CN104690446A - Flux-cored wire for nickel-saving 2205 duplex stainless steel and preparation method of flux-cored wire - Google Patents

Flux-cored wire for nickel-saving 2205 duplex stainless steel and preparation method of flux-cored wire Download PDF

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Publication number
CN104690446A
CN104690446A CN201510075164.5A CN201510075164A CN104690446A CN 104690446 A CN104690446 A CN 104690446A CN 201510075164 A CN201510075164 A CN 201510075164A CN 104690446 A CN104690446 A CN 104690446A
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flux
cored wire
stainless steel
nickel
powder
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CN201510075164.5A
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CN104690446B (en
Inventor
张敏
张明
李继红
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Bonliwei Welding Jiangsu Co ltd
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Xian University of Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The invention discloses a flux-cored wire for nickel-saving 2205 duplex stainless steel. The flux-cored wire comprises skin and a flux core, wherein the flux core is prepared from the following components in percentage by weight: 20-30% of metallic chrome, 12-18% of ferrochrome nitride, 3-5% of metallic nickel, 12-15% of molybdenum, 2-4% of electrolytic manganese, 5-7% of aluminum-magnesium powder and the balance of ferrous powder. The invention further discloses a preparation method of the flux-cored wire. The preparation method comprises the following steps: fully mixing the weighed materials and drying the materials; adding the materials into a U-shaped slot rolled by a 304 stainless steel strip, grinding and drawing in a closed manner, straightening, coiling into a round disc, and hermetically packaging. The flux-cored wire for nickel-saving 2205 duplex stainless steel disclosed by the invention is specially use for welding nickel-saving 2205 duplex stainless steel, is few in welding spatter and attractive in appearance of weld, has good welding manufacturability, is suitable for continuous wire-feeding welding equipment and has a relatively high production efficiency; the flux-cored wire is simple in preparation method, convenient to operate and suitable for batch production.

