CN104690445B - 2505 phase stainless steel use metal flux-cored wires and preparation method thereof - Google Patents

2505 phase stainless steel use metal flux-cored wires and preparation method thereof Download PDF

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Publication number
CN104690445B
CN104690445B CN201510075161.1A CN201510075161A CN104690445B CN 104690445 B CN104690445 B CN 104690445B CN 201510075161 A CN201510075161 A CN 201510075161A CN 104690445 B CN104690445 B CN 104690445B
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China
Prior art keywords
flux
stainless steel
medicine core
cored wire
type groove
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Expired - Fee Related
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CN201510075161.1A
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Chinese (zh)
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CN104690445A (en
Inventor
张敏
张明
李继红
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Bonliwei Welding Jiangsu Co ltd
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Xian University of Technology
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/32Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

Abstract

2505 phase stainless steel use metal flux-cored wires, are made up of crust and medicine core, and medicine core is metal-powder, composed of the following components by mass percentage:Cr38 50%, Ni10 15%, Mo3 5%, Mn2 4%, remaining is iron, and above constituent mass percentage sum is 100%.The invention also discloses its preparation method:Drying obtains medicine core powder after each component is well mixed;Medicine core powder is added in the U-type groove that stainless steel 304 steel band is rolled into, U-type groove is rolled into closure, drawing is stretched, disk is packed into disk.Flux-cored wire of the present invention can obtain ferrite and austenitic duplex seam organization, and welding point has excellent mechanical property and corrosion resisting property, with good welding usability, and spatter is few, and weld fumes is few, without slag inclusion problem in welding process;Face of weld is bright and clean smooth, postwelding without cleaning, can continuous sequence, effectively increase welding production efficiency.

