CN107900556A - A kind of austenitic stainless steel self-protection flux-cored wire - Google Patents

A kind of austenitic stainless steel self-protection flux-cored wire Download PDF

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Publication number
CN107900556A
CN107900556A CN201711426440.3A CN201711426440A CN107900556A CN 107900556 A CN107900556 A CN 107900556A CN 201711426440 A CN201711426440 A CN 201711426440A CN 107900556 A CN107900556 A CN 107900556A
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CN
China
Prior art keywords
stainless steel
cored wire
austenitic stainless
protection flux
steel self
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711426440.3A
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Chinese (zh)
Inventor
蔡鸿祥
庄石城
叶桂林
周峙宏
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KUNSHAN GINTUNE WELDING CO Ltd
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KUNSHAN GINTUNE WELDING CO Ltd
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Priority to CN201711426440.3A priority Critical patent/CN107900556A/en
Publication of CN107900556A publication Critical patent/CN107900556A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • B23K35/3602Carbonates, basic oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

It is composed of the following components by mass percentage the present invention relates to a kind of austenitic stainless steel self-protection flux-cored wire:Rutile:1~5%, potassium titanate:0.1~1.5%, sodium titanate:1~3%, potassium feldspar:0.01~0.5%, metallic nickel:8~14%, crome metal:18~25%, manganese metal:1~5%, metallic silicon:0.1~1%, metal niobium≤0.8%, oxide:2~6%, fluorine China thing:1~4%;Surplus is iron.The present invention makes slag reach appropriate fusing point, slag can be with completely isolated air in process of setting by adjusting the proportioning of rutile, oxide and fluoride; welding bead is avoided to produce stomata; and appropriate adjustment potassium titanate and the ratio of sodium titanate, make arc length appropriate, thus have excellent arc force; splash small; and stomata will not be produced, it is easy to use without gas shield; welding efficiency is high, is welded especially suitable for field.