Description

Nickel-saving type 2205 phase stainless steel use flux-cored wire and preparation method thereof
Technical field
The invention belongs to technical field of welding materials, be specifically related to a kind of nickel-saving type 2205 phase stainless steel use flux-cored wire, the invention still further relates to the preparation method of this flux-cored wire.
Background technology
Two phase stainless steel is the stainless steel that a kind of ferritic phase coexists mutually with austenite, is also simultaneously the steel grade integrating excellent corrosion resisting property, high strength and be easy to many excellent properties such as processing and manufacturing.
The stainless steel that 2205 two phase stainless steels are made up of Cr, the Mo of 2.5% of 21%, the N of the Ni of 4.5% and 0.17%.2205 two phase stainless steels regulate ferrite and austenitic ratio, wherein [Ni]=9.5, [Cr]=25.5 by controlling [Ni] equivalent with [Cr] equivalent; Its tissue is made up of the ferrite of 40%-60% and the austenite of 60%-40%, and the kind of domestic two phase stainless steel has duplex stainless steel 2205 sheet material, duplex stainless steel 2205 steel pipe, duplex stainless steel 2205 seamless pipe, duplex stainless steel 2205 bar, tubing, forging material etc.
2205 two phase stainless steels are as the most frequently used a kind of two phase stainless steel, and its use amount accounts for more than 80% of dual phase steel.Thus develop a kind of flux-cored wire matched to have important practical significance.In 2205 two phase stainless steels, the content of alloying element is higher, nickel element especially used, and as rare material, price is high, and research and development nickel-saving type diphase stainless steel welding material can reduce the cost of wlding greatly.
Summary of the invention
The object of this invention is to provide a kind of nickel-saving type 2205 phase stainless steel use flux-cored wire, spatter is few, and appearance of weld is attractive in appearance, has good welding usability.
Another object of the present invention is to provide a kind of preparation method of nickel-saving type 2205 phase stainless steel use flux-cored wire.
The technical solution adopted in the present invention is, nickel-saving type 2205 phase stainless steel use flux-cored wire, be made up of crust and medicine core, medicine core is composed of the following components by mass percentage: crome metal 20%-30%, nitrided ferro-chromium 12%-18%, metallic nickel 3%-5%, molybdenum 12%-15%, electrolytic manganese 2%-4%, al-mg powder 5%-7%, surplus is iron powder, and above constituent mass percentage sum is 100%.
Feature of the present invention is also:
Skin material is 304 stainless steel belts.
The granularity of this flux for flux-cored wire powder is 80-100 order.
The filling rate (mass ratio) of this flux-cored wire Chinese medicine core is 20%-25%.
The diameter of this flux-cored wire is 1.2-2.0mm.
Another technical scheme of the present invention is, the preparation method of nickel-saving type 2205 phase stainless steel use flux-cored wire, and concrete steps are as follows:
Step 1, takes crome metal 20%-30% by mass percentage respectively, nitrided ferro-chromium 12%-18%, metallic nickel 3%-5%, molybdenum 12%-15%, electrolytic manganese 2%-4%, al-mg powder 5%-7%, and surplus is iron powder, and above constituent mass percentage sum is 100%;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 20%-25%, U-type groove is rolled closed by forming machine again, and be drawn to 1.2-2.0mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
The invention has the beneficial effects as follows,
1. nickel-saving type 2205 phase stainless steel use flux-cored wire of the present invention, be exclusively used in the welding of nickel-saving type 2205 two phase stainless steel, spatter is few, and appearance of weld is attractive in appearance, has good welding usability; Be suitable for continuous wire feed welding equipment, there is higher production efficiency.
2. nickel-saving type 2205 phase stainless steel use flux-cored wire of the present invention, utilizes nitrogen element portions to substitute the use of rare nickel element, has saved the production cost of flux-cored wire.
3. the preparation method of nickel-saving type 2205 phase stainless steel use flux-cored wire of the present invention is simple, easy to operate, is applicable to mass production.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is described in detail.
Nickel-saving type 2205 phase stainless steel use flux-cored wire of the present invention, be made up of crust and medicine core, medicine core is composed of the following components by mass percentage: crome metal 20%-30%, nitrided ferro-chromium 12%-18%, metallic nickel 3%-5%, molybdenum 12%-15%, electrolytic manganese 2%-4%, al-mg powder 5%-7%, surplus is iron powder, and above constituent mass percentage sum is 100%.Skin material is 304 stainless steel belts.
The granularity of this flux for flux-cored wire powder is 80-100 order.
The filling rate (mass ratio) of this flux-cored wire Chinese medicine core is 20%-25%.
The diameter of this flux-cored wire is 1.2-2.0mm.
The preparation method of nickel-saving type 2205 phase stainless steel use flux-cored wire, concrete steps are as follows:
Step 1, takes crome metal 20%-30% by mass percentage respectively, nitrided ferro-chromium 12%-18%, metallic nickel 3%-5%, molybdenum 12%-15%, electrolytic manganese 2%-4%, al-mg powder 5%-7%, and surplus is iron powder, and above constituent mass percentage sum is 100%;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 20%-25%, U-type groove is rolled closed by forming machine again, and be drawn to 1.2-2.0mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
The effect of each component in medicine core:
