CN104645597B

CN104645597B - A kind of non-crystaline amorphous metal skates and ice skates and its manufacture method

Info

Publication number: CN104645597B
Application number: CN201510071786.0A
Authority: CN
Inventors: 李奉珪
Original assignee: Dongguan Pa Mudi Hao Yu Liquid Metal Co Ltd
Current assignee: Dongguan Pa Mudi Hao Yu liquid metal Co., Ltd
Priority date: 2015-02-11
Filing date: 2015-02-11
Publication date: 2017-03-01
Anticipated expiration: 2035-02-11
Also published as: CN104645597A

Abstract

The present invention relates to the applied technical field of non-crystaline amorphous metal, more particularly to a kind of non-crystaline amorphous metal skates and ice skates and its manufacture method, this skates is the non-crystaline amorphous metal skates being manufactured using zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous alloy, ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy.The manufacture method of non-crystaline amorphous metal skates, first passes through die cast process or double-roller rolling method prepares the monnolithic case profile of skates；Again molding is carried out to the cutter tooth part of skates by TPF or RDF, obtain non-crystaline amorphous metal skates.This non-crystaline amorphous metal skates has the advantages that high precision, high intensity, high resiliency, high rigidity, scratch resistance, wear-resisting, anticorrosive, lightweight, surface effect be good and long service life.The manufacture method of this non-crystaline amorphous metal skates has the advantages that process is simple, production efficiency height and low production cost.

Description

A kind of non-crystaline amorphous metal skates and ice skates and its manufacture method

Technical field

The present invention relates to the applied technical field of non-crystaline amorphous metal, more particularly to a kind of non-crystaline amorphous metal skates and ice skates and Its manufacture method.

Background technology

In prior art, ice skates with skates typically made with rustless steel or carbon steel, this rustless steel or carbon steel The skates made have the shortcomings that precise structure degree is not high, heavier and are easier to wear and tear, also exist intensity, elastic limit, hardness, Scratch resistance performance and the poor defect of corrosion resistance, thus result in its service life not long.

In addition, have also appeared the skates preparing ice skates using coated high speed steel in prior art.This coating is at a high speed The standby skates of steel, its blade integrally adopts bimetallic clad steel, then passes through to apply last layer titanium nitride in the both sides of blade （TiN）Or titanium carbide（TiC）, then again after the ground cutting edge of a knife or a sword with mill, that is, form hardness and precision compared to rustless steel or carbon steel system The slightly good blade of skates becoming.However, there is complex process, low production efficiency in the preparation method of this high-speed steel coated ice skate Shortcoming, and the poor shortcoming of toughness of prepared high-speed steel coated ice skate, and also there is intensity, elastic limit, wear-resisting, resistance to Scrape performance and the not good defect of corrosion resistance.

The structures such as the radian due to ice skates skates are quite important, in order to form the better suited radian of ratio, prior art In skates more pass through CNC（Digit Control Machine Tool）It is machined out and manufactures, this manufacture method has high cost, low production efficiency Shortcoming.

Content of the invention

An object of the present invention is to provide a kind of high precision, high-strength for weak point of the prior art Degree, high resiliency, high rigidity, scratch resistance, wear-resisting, anticorrosive, lightweight, surface effect be good and the non-crystaline amorphous metal ice of long service life Knife.

The second object of the present invention is for weak point of the prior art provides a kind of non-crystaline amorphous metal ice skates, This ice skates employs non-crystaline amorphous metal skates, has high precision, high intensity, high resiliency, high rigidity, scratch resistance, wear-resisting, anti-corruption Erosion, lightweight, surface effect be good and the advantage of long service life.

The third object of the present invention is to provide a kind of process is simple for weak point of the prior art, produces effect The manufacture method of the high non-crystaline amorphous metal skates with low production cost of rate.

For reaching one of above-mentioned purpose, the present invention is achieved through the following technical solutions.

There is provided a kind of non-crystaline amorphous metal skates, described skates are using zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous Alloy, ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy and the non-crystaline amorphous metal skates that manufacture.

It is alloy, Zr-Cu-Ni-Co- that described zirconium-base amorphous alloy includes Zr-Cu- (Ni/Co)-Al+(Nb/Ti/Sn) Al+(Nb/Ti/Sn) is alloy；Described cu-based amorphous alloys include Cu-Ti-Zr- (Ni/Co)+(Sn/Nb) be alloy, Cu-Ti-Zr-Ni-Co+(Sn/Nb) is alloy.

The Vickers hardness of described non-crystaline amorphous metal skates is 400 ~ 600, and yield strength is 1000MPa ~ 3000MPa, elasticity limit Spend for 2% ~ 3%, after standing the salt spray test of 500 hours ~ 2000 hours, its surface is still well corrosion-free.

Described non-crystaline amorphous metal skates include cutter hub, and the front end of described cutter hub is provided with cutter tooth.

For reaching the two of above-mentioned purpose, the present invention is achieved through the following technical solutions.

There is provided a kind of non-crystaline amorphous metal ice skates, described non-crystaline amorphous metal ice skates includes non-crystaline amorphous metal skates described above.

For reaching the three of above-mentioned purpose, the present invention is achieved through the following technical solutions.

A kind of manufacture method of non-crystaline amorphous metal skates is provided, comprises the steps：

Step one, the preparation of skates monnolithic case profile：Under the protection of vacuum state or inert atmosphere, non-using zirconio Peritectic alloy, cu-based amorphous alloys, titanium-based amorphous alloy, the conjunction of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy Ingot prepares the monnolithic case profile of skates by die cast process or double-roller rolling method；

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）Or the repid discharge method of forming（RDF）Right The cutter tooth part of skates carries out molding, obtains non-crystaline amorphous metal skates.

In technique scheme, also include step 3, surface treatment step：The non-crystaline amorphous metal ice that described step 2 is obtained Knife carries out deburring and/or polishing and/or PVD is processed and/or chromium plating process and/or blasting treatment and/or spray treatment And/or wire drawing process and/or cylinder grind and/or magnetic grinding.

In technique scheme, the cutter tooth part of described step 2 molding skates, by thermoplastic shaping method（TPF）To skates Cutter tooth part carry out concretely comprising the following steps of molding：Make the cutter tooth mould of the cutter tooth part of energy molding skates, using the line of induction Circle or cutter tooth mould described in Resistant heating, touch the position of the cutter tooth part wanting molding skates using described cutter tooth mould and incite somebody to action After it is heated to supercooling liquid phase region, using described cutter tooth mould, the position of the cutter tooth part wanting molding skates is applied by pressure and becomes Type is cutter tooth part, then blows to the cutter tooth part of described skates with to described ice using the nitrogen or noble gases of certain pressure The cutter tooth part of knife is cooled down, that is, complete the molding of the cutter tooth part of skates.