Description

A kind of austenitic stainless steel self-protection flux-cored wire
Technical field
The invention belongs to field of welding material, more particularly to a kind of austenitic stainless steel self-protection flux-cored wire.
Background technology
Self-protection flux-cored wire is the novel welding material developed rapidly in recent years, it is not required to additional protection source of the gas, weldering Rifle is simple in structure, light-weight, easy to operation;Wind resistance is excellent, can be welded under the wind speed below 4 grades;Will to fitted position Ask not high;Rust-resisting property is excellent, and deposition rate is high, is applicable to all-position welding.
Austenitic stainless steel has non-magnetic austenite structure at room temperature, and the yield tensile ratio of steel is low, and plasticity is good, weldability Can be good, it is easy to smelt and casts forging hot forming;Its composition characteristic be containing higher chromium (>=18%), nickel (8%~25%) and It is other to improve corrosion proof element (such as molybdenum, copper, silicon, niobium, titanium).Therefore, austenitic stainless steel not only has good anti-corrosion Property, and also good mechanical property and processing performance, so as to be had been widely used on mechanical equipment.
The characteristic of austenite self-shield stainless flux-cored wire combination self-protection flux-cored wire and stainless flux-cored wire, because And it is rapidly progressed in the recent period.
The content of the invention
The present invention provides a kind of austenitic stainless steel self-protection flux-cored wire, is made of steel band and welding agent, has excellent Arc force, splashes small, and will not produce stomata, therefore is welded especially suitable for field.
To realize above-mentioned technical purpose, the technical scheme is that:A kind of austenitic stainless steel self-protection flux-cored wire, It is made of steel band and welding agent, the austenitic stainless steel self-protection flux-cored wire includes following component:Rutile:1~5%, titanium Sour potassium:0.1~1.5%, sodium titanate:1~3%, potassium feldspar:0.01~0.5%, metallic nickel:8~14%, crome metal:18~ 25%, manganese metal:1~5%, metallic silicon:0.1~1%, metal niobium≤0.8%, oxide:2~6%, fluoride:1~4%, Surplus is iron.
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:Golden red Stone:4~4.5%, potassium titanate:1.1~1.4%, sodium titanate:2.2~2.7%, potassium feldspar:0.3~0.5%, metallic nickel:9~ 12%, crome metal:19.0~21.5%, manganese metal:1.6~2.6%, metallic silicon:0.3~0.8%, oxide:4.5~ 5.2%, fluoride:2.6~3%, surplus is iron.
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:
Preferably, according to percentage by weight, the deposited metal of the austenitic stainless steel self-protection flux-cored wire include with Lower component, surplus Fe:
9th, preferable, according to mass percent, the deposited metal of the austenitic stainless steel self-protection flux-cored wire includes Following component, surplus Fe:
10th, preferable, according to mass percent, the deposited metal of the austenitic stainless steel self-protection flux-cored wire includes Following component, surplus Fe:
The effect that welding agent each component each plays in flux-cored wire in the present invention is as follows:
Rutile:Slag former, main function stablize electric arc, reduce and fly to improve the covering performance and the weld seam removability of slag of slag Splash.
Potassium titanate:Slag former, main function are reduced and splashed to improve the spreadability of welding slag and welding bead shaping.
Sodium titanate:Slag former, main function are reduced and splashed to improve the spreadability of welding slag and welding bead shaping.
Potassium feldspar:Arc stabilizer.Main function is reduced and splashed to stablize electric arc.
Metallic nickel:To weld seam Transition-metal Alloys.
Crome metal:To weld seam Transition-metal Alloys.
Manganese metal:Main function is deoxidation, desulfurization and the transition alloy elements into weld seam.
Metallic silicon:Primary effect be by silicomanganese combined deoxidation, such deoxidation effect more preferably, while transition alloy elements.
Metal niobium:To weld seam Transition-metal Alloys.
Oxide:Slag former, main function are molded to improve welding bead.
Fluoride:Reduce stomata incidence.
The beneficial effects of the present invention are:
(1) because its proportion of fluoride is higher than Yi Ban Jin Red stone-type gas protection wires, so as to reduce the fusing point of slag, welding is made Molten bath process of setting, liquid slag are adequately isolated the air in the external world, avoid stomata from producing, and fluoride can be produced with hydride reaction The effect of raw dehydrogenation, therefore undesirable gas is protected during welding, is welded suitable for field, the welding wire removability of slag is good, and mechanical performance is excellent;
(2) seam organization is austenite, and welding line joint is excellent, available for 18%Cr-8%Ni stainless steels (SUS304, Welding 304L).
The present invention makes slag reach appropriate fusing point, is solidifying by adjusting the proportioning of rutile, oxide and fluoride During slag with completely isolated air welding bead can be avoided to produce stomata, and appropriate adjustment potassium titanate and the ratio of sodium titanate Example, makes arc length appropriate, thus has excellent arc force, splashes small, and will not produce stomata, without gas shield, is applicable in Welded in field.
