sulfuric acid ester salt, citric acid, diatomite, fatty acid copra oil DEA, soda ash, sodium sulfate, an industrial antimicrobial agent, deionized water, calomel, and a plant extract. The odor scavenger provided by the invention adopts raw materials high in safety and nontoxic, the prepared odor scavenger is non-irritant, has no toxic or side effects, is high in safety, overcomes the defects that bad odors are masked by an odor masking agent and odor removal is achieved through combating poison with poison, and the odor scavenger obtained is high in safety and is environment-friendly and efficient; according to the odor scavenger provided by the invention, the preparation method is simple, and easy to operate.
Description
Technical field
The invention belongs to biological chemical field, particularly a kind of odor scavenging agent and method for making thereof.
Technical background
Current, odor scavenging agent main component on the market all: penetrating agent, antibacterial, industrial quintessence oil (taste masking), essence, the compositions such as photocatalyst, poor stability, general own taste is very large, carrys out taste removal, can not solve abnormal flavour thoroughly by taste masking; Further, these industrial chemicals not environmentally, easily affect to the health of human body and environment; Photocatalyst takes effect slowly, and effect is comparatively large according to the mass discrepancy of the quality of product and construction, executes man-hour requirement and wears the protective articless such as mask.
Summary of the invention
The object of this invention is to provide a kind of avirulence composition to add, can safety be guaranteed, directly can remove the odor scavenging agent of abnormal flavour, real environmental protection.
Another object of the present invention is to provide the preparation method of this odor scavenging agent.
Odor scavenging agent of the present invention, is prepared from by the raw material of following weight portion:
The composition of plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 5-15, parts by weight are 5-15, and parts by weight are the Cacumen Tamaricis extracting solution of 5-15, parts by weight are the amomum villosum extract of 10-20;
Industrial antibacterial agent comprise in silver ion antimicrobial agent, zinc oxide, copper oxide, Ammonium biphosphate, lithium carbonate, vanillin, chitin, mustard, Oleum Ricini, Wasabia japonic (Euterma Wasabi) one or more.
Odor scavenging agent provided by the present invention, material choice is reasonable, and advantages of nontoxic raw materials, safety are high, overcomes the shortcoming coming covering smell, treating the poisonous disease with poisonous drugs taste removal by taste masking, the odor scavenging agent safety obtained is high, environmental protection.
Preferably, odor scavenging agent of the present invention, is prepared from by the raw material of following weight portion:
The composition of described plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 10, parts by weight are 10, parts by weight be 10 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 15.
This odor scavenging agent, the reasonable mixture ratio of raw material, while reaching removing abnormal flavour object, also forms a protective barrier to the respiratory system of human body, has health-care effect to human body.
Odor scavenging agent of the present invention, industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 2-6:3-8:1, lithium carbonate and Oleum Ricini form.
The industrial antibacterial agent formed by a certain percentage by silver ion antimicrobial agent, lithium carbonate and Oleum Ricini, can pot-life of significant prolongation odor scavenging agent, improves the quality of odor scavenging agent.
Odor scavenging agent of the present invention, industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 4:5:1, lithium carbonate and Oleum Ricini form.
The industrial antibacterial agent formed in the ratio of 4:5:1 by silver ion antimicrobial agent, lithium carbonate and Oleum Ricini, can pot-life of significant prolongation odor scavenging agent, improves the quality of odor scavenging agent, can also significantly improve the taste removal effect of odor scavenging agent simultaneously.
Odor scavenging agent of the present invention, industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 4-8:1-3:1:1, vanillin, zinc oxide and mustard form.
The industrial antibacterial agent formed by a certain percentage by Ammonium biphosphate, vanillin, zinc oxide and mustard, can pot-life of significant prolongation odor scavenging agent, improves the quality of odor scavenging agent.
Odor scavenging agent of the present invention, industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 6:2:1:1, vanillin, zinc oxide and mustard form.