In technique scheme, the cutter tooth part of described step 2 molding skates, by the repid discharge method of forming（RDF）Right The cutter tooth part of skates carries out concretely comprising the following steps of molding：Make the electrode of the cutter tooth part of energy molding skates, by described electricity Pole discharges the electric energy of storage in electric capacity, the position of cutter tooth part of molding skates will be heated to vitrification and turn using described electrode Temperature（Tg）With melting temperature（Tm）Between, the then position to the cutter tooth part wanting molding skates using described electrode as drift Put applying pressure, and be shaped to the cutter tooth part of skates, then blow to described ice using the nitrogen or noble gases of certain pressure The cutter tooth part of knife is cooled down with the cutter tooth part to described skates, that is, complete the molding of the cutter tooth part of skates.

In technique scheme, the pressure to the position applying of the cutter tooth part wanting molding skates is 1MPa ~ 30MPa；Profit The nitrogen being 0.1Pa ~ 5Pa with pressure or noble gases blow to the cutter tooth part of described skates with the cutter tooth part to described skates Cooled down.

In technique scheme, being prepared as of described step one skates monnolithic case profile：In vacuum state or indifferent gas Under the protection of atmosphere, closed using zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous alloy, ni-based amorphous alloy, palladio amorphous The alloy pig of gold or Fe-based amorphous alloy prepares the monnolithic case profile of skates by die cast process, comprises the steps：

Step（1）, feed intake：By zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous alloy, ni-based amorphous alloy, palladium The alloy pig of base noncrystal alloy or Fe-based amorphous alloy puts into vertical or horizontal plunger die casting machine feeding device, and is filled by described feed Put and put in the vertical or melting plant of horizontal plunger die casting machine；

Step（2）, melting：Alloy pig in step one is melted and is formed by the mode using sensing heating or resistance heating Molten soup, the temperature of described molten soup is 900 DEG C ~ 1200 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 0.1 m/s ~ 5 m/s；The temperature of skates mould is 200 DEG C ~ 250 DEG C；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10⁰K/s ~10⁶K/s；Cool time is 15 seconds ~ 30 seconds；

Step（5）, product taking-up：Caught after the non-crystaline amorphous metal skates of skates mould ejection again using product withdrawing device It is transported to products export, obtain non-crystaline amorphous metal skates.

In technique scheme, described step（1）In, described vertical or horizontal plunger die casting machine vacuum is 10^-1torr~ 10^-3torr.

Beneficial effects of the present invention：

（1）The present invention provide a kind of non-crystaline amorphous metal skates, due to be using zirconium-base amorphous alloy, cu-based amorphous alloys, Titanium-based amorphous alloy, ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy and the non-crystaline amorphous metal skates that manufacture so that Manufactured non-crystaline amorphous metal skates have high precision, high intensity, high resiliency, high rigidity, scratch resistance, wear-resisting, anticorrosive, toughness Good, lightweight, surface effect is good and the advantage of long service life；Wherein, the Vickers hardness of this non-crystaline amorphous metal skates be 400 ~ 600, yield strength is 1000MPa ~ 3000MPa, and elastic limit is 2% ~ 3%, stands the salt spray test of 500 hours ~ 2000 hours Its surface is still well corrosion-free afterwards.

（2）A kind of manufacture method of non-crystaline amorphous metal skates that the present invention provides, first adopts die cast process or double-roller rolling Method prepares the monnolithic case profile of skates, then passes through thermoplastic shaping method（TPF）Or the repid discharge method of forming（RDF）To skates Cutter tooth part carries out molding, obtains non-crystaline amorphous metal skates；During using ice skates, because the cutter tooth of skates is partly frequent Bear larger impulsive force, therefore, the mechanical property such as the precision of cutter tooth and intensity is quite important；Due to adopting die cast process Or double-roller rolling method prepares in the die casting product of the monnolithic case profile of skates, how much all can there is pore, the depositing of these pores Affect the mechanical properties such as precision and the intensity of skates in meeting, therefore, by thermoplastic shaping method（TPF）Or the repid discharge method of forming （RDF）Molding is carried out to the cutter tooth part of skates, the pore of cutter tooth part can be eliminated, thus greatly improving the essence of cutter tooth part The mechanical property such as density and intensity；And, the manufacture method of this non-crystaline amorphous metal skates has process is simple, production efficiency height and life The advantage producing low cost.

（3）A kind of manufacture method of non-crystaline amorphous metal skates that the present invention provides, is closed using zirconium-base amorphous alloy, cu-base amorphous alloy Gold, titanium-based amorphous alloy, the alloy pig of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy pass through die cast process Or double-roller rolling method prepares the monnolithic case profile of skates, there is the net molding of die casting；And evacuated die-casting process molding or During die cast under inert atmosphere protection, due to zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous alloy, There is not the phase transformation stage that liquid turns solid-state in ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy, therefore, zirconio is non- Peritectic alloy, cu-based amorphous alloys, titanium-based amorphous alloy, the contracting of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy Water rate is very low（Washing shrinkage only 0.17% about）, therefore, it is possible to non-using zirconium-base amorphous alloy, cu-based amorphous alloys, titanio Peritectic alloy, the alloy pig of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy are disposably become by die cast process Type, and substantial amounts of subsequent machining technology can be saved, have and be easy to molding, preparation process is simple, and be applied to extensive The advantage producing.

（4）A kind of manufacture method of non-crystaline amorphous metal skates that the present invention provides, in the protection of vacuum state or inert atmosphere Under, using zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous alloy, ni-based amorphous alloy, palladio non-crystaline amorphous metal or iron-based When the alloy pig of non-crystaline amorphous metal prepares non-crystaline amorphous metal skates by die cast process, in step 3, during soup, directly fall Soup completes, and sprays inert atmosphere to reach the mesh of the molten soup chip of cleaning skates die surface using spray gun to skates die surface Because, during soup it may appear that melt a little soup splash the situation of skates die surface and in skates die surface shape Become molten soup chip, if not being cleaned to the molten soup chip of skates die surface removing, in the matched moulds process of successive process In, these molten soup chips easily crush skates die surface, thus damaging skates mould；The present invention is by using spray gun to skates Die surface sprays inert atmosphere to reach the purpose of the molten soup chip of cleaning skates die surface, thus avoiding molten soup chip folder Hinder skates die surface, thus substantially prolongs the skates mold use life-span.