Embodiment
Technical scheme is further described with reference to specific embodiment, but the present invention is not limited to this A little embodiments.
The austenitic stainless steel self-protection flux-cored wire of the present invention, is made of, the austenitic stainless steel steel band and welding agent Self-protection flux-cored wire includes following component:Rutile:1~5%, potassium titanate:0.1~1.5%, sodium titanate:1~3%, potassium length Stone:0.01~0.5%, metallic nickel:8~14%, crome metal:18~25%, manganese metal:1~5%, metallic silicon:0.1~1%, Metal niobium≤0.8%, oxide:2~6%, fluoride:1~4%, surplus is iron.
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:Golden red Stone:4~4.5%, potassium titanate:1.1~1.4%, sodium titanate:2.2~2.7%, potassium feldspar:0.3~0.5%, metallic nickel:12.5 ~13%, crome metal:21.5~23%, manganese metal:2.8~3.5%, metallic silicon:0.6~0.8%, metal niobium:0.2~0.6, Oxide:4.5~5.2%, fluoride:2.6~3%, surplus is iron.
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:
Preferably, following component is included according to mass percent, the austenitic stainless steel self-protection flux-cored wire:
Preferably, according to percentage by weight, the deposited metal of the austenitic stainless steel self-protection flux-cored wire include with Lower component, surplus Fe:
Preferably, according to mass percent, the deposited metal of the austenitic stainless steel self-protection flux-cored wire include with Lower component, surplus Fe:
Preferably, according to mass percent, the deposited metal of the austenitic stainless steel self-protection flux-cored wire include with Lower component, surplus Fe:
The austenitic stainless steel weld for self-shielded flux-cored arc welding is organized as austenite, and welding line joint is excellent.
In an embodiment of the invention, it is made of steel band and welding agent, welding agent is wrapped in steel band, using stainless steel Steel band, its steel band, welding agent component (percentage by weight %) such as following table:
Table 1-1 steel band component (units:Percentage by weight)
C Si Mn P S Ni Cr Mo Cu
0.012 0.36 1.60 0.016 0.002 8.22 18.43 0.002 0.020
Table 1-2 welding agent components match (unit:Percentage by weight)
Its deposited metal composition is shown in Table 1-3, and deposited metal mechanical property is shown in Table 1-4:
Chemical composition (the unit of table 1-3 deposited metals:Percentage by weight)
C Si Mn P S Ni Cr M0 Cu Fe
0.016 0.40 1.53 0.015 0.004 9.25 19.05 0.006 0.050 Surplus
Table 1-4:Mechanical property
Yield strength (MPa) Tensile strength (MPa) Elongation percentage (%)
452 629 38.0
In another embodiment of the present invention, it is made of steel band and welding agent, welding agent is wrapped in steel band, using stainless steel Steel band, its steel band, welding agent component (percentage by weight %) such as following table:
Table 2-1 steel band component (units:Percentage by weight)
C Si Mn P S Ni Cr M0 Cu
0.008 0.34 1.35 0.013 0.001 8.10 18.7 0.004 0.020
Table 2-2 welding agent components match (unit:Percentage by weight)
Its deposited metal composition is shown in Table 2-3, and deposited metal mechanical property is shown in Table 2-4:
Chemical composition (the unit of table 2-3 deposited metals:Percentage by weight)
C Si Mn P S Ni Cr Mo Cu Fe
0.012 0.41 1.66 0.016 0.004 9.55 19.35 0.006 0.060 Surplus
Table 2-4:Mechanical property
Yield strength (MPa) Tensile strength (MPa) Elongation percentage (%)
450 610 40.0
In another embodiment of the present invention, it is made of steel band and welding agent, welding agent is wrapped in steel band, using stainless steel Steel band, its steel band, welding agent component (percentage by weight %) such as following table:
Table 3-1 steel band component (units:Percentage by weight)
C Si Mn P S Ni Cr Mo Cu
0.010 0.31 1.40 0.015 0.002 8.34 18.75 0.004 0.008
Table 3-2 welding agent components match (unit:Percentage by weight)
Its deposited metal composition is shown in Table 3-3, and deposited metal mechanical property is shown in Table 3-4:
Chemical composition (the unit of table 3-3 deposited metals:Percentage by weight)
Table 3-4:Mechanical property
Yield strength (MPa) Tensile strength (MPa) Elongation percentage (%)
470 650 42.0
The present invention makes slag reach appropriate fusing point, is solidifying by adjusting the proportioning of rutile, oxide and fluoride During slag with completely isolated air welding bead can be avoided to produce stomata, and appropriate adjustment potassium titanate and the ratio of sodium titanate Example, makes arc length appropriate, thus has excellent arc force, splashes small, and will not produce stomata.Seam organization is austenite, Welding line joint is excellent, the welding available for 18%Cr-8%Ni stainless steels (SUS304,304L).Gas is not required during present invention welding Body is protected, and is welded suitable for field, the welding wire removability of slag is good, and mechanical performance is excellent.
Above-described is only the preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art For, without departing from the concept of the premise of the invention, various modifications and improvements can be made, these belong to the present invention Protection domain.

