CN104693875A - Nano-emulsion varnish coating additive - Google Patents
Nano-emulsion varnish coating additive Download PDFInfo
- Publication number
- CN104693875A CN104693875A CN201310664584.8A CN201310664584A CN104693875A CN 104693875 A CN104693875 A CN 104693875A CN 201310664584 A CN201310664584 A CN 201310664584A CN 104693875 A CN104693875 A CN 104693875A
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- calcium carbonate
- titanium dioxide
- zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a nano-emulsion varnish coating additive. The nano-emulsion varnish coating additive is prepared from the following raw material formulas in percentage by mass: 50-100 parts of nano-ferrum dioxide, 50-100 parts of nano-sodium dioxide, 50-100 parts of nano-zinc dioxide, 80-100 parts of nano-calcium carbonate, 80-100 parts of nano-copper carbonate, 80-100 parts of nano-zinc carbonate, 80-100 parts of nano-silicon carbonate, 100-120 parts of nano-titanium oxide, 150-200 parts of nano-kaoline powder, 150-200 parts of titanium dioxide, 10-50 parts of potassium sorbate, 5-10 parts of accelerators, 5-10 parts of stabilizing agents, 20-50 parts of carrageenan, 20-50 parts of agar, and 250-300 parts of deionized water. The nano-emulsion varnish coating additive is low in production cost, simple in preparation process, and green and environmentally friendly; the functions of mildew prevention, corrosion prevention, sterilization and decomposition of harmful substances in the air are integrated.
Description
Technical field
The present invention relates to a kind of technical field of auxiliary chemicals, particularly relate to a kind of nano-latex paint auxiliary agent.
Background technology
Emulsion paint is being commonly called as of newborn coating, is born in the next period in nineteen seventies, is take acrylate copolymer emulsion as a large class synthetic resin emulsion coating of representative.Emulsion paint is water-dispersible paint, and it take synthetic resin emulsion as base-material, and filler adds the coating that various auxiliary agent is refined after grinding distribution.Emulsion paint has possessed the many merits different from conventional wall coating materials, and as being easy to brushing, drying is rapid, paint film is water-fast, scrub resistance is good.
Emulsion paint auxiliary agent is the indispensable component of emulsion paint, and it can improvement of production process, keeps shelf-stable, improves execution conditions, improve the quality of products, and gives specific function.Emulsion paint auxiliary agent, also known as paint auxiliary material, is the subsidiary material of preparation coating, can improves coating property, promotes that film is formed.Kind is a lot, comprise siccative, toughner, emulsifying agent, thickening material, pigment dispersing agent, defoamer, flow agent, anti-skinning agent, matting agent, photostabilizer, mould inhibitor, static inhibitor (see additives for plastics) etc., what wherein consumption was maximum is siccative and toughner.Current, the research of coatings additive(s), the auxiliary agent for water and milk shellac varnish is attached most importance to.
The important role of emulsion paint auxiliary agent in traditional emulsion paint is also the object of domestic and international competition among enterprises, and for the auxiliary agent annual multi-billion dollar in the world of coating, most domestic market is all captured by many overseas enterprises product.Many auxiliary agent major parts as pigment resin emulsion paint are harmful, and this is the domestic and international problem extremely paid close attention to of people for many years.Along with the enhancing of people's uphold nature and environmental consciousness, biological and fermentation tensio-active agent will have more wide application prospect, and likely become substitute or the upgrading product of synthetic surfactant.
Need in the production process of water-borne coatings to add mould inhibitor, sanitas etc. to kill mould, the growth of anti-bacteria, mould, yeast etc., thus prevent that coating is mouldy, fouling, variable color, viscosity degradation.Current coating mildew-resistant, sanitas only have simple function, and the sanitas had is also containing objectionable impuritiess such as formaldehyde.This kind of material will evaporate in air lentamente, have long-term pollution to room air; Often cost is higher and have pollution to environment for the building-up process of this analog assistant in addition.