（5）A kind of manufacture method of non-crystaline amorphous metal skates that the present invention provides, due to non-using zirconium-base amorphous alloy, cuprio Peritectic alloy, titanium-based amorphous alloy, the alloy pig of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy pass through to be cast into Type method when preparing the monnolithic case profile of skates, be carry out under the protection of vacuum state or inert atmosphere such that it is able to Avoid non-crystaline amorphous metal during preparing non-crystaline amorphous metal skates that oxidation reaction or crystallization reaction occur.

Brief description

Fig. 1 is a TTT of the die cast of a kind of non-crystaline amorphous metal skates of the present invention and ice skates and its manufacture method Figure.

Fig. 2 is a kind of non-crystaline amorphous metal skates of the present invention and the thermoplastic shaping of ice skates and its manufacture method（TPF）? Two TTT figures.

Fig. 3 is a kind of non-crystaline amorphous metal skates of the present invention and the repid discharge molding of ice skates and its manufacture method（RDF） The 3rd TTT figure.

Fig. 1 to Fig. 3 includes：

1 crystalline areas,

2 non-crystallization regions,

3 temperatur-timel curves,

Tg glass transition temperature,

Tl melt temperature,

T_xCrystallization temperature.

Specific embodiment

In order that technical problem solved by the invention, technical scheme and beneficial effect become more apparent, below in conjunction with Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only in order to explain The present invention, is not intended to limit the present invention.

Wherein, the inert atmosphere that the present invention refers to is one of nitrogen, helium, neon, argon, Krypton or xenon.

Wherein, the present invention measures the standard test that Vickers hardness is according to ASTM E92-82；The salt spray test of the present invention It is the standard test according to ASTM B117-2011.

Wherein, the die cast process of the present invention, on the basis of a TTT figure, makes temperatur-timel curve not touch first The crystallization region of TTT in figure.

Wherein, the thermoplastic shaping of the present invention（TPF）Process, on the basis of the 2nd TTT figure, makes temperatur-timel curve not touch Crystallization region to the 2nd TTT in figure.

Wherein, the repid discharge method of forming of the present invention（RDF）Process, on the basis of the 3rd TTT figure, makes temperatur-timel curve Do not touch the crystallization region of the 3rd TTT in figure.

Wherein, the vacuum of the vertical or horizontal plunger die casting machine that the present invention refers to is 10^-1torr~10^-3torr.

Wherein, the present invention passes through thermoplastic shaping method（TPF）Or the repid discharge method of forming（RDF）The cutter tooth part of skates is entered During row molding, the pressure to the position applying of the cutter tooth part wanting molding skates is 1MPa ~ 30MPa；Using pressure it is The nitrogen of 0.1Pa ~ 5Pa or noble gases blow to described skates cutter tooth part carried out with the cutter tooth part to described skates cold But.

Embodiment 1.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 530, and yield strength is 1400MPa, Elastic limit is 2%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 2000 hours is still well corrosion-free.

The manufacture method of above-mentioned non-crystaline amorphous metal skates, comprises the steps：

Step one, the preparation of skates monnolithic case profile：It is 10 in vacuum^-1Under the protection of the vacuum state of torr,

Alloy pig using Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy prepares the whole of skates by die cast process Body appearance profile, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；The vacuum of vertical die-casting machine is 10^-1torr；This In embodiment, Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Ni metal, Al metal and Ab metal, and Zr metal, Cu metal, the purity of Ni metal, Al metal and Ab metal are more than 99.9%.

Step（2）, melting：Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 900 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 0.1 m/s；The temperature of skates mould is 200 DEG C；Wherein, in the process of falling soup In, spray argon to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10⁰K/s；Cool time is 30 seconds；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 2mm；

Wherein, step（3）In skates mould be multi-point mould mould.

Wherein, step（5）Afterwards, also include step（6）, by step（5）The non-crystaline amorphous metal skates obtaining carry out cutting casting Mouth and overfall.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, heat point of a knife mould, profit using induction coil Touch the position of the cutter tooth part wanting molding skates with point of a knife mould and be heated to behind supercooling liquid phase region, using point of a knife mould The position of the cutter tooth part wanting molding skates is applied by the pressure of 15MPa and is shaped to the cutter tooth part of skates, then using pressure The cutter tooth part that the nitrogen for 3Pa for the power blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth portion of skates The molding dividing, obtains non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out cylinder grinding and polishing.Wherein, polishing Process for mirror finish.

Embodiment 2.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Zr-Cu-Ni-Al-Ti system zirconium-base amorphous alloy Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 400, and yield strength is 1800MPa, Elastic limit is 3%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 1000 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of helium, using Zr-Cu-Ni-Al-Ti system zirconio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Ni-Al-Ti system zirconium-base amorphous alloy alloy pig is put into the feed of horizontal plunger die casting machine Device, and put into by feeding device in the melting plant of horizontal plunger die casting machine；In the present embodiment, horizontal plunger die casting machine is filled with helium and enters Row protection；In the present embodiment, Zr-Cu-Ni-Al-Ti system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Ni metal, Al metal and Ti metal, and Zr metal, Cu metal, the purity of Ni metal, Al metal and Ti metal are more than 99.9%.

Step（2）, melting：Zr-Cu-Ni-Al-Ti system zirconium-base amorphous alloy alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 950 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 0.5 m/s；The temperature of skates mould is 210 DEG C；Wherein, in the process of falling soup In, spray nitrogen to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10¹K/s；Cool time is 28 seconds；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 5mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, using Resistant heating point of a knife mould, utilize After point of a knife mould touches the position of cutter tooth part wanting molding skates and is heated to supercooling liquid phase region, using point of a knife mould pair Want the position of the cutter tooth part of molding skates to apply the pressure of 30MPa and be shaped to the cutter tooth part of skates, then utilize pressure The cutter tooth part that helium for 5Pa blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth part of skates Molding, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out wire drawing process.

Embodiment 3.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Zr-Cu-Co-Al-Nb system zirconium-base amorphous alloy Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 600, and yield strength is 2000MPa, Elastic limit is 2.5%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 2000 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of neon, using Zr-Cu-Co-Al-Nb system zirconio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Co-Al-Nb system zirconium-base amorphous alloy alloy pig is put into the feed of horizontal plunger die casting machine Device, and put into by feeding device in the melting plant of horizontal plunger die casting machine；In this enforcement, horizontal plunger die casting machine is filled with neon to be carried out Protection；In the present embodiment, Zr-Cu-Co-Al-Nb system zirconium-base amorphous alloy alloy pig includes Zr metal, Cu metal, Co metal, Al Metal and Nb metal, and Zr metal, Cu metal, the purity of Co metal, Al metal and Nb metal are more than 99.9%.