Description

2505 phase stainless steel use metal flux-cored wires and preparation method thereof
Technical field
The invention belongs to technical field of welding materials, and in particular to a kind of 2505 phase stainless steel use metal mold medicine core weldering Silk, the invention further relates to the preparation method of the flux-cored wire.
Background technology
Two phase stainless steel since the U.S. is born, has had evolved to the third generation from 1940s.Its main feature Be yield strength up to 400-550MPa, be 2 times of common stainless steel, therefore can economize on material, reduce device fabrication cost. Under conditions of anticorrosive aspect, particularly media environment relatively more severe (such as seawater, chloride ion content is higher), two phase stainless steel Anti- spot corrosion, crevice corrosion, stress corrosion and Corrosion Fatigue Properties be substantially better than common austenitic stainless steel, can with height conjunction Golden austenitic stainless steel matches in excellence or beauty.
Ferritic phase is makeed an appointment with austenite and respectively accounts for half in the metallographic structure of two phase stainless steel, the content of the few phase of general quantity Need to reach 30%.In the case of relatively low containing C, Cr contents are in 18%~28%, Ni contents 3%~10%.Some steel are also Contain Mo, Cu, Nb, Ti, the alloying element such as N.The characteristics of such steel has austenite and ferritic stainless steel concurrently, with ferritic phase Than plasticity, toughness are higher, and no brittleness at room temperature, intergranular corrosion resistance performance and welding performance are significantly increased, while also maintaining iron The 475 DEG C of fragility and thermal conductivity factor of ferritic stainless steel are high, the features such as with superplasticity.Compared with austenitic stainless steel, intensity High and intergranular corrosion resistance and resistance to chloride stress corrosion are significantly improved.
The stainless steel that 2505 two phase stainless steels are made up of 25% Cr, 2% Mo, 5% Ni and 0.25% N. 2505 phase stainless steel use metal flux-cored wires are developed, make welding point that there is the mechanical property matched with 2505 two phase stainless steels Can and corrosion resisting property, obtain 2505 two-phase stainless steel welding constructions can the two phase stainless steel of further genralrlization 2505 use.
The content of the invention
It is an object of the invention to provide a kind of 2505 phase stainless steel use metal flux-cored wire, ferrite and Ovshinsky are obtained The seam organization of body, its welding point has the mechanical property and corrosion resisting property matched with 2505 two phase stainless steels.
It is a further object to provide a kind of preparation method of 2505 phase stainless steel use metal flux-cored wire.
The technical solution adopted in the present invention is, 2505 phase stainless steel use metal flux-cored wires, by crust and medicine core Composition, medicine core is metal-powder, composed of the following components by mass percentage:Cr38%-50%, Ni10%-15%, Mo3%- 5%, Mn2%-4%, remaining is iron, and above constituent mass percentage sum is 100%.
The features of the present invention is also resided in:
Skin material is 304 stainless steel belts.
The filling rate (mass ratio) of medicine core is 25%-27% in the flux-cored wire.
A diameter of 1.2-2.0mm of the flux-cored wire.
Another technical scheme of the present invention is, the preparation side of 2505 phase stainless steel use metal flux-cored wires Method, is comprised the following steps that:
Step 1, Cr38%-50%, Ni10%-15%, Mo3%-5%, Mn2%- are weighed respectively by mass percentage 4%, remaining is iron, and above constituent mass percentage sum is 100%;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 200-300 DEG C, the time is 2-2.5h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 1.2mm-2.0mm, obtains medicine core weldering Silk;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The beneficial effects of the invention are as follows,
1. flux-cored wire of the present invention can obtain ferrite and austenitic duplex seam organization, its welding point have with The mechanical property and corrosion resisting property of 2505 two phase stainless steels matching.
2. the flux-cored wire has good welding usability, spatter is few, and weld fumes is few, without folder in welding process Slag problem.
3. the flux-cored wire face of weld is bright and clean smooth, postwelding without cleaning, can continuous sequence, effectively increase welding life Produce efficiency.It is suitable for automatic welding device, with higher production efficiency.
4. flux-cored wire preparation method of the present invention, technique is simple, easy to operate, it is adapted to mass production.
Embodiment
With reference to embodiment, the present invention is described in detail.
2505 phase stainless steel use metal flux-cored wires of the invention, are made up of, medicine core is metal-powder crust and medicine core, It is composed of the following components by mass percentage:Cr38%-50%, Ni10%-15%, Mo3%-5%, Mn2%-4%, remaining is Iron, above constituent mass percentage sum is 100%.Skin material is 304 stainless steel belts.
The filling rate (mass ratio) of medicine core is 25%-27% in the flux-cored wire.A diameter of 1.2- of the flux-cored wire 2.0mm。
The preparation method of above-mentioned 2505 phase stainless steel use metal flux-cored wire, is comprised the following steps that:
Step 1, Cr38%-50%, Ni10%-15%, Mo3%-5%, Mn2%- are weighed respectively by mass percentage 4%, remaining is iron, and above constituent mass percentage sum is 100%;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 200-300 DEG C, the time is 2-2.5h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 1.2mm-2.0mm, obtains medicine core weldering Silk;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