Summary of the invention
The object of the invention is the shortcoming in order to overcome above-mentioned prior art, a kind of nano-latex paint auxiliary agent is provided, this nano-latex paint auxiliary agent production cost is low, preparation technology is simple, environmental protection and integrate toxic substance in mildew-resistant, anticorrosion, sterilization, decomposition air.
The technical solution adopted for the present invention to solve the technical problems is: a kind of nano-latex paint auxiliary agent, be made up of the composition of raw materials component of following mass percent: 50-100 part nanometer titanium dioxide iron, 50-100 part nanometer titanium dioxide sodium, 50-100 part Nano zinc dioxide impact-resistant, 80-100 part nano-calcium carbonate, 80-100 part nano-calcium carbonate copper, 80-100 part nanometer zinc carbonate, 80-100 part nano-calcium carbonate silicon, 100-120 part nano-titanium oxide, 150-200 part nano kaoline powder, 150-200 part titanium dioxide, 10-50 part potassium sorbate, 5-10 part promotor, 5-10 part stablizer, 20-50 part carrageenin, 20-50 part agar, 250-300 part deionized water.
Further, described nanometer titanium dioxide iron is 50 parts, nanometer titanium dioxide sodium is 50 parts, Nano zinc dioxide impact-resistant is 50 parts, nano-calcium carbonate is 80 parts, nano-calcium carbonate copper is 80 parts, nanometer zinc carbonate is 80 parts, nano-calcium carbonate silicon is 80 parts, nano-titanium oxide is 100 parts, nano kaoline powder is 150 parts, titanium dioxide is 150 parts, potassium sorbate is 10 parts, promotor is 5 parts, stablizer is 5 parts, carrageenin is 20 parts, agar is 20 parts, deionized water is 250 parts.
Or described nanometer titanium dioxide iron be 100 parts, nanometer titanium dioxide sodium is 100 parts, Nano zinc dioxide impact-resistant is 100 parts, nano-calcium carbonate is 100 parts, nano-calcium carbonate copper is 100 parts, nanometer zinc carbonate is 100 parts, nano-calcium carbonate silicon is 100 parts, nano-titanium oxide is 120 parts, nano kaoline powder is 200 parts, titanium dioxide is 200 parts, potassium sorbate is 50 parts, promotor is 10 parts, stablizer is 10 parts, carrageenin is 50 parts, agar is 50 parts, deionized water is 300 parts.
In sum, the invention has the beneficial effects as follows: nano-latex paint auxiliary agent production cost of the present invention is low, preparation technology is simple, environmental protection and integrate toxic substance in mildew-resistant, anticorrosion, sterilization, decomposition air.
Embodiment
Embodiment 1
A kind of nano-latex paint auxiliary agent described by the present embodiment 1, is made up of the composition of raw materials component of following mass percent: 50 parts of nanometer titanium dioxide iron, 50 parts of nanometer titanium dioxide sodium, 50 parts of Nano zinc dioxide impact-resistant, 80 parts of nano-calcium carbonates, 80 parts of nano-calcium carbonate copper, 80 parts of nanometer zinc carbonates, 80 parts of nano-calcium carbonate silicon, 100 parts of nano-titanium oxides, 150 parts of nano kaoline powder, 150 parts of titanium dioxides, 10 parts of potassium sorbate, 5 parts of promotor, 5 parts of stablizers, 20 parts of carrageenins, 20 parts of agar, 250 parts of deionized waters.
Embodiment 2
A kind of nano-latex paint auxiliary agent described by the present embodiment 2, is made up of the composition of raw materials component of following mass percent: 100 parts of nanometer titanium dioxide iron, 100 parts of nanometer titanium dioxide sodium, 100 parts of Nano zinc dioxide impact-resistant, 100 parts of nano-calcium carbonates, 100 parts of nano-calcium carbonate copper, 100 parts of nanometer zinc carbonates, 100 parts of nano-calcium carbonate silicon, 120 parts of nano-titanium oxides, 200 parts of nano kaoline powder, 200 parts of titanium dioxides, 50 parts of potassium sorbate, 10 parts of promotor, 10 parts of stablizers, 50 parts of carrageenins, 50 parts of agar, 300 parts of deionized waters.