The industrial antibacterial agent formed by a certain percentage by Ammonium biphosphate, vanillin, zinc oxide and mustard, can pot-life of significant prolongation odor scavenging agent, improve the quality of odor scavenging agent, the taste removal effect of odor scavenging agent can also be significantly improved simultaneously, improve the air quality of environment.
Odor scavenging agent of the present invention, in plant extraction liquid, Fructus Luffae extracting solution obtains as follows:
Get Fructus Luffae to clean, pulverize, add deionized water by weight the amount for 1:3, at 80-100 DEG C, extract 10-30min, be cooled to 30-39 DEG C of making beating, be placed in hold-up tank lixiviate 20-40min, filter, obtain Fructus Luffae extracting solution;
Described Radix Kansui extracting solution, Cacumen Tamaricis extracting solution and amomum villosum extract obtain respectively in the same way.
In plant extraction liquid, Fructus Luffae extracting solution, Radix Kansui extracting solution, Cacumen Tamaricis extracting solution and amomum villosum extract also can extract according to alcohol extracting method and obtain.
The preparation method of odor scavenging agent of the present invention, comprises the steps:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, silver ion antimicrobial agent, lithium carbonate grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) fatty acid Oleum Cocois diethanolamine and the Oleum Ricini of recipe quantity is got, mix homogeneously, obtained mixture 2;
C) mixture 1 step a) obtained while stirring joins step b) in the mixture 2 that obtains, mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.The preparation method of odor scavenging agent of the present invention, comprises the steps:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, Ammonium biphosphate, vanillin, zinc oxide, mustard grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) mixture 1 step a) obtained while stirring joins in the fatty acid Oleum Cocois diethanolamine of recipe quantity, and mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
Preparation technology is simple, easy to operate.
Beneficial effect of the present invention is:
(1) odor scavenging agent of the present invention, raw material is adopted to be high, the nontoxic raw material of degree of safety, preparation odor scavenging agent non-stimulated, have no side effect, degree of safety is high, overcome the shortcoming coming covering smell, treating the poisonous disease with poisonous drugs taste removal by taste masking, and the odor scavenging agent safety obtained is high, environment-friendly high-efficiency.
(2) odor scavenging agent of the present invention, preparation method is simple, easy to operate.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
Prescription:
Industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 2:8:1, lithium carbonate and Oleum Ricini form;
The composition of plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 5, parts by weight are 5, parts by weight be 5 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 10;
Preparation method:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, silver ion antimicrobial agent, lithium carbonate grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) fatty acid Oleum Cocois diethanolamine and the Oleum Ricini of recipe quantity is got, mix homogeneously, obtained mixture 2;
C) mixture 1 step a) obtained while stirring joins step b) in the mixture 2 that obtains, mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
Embodiment 2
Prescription:
Industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 6:3:1, lithium carbonate and Oleum Ricini form;
The composition of plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 15, parts by weight are 15, parts by weight be 15 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 20;
Preparation method: obtain odor scavenging agent according to the preparation method of embodiment 1.
Embodiment 3
Prescription:
Industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 6:3:1, lithium carbonate and Oleum Ricini form;
The composition of described plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 10, parts by weight are 10, parts by weight be 10 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 15;
Preparation method: obtain odor scavenging agent according to the preparation method of embodiment 1.
Embodiment 4
Prescription:
Industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 4:3:1:1, vanillin, zinc oxide and mustard form;
The composition of plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 5, parts by weight are 5, parts by weight be 5 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 10;
Preparation method:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, Ammonium biphosphate, vanillin, zinc oxide, mustard grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) mixture 1 step a) obtained while stirring joins in the fatty acid Oleum Cocois diethanolamine of recipe quantity, and mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
Embodiment 5
Prescription:
Industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 8:1:1:1, vanillin, zinc oxide and mustard form;
The composition of plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 15, parts by weight are 15, parts by weight be 15 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 20;
Preparation method: obtain odor scavenging agent according to the preparation method of embodiment 4.