Flux-cored wire of the present invention is applied to gas metal-arc welding (GMAW), and welding current is 180-220A, and voltage is 20-25V, protective gas is CO2, Ar, or Ar20%-CO280% mixed gas, gas flow rate is 15-20L/min.
The effect of each component in medicine core:
1st, Cr, Mo are ferritiseies, make to have the tendency of to generate ferritic structure in weld seam;Ni, Mn are austenitizings Element, makes to have the tendency of to produce austenite structure in weld seam.Cr, Ni, Mo, Mn coordinate, when designed ratio is suitable, The duplex structure of weld seam meeting ferrite and austenite, therefore Cr, Ni, Mo, Mn use are in order that ultimately generating iron in weld seam The duplex structure of ferritic and austenite.
2nd, Cr, which also has, significantly improves the corrosion proof ability of weld metal, the corrosion resistance of weld seam is reached that what is used wants Ask.
3rd, Mo and Mn also have the effect for improving weld strength.
4th, Ni can ensure that weld seam has certain toughness.
5th, iron supplements remaining weight in powder core, powder core weight is reached 100%.
Embodiment 1
Step 1, Cr380g, Ni120g, Mo50g, Mn40g, Fe410g are weighed respectively;
Step 2, the powder that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 200 DEG C, the time is 2h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 1.2mm, obtains flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The flux-cored wire prepared with embodiment 1, using gas metal-arc welding (GMAW), welding current is 180- 200A, voltage is 22V, and protective gas is CO2, gas flow rate is 15L/min.The tensile strength of welding point is 675Mpa, is bent The limit is taken for 578Mpa, the contraction percentage of area is 55%, and ballistic work is 52J.Performance meets the use requirement of 2505 two phase stainless steels.
Embodiment 2
Step 1, Cr400g, Ni150g, Mo40g, Mn20g, Fe390g are weighed respectively;
Step 2, the powder that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 250 DEG C, the time is 2.25h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 1.4mm, obtains flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The flux-cored wire prepared with embodiment 2, using gas metal-arc welding (GMAW), welding current is 190- 200A, voltage is 22V, and protective gas is CO2, gas flow rate is 15L/min.The tensile strength of joint is 647Mpa, surrender The limit is 526Mpa, and the contraction percentage of area is 53%, and ballistic work is 56J.Performance meets the use requirement of 2505 two phase stainless steels.
Embodiment 3
Step 1, Cr420g, Ni110g, Mo30g, Mn40g, Fe400g are weighed respectively;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 300 DEG C, the time is 2.5h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 1.6mm, obtains flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The flux-cored wire prepared with embodiment 3, using gas metal-arc welding (GMAW), welding current is 200- 220A, voltage is 23V, and protective gas is CO2, gas flow rate is 17L/min.The tensile strength of joint is 689Mpa, surrender The limit is 582Mpa, and the contraction percentage of area is 56%, and ballistic work is 60J.Performance meets the use requirement of 2505 two phase stainless steels.
Embodiment 4
Step 1, Cr460g, Ni140g%, Mo40g, Mn30g, Fe330g are weighed respectively;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 200 DEG C, the time is 2.5h, obtains medicine core powder;
Step 3, by stainless steel 304 steel band be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 1.8mm, obtains flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The flux-cored wire prepared with embodiment 4, using gas metal-arc welding (GMAW), welding current is 220- 220A, voltage is 25V, and protective gas is CO2, gas flow rate is 20L/min.The tensile strength of joint is 672Mpa, surrender The limit is 535Mpa, and the contraction percentage of area is 56%, and ballistic work is 62J.Performance meets the use requirement of 2505 two phase stainless steels.
Embodiment 5
Step 1, Cr480g, Ni130g, Mo50g, Mn40g, Fe300g are weighed respectively;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 220 DEG C, the time is 2.3h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 2.0mm, obtains flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The flux-cored wire prepared with embodiment 5, using gas metal-arc welding (GMAW), welding current is 200- 220A, voltage is 23V, and protective gas is argon gas, and gas flow rate is 17L/min.The tensile strength of joint is 661Mpa, surrender The limit is 522Mpa, and the contraction percentage of area is 52%, and ballistic work is 56J.Performance meets the use requirement of 2505 two phase stainless steels.
Embodiment 6
Step 1, Cr500g, Ni100g, Mo30g, Mn20g, Fe350g are weighed respectively;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 270 DEG C, the time is 2.4h, obtains medicine core powder;
Step 3, by 304 stainless steel belts be placed on flux-cored wire forming machine put band machine on, will be stainless by forming machine The steel band of steel 304 is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, controls the filling of medicine core powder Rate is 25%-27%, then U-type groove is rolled into closure by forming machine, and is drawn to 2.0mm, obtains flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
The flux-cored wire prepared with embodiment 6, using gas metal-arc welding (GMAW), welding current is 220- 220A, voltage is 25V, and protective gas is Ar20%+CO280%, gas flow rate is 20L/min.The tensile strength of joint is 680Mpa, yield limit is 562Mpa, and the contraction percentage of area is 54%, and ballistic work is 60J.Performance meets 2505 two phase stainless steels Use requirement.