Step（2）, melting：Zr-Cu-Co-Al-Nb system zirconium-base amorphous alloy alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 1000 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 5 m/s；The temperature of skates mould is 250 DEG C；Wherein, in the process of falling soup In, spray helium to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10⁶K/s；Cool time is 15 seconds；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 0.2mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 1MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the neon for 0.1Pa is blowed to the cutter tooth part of skates and is entered with the cutter tooth part to skates Row cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out PVD process.

Embodiment 4.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Zr-Cu-Co-Al-Ti system zirconium-base amorphous alloy Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 500, and yield strength is 2300MPa, Elastic limit is 2.2%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 1500 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of argon, using Zr-Cu-Co-Al-Ti system zirconio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Co-Al-Ti system zirconium-base amorphous alloy alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with argon and enters Row protection；In the present embodiment, Zr-Cu-Co-Al-Ti system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Co metal, Al metal and Ti metal, and Zr metal, Cu metal, the purity of Co metal, Al metal and Ti metal are more than 99.9%.

Step（2）, melting：Zr-Cu-Co-Al-Ti system zirconium-base amorphous alloy alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 1100 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 2 m/s；The temperature of skates mould is 230 DEG C；Wherein, in the process of falling soup In, spray neon to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10⁵K/s；Cool time is 17 seconds；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 3mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 5MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the argon for 4Pa is blowed to the cutter tooth part of skates and is carried out with the cutter tooth part to skates Cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained first are carried out wire drawing process, then carry out PVD process.

Embodiment 5.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Zr-Cu-Co-Al-Sn system zirconium-base amorphous alloy Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 580, and yield strength is 1200MPa, Elastic limit is 2.7%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 800 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of nitrogen, using Zr-Cu-Co-Al-Sn system zirconio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Co-Al-Sn system zirconium-base amorphous alloy alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with nitrogen and enters Row protection；In the present embodiment, Zr-Cu-Co-Al-Sn system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Co metal, Al metal and Sn metal, and Zr metal, Cu metal, the purity of Co metal, Al metal and Sn metal are more than 99.9%.

Step（2）, melting：Zr-Cu-Co-Al-Sn system zirconium-base amorphous alloy alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 1200 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 2 m/s；The temperature of skates mould is 230 DEG C；Wherein, in the process of falling soup In, spray Krypton to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 4mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 20MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the Krypton for 1Pa is blowed to the cutter tooth part of skates and is carried out with the cutter tooth part to skates Cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out blasting treatment.

Embodiment 6.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Zr-Cu-Ni-Al-Sn system zirconium-base amorphous alloy Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 430, and yield strength is 2600MPa, Elastic limit is 2.1%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 1700 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of Krypton, using Zr-Cu-Ni-Al-Sn system zirconio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Ni-Al-Sn system zirconium-base amorphous alloy alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with argon and enters Row protection；In the present embodiment, Zr-Cu-Ni-Al-Sn system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Ni metal, Al metal and Sn metal, and Zr metal, Cu metal, the purity of Ni metal, Al metal and Sn metal are more than 99.9%.

Step（2）, melting：Zr-Cu-Ni-Al-Sn system zirconium-base amorphous alloy alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 1150 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 2 m/s；The temperature of skates mould is 230 DEG C；Wherein, in the process of falling soup In, spray xenon to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, using Resistant heating point of a knife mould, utilize After point of a knife mould touches the position of cutter tooth part wanting molding skates and is heated to supercooling liquid phase region, using point of a knife mould pair Want the position of the cutter tooth part of molding skates to apply the pressure of 25MPa and be shaped to the cutter tooth part of skates, then utilize pressure The cutter tooth part that xenon for 2Pa blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth part of skates Molding, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out magnetic grinding, wire drawing process and blasting treatment.

Embodiment 7.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, utilize Zr-Cu-Ni-Co-Al-Nb system zirconium-base amorphous alloy Alloy pig prepare non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 590, and yield strength is 2800MPa, elastic limit is 2.8%, stands the still good no corruption in surface of non-crystaline amorphous metal skates after the salt spray test of 1900 hours Erosion.

Step one, the preparation of skates monnolithic case profile：It is 10 in vacuum^-2Under the protection of the vacuum state of torr, profit Prepare the monnolithic case wheel of skates with the alloy pig of Zr-Cu-Ni-Co-Al-Nb system zirconium-base amorphous alloy by die cast process Exterior feature, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Ni-Co-Al-Nb system zirconium-base amorphous alloy alloy pig is put into vertical die-casting machine Feeding device, and put into by feeding device in the melting plant of vertical die-casting machine；The vacuum of vertical die-casting machine is 10^- ²torr；In the present embodiment, Zr-Cu-Ni-Co-Al-Nb system zirconium-base amorphous alloy alloy pig includes Zr metal, Cu metal, Ni gold Genus, Co metal, Al metal and Nb metal, and Zr metal, Cu metal, Ni metal, Co metal, Al metal and Nb metal purity equal For more than 99.9%.

Step（2）, melting：Using sensing heating mode by Zr-Cu-Ni-Co-Al-Nb system zirconium-base amorphous alloy alloy Ingot melts and is formed molten soup, and the temperature of molten soup is 1180 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 2 m/s；The temperature of skates mould is 230 DEG C；Wherein, in the process of falling soup In, spray argon to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 1mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, heat point of a knife mould, profit using induction coil Touch the position of the cutter tooth part wanting molding skates with point of a knife mould and be heated to behind supercooling liquid phase region, using point of a knife mould The position of the cutter tooth part wanting molding skates is applied by the pressure of 10MPa and is shaped to the cutter tooth part of skates, then using pressure The cutter tooth part that the argon for 0.5Pa for the power blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth of skates Partial molding, obtains non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained are processed by shot blasting.

Embodiment 8.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, utilize Zr-Cu-Ni-Co-Al-Ti system zirconium-base amorphous alloy Alloy pig prepare non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 570, and yield strength is 2900MPa, elastic limit is 2.6%, stands the still good no corruption in surface of non-crystaline amorphous metal skates after the salt spray test of 1100 hours Erosion.