Embodiment 6
Prescription:
Industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 6:2:1:1, vanillin, zinc oxide and mustard form;
The composition of described plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 10, parts by weight are 10, parts by weight be 10 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 15;
Preparation method: obtain odor scavenging agent according to the preparation method of embodiment 4.
Comparative examples 1
Prescription:
Plant extraction liquid 45 citric acid 18 kieselguhr 15
Fatty acid Oleum Cocois diethanolamine 20 soda 15 sodium sulfate 15
Industrial antibacterial agent 150 deionized water 27 Calomelas 15,
Industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 6:3:1, lithium carbonate and Oleum Ricini form;
The composition of described plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 10, parts by weight are 10, parts by weight be 10 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 15;
Preparation method:
A) get the citric acid of recipe quantity, kieselguhr, soda, sodium sulfate, Calomelas, silver ion antimicrobial agent, lithium carbonate grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) fatty acid Oleum Cocois diethanolamine and the Oleum Ricini of recipe quantity is got, mix homogeneously, obtained mixture 2;
C) mixture 1 step a) obtained while stirring joins step b) in the mixture 2 that obtains, mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
Comparative examples 2
Prescription:
Industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 1:9:1, zinc oxide and Oleum Ricini form;
The composition of plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 5, parts by weight are 5, parts by weight be 5 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 10;
Preparation method:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, silver ion antimicrobial agent, zinc oxide grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) fatty acid Oleum Cocois diethanolamine and the Oleum Ricini of recipe quantity is got, mix homogeneously, obtained mixture 2;
C) mixture 1 step a) obtained while stirring joins step b) in the mixture 2 that obtains, mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
Comparative examples 3
Except for the following differences, all the other are all identical with embodiment 6:
Industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 3:4:1:1, vanillin, zinc oxide and mustard form.
For this situation is described, now further illustrate effect of the present invention by test example as follows:
Test example 1 abnormal flavour elimination effect
1. place election:
Select the closet in 6 same ten square meter spaces, after carrying out same finishing, start test, be numbered test group 1, test group 2, matched group 1, matched group 2, matched group 3, matched group 4 respectively.
2. field conditions:
Abnormal flavour grade is 5, and content of formaldehyde grade is 5.
3. test method:
Test group 1: the odor scavenging agent of embodiment 3 is placed in selected closet space, start timing, and respectively test 0,2,5,10,24,48,120h time, record its abnormal flavour grade and content of formaldehyde grade;
Test group 2: with the odor scavenging agent of embodiment 6, at identical conditions, adopting uses the same method tests;
Matched group 1: with the odor scavenging agent of comparative examples 1, at identical conditions, adopting uses the same method tests;
Matched group 2: with the odor scavenging agent of comparative examples 2, at identical conditions, adopting uses the same method tests;
Matched group 3: with the odor scavenging agent of comparative examples 3, at identical conditions, adopting uses the same method tests;
Matched group 4: with green Environmental Protection Technology Co., Ltd produce abnormal flavour remove matchmaker, at identical conditions, adopting uses the same method tests.
4. criterion:
1 grade: abnormal flavour grade is 1, content of formaldehyde grade is 1; That is, in closet space free from extraneous odour or abnormal flavour faint, content of formaldehyde is at 0-0.1mg/cm
3in scope;
2 grades: abnormal flavour grade is 2, content of formaldehyde grade is 2; That is, have slightly strong abnormal flavour in closet space, content of formaldehyde is at 0.1-0.5mg/cm
3in scope;
3 grades: abnormal flavour grade is 3, content of formaldehyde grade is 3; That is, have stronger abnormal flavour in closet space, content of formaldehyde is at 0.5-0.6mg/cm
3in scope;
4 grades: abnormal flavour grade is 4, content of formaldehyde grade is 4; That is, have very strong abnormal flavour in closet space, content of formaldehyde is at 0.6-0.65mg/cm
3in scope;
5 grades: abnormal flavour grade is 5, content of formaldehyde grade is 4; That is, have strong abnormal flavour in closet space, content of formaldehyde is greater than 0.65mg/cm
3.