1, crome metal, molybdenum has ferritizing effect, makes to have in weld seam to generate ferritic trend, metallic nickel, electrolytic manganese has the effect of austenitizing, makes to have in weld seam to generate austenitic trend, four with the use of, be produce a certain proportion of ferrite and austenite in weld seam to make.
2, crome metal also has and improves joint corrosion proof effect, time welding point meet stainless instructions for use.
3, the chromium in nitrided ferro-chromium and crome metal have same effect, namely ferritizing with raising corrosion resistance.Nitrogen wherein and nickel have same effect, i.e. the effect of austenitizing.
4, metallic nickel, also has the effect improving welding point toughness.
5, al-mg powder easily and combination with oxygen and the oxygen element that removes in molten bath, protects other components in weld seam.
6, iron is used for supplementary residual mass, is that the quality of powder core reaches 100%.
Embodiment 1
Step 1, takes crome metal 280g respectively, nitrided ferro-chromium 120g, metallic nickel 40g, molybdenum 120g, electrolytic manganese 40g, al-mg powder 70g, iron powder 330g;
Step 2, claims material fully stirs by step 1, put into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 25%, U-type groove is rolled closed by forming machine again, and be drawn to 2.0mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
Flux-cored wire prepared by embodiment 1 is applicable to gas metal-arc welding (GMAW), and welding current is 180-240A, and voltage is 20-25V, and protective gas is Ar20%-CO 280% mist, gas flow rate is 15-20L/min.The tensile strength of welding point is 654Mpa, and yield limit is 523Mpa, the contraction percentage of area 56%, and ballistic work is 65J.Performance meets the instructions for use of 2205 two phase stainless steels.
Embodiment 2
Step 1, takes crome metal 200g respectively, nitrided ferro-chromium 180g, metallic nickel 30g, molybdenum 150g, electrolytic manganese 20g, al-mg powder 70g, iron powder 350g;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 23%, U-type groove is rolled closed by forming machine again, and be drawn to 1.6mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
Flux-cored wire prepared by embodiment 2 is applicable to gas metal-arc welding (GMAW), and welding current is 180-240A, and voltage is 20-25V, and protective gas is Ar20%-CO 280% mist, gas flow rate is 15-20L/min.The tensile strength of welding point is 657Mpa, and yield limit is 521Mpa, the contraction percentage of area 54%, and ballistic work is 62J.Performance meets the instructions for use of 2205 two phase stainless steels.
Embodiment 3
Step 1, takes crome metal 240g respectively, nitrided ferro-chromium 160g, metallic nickel 50g, molybdenum 120g, electrolytic manganese 30g, al-mg powder 50g, iron powder 350g;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 22%, U-type groove is rolled closed by forming machine again, and be drawn to 1.4mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
Flux-cored wire prepared by embodiment 3 is applicable to gas metal-arc welding (GMAW), and welding current is 180-240A, and voltage is 20-25V, and protective gas is Ar20%-CO 280% mist, gas flow rate is 15-20L/min.The tensile strength of welding point is 690Mpa, and yield limit is 576Mpa, the contraction percentage of area 62%, and ballistic work is 65J.Performance meets the instructions for use of 2205 two phase stainless steels.
Embodiment 4
Step 1, takes crome metal 300g respectively, nitrided ferro-chromium 150g, metallic nickel 30g, molybdenum 13g, electrolytic manganese 30g, al-mg powder 70g, iron powder 290g;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 20%, U-type groove is rolled closed by forming machine again, and be drawn to 1.8mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
Flux-cored wire prepared by embodiment 4 is applicable to gas metal-arc welding (GMAW), and welding current is 180-240A, and voltage is 20-25V, and protective gas is Ar20%-CO 280% mist, gas flow rate is 15-20L/min.The tensile strength of welding point is 601Mpa, and yield limit is 519Mpa, the contraction percentage of area 51%, and ballistic work is 62J.Performance meets the instructions for use of 2205 two phase stainless steels.
Embodiment 5
Step 1, takes crome metal 220g respectively, nitrided ferro-chromium 130g, metallic nickel 50g, molybdenum 140g, electrolytic manganese 40g, al-mg powder 60g, iron powder 460g;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 22%, U-type groove is rolled closed by forming machine again, and be drawn to 1.4mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
Flux-cored wire prepared by embodiment 5 is applicable to gas metal-arc welding (GMAW), and welding current is 180-240A, and voltage is 20-25V, and protective gas is Ar20%-CO 280% mist, gas flow rate is 15-20L/min.The tensile strength of welding point is 672Mpa, and yield limit is 534Mpa, the contraction percentage of area 54%, and ballistic work is 65J.Performance meets the instructions for use of 2205 two phase stainless steels.
Embodiment 6
Step 1, takes crome metal 260g respectively, nitrided ferro-chromium 140g, metallic nickel 40g, molybdenum 130g, electrolytic manganese 20g, al-mg powder 50g, iron powder 360g;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 20%, U-type groove is rolled closed by forming machine again, and be drawn to 1.2mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
Flux-cored wire prepared by embodiment 5 is applicable to gas metal-arc welding (GMAW), and welding current is 180-240A, and voltage is 20-25V, and protective gas is Ar20%-CO 280% mist, gas flow rate is 15-20L/min.The tensile strength of welding point is 691Mpa, and yield limit is 556Mpa, the contraction percentage of area 52%, and ballistic work is 65J.Performance meets the instructions for use of 2205 two phase stainless steels.