Step one, the preparation of skates monnolithic case profile：Under the protection of argon, using Zr-Cu-Ni-Co-Al-Ti system The alloy pig of zirconium-base amorphous alloy prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Ni-Co-Al-Ti system zirconium-base amorphous alloy alloy pig is put into vertical die-casting machine Feeding device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with argon Gas is protected；In the present embodiment, Zr-Cu-Ni-Co-Al-Ti system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Ni metal, Co metal, Al metal and Ti metal, and Zr metal, Cu metal, Ni metal, Co metal, Al metal and Ti metal is pure Degree is more than 99.9%.

Step（2）, melting：Using sensing heating mode by Zr-Cu-Ni-Co-Al-Ti system zirconium-base amorphous alloy alloy Ingot melts and is formed molten soup, and the temperature of molten soup is 1130 DEG C；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 0.5mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, heat point of a knife mould, profit using induction coil Touch the position of the cutter tooth part wanting molding skates with point of a knife mould and be heated to behind supercooling liquid phase region, using point of a knife mould The position of the cutter tooth part wanting molding skates is applied by the pressure of 3MPa and is shaped to the cutter tooth part of skates, then utilizes pressure The cutter tooth part that argon for 0.8Pa blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth portion of skates The molding dividing, obtains non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out spray treatment, the spray treatment of the present embodiment be into The spray treatment of row anti-fingerprint paint.

Embodiment 9.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, utilize Zr-Cu-Ni-Co-Al-Sn system zirconium-base amorphous alloy Alloy pig prepare non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 480, and yield strength is 1300MPa, elastic limit is 2.4%, stands the still good no corruption in surface of non-crystaline amorphous metal skates after the salt spray test of 700 hours Erosion.

Step one, the preparation of skates monnolithic case profile：Under the protection of argon, using Zr-Cu-Ni-Co-Al-Sn system The alloy pig of zirconium-base amorphous alloy prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Zr-Cu-Ni-Co-Al-Sn system zirconium-base amorphous alloy alloy pig is put into vertical die-casting machine Feeding device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with argon Gas is protected；In the present embodiment, Zr-Cu-Ni-Co-Al-Sn system zirconium-base amorphous alloy alloy pig include Zr metal, Cu metal, Ni metal, Co metal, Al metal and Sn metal, and Zr metal, Cu metal, Ni metal, Co metal, Al metal and Sn metal is pure Degree is more than 99.9%.

Step（2）, melting：Using sensing heating mode by Zr-Cu-Ni-Co-Al-Sn system zirconium-base amorphous alloy alloy Ingot melts and is formed molten soup, and the temperature of molten soup is 1160 DEG C；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 2.5mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, heat point of a knife mould, profit using induction coil Touch the position of the cutter tooth part wanting molding skates with point of a knife mould and be heated to behind supercooling liquid phase region, using point of a knife mould The position of the cutter tooth part wanting molding skates is applied by the pressure of 8MPa and is shaped to the cutter tooth part of skates, then utilizes pressure The cutter tooth part that argon for 1.5Pa blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth portion of skates The molding dividing, obtains non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained first carry out magnetic grinding process, then carry out PVD process.

Embodiment 10.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 550, and yield strength is 2200MPa, Elastic limit is 2.3%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 2000 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of xenon, using Cu-Ti-Zr-Ni-Sn system cuprio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with Krypton and enters Row protection；In the present embodiment, Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys alloy pig include Cu metal, Ti metal, Zr metal, Ni metal and Sn metal, and Cu metal, Ti metal, the purity of Zr metal, Ni metal and Sn metal are more than 99.9%.

Step（2）, melting：Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 1050 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 4 m/s；The temperature of skates mould is 220 DEG C；Wherein, in the process of falling soup In, spray argon to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10⁴K/s；Cool time is 20 seconds；

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, heat point of a knife mould, profit using induction coil Touch the position of the cutter tooth part wanting molding skates with point of a knife mould and be heated to behind supercooling liquid phase region, using point of a knife mould The position of the cutter tooth part wanting molding skates is applied by the pressure of 27MPa and is shaped to the cutter tooth part of skates, then using pressure The cutter tooth part that the argon for 3.5Pa for the power blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth of skates Partial molding, obtains non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained first carry out blasting treatment, then carry out spray treatment.

Embodiment 11.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Cu-Ti-Zr-Ni-Nb system cu-based amorphous alloys Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 550, and yield strength is 2600MPa, Elastic limit is 2.1%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 1500 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of xenon, using Cu-Ti-Zr-Ni-Nb system cuprio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Cu-Ti-Zr-Ni-Nb system cu-based amorphous alloys alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with Krypton and enters Row protection；In the present embodiment, Cu-Ti-Zr-Ni-Nb system cu-based amorphous alloys alloy pig include Cu metal, Ti metal, Zr metal, Ni metal and Sn metal, and Cu metal, Ti metal, the purity of Zr metal, Ni metal and Nb metal are more than 99.9%.

Step（2）, melting：Cu-Ti-Zr-Ni-Nb system cu-based amorphous alloys alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 1050 DEG C；

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）The cutter tooth part of skates is become Type, concretely comprises the following steps：Make the point of a knife mould of the cutter tooth part of energy molding skates, heat point of a knife mould, profit using induction coil Touch the position of the cutter tooth part wanting molding skates with point of a knife mould and be heated to behind supercooling liquid phase region, using point of a knife mould The position of the cutter tooth part wanting molding skates is applied by the pressure of 12MPa and is shaped to the cutter tooth part of skates, then using pressure The cutter tooth part that the argon for 4.5Pa for the power blows to skates is cooled down with the cutter tooth part to skates, that is, complete the cutter tooth of skates Partial molding, obtains non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out deburring process.

Embodiment 12.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Cu-Ti-Zr-Co-Sn system cu-based amorphous alloys Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 450, and yield strength is 2800MPa, Elastic limit is 2.2%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 1700 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of xenon, using Cu-Ti-Zr-Co-Sn system cuprio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Cu-Ti-Zr-Co-Sn system cu-based amorphous alloys alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with xenon and enters Row protection；In the present embodiment, Cu-Ti-Zr-Co-Sn system cu-based amorphous alloys alloy pig include Cu metal, Ti metal, Zr metal, Co metal and Sn metal, and Cu metal, Ti metal, the purity of Zr metal, Co metal and Sn metal are more than 99.9%.