Claims (3)

1.2505 phase stainless steel use metal flux-cored wires, it is characterised in that be made up of crust and medicine core, medicine core is metal powder Body, it is composed of the following components by mass percentage:Cr38%-50%, Ni10%-15%, Mo3%-5%, Mn2%-4%, its Yu Weitie, above constituent mass percentage sum is 100%;
The skin material is 304 stainless steel belts;
The filling rate (mass ratio) of medicine core is 25%-27% in the flux-cored wire.
2. 2505 phase stainless steel use metal flux-cored wire according to claim 1, it is characterised in that the flux-cored wire A diameter of 1.2-2.0mm.
The preparation method of 3.2505 phase stainless steel use metal flux-cored wires, it is characterised in that comprise the following steps that:
Step 1, Cr38%-50%, Ni10%-15%, Mo3%-5%, Mn2%-4% are weighed respectively by mass percentage, its Yu Weitie, above constituent mass percentage sum is 100%;
Step 2, the material that step 1 is weighed is well mixed, is then placed within drying oven and dries, the temperature of drying is 200- 300 DEG C, the time is 2-2.5h, obtains medicine core powder;
Step 3,304 stainless steel belts are placed on the putting on band machine of flux-cored wire forming machine, by forming machine by stainless steel 304 Steel band is rolled into U-type groove, and the medicine core powder that step 2 is obtained then is added into U-type groove, and the filling rate for controlling medicine core powder is 25%-27%, then U-type groove is rolled by closure by forming machine, and 1.2mm-2.0mm is drawn to, obtain flux-cored wire;
Step 4, finally flux-cored wire prepared by step 3 is stretched with wire drawing machine, disk is packed into disk.
CN201510075161.1A 2015-02-12 2015-02-12 2505 phase stainless steel use metal flux-cored wires and preparation method thereof Expired - Fee Related CN104690445B (en)

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CN106736048B (en) * 2016-11-29 2019-04-19 洛阳双瑞特种合金材料有限公司 A kind of high-strength weathering steel metal powder core pattern seamless flux-cored wire
CN113714682B (en) * 2021-08-27 2022-07-01 广东省科学院中乌焊接研究所 Super duplex stainless steel self-protection flux-cored wire and preparation method thereof

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KR100352644B1 (en) * 2000-07-28 2002-09-12 고려용접봉 주식회사 Flux cored welding wire having properties of anti-stress corrosion, anti-pitting and good weldibilty for dual phase stainless steel
JP4672177B2 (en) * 2001-05-15 2011-04-20 新日鐵住金ステンレス株式会社 Submerged arc welding method for duplex stainless steel
KR100774155B1 (en) * 2006-10-20 2007-11-07 고려용접봉 주식회사 Flux cored wire for duplex stainless steel and the manufacturing method thereof
WO2009145347A1 (en) * 2008-05-27 2009-12-03 新日鐵住金ステンレス株式会社 Flux-cored wire for welding of duplex stainless steel which enables the miniaturization of solidified crystal particles
CN102049632A (en) * 2009-10-30 2011-05-11 北京赛亿科技股份有限公司 High-hardness self-protecting cold roll build-up welding flux-cored wire
JP4995888B2 (en) * 2009-12-15 2012-08-08 株式会社神戸製鋼所 Stainless steel arc welding flux cored wire
JP5431373B2 (en) * 2011-01-18 2014-03-05 日鐵住金溶接工業株式会社 Flux-cored wire for duplex stainless steel welding
CN102962562A (en) * 2012-12-03 2013-03-13 永胜机械工业(昆山)有限公司 Control method for ferrite of duplex stainless steel welded joint

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