5. result of the test:
The abnormal flavour elimination effect comparative result of test group and matched group is in table 1;
The abnormal flavour elimination effect of table 1 test group and matched group compares
Treatment group and matched group compare and have diversity (P < 0.05).
6. effect judges:
From test example 1 effectiveness comparison with matched group 1,4, the combination of each raw material in the present invention, significantly improves the elimination effect of odor scavenging agent, to illustrate in the present invention each composition of raw materials rationally, effective, Be very effective;
By test example 1 and matched group 2, the effectiveness comparison of 4 is known, the selection of industrial antibacterial agent in the present invention, each component silver ion antimicrobial agent in industrial antibacterial agent, the selection of proportioning between the selection of lithium carbonate and Oleum Ricini and each component, significantly improve the elimination effect of odor scavenging agent, illustrate in the present invention, the component of industrial antibacterial agent and the reasonable mixture ratio of each component, effectively, Be very effective, ratio of weight and number is selected to be the silver ion antimicrobial agent of 2-6:3-8:1, lithium carbonate and Oleum Ricini are as industrial antibacterial agent, the removing speed of obtained odor scavenging agent significantly improves, elimination effect significantly improves,
By test example 2 and matched group 3, the effectiveness comparison of 4 is known, the selection of industrial antibacterial agent in the present invention, each component Ammonium biphosphate in industrial antibacterial agent, vanillin, the selection of proportioning between the selection of zinc oxide and mustard and each component, significantly improve the elimination effect of odor scavenging agent, illustrate in the present invention, the component of industrial antibacterial agent and the reasonable mixture ratio of each component, effectively, Be very effective, ratio of weight and number is selected to be the Ammonium biphosphate of 4-8:1-3:1:1, vanillin, zinc oxide and mustard are as industrial antibacterial agent, the removing speed of obtained odor scavenging agent significantly improves, elimination effect significantly improves,
Odor scavenging agent of the present invention, abnormal flavour removing speed is fast, effective, and can also reduce content of formaldehyde fast, Be very effective is better than matched group simultaneously.
Claims (9)
1. an odor scavenging agent, is characterized in that, described odor scavenging agent is prepared from by the raw material of following weight portion:
The composition of described plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 5-15, parts by weight are 5-15, and parts by weight are the Cacumen Tamaricis extracting solution of 5-15, parts by weight are the amomum villosum extract of 10-20;
Described industrial antibacterial agent comprise in silver ion antimicrobial agent, zinc oxide, copper oxide, Ammonium biphosphate, lithium carbonate, vanillin, chitin, mustard, Oleum Ricini, Wasabia japonic (Euterma Wasabi) one or more.
2. by odor scavenging agent according to claim 1, it is characterized in that, described odor scavenging agent is prepared from by the raw material of following weight portion:
The composition of described plant extraction liquid is: the Radix Kansui extracting solution that the Fructus Luffae extracting solution that parts by weight are 10, parts by weight are 10, parts by weight be 10 Cacumen Tamaricis extracting solution, parts by weight be the amomum villosum extract of 15.
3. odor scavenging agent according to claim 1, is characterized in that, described industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 2-6:3-8:1, lithium carbonate and Oleum Ricini form.
4. odor scavenging agent according to claim 3, is characterized in that, described industrial antibacterial agent by ratio of weight and number be the silver ion antimicrobial agent of 4:5:1, lithium carbonate and Oleum Ricini form.
5. odor scavenging agent according to claim 1, is characterized in that, described industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 4-8:1-3:1:1, vanillin, zinc oxide and mustard form.
6. odor scavenging agent according to claim 5, is characterized in that, described industrial antibacterial agent by ratio of weight and number be the Ammonium biphosphate of 6:2:1:1, vanillin, zinc oxide and mustard form.