Step（2）, melting：Cu-Ti-Zr-Co-Sn system cu-based amorphous alloys alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 980 DEG C；

Step（3）, soup：The molten soup that step 2 is obtained is poured in skates die gate casing, then with drift by molten soup In injection skates mould；Wherein, the speed of drift is 3 m/s；The temperature of skates mould is 240 DEG C；Wherein, in the process of falling soup In, spray argon to reach the purpose of the molten soup chip of cleaning skates die surface using spray gun to skates die surface；

Step（4）, cooling：Cooling shaping is carried out to the skates mould being filled with molten soup in step 3, obtains non-crystaline amorphous metal Skates, rate of cooling is 10³K/s；Cool time is 22 seconds；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 4.5mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 18MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the neon for 2.7Pa is blowed to the cutter tooth part of skates and is entered with the cutter tooth part to skates Row cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out chromium plating process.

Embodiment 13.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, using Cu-Ti-Zr-Co-Nb system cu-based amorphous alloys Alloy pig prepares non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 450, and yield strength is 1600MPa, Elastic limit is 2.5%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 1300 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of xenon, using Cu-Ti-Zr-Co-Nb system cuprio The alloy pig of non-crystaline amorphous metal prepares the monnolithic case profile of skates by die cast process, specifically includes following steps：

Step（1）, feed intake：Cu-Ti-Zr-Co-Nb system cu-based amorphous alloys alloy pig is put into the feed of vertical die-casting machine Device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, vertical die-casting machine is filled with xenon and enters Row protection；In the present embodiment, Cu-Ti-Zr-Co-Nb system cu-based amorphous alloys alloy pig include Cu metal, Ti metal, Zr metal, Co metal and Sn metal, and Cu metal, Ti metal, the purity of Zr metal, Co metal and Nb metal are more than 99.9%.

Step（2）, melting：Cu-Ti-Zr-Co-Nb system cu-based amorphous alloys alloy pig is melted by the mode using sensing heating Melt and formed molten soup, the temperature of molten soup is 980 DEG C；

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 3MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the neon for 1.7Pa is blowed to the cutter tooth part of skates and is entered with the cutter tooth part to skates Row cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained first carry out magnetic grinding, then are processed by shot blasting.

Embodiment 14.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, utilize Cu-Ti-Zr-Ni-Co-Sn system cu-based amorphous alloys Alloy pig prepare non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 560, and yield strength is 1900MPa, elastic limit is 2%, and the surface standing non-crystaline amorphous metal skates after the salt spray test of 500 hours is still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：It is 10 in vacuum^-3Under the protection of the vacuum state of torr,

Alloy pig using Cu-Ti-Zr-Ni-Co-Sn system cu-based amorphous alloys prepares skates by die cast process Monnolithic case profile, specifically includes following steps：

Step（1）, feed intake：Cu-Ti-Zr-Ni-Co-Sn system cu-based amorphous alloys alloy pig is put into vertical die-casting machine Feeding device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, the vacuum of vertical die-casting machine Spend for 10^-3torr；In the present embodiment, Cu-Ti-Zr-Ni-Co-Sn system cu-based amorphous alloys alloy pig includes Cu metal, Ti gold Genus, Zr metal, Ni metal, Co metal and Sn metal, and Cu metal, Ti metal, Zr metal, Ni metal, Co metal and Sn metal Purity be more than 99.9%.

Step（2）, melting：Using sensing heating mode by Cu-Ti-Zr-Ni-Co-Sn system cu-based amorphous alloys alloy Ingot melts and is formed molten soup, and the temperature of molten soup is 970 DEG C；

Step（5）, product taking-up：Using product withdrawing device catch by after the non-crystaline amorphous metal skates of skates mould ejection again It is transported to products export, obtain the monnolithic case profile of non-crystaline amorphous metal skates.Wherein, in the present embodiment, the monnolithic case of skates The thickness of profile is 2.8mm.

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 22MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the neon for 3.7Pa is blowed to the cutter tooth part of skates and is entered with the cutter tooth part to skates Row cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained first carry out cylinder grinding, then are processed by shot blasting.

Embodiment 15.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, utilize Cu-Ti-Zr-Ni-Co-Nb system cu-based amorphous alloys Alloy pig prepare non-crystaline amorphous metal skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 560, and yield strength is 1700MPa, elastic limit is 2.9%, stands the still good no corruption in surface of non-crystaline amorphous metal skates after the salt spray test of 900 hours Erosion.

Alloy pig using Cu-Ti-Zr-Ni-Co-Nb system cu-based amorphous alloys prepares skates by die cast process Monnolithic case profile, specifically includes following steps：

Step（1）, feed intake：Cu-Ti-Zr-Ni-Co-Nb system cu-based amorphous alloys alloy pig is put into vertical die-casting machine Feeding device, and put into by feeding device in the melting plant of vertical die-casting machine；In the present embodiment, the vacuum of vertical die-casting machine Spend for 10^-3torr；In the present embodiment, Cu-Ti-Zr-Ni-Co-Nb system cu-based amorphous alloys alloy pig includes Cu metal, Ti gold Genus, Zr metal, Ni metal, Co metal and Sn metal, and Cu metal, Ti metal, Zr metal, Ni metal, Co metal and Sn metal Purity be more than 99.9%.

Step（2）, melting：Using sensing heating mode by Cu-Ti-Zr-Ni-Co-Nb system cu-based amorphous alloys alloy Ingot melts and is formed molten soup, and the temperature of molten soup is 970 DEG C；

Wherein, step（3）In skates mould be multi-point mould mould.

Step 2, the cutter tooth part of molding skates：By the repid discharge method of forming（RDF）The cutter tooth part of skates is carried out The concretely comprising the following steps of molding：Make can molding skates cutter tooth part electrode, by electrode discharge electric capacity in storage electricity Can, the position of cutter tooth part of molding skates will be heated to glass transition temperature using electrode（Tg）With melting temperature（Tm） Between, then using electrode as drift, the position of the cutter tooth part wanting molding skates is applied with the pressure of 5MPa, and is shaped to ice The cutter tooth part of knife, then using pressure, the neon for 3.7Pa is blowed to the cutter tooth part of skates and is entered with the cutter tooth part to skates Row cooling, that is, complete the molding of the cutter tooth part of skates, obtain non-crystaline amorphous metal skates.