The above is only preferred embodiment of the present invention, not does any pro forma restriction to principle of the present invention and framework.Every above embodiment is done according to technical spirit of the present invention any simple modification, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.
Claims (3)
1. a nano-latex paint auxiliary agent, it is characterized in that, be made up of the composition of raw materials component of following mass percent: 50-100 part nanometer titanium dioxide iron, 50-100 part nanometer titanium dioxide sodium, 50-100 part Nano zinc dioxide impact-resistant, 80-100 part nano-calcium carbonate, 80-100 part nano-calcium carbonate copper, 80-100 part nanometer zinc carbonate, 80-100 part nano-calcium carbonate silicon, 100-120 part nano-titanium oxide, 150-200 part nano kaoline powder, 150-200 part titanium dioxide, 10-50 part potassium sorbate, 5-10 part promotor, 5-10 part stablizer, 20-50 part carrageenin, 20-50 part agar, 250-300 part deionized water.
2. a kind of nano-latex paint auxiliary agent according to claim 1, it is characterized in that, described nanometer titanium dioxide iron is 50 parts, nanometer titanium dioxide sodium is 50 parts, Nano zinc dioxide impact-resistant is 50 parts, nano-calcium carbonate is 80 parts, nano-calcium carbonate copper is 80 parts, nanometer zinc carbonate is 80 parts, nano-calcium carbonate silicon is 80 parts, nano-titanium oxide is 100 parts, nano kaoline powder is 150 parts, titanium dioxide is 150 parts, potassium sorbate is 10 parts, promotor is 5 parts, stablizer is 5 parts, carrageenin is 20 parts, agar is 20 parts, deionized water is 250 parts.
3. a kind of nano-latex paint auxiliary agent according to claim 1, it is characterized in that, described nanometer titanium dioxide iron is 100 parts, nanometer titanium dioxide sodium is 100 parts, Nano zinc dioxide impact-resistant is 100 parts, nano-calcium carbonate is 100 parts, nano-calcium carbonate copper is 100 parts, nanometer zinc carbonate is 100 parts, nano-calcium carbonate silicon is 100 parts, nano-titanium oxide is 120 parts, nano kaoline powder is 200 parts, titanium dioxide is 200 parts, potassium sorbate is 50 parts, promotor is 10 parts, stablizer is 10 parts, carrageenin is 50 parts, agar is 50 parts, deionized water is 300 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310664584.8A CN104693875A (en) | 2013-12-07 | 2013-12-07 | Nano-emulsion varnish coating additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310664584.8A CN104693875A (en) | 2013-12-07 | 2013-12-07 | Nano-emulsion varnish coating additive |
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| Publication Number | Publication Date |
|---|---|
| CN104693875A true CN104693875A (en) | 2015-06-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310664584.8A Pending CN104693875A (en) | 2013-12-07 | 2013-12-07 | Nano-emulsion varnish coating additive |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479244A (en) * | 2015-11-25 | 2017-03-08 | 湖南开磷雁峰塔涂料有限公司 | A kind of synthetic method of coating additive |
| CN108480550A (en) * | 2018-05-25 | 2018-09-04 | 邹峰 | A kind of preparation method of high-strength corrosion-resisting mold casting coating |
-
2013
- 2013-12-07 CN CN201310664584.8A patent/CN104693875A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479244A (en) * | 2015-11-25 | 2017-03-08 | 湖南开磷雁峰塔涂料有限公司 | A kind of synthetic method of coating additive |
| CN108480550A (en) * | 2018-05-25 | 2018-09-04 | 邹峰 | A kind of preparation method of high-strength corrosion-resisting mold casting coating |
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Application publication date: 20150610 |