7. the odor scavenging agent according to any one of claim 1-6, is characterized in that, in described plant extraction liquid, Fructus Luffae extracting solution obtains as follows:
Get Fructus Luffae to clean, pulverize, add deionized water by weight the amount for 1:3, at 80-100 DEG C, extract 10-30min, be cooled to 30-39 DEG C of making beating, be placed in hold-up tank lixiviate 20-40min, filter, obtain Fructus Luffae extracting solution;
Described Radix Kansui extracting solution, Cacumen Tamaricis extracting solution and amomum villosum extract obtain respectively in the same way.
8. a preparation method for the odor scavenging agent as described in any one of claim 3-4, is characterized in that, described preparation method comprises the steps:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, silver ion antimicrobial agent, lithium carbonate grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) fatty acid Oleum Cocois diethanolamine and the Oleum Ricini of recipe quantity is got, mix homogeneously, obtained mixture 2;
C) mixture 1 step a) obtained while stirring joins step b) in the mixture 2 that obtains, mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
9. a preparation method for the oral formulations as described in any one of claim 5-6, is characterized in that, described method comprises the steps:
A) get the polyethoxy hydrocarbyl ether sulfuric acid of recipe quantity, citric acid, kieselguhr, soda, sodium sulfate, Calomelas, Ammonium biphosphate, vanillin, zinc oxide, mustard grind to form fine powder, mixing mixing, obtained mixture 1 respectively;
B) mixture 1 step a) obtained while stirring joins in the fatty acid Oleum Cocois diethanolamine of recipe quantity, and mix homogeneously, then adds plant extraction liquid while stirring, and mix homogeneously obtains odor scavenging agent.
Priority Applications (1)
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| CN201510101643.XA CN104707159A (en) | 2015-03-09 | 2015-03-09 | Odor scavenger and preparation method thereof |
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| CN201510101643.XA CN104707159A (en) | 2015-03-09 | 2015-03-09 | Odor scavenger and preparation method thereof |
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| CN104707159A true CN104707159A (en) | 2015-06-17 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107670084A (en) * | 2017-10-21 | 2018-02-09 | 芮志行 | A kind of room air sterilization deodorant and preparation method thereof |
| CN109224108A (en) * | 2018-09-20 | 2019-01-18 | 赵顺全 | A kind of preparation method of pouity dwelling place deodorant |
| CN113509582A (en) * | 2021-04-19 | 2021-10-19 | 湖南普泰尔环境股份有限公司 | Preparation method of composite deodorant containing natural plant extract |
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| CN102815949A (en) * | 2012-09-03 | 2012-12-12 | 中国地质大学（武汉） | Ceramic green body antifungal additive and preparation method thereof |
| CN103476811A (en) * | 2011-04-20 | 2013-12-25 | 赢创德固赛有限公司 | Process for producing water-absorbing polymers with high absorption rate |
| CN103656717A (en) * | 2013-12-24 | 2014-03-26 | 北京绿伞化学股份有限公司 | Plant-extract-based footgear deodorant and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103476811A (en) * | 2011-04-20 | 2013-12-25 | 赢创德固赛有限公司 | Process for producing water-absorbing polymers with high absorption rate |
| CN102815949A (en) * | 2012-09-03 | 2012-12-12 | 中国地质大学（武汉） | Ceramic green body antifungal additive and preparation method thereof |
| CN103656717A (en) * | 2013-12-24 | 2014-03-26 | 北京绿伞化学股份有限公司 | Plant-extract-based footgear deodorant and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107670084A (en) * | 2017-10-21 | 2018-02-09 | 芮志行 | A kind of room air sterilization deodorant and preparation method thereof |
| CN107670084B (en) * | 2017-10-21 | 2020-02-04 | 广州市纳能环保技术开发有限公司 | Indoor air sterilization deodorant and preparation method thereof |
| CN109224108A (en) * | 2018-09-20 | 2019-01-18 | 赵顺全 | A kind of preparation method of pouity dwelling place deodorant |
| CN113509582A (en) * | 2021-04-19 | 2021-10-19 | 湖南普泰尔环境股份有限公司 | Preparation method of composite deodorant containing natural plant extract |
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Application publication date: 20150617 |