Embodiment 16.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, prepare amorphous using the alloy pig of titanium-based amorphous alloy close Golden skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 490, and yield strength is 2100MPa, and elastic limit is 2.9%, Corrosion resistance be stand non-crystaline amorphous metal skates after the salt spray test of 900 hours surface still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：It is 10 in vacuum^-3Under the protection of the vacuum state of torr, profit Prepare the monnolithic case profile of skates with the alloy pig of titanium-based amorphous alloy by double-roller rolling method；

Embodiment 17.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, prepare amorphous using the alloy pig of ni-based amorphous alloy close Golden skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 560, and yield strength is 1700MPa, and elastic limit is 2.9%, Corrosion resistance be stand non-crystaline amorphous metal skates after the salt spray test of 900 hours surface still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：It is 10 in vacuum^-2Under the protection of the vacuum state of torr, profit Prepare the monnolithic case profile of skates with the alloy pig of titanium-based amorphous alloy by double-roller rolling method；

Step 3, the non-crystaline amorphous metal skates that step 2 is obtained carry out mirror finish and process.

Embodiment 18.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, prepare amorphous using the alloy pig of Fe-based amorphous alloy close Golden skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 560, and yield strength is 1700MPa, and elastic limit is 2.2%, Corrosion resistance be stand non-crystaline amorphous metal skates after the salt spray test of 900 hours surface still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：It is 10 in vacuum^-1Under the protection of the vacuum state of torr, profit Prepare the monnolithic case profile of skates with the alloy pig of titanium-based amorphous alloy by double-roller rolling method；

Embodiment 19.

A kind of non-crystaline amorphous metal skates of the present embodiment, specifically, prepare amorphous using the alloy pig of palladio non-crystaline amorphous metal close Golden skates.The Vickers hardness of prepared non-crystaline amorphous metal skates is 560, and yield strength is 1700MPa, and elastic limit is 2.9%, Corrosion resistance be stand non-crystaline amorphous metal skates after the salt spray test of 900 hours surface still well corrosion-free.

Step one, the preparation of skates monnolithic case profile：Under the protection of argon, using the alloy pig of titanium-based amorphous alloy Prepare the monnolithic case profile of skates by double-roller rolling method；

Embodiment 20.

Ice skates prepared by the Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy skates of the present embodiment embodiment 1.

Embodiment 21.

Ice skates prepared by the Zr-Cu-Ni-Al-Ti system zirconium-base amorphous alloy skates of the present embodiment embodiment 2.

Embodiment 22.

Ice skates prepared by the Zr-Cu-Co-Al-Nb system zirconium-base amorphous alloy skates of the present embodiment embodiment 3.

Embodiment 23.

Ice skates prepared by the Zr-Cu-Co-Al-Ti system zirconium-base amorphous alloy skates of the present embodiment embodiment 4.

Embodiment 24.

Ice skates prepared by the Zr-Cu-Co-Al-Sn system zirconium-base amorphous alloy skates of the present embodiment embodiment 5.

Embodiment 25.

Ice skates prepared by the Zr-Cu-Ni-Al-Sn system zirconium-base amorphous alloy skates of the present embodiment embodiment 6.

Embodiment 26.

Ice skates prepared by the Zr-Cu-Ni-Co-Al-Nb system zirconium-base amorphous alloy skates of the present embodiment embodiment 7.

Embodiment 27.

Ice skates prepared by the Zr-Cu-Ni-Co-Al-Ti system zirconium-base amorphous alloy skates of the present embodiment embodiment 8.

Embodiment 28.

Ice skates prepared by the Zr-Cu-Ni-Co-Al-Sn system zirconium-base amorphous alloy skates of the present embodiment embodiment 9.

Embodiment 29.

Ice skates prepared by the Cu-Ti-Zr-Ni-Sn system zirconium-base amorphous alloy skates of the present embodiment embodiment 10.

Embodiment 30.

Ice skates prepared by the Cu-Ti-Zr-Ni-Nb system cu-based amorphous alloys skates of the present embodiment embodiment 11.

Embodiment 31.

Ice skates prepared by the Cu-Ti-Zr-Co-Sn system cu-based amorphous alloys skates of the present embodiment embodiment 12.

Embodiment 32.

Ice skates prepared by the Cu-Ti-Zr-Co-Nb system cu-based amorphous alloys skates of the present embodiment embodiment 13.

Embodiment 33.

Ice skates prepared by the Cu-Ti-Zr-Ni-Co-Sn system cu-based amorphous alloys skates of the present embodiment embodiment 14.

Embodiment 34.

Ice skates prepared by the Cu-Ti-Zr-Ni-Co-Nb system cu-based amorphous alloys skates of the present embodiment embodiment 15.

Embodiment 35.

Ice skates prepared by the titanium-based amorphous alloy skates of the present embodiment embodiment 16.

Embodiment 36.

Ice skates prepared by the ni-based amorphous alloy skates of the present embodiment embodiment 17.

Embodiment 37.

Ice skates prepared by the Fe-based amorphous alloy skates of the present embodiment embodiment 18.

Embodiment 38.

Ice skates prepared by the palladio non-crystaline amorphous metal skates of the present embodiment embodiment 20.

Performance test contrast experiment

The skates of Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy preparation will be utilized in embodiment 1, utilize in embodiment 10 The ice prepared using rustless steel (SUS304) in the skates of Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys preparation, with prior art Knife, using carbon steel preparation skates, using coated high speed steel preparation skates carry out performance test comparison experiment, the property tested Vickers hardness, yield strength, elastic limit, corrosion resistance can be included（Salt spray test）, scratch resistance, wearability and fineness, The experimental data tested is shown in Table 1.

The performance test correction data table of the skates of 1 five kinds of materials of table

Shown according to the experimental data of table 1, in embodiment 1, utilize the zirconium-base amorphous alloy preparation of Zr-Cu-Ni-Al-Nb system Skates, embodiment 10 utilizes the skates of Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys preparation, utilizes with respect in prior art Skates prepared by rustless steel (SUS304), the skates using carbon steel preparation, using coated high speed steel preparation skates, be respectively provided with more Plus excellent Vickers hardness, yield strength, the performance of elastic limit, anticorrosive, scratch resistance, wearability, toughness and fineness.Separately Outward, the non-crystaline amorphous metal skates of other embodiments preparation, with respect to the skates prepared using rustless steel (SUS304) in prior art, The skates prepared using carbon steel, the skates prepared using coated high speed steel, are also respectively provided with more excellent Vickers hardness, subdue by force Degree, the performance of elastic limit, anticorrosive, scratch resistance, wearability, toughness and fineness.

Wherein, in the project of above-mentioned performance test, anticorrosive（Salt spray test）Detailed Experimental result as shown in table 2.