Claims (8)

1. a kind of austenitic stainless steel self-protection flux-cored wire, is made of steel band and welding agent, it is characterised in that according to weight percent Than the austenitic stainless steel self-protection flux-cored wire includes following component:Rutile:1~5%, potassium titanate:0.1~ 1.5%, sodium titanate:1~3%, potassium feldspar:0.01~0.5%, metallic nickel:8~14%, crome metal:18~25%, manganese metal: 1~5%, metallic silicon:0.1~1%, metal niobium≤0.8%, oxide:2~6%, fluoride:1~4%, surplus is iron.
2. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to mass percent, The austenitic stainless steel self-protection flux-cored wire includes following component:Rutile:4~4.5%, potassium titanate:1.1~1.4%, Sodium titanate:2.2~2.7%, potassium feldspar:0.3~0.5%, metallic nickel:9~12%, crome metal:19~21.5%, manganese metal: 1.6~2.6%, metallic silicon:0.3~0.8%, oxide:4.5~5.2%, fluoride:2.6~3%, surplus is iron.
3. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to mass percent, The austenitic stainless steel self-protection flux-cored wire includes following component:
4. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to mass percent, The austenitic stainless steel self-protection flux-cored wire includes following component:
5. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to mass percent, The austenitic stainless steel self-protection flux-cored wire includes following component:
6. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to percentage by weight, The deposited metal of the austenitic stainless steel self-protection flux-cored wire includes following component, surplus Fe:
7. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to mass percent, The deposited metal of the austenitic stainless steel self-protection flux-cored wire includes following component, surplus Fe:
8. austenitic stainless steel self-protection flux-cored wire as claimed in claim 1, it is characterised in that according to mass percent, The deposited metal of the austenitic stainless steel self-protection flux-cored wire includes following component, surplus Fe:
CN201711426440.3A 2017-12-25 2017-12-25 A kind of austenitic stainless steel self-protection flux-cored wire Withdrawn CN107900556A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108971798A (en) * 2018-09-29 2018-12-11 四川大西洋焊接材料股份有限公司 Mixed gas protected austenitic stainless steel special welding wire and preparation method
CN110253173A (en) * 2019-07-17 2019-09-20 新乡市和光科技有限公司 A kind of austenitic stainless steel self-shielded arc welding increasing material manufacturing flux cored wire
CN110508969A (en) * 2019-09-05 2019-11-29 昆山京群焊材科技有限公司 A kind of alkalescent full-position CO2Gas protects flux-cored wire
CN111136403A (en) * 2020-01-03 2020-05-12 北京工业大学 High-toughness 17-4PH precipitation hardening stainless steel metal core welding wire
CN112935630A (en) * 2021-03-22 2021-06-11 西安理工大学 Argon-filling-free self-protection flux-cored wire on back of stainless steel pipeline and preparation method thereof

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CN102451961A (en) * 2010-10-20 2012-05-16 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel welding
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CN103418940A (en) * 2012-05-23 2013-12-04 中冶焊接科技有限公司 Flux-cored wire for titanium- or niobium-contained austenitic stainless steel welding
CN103521951A (en) * 2013-11-04 2014-01-22 北京金威焊材有限公司 Flux-cored wire for stainless steel welding
CN103949796A (en) * 2014-05-05 2014-07-30 常州新德焊材科技有限公司 Austenitic stainless steel flux-cored wire having no oxidation tint on surface of welding joint
JP2017131912A (en) * 2016-01-26 2017-08-03 日鐵住金溶接工業株式会社 Flux-cored wire for two-phase stainless steel welding

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Publication number Priority date Publication date Assignee Title
CN101690996A (en) * 2009-10-16 2010-04-07 河北翼辰实业集团有限公司 All-position niobium -contained stainless steel flux-cored wire
CN102451961A (en) * 2010-10-20 2012-05-16 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel welding
CN102229029A (en) * 2011-05-30 2011-11-02 中冶焊接科技有限公司 Flux-cored wire for austenitic stainless steel all-position welding
CN102267023A (en) * 2011-07-29 2011-12-07 台州海翔焊接材料有限公司 Metal-powder type stainless steel flux-cored wire
CN103418940A (en) * 2012-05-23 2013-12-04 中冶焊接科技有限公司 Flux-cored wire for titanium- or niobium-contained austenitic stainless steel welding
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CN103521951A (en) * 2013-11-04 2014-01-22 北京金威焊材有限公司 Flux-cored wire for stainless steel welding
CN103949796A (en) * 2014-05-05 2014-07-30 常州新德焊材科技有限公司 Austenitic stainless steel flux-cored wire having no oxidation tint on surface of welding joint
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108971798A (en) * 2018-09-29 2018-12-11 四川大西洋焊接材料股份有限公司 Mixed gas protected austenitic stainless steel special welding wire and preparation method
CN110253173A (en) * 2019-07-17 2019-09-20 新乡市和光科技有限公司 A kind of austenitic stainless steel self-shielded arc welding increasing material manufacturing flux cored wire
CN110508969A (en) * 2019-09-05 2019-11-29 昆山京群焊材科技有限公司 A kind of alkalescent full-position CO2Gas protects flux-cored wire
CN111136403A (en) * 2020-01-03 2020-05-12 北京工业大学 High-toughness 17-4PH precipitation hardening stainless steel metal core welding wire
CN111136403B (en) * 2020-01-03 2021-09-24 北京工业大学 High-toughness 17-4PH precipitation hardening stainless steel metal core welding wire
CN112935630A (en) * 2021-03-22 2021-06-11 西安理工大学 Argon-filling-free self-protection flux-cored wire on back of stainless steel pipeline and preparation method thereof
CN112935630B (en) * 2021-03-22 2022-07-22 西安理工大学 Argon-filling-free self-protection flux-cored wire for back of stainless steel pipeline and preparation method thereof

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