Claims (6)

1. nickel-saving type 2205 phase stainless steel use flux-cored wire, it is characterized in that, be made up of crust and medicine core, medicine core is composed of the following components by mass percentage: crome metal 20%-30%, nitrided ferro-chromium 12%-18%, metallic nickel 3%-5%, molybdenum 12%-15%, electrolytic manganese 2%-4%, al-mg powder 5%-7%, surplus is iron powder, and above constituent mass percentage sum is 100%.
2. nickel-saving type 2205 phase stainless steel use flux-cored wire according to claim 1, it is characterized in that, described skin material is 304 stainless steel belts.
3. nickel-saving type 2205 phase stainless steel use flux-cored wire according to claim 1, is characterized in that, the granularity of this flux for flux-cored wire powder is 80-100 order.
4. nickel-saving type 2205 phase stainless steel use flux-cored wire according to claim 1, is characterized in that, the filling rate (mass ratio) of this flux-cored wire Chinese medicine core is 20%-25%.
5. nickel-saving type 2205 phase stainless steel use flux-cored wire according to claim 1, is characterized in that, the diameter of this flux-cored wire is 1.2-2.0mm.
6. the preparation method of nickel-saving type 2205 phase stainless steel use flux-cored wire, it is characterized in that, concrete steps are as follows:
Step 1, takes crome metal 20%-30% by mass percentage respectively, nitrided ferro-chromium 12%-18%, metallic nickel 3%-5%, molybdenum 12%-15%, electrolytic manganese 2%-4%, al-mg powder 5%-7%, and surplus is iron powder, and above constituent mass percentage sum is 100%;
Step 2, material step 1 claimed fully stirs, and puts into drying oven and dry 200 degrees Celsius, 2 hours after mixing;
Step 3, what 304 stainless steel belts are placed on flux-cored wire forming machine puts on band machine, by forming machine, steel band is rolled into U-type groove, then in U-type groove, add the medicine core powder that step 3 obtains, the filling rate controlling medicine core powder is 20%-25%, U-type groove is rolled closed by forming machine again, and be drawn to 1.2-2.0mm, obtain flux-cored wire;
Step 4, finally stretching with the flux-cored wire that step 3 is prepared by wire drawing machine, coil into disk, pack.
CN201510075164.5A 2015-02-12 2015-02-12 Phase stainless steel use flux-cored wire of nickel-saving type 2205 and preparation method thereof Expired - Fee Related CN104690446B (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN106514040A (en) * 2016-11-04 2017-03-22 四川大西洋焊接材料股份有限公司 Gas-shielded stainless steel flux-cored wire for boiler burner, and production process thereof
CN107160055A (en) * 2017-06-29 2017-09-15 西安理工大学 A kind of phase stainless steel use self-protection flux-cored wire and preparation method thereof
CN107350658A (en) * 2017-07-12 2017-11-17 西安理工大学 PH13 8Mo stainless steels metal mold welding wire and preparation method thereof
CN110181197A (en) * 2019-06-17 2019-08-30 武汉科技大学 A kind of high nitrogen metal powder-cored wire suitable for the welding of high nitrogen armour steel
JP7485895B2 (en) 2020-01-10 2024-05-17 日本製鉄株式会社 Flux-cored wire and method for manufacturing welded joint

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CN103042321A (en) * 2012-12-21 2013-04-17 中国兵器工业第五二研究所 Metal powder-cored type nitrogen austenite stainless steel flux-cored wire and method for manufacturing same
JP5431373B2 (en) * 2011-01-18 2014-03-05 日鐵住金溶接工業株式会社 Flux-cored wire for duplex stainless steel welding
CN104259690A (en) * 2014-07-09 2015-01-07 北京工业大学 Stainless heat-proof self-protecting flux-cored wire for magnesium smelting reduction tank

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Publication number Priority date Publication date Assignee Title
CN101157160A (en) * 2007-04-20 2008-04-09 北京工业大学 A flux-cored wire for soldering diphasic stainless steel
CN101134271A (en) * 2007-10-11 2008-03-05 北京工业大学 Full-position soldering biphase stainless steel flux-cored wire
JP5431373B2 (en) * 2011-01-18 2014-03-05 日鐵住金溶接工業株式会社 Flux-cored wire for duplex stainless steel welding
CN103042321A (en) * 2012-12-21 2013-04-17 中国兵器工业第五二研究所 Metal powder-cored type nitrogen austenite stainless steel flux-cored wire and method for manufacturing same
CN104259690A (en) * 2014-07-09 2015-01-07 北京工业大学 Stainless heat-proof self-protecting flux-cored wire for magnesium smelting reduction tank

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106514040A (en) * 2016-11-04 2017-03-22 四川大西洋焊接材料股份有限公司 Gas-shielded stainless steel flux-cored wire for boiler burner, and production process thereof
CN106514040B (en) * 2016-11-04 2019-07-26 四川大西洋焊接材料股份有限公司 A kind of gas shielded stainless flux-cored wire and its production technology for boiler-burner
CN107160055A (en) * 2017-06-29 2017-09-15 西安理工大学 A kind of phase stainless steel use self-protection flux-cored wire and preparation method thereof
CN107350658A (en) * 2017-07-12 2017-11-17 西安理工大学 PH13 8Mo stainless steels metal mold welding wire and preparation method thereof
CN110181197A (en) * 2019-06-17 2019-08-30 武汉科技大学 A kind of high nitrogen metal powder-cored wire suitable for the welding of high nitrogen armour steel
CN110181197B (en) * 2019-06-17 2021-03-16 武汉科技大学 High-nitrogen metal powder-cored flux-cored wire suitable for welding high-nitrogen armored steel
JP7485895B2 (en) 2020-01-10 2024-05-17 日本製鉄株式会社 Flux-cored wire and method for manufacturing welded joint

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