The salt spray test tables of data of the skates of 2 five kinds of materials of table

From the test data of table 2, in embodiment 1, utilize the ice of Zr-Cu-Ni-Al-Nb system zirconium-base amorphous alloy preparation Knife, embodiment 10 utilizes the skates of Cu-Ti-Zr-Ni-Sn system cu-based amorphous alloys preparation, utilizes not with respect in prior art Become rusty steel (SUS304) skates prepared, the skates utilizing carbon steel preparation, the skates prepared using coated high speed steel, has more preferable Corrosion resistance.

Finally it should be noted that above example is merely to illustrate technical scheme rather than the present invention is protected The restriction of scope, although being explained in detail to the present invention with reference to preferred embodiment, those of ordinary skill in the art should manage Solution, technical scheme can be modified or equivalent, without deviating from technical solution of the present invention essence and Scope.

Claims

1. a kind of manufacture method of non-crystaline amorphous metal skates it is characterised in that：Described skates are non-using zirconium-base amorphous alloy, cuprio Peritectic alloy, titanium-based amorphous alloy, ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy and the non-crystaline amorphous metal ice that manufactures Knife；

The manufacture method of described non-crystaline amorphous metal skates comprises the steps：

Step one, the preparation of skates monnolithic case profile：Under the protection of vacuum state or inert atmosphere, using zirconium-base amorphous conjunction Gold, cu-based amorphous alloys, titanium-based amorphous alloy, the alloy pig of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy Prepare the monnolithic case profile of skates by die cast process or double-roller rolling method；

Step 2, the cutter tooth part of molding skates：By thermoplastic shaping method（TPF）Or the repid discharge method of forming（RDF）To skates Cutter tooth part carry out molding, obtain non-crystaline amorphous metal skates.

2. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Described zirconium-base amorphous conjunction Gold include Zr-Cu- (Ni/Co)-Al+(Nb/Ti/Sn) be alloy, Zr-Cu-Ni-Co-Al+(Nb/Ti/Sn) be alloy； It is alloy, Cu-Ti-Zr-Ni-Co+(Sn/Nb) that described cu-based amorphous alloys include Cu-Ti-Zr- (Ni/Co)+(Sn/Nb) It is alloy.

3. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Described non-crystaline amorphous metal ice The Vickers hardness of knife be 400 ~ 600, yield strength be 1000MPa ~ 3000MPa, elastic limit be 2% ~ 3%, stand 500 hours ~ After the salt spray test of 2000 hours, its surface is still well corrosion-free.

4. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Described non-crystaline amorphous metal ice Knife includes cutter hub, and the front end of described cutter hub is provided with cutter tooth.

5. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Also include step 3, Surface treatment step：The non-crystaline amorphous metal skates that described step 2 obtains are carried out at deburring and/or polishing and/or PVD Reason and/or chromium plating process and/or blasting treatment and/or spray treatment and/or wire drawing process and/or cylinder grinding and/or magnetic force Grind.

6. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Described step 2 molding The cutter tooth part of skates, by thermoplastic shaping method（TPF）Concretely comprising the following steps of molding is carried out to the cutter tooth part of skates：Make energy The cutter tooth mould of the cutter tooth part of molding skates, using cutter tooth mould described in induction coil or Resistant heating, using described knife After tooth mould touches the position of cutter tooth part wanting molding skates and is heated to supercooling liquid phase region, using described cutter tooth mould Pressure is applied to the position of the cutter tooth part wanting molding skates and is shaped to cutter tooth part, then utilize certain pressure nitrogen or The cutter tooth part that noble gases blow to described skates is cooled down with the cutter tooth part to described skates, that is, complete the cutter tooth of skates Partial molding.

7. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Described step 2 molding The cutter tooth part of skates, by the repid discharge method of forming（RDF）Concretely comprising the following steps of molding is carried out to the cutter tooth part of skates：System Make the electrode of the cutter tooth part of energy molding skates, discharge the electric energy of storage in electric capacity by described electrode, will using described electrode The position wanting the cutter tooth part of molding skates is heated to glass transition temperature（Tg）With melting temperature（Tm）Between, then with institute State electrode and as drift the position of the cutter tooth part wanting molding skates is applied with pressure, and be shaped to the cutter tooth part of skates, so Entered with the cutter tooth part to described skates using the cutter tooth part that the nitrogen of certain pressure or noble gases blow to described skates afterwards Row cooling, that is, complete the molding of the cutter tooth part of skates.

8. a kind of non-crystaline amorphous metal skates according to claim 1 manufacture method it is characterised in that：Described step one skates Being prepared as of monnolithic case profile：Under the protection of vacuum state or inert atmosphere, closed using zirconium-base amorphous alloy, cu-base amorphous alloy Gold, titanium-based amorphous alloy, the alloy pig of ni-based amorphous alloy, palladio non-crystaline amorphous metal or Fe-based amorphous alloy pass through die cast process Prepare the monnolithic case profile of skates, comprise the steps：

Step（1）, feed intake：Will be non-to zirconium-base amorphous alloy, cu-based amorphous alloys, titanium-based amorphous alloy, ni-based amorphous alloy, palladio The alloy pig of peritectic alloy or Fe-based amorphous alloy puts into vertical or horizontal plunger die casting machine feeding device, and is thrown by described feeding device Enter in the vertical or melting plant of horizontal plunger die casting machine；

Step（2）, melting：Alloy pig in step one is melted and is formed molten by the mode using sensing heating or resistance heating Soup, the temperature of described molten soup is 900 DEG C ~ 1200 DEG C；

Step（3）, soup：By step（2）The molten soup obtaining is poured in skates die gate casing, is then injected molten soup with drift In skates mould；Wherein, the speed of drift is 0.1 m/s ~ 5 m/s；The temperature of skates mould is 200 DEG C ~ 250 DEG C；

Step（4）, cooling：To step（3）In be filled with the skates mould of molten soup and carry out cooling shaping, obtain non-crystaline amorphous metal ice Knife, rate of cooling is 10⁰K/s ~10⁶K/s；Cool time is 15 seconds ~ 30 seconds；

Step（5）, product taking-up：Caught using product withdrawing device and convey again after the non-crystaline amorphous metal skates of skates mould ejection To products export, obtain non-crystaline amorphous metal skates.

9. a kind of non-crystaline amorphous metal ice skates it is characterised in that：It is any one that described non-crystaline amorphous metal ice skates includes claim 1 to 8 A kind of non-crystaline amorphous metal skates manufactured by manufacture method of the non-crystaline amorphous metal